Search Documents

By E. Fiset, T. Hennebel, F. Verbruggen, A. Prévoteau, K. Rabaey

Arsenic (As), bismuth (Bi) and antimony (Sb) are known to affect the quality of copper deposits in copper electrowinning operations. The codeposition of As was previously believed to occur only at current densities far exceeding the range of typical current densities for copper electrowinning. In this study, we investigate the copper electrodeposition on different pretreated stainless steel (SS) substrates from bleed electrolyte in galvanostatic mode at –45 mA/cm². Scanning electron microscopy (SEM) micrographs illustrate that during the initial phases of copper nucleation and growth, the current density was locally increased due to the pretreatments. It was reasoned that the codepostion of As could possibly occur in normal electrowinning conditions, but the risk can be substantially reduced by good SS substrate handling and maintenance practices. INTRODUCTION The presence of As, Bi and Sb is known to have a deleterious effect on the copper cathode quality in copper electrowinnings (Hiskey & Maeda, 2003; Hoffmann, 2004; Xiao, Cao, Shen, & Volinsky, 2012; Xiao, Cao, Mao, Shen, & Ren, 2014; Jafari et al., 2017). They are known to influence both the chemical and physical quality of the copper as they can contaminate the copper (Jafari et al., 2017) and affect the copper deposit structure (Hiskey & Maeda, 2003; Kim, Kim, & Chung, 2009), which contributes to a degraded market value of the copper (Tuddenham, 1984). The incorporation mechanisms of these impurities are believed to occur mainly through slime inclusion (F. Xiao et al, 2012) and electrolyte inclusion (Hiskey & Maeda, 2003). Other studies suggested that codeposition of these impurities is possible by their standard reduction potential being close to the one of copper (Xiao et al, 2014). Hiskey and Maeda (2003) investigated the copper electrodeposition on a copper electrode substrate in Cu electrolytes with a Cu, H2SO4, As, Bi, Sb composition representative for commercial copper tankhouses. The combination of voltammographic techniques and Auger electron spectroscopy showed that As was the first impurity to be electrodeposited from this electrolyte, yet at potentials where the limiting current density of the copper electrodeposition reaction is exceeded. The copper tankhouses usually operate at a current density ratio of 0.3 to the limiting current density in order to achieve tolerable copper quality deposits. The codeposition of As could be considered impossible in this current density condition. However, it is known that during the initial phases of electrodeposition on foreign substrates, a substantial part of the reaction proceeds by growth of individual nuclei where the current density is locally high and diffusion limited (Radisic, Ross, & Searson, 2006). Furthermore, it was observed that copper nucleation on TiO substrates occurred preferentially in the scratched oxide free areas which could serve as parts with high localized current densities (Chang, Choe, & Lee, 2005).

