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By Kazutoshi Haga, Batnasan Altansukh, Atsushi Shibayama, Ryuji Oinuma

"Recently, the arsenic grade in copper ores has been increasing year by year. Arsenic bearing minerals (enargite (Cu3AsS4) and tennantite (Cu12As4S13)) coexist with typical copper minerals such as chalcopyrite (CuFeS2). The removal of arsenic from copper ores that contain relatively high arsenic content is essential due to its adverse impact on the environment and the resulting economic consequences. In this study, arsenic removal and dissolution behaviour of Cu and As from enargite (Cu3AsS4) were investigated using ferric sulphate (Fe2(SO4)3) solutions containing sodium chloride under high pressure oxidation conditions. The effects of numerous parameters including the concentration of Fe2(SO4)3 and NaCl, temperature, total pressure, leaching time and particle size were studied while other variables such as pulp density and stirring speed were fixed at 100 g/L and 750 rpm. The results showed that more than 60% of the copper was dissolved in a 0.1 M ferric sulphate solution under the high pressure oxidative conditions, whereas the leaching rate of arsenic was less than 20%. SEM observation revealed that elemental sulphur was deposited on the surface of enargite forming a passivation layer and the residue was agglomerated. Those phenomena may cause a decrease in the copper leaching rate. It was found that more than 80% of copper was dissolved in the ferric sulphate solution in the presence of 0.34 M sodium chloride under the conditions optimized, whereas the dissolution of arsenic in the mixture did not exceed 2%. XRD analysis of the solid residues from the leaching experiments used ferric sulphate and mixtures of ferric sulphate and sodium chloride showed arsenic to be present as scorodite (FeAsO4).INTRODUCTION In recent years, there has been an increase of the arsenic (As) content of copper ores due to the gradual depletion of high grade copper ores. In some copper deposits, arsenic occurs in the form of minerals such as enargite and tennantite. The removal of arsenic in ores containing copper is critical to the production of pure copper and the management of the environmental challenges caused by the smelting process. Due to the environmental risk caused by arsenic emission and the deteriorated quality of the copper product, smelting of enargite concentrates is not an effective method for the extraction of copper (Padilla et al., 2010; Safarzadeh et al., 2014; Long et al., 2012). Therefore, a number of studies have been carried out to develop arsenic removal technologies from copper ores using various methods such as hydrometallurgy (Curreli et al., 2009; Tongamp et al. 2010), pyrometallurgy (Dalewski., 1999; Padilla. et al, 2012) and bio-oxidation (Ehrlich, 1964; Sasaki et al., 2010). Several hydrometallurgical leaching processes like sulphuric acid, alkaline sodium sulphide and sodium sulphate and ferric sulphate leaching have been developed to treat enargite ores and concentrates. The alkaline sodium sulphide leaching process has been developed for the removal of arsenic from enargite (Anderson, & Twidwell, 2008; Parada et al., 2014). The mechanism of the dissolution of arsenic from enargite in sodium sulphite solution is"

Jan 1, 2016

By M. Niinae, F. Nakahara, T. Kawamoto, T. Suzuki

"MgO was chosen as an As(V) immobilization agent and a series of immobilization experiments was performed to obtain insights into the behavior of As(V)and MgO during leaching tests. Our experimental and modeling results demonstrated that As(V) immobilization by MgO consists of the following steps: (i) an increase in soil pH, (ii) desorption of As(V) from the soil, and (iii) the re-immobilization of As(V) by MgO/Mg(OH)2particles. Regarding the behavior of MgO, the modeling results showed that when the MgO dosage was 25 mg MgO/4g-drysoilor less, the majority of MgO was used to increase pH, and less than 1% of MgO was used to sorb As(V), which was consistent with the result of leaching tests showing that a high level of As(V) was leached at the MgO dosages. On the other hand, when the MgO dosage was above 25 mg MgO/4g-drysoil, the percentage of MgO used for As(V) sorption increased up to 35%, and correspondingly, the As(V) leaching level decreased to below 0.01 mg/L As at an MgO dosage of 75 mg MgO/4g-drysoil.INTRODUCTIONOne of the major arsenictransport pathways causing groundwater contamination is the migration of arsenicfrom artificially or naturally contaminated surface soils. Therefore, in this study, the immobilization of arsenate (As(V)) in soils was investigated using commercial-grade magnesium oxide (MgO) as a potential cost-effective measurement to prevent the occurrence of groundwater contamination with As(V).With respect to the use of MgO for remediating As(V)-contaminated environmental media, MgO has been used in several studies to remove As(V)from water(Yu et al., 2011; Jia et al., 2013; Tresintsi et al., 2014). Although these studies demonstrated that MgO effectively removes As(V)from water in water-MgO systems, the behavior of As(V)in water-soil-MgO systems has not been evaluated in the literature, and several questions remain to be answered to comprehensively evaluate the use of MgO as an As(V)immobilization agent in soils. For instance, as is well-documented in the literature(Ford, 2002; Lenoble et al., 2002; Zeng et al., 2008), iron oxy-hydroxide (FeOOH) is one of the important adsorbents for As(V)in both natural and engineered systems. Therefore, it is anticipated that the presence of FeOOH in soils significantly influences the behavior of As(V)in water-soil-MgO systems and consequently, the immobilization performance by MgO. Another important question to be answered is the behavior of MgO during the immobilization treatment. In our previous studies (Suzuki et al., 2013a, 2