Jan 1, 2019

By J. M. Ortiz, J. Haas, W. Kracht, G. Pamparana

This work explores the effect of ore hardness variability on the design of a solar photovoltaic system with battery storage and grid backup, to operate a semi-autogenous grinding mill (SAG). First, a case of two synthetic ore populations was studied, without any consideration of spatial distribution. The mean and variance of the ore hardness (measured in specific energy consumption) of both populations were subjected to a sensitivity analysis. The operation was evaluated with one and two stockpiles. The latter allows classifying according to ore hardness to adapt the SAG energy consumption to the solar cycle. The results show that using two stockpiles allows achieving a larger autonomy (i.e., fewer energy imports) at lower total costs, especially when the difference of mean hardness between the two populations is large. The difference in variance (between the two populations) has a smaller impact on the design recommendations. Second, a case study was performed considering the spatial distribution of geometallurgical units. Two cases were considered: (a) brownfield, when there is historical information of the actual variability of the ore hardness; and (b) greenfield, when the system design relies mainly on geometallurgical modeling. Brownfield and greenfield planning result in similar sizing recommendations of the solar power plant if precise drill cores are available. In this case, geometallurgical modeling is an effective tool for forecasting the energy demand necessary for designing the power plant. INTRODUCTION Solar energy can help make mining more sustainable (Moreno-Leiva et al., 2017). With falling battery costs, an autonomous solar supply is soon to become an economical alternative in many parts of the world, even in the presence of a larger power grid (Child et al., 2017). Although this, places with high solar radiation such as the Atacama Desert in Chile, nowadays show a large potential of incorporating solar energy as a supply of energy. Many of the Chilean copper mines are in this zone making it interesting to study their compatibility and potential of integrating this renewable source to their operation. The power demand in a copper mineral processing plant is determined by the main power loads in grinding and flotation, with grinding typically the largest power consumer, especially the semi-autogenous grinding (SAG) mills (Wei and Craig, 2009). In Chile, it corresponds on average the 50% of the electrical energy consumption (COCHILCO, 2013). Solar energy production is determined by the irradiance perceived into the solar photovoltaic (PV) panels (which varies through the geographic location) and several other climatic parameters such as the current season, humidity, temperature, altitude, and others (Molina et al., 2017). Also, solar energy is only generated during the sun hours, getting to a maximum generation at a certain peak hour during midday, and finally dropping to zero during the night. This shows a cyclic parabolic profile as shown in Figure 1. Due to the SAG mill operated continuously, the power supply always must be available. During the night, to continue supplying the energy, it is necessary to complement the solar power generation with a battery energy storage system (BESS), which will act as a power backup and a buffer. For the optimal sizing of this PV- BESS system, information of the demand profile is needed (Pamparana et al., 2017). In the case of the SAG mill operation, the resulting demand relates to the ore-hardness for a specific throughput and grind size (Morrell, 2004). Therefore, for a given throughput and target grind size, a harder ore would require more power, and variable hardness results in more variable demand and a subsequent need for larger energy storage (Bueno et al., 2015). Due to the ore-hardness variability and the operation of the mill, the power demand profile in inherently variable.

Jan 1, 2019

By Rob Kelso

The PISCES Goals ? To conduct research and develop programs to enable and promote planetary surface exploration ? To host international tests and technology demonstrations at the PISCES Test Site. ? To promote STEM education, inspiring students by connecting Hawaiian culture to space exploration and settlement. - economic and workforce development ? To involve the commercial sector, spinning off technologies to help the local Hawaiian economy. ? To develop a full-scale, technically valid, analog lunar/Martian outpost on Hawai`i Island.

May 1, 2013

By James R. Kuipers

Center for Science in Public Participation CSP2 ? Organized in 1997 to provide technical assistance to public interest groups on mining and water quality issues ? 80%of effort devoted to direct support of grassroots groups and tribal governments ? 20% of effort devoted to public-oriented education for public, tribal, state and federal regulators, and for industry ? Board represented by public interest groups, at large citizens, and academia ? Professional staff with experience from mining industry, academia and government ? website: www.csp2.org CSP2 Mission Statement The CENTER for SCIENCE in PUBLIC PARTICIPATION provides training and technical advice to grassroots groups on water pollution and natural resource development issues, especially those related to mining. CSP2 seeks to focus the debate on factual issues, as brought to light by its technical analyses, and whenever possible to seek consensus and win-win solutions. CSP2 also performs policy related work with federal and state regulatory agencies on the implementation of water quality, waste disposal, and mining reclamation regulations.

May 1, 2002

By T. E. Newkirk

In the past few years there has been considerable controversy on the most suitable material to be used in ventilation doors which will have to serve also as fire doors. For this reason it was thought useful at Mclntyre to find out to what extent our zinc chloride treated spruce doors were fire resistant and what protection we could expect in case of an underground fire. The doors to be tested were constructed of the same material as that used in our regular ventilation doors underground, namely, 2-inch tongue-and-groove well seasoned spuce. It is to be noted, however, that whereas the dimensions of the ventilation doors are 5 ft. by 6 ft., those of the test doors were only 14 in. by 17½ in. The treated doors were made up from lumber that l1ad been treated with chromated zinc chloride, as described in Mr. Keeley's paper. Two kinds of tests were carried out: a heat test and a flame test. An electric muffle furnace for assaying, equipped with a pyrometer, was used for the beat test, the furnace door being replaced by the wooden door to be tested. In the flame test, the door to be tested formed one end of a rectangular steel box in which was placed a large blow-torch. Air was admitted at the rear of the box. A pyrometer recorded the temperature at the inside surface of the door where flame impinged. The results of the tests are presented in the accompanying table, in which the word 'failed' is to be interpreted as meaning that the door had been damaged to the extent that smoke, but not necessarily flame, issued from its outside surface.

Jan 1, 1949

By Z. D’Amico

"IntroductionWE HAVE HEARD quite a lot recently on newer methods -of supporting roof, such as roof bolting or the use of metal props and •booms, but, with the exception of roof bolting, these methods are confined mostly to comparatively low, regular seams and even .bolting cannot be used to hold soft sides. Thus, where a seam of coal has great variations in thickness, or where it is faulty, or where the coal sides must be supported, nothing can wholly take the place of timbering with wood. This paper will deal mainly with the method of timbering such a seam, namely, the No. 3 seam mined by Brazeau Collieries, Limited, at Nordegg, Alberta, where the full height of a thick seam is mined in development. However, a few words on one or two other systems practised in Alberta when, in development work, a thick seam is only partially mined, should be of interest.Examples of Timbering in High SeamsThere .are several methods in use today for dealing with high seams of coal. The most popular is to develop the seam by driving road-ways in the coal by some conventional method, usually recovering the full thickness of the seam on the retreat. The following examples illustrate two variations of this method.In Figure I we have a thick •seam of friable coal, with a good roof, pitching about 30 degrees, which is being mined by taking the upper part of the seam in the development work, leaving the •bench coal in place. Figure 1A shows a section through a room."

Jan 1, 1954

By H. M. Roscoe

Fifty per cent. increased lump coal production and at the same time a reduction of from 20 to 40 per cent. in explosive consumption. These results were achieved by the use of the rock-dust cartridge method of stemming shots in the Ruhr coal mines, as announced by Dr. Alfred Stettbacher in the September 1923 number of the Explosive Engineer. Immediately, the explosive and the coal-mining industries on this continent became intensely interested. Considerable experimental work has been carried on in a number of American and Canadian mines during the past year, by which our engineers have become assured that the use of rock-dust cart-ridges for stemming shots increases the efficiency of explosives and promotes safety in coal mines.

Jan 1, 1924

By Nancy C. Mohn

?Even though the age of many existing coal units exceeds 30 years, these units continue to perform with excellent reliability and at a competitive cost with other fossil fuel units. ?NERC data shows a consistent increase in availability for all utility coal generation ?With the opening of power markets, the challenge for coal is to produce competitive electricity while meeting increasingly stringent, and costly environmental limits. ?During the 60s and 70s, subcritical steam power plants dominated the market. The emphasis was on scale-up to larger MW size units. ?In the last decade, we have seen interest in a broader set of technologies with new drivers: ?Fluidized bed technology was developed to respond to increased environmental requirements, particularly with lower quality fuels ?Supercritical pressure units have gained interest for both fuel cost savings and reduced emissions due to higher efficiency.

May 1, 2001

By Ernest A. Hodgson

WHEN excavations are made, at depth, in hard brittle rock structures, as in certain mines in India, in South Africa, and in Ontario, the pressure due to overburden, together perhaps with inherent geologic strain, tends to become concentrated in the walls of some of these openings and the rock bursts, often closing the adjacent drifts and scopes and presenting a serious menace to the miners. Where the rock is much fractured and faulted, the danger is greater, since the pressures tend to shift without warning from point to point, sometimes within a few hours. Attempts have been repeatedly made to find some physical property of the rock which will change with pressure, which can be measured for rock 'in place' in the mine, and which will give an indication of the state of strain, thus warning of an approach to bursting conditions. Some of the properties tested have been the speed of propagation of elastic waves in the suspect rock, variations in temperature due to pressure changes, rate of closure of openings or shifts along fault planes, strain gauge measures, and others. Each of these has proved unsatisfactory for the purpose. The most promising method so far proposed has been the study of the very faint, sub-audible snaps (microseismims) which are produced in rocks under pressure. Such a study has been in progress at Lake Shore Mines since May, 1942. Instruments designed to pick up, amplify, and record the microseismims were perfected and a programme of observing, using the microseismic method, has been carried through with persistent diligence and at considerable expense. In 1943, experience with the method in a pillar section on the west side of the Lake Shore mine gave much promise of predicting bursts. A very heavy burst on January 29th of that year occurred in the exact section of the mine covered by the instruments, and the records indicated a measure of prediction. In response to repeated requests for information, a number of reports were given out, among others a radio talk by the writer over CJKL (Kirkland Lake), which was reported in full in the Northern News . Also, a detailed account of the occurrence was given in an illustrated paper by the writer (l).

Jan 1, 1945

By J. E. Gill, A. R. Byers

The Surf and Pugsley gold-copper mines; owned and operated by Surf Inlet Consolidated Gold Mines; Limited; are about 6 miles inland from; the head of Surf inlet; on Princess Royal island; Skeena mining division; British Columbia. Surf inlet is a fiord 360 miles in an air line northwest of; Vancouver.

Jan 1, 1954

By J F. Short

The jet piercing process, developed by Union Carbide Canada Ltd., is well established in blasthole production in open-pit mining. By this process, holes can be drilled, shaped and chambered for blasting. In suitable ore or rock formations, a considerable cost reduction can be achieved. This paper reviews the equipment used, relates how cost savings may be accomplished, and concludes with a mention of the most recent developments in this field. JET piercing and chambering, a process for blasthole production in open-pit mining, leads, in many instances, to improved drilling and blasting techniques and costs. It is a method of working rock with a supersonic flame and, to be most effective, depends upon a characteristic of the rock called spallability. Spalling, in this case, is the breaking away of surface particles from the rock body due to stresses caused by the thermal shock of the jet flame. Various rock properties contribute to this action, but, in general, the harder the rock the greater the spallability and the more effective and economical is the jet process. The jet process has the capability to drill, ream, shape and chamber holes for blasting.

Jan 1, 1965

By C. Hu

A MOS capacitor hydrogen sensor array is reported for hydrogen gas distribution mapping. Si(100) was used as substrate for film deposition. After silicon oxide growing on the silicon surface with dry thermal oxidation, palladium film was sputtered on silicon oxide as hydrogen-sensitive gate material in MOS structure. The 3x3 sensor array was patterned on silicon substrate and packaged in one chip. Sensors' response was test with impedance analyzer. The sensors in array were calibrated in the hydrogen concentration range from 10ppm to 10000ppm. The 2D hydrogen concentration distribution was obtained with the calibrated sensor array.

Jan 1, 2005

By D. Murray

A 2-hectare uranium tailings area has been reclaimed. The exposed tailings of 1.4 hectares were capped with glacial till and vegetated with grasses and legumes. The water running through the tailings was diverted around the tailings in a line ditch and treated with sodium hydroxide and barium chloride. Difficulties occurred in placing the till capping because of the low bearing strength and the uneven surface of the tailings. This led to varying thicknesses of till and the need for manual labour in some areas. Total reclamation costs were $32,200, with vegetation establishment costs at $13,700 per hectare. This report provides a record of work for use in assessing the long-term suitability of these treatments.

Jan 1, 1979

By Hans Lundberg

During the last few years, geophysical methods have been introduced to aid mining geologists and mining engineers in locating mineral deposits. These methods have been developed as the result of investigations of various physical characters of minerals and rocks. In prospecting for ore-bodies, electrical methods have proved most successful. These methods are based on the great differences in electrical properties, and especially in conductivity, between ore minerals and rock minerals. The electrical resistance of the common minerals, rocks, and ores in ohms per cubic céntimeter is given in the following table: [ ] The first attempts at electrical prospecting were based on observing currents of polarization around certain ore bodies, which currents it was possible to measure. This method has been developed by Prof. Schlumberger and has been utilized by him successfully. He is represented on this continent by Mr. Sherwin Kelly, who has successfully operated the method here.

Jan 1, 1926

By Ronald C. Schimmel

In 2006, the Corus IJmuiden pellet plant produced approximately 4.6 mln tonnes of pellets. Corus IJmuiden is about to increase its pig iron production to 6.4 mln tonne HM per annum. The burden of the Corus IJmuiden blast furnaces consists of approximately 50% high basicity sinter and 50% acid pellets, both produced in-house. To enable an increased iron production, the capacity of the pellet plant needs to be raised to 5.0 mln tonne per annum. The capacity is increased by modifications to the plant layout, which were implemented during the 2006 cold maintenance stop. In addition, the composition of the ore blends is optimised to gain productivity.

May 1, 2007

By L. G. Smith, C. A. Shook, W. H. W. Husband, W. Schriek

"The flow of slurries in pipelines is governed by many variables, and the study of the influence of each of these variables is difficult, if not impossible, in some cases. Many correlations are available which fit data within a given range. However, no one method is yet available to design a slurry pipeline for all desired conditions without at least some physical measurements on the slurry itself. For this reason, the slurry pipeline facilities at the Saskatchewan Research Council have been developed during the past 12 years and it is hoped that the development will continue until the process is thoroughly understood and test facilities are no longer necessary. This paper outlines methods currently used and under development at the Saskatchewan Research Council for measurement, control and study of the variables governing the flow of slurries."

Jan 1, 1973

By H. Fujihara, K. Uesugi, H. Toda, A. Takeuchi, K. Shimizu

"Hydrogen is trapped at a variety of microstructures, for example grain boundaries, dislocations and particles. It is thought that hydrogen trapped at trapping sites is redistributed to the other sites under loading and then brittle fracture occurs with hydrogen accumulation. In order to understand hydrogen embrittlement behavior, it is necessary to investigate the time evolution behavior of hydrogen accumulation at each trap site. In the present study, changes in hydrogen distribution are observed under stress using Kelvin force microscopy (KFM) that can visualize hydrogen concentration distribution on material surface at high resolution. Spot-like hydrogen enriched regions are observed on the surface of a material. In addition, hydrogen depleted regions are observed around those enriched regions, and the appearance of hydrogen trap due to particles existing near the material surface is revealed. On the other hand, hydrogen trapped at grain boundary can be visualized. From in this result, it was suggested that crystallographic factors influence hydrogen accumulation. The relationship between initiation and propagation of intergranular crack and hydrogen accumulation under stress will be discussed.INTRODUCTIONHydrogen present in a metal sometimes has significant effects on various properties. Hydrogen in a metal is trapped at a variety of microstructure, for example dislocations and grain boundaries. Grain boundaries, dislocations and micro pores are the major trap sites in aluminum alloys. Some researchers considered that hydrogen redistribution and accumulation between these trap sites in a material with loading plays an important role in the brittle fracture behavior. In general, in intergranular fracture and quasi-cleavage fracture, the hydrogen trapped at grain boundaries and dislocations contributes to fracture behavior, respectively. Recently some researchers have shown that the ductile fracture in aluminum alloys is resulted from growth and coalescence of hydrogen micro pores. Analysis using first principles calculation indicates that intergranular fracture occurs when hydrogen concentration reaches 20 atom H/nm2ongrain boundary. From this report, it is considered that hydrogen redistributed during deformation accumulates locally in order to cause hydrogen brittle fracture. In order to understand hydrogen embrittlement, it is necessary to investigate the time evolution behavior of hydrogen accumulation at each trap site. In the present study, we evaluate the relationship between hydrogen accumulation behavior and fracture behavior in Al-Zn-Mg based alloys. In-situ observation was made by combining the tensile test with Kelvin force microscope (KFM) that can visualize the hydrogen concentration distribution on the material surface with high resolution. We also investigate the relationship between hydrogen distribution behavior and crystal orientation."

Jan 1, 2018

By John R. Morgan, Peter Graham

"Onakawana Development Ltd. and Mana/ta Coal Ltd. have completed feasibility studies on a large lignite deposit located in the James Bay lowlands of northeastern Ontario. The mining plan described in this paper would supply coal for approximately a 33-year period with peak production in the early years of approximately 6.5 million tonnes per year then declining to 1.2 million tonnes in year 33. This paper describes the geology, resources, lignite quality, mine planning and related topics. LocationThe Onakawana lignite deposit is located in northeastern Ontario in the James Bay lowlands (Fig. l). The Ontario Northland Railway crosses the property and links it to Moosonee, JOO km further north, and Cochrane 180 km south. The area is crossed by latitude 50° 37', the approximate latitude of Calgary. Toronto lies 800 km south of the study area. History of Development The deposit has been known since the late 1600s when early English settlers extracted limited amounts of lignite for use at Moose Factory. The deposit has undergone sporadic periods of exploration activity in the late 1920s and early 1930s when the Ontario government drilled 116 holes, sunk two exploration shafts and published several technical and economic studies. Interest in the property was reactivated from 1939 to 1945 when the Timiskaming and Northern Ontario Railway Ltd. drilled 182 additional closely spaced holes, excavated a test pit adjacent to the rail line and installed a boiler for testing purposes. In 1965, Alberta Coal Ltd., the predecessor of Manalta Coal Ltd., first became involved. Since then a further 182 holes have been drilled and coied, and the existing test pit reopened for sampling. In 1980, various reassessment studies were launched, including geology, mine engineering, conceptual design and environmental assessment studies. The following discussions have been drawn extensively from these reports."

Jan 1, 1985

By Roger V. Pierce

"WITHOUT mineral wealth, modern man would not exist. True, man could survive on a stone-age basis with an average life expectancy of, say, 25 to 30 years -once he got past infancy.However, no metal would tip his arrow in a hunt for protein; no steel plough would break the soil for the organized planting of seed; and no coal, nor oil, nor natural gas nor uranium fuels would pro-vide him with light or beat or safety from either beasts, or other men, or an unkind nature that threatened him and his family.Modern agriculture, fishing and forestry represent the other three wealth-producing industries. With-out metals, non-metallics and energy minerals, however, it would be impossible to fit any of these to man's modern needs."

Jan 1, 1967

By A. M. Bell

"Hallnor mine is in the township of Whitney, Porcupine district. To date, its production of gold has been second largest in the east Porcupine field. Ore was discovered in the property in 1936 by diamond drilling in overburdened country. This drilling was undertaken by Noranda Mines following the discovery of ore in conglomerate at Pamour 1 mile to the east.Milling commenced at the Hallnor in June 1938, and to the end of 1945 432,000 oz. gold had been produced from 889,000 tons of ore, giving an average recovery of 0.49 oz. a ton.The West mine of Pamour, the Broulan orebody, and the veins on the Hallnor and Bonetal are all parts of a mile long vein system that has been separated into three sections by cross faulting. In consequence, they could well have been described in one paper. In treating them individually the viewpoint obtained from each may lead to conflicting opinions, and any conclusions advanced in this paper on the general structure should be modified by the conclusions advanced in papers on the neighbouring properties.GENERAL GEOLOGYRock FormationsThe Hallnor orebodies occur within 400 feet of the contact between lavas and sediments, and may lie in either lavas or sediments. The lavas near the ore consist of flows of pillowed andesite and one flow of more acid and less sheared and chloritized lava locally named trachyte. These flows strike east-west and dip steeply. At the surface on the east side of the property the volcanics have been intensely altered to a massive carbonate rock having a north-south thickness in excess of 1,000 feet . This carbonate body extends west across the property with a plunge of 45° (Fig. 1)."

Jan 1, 1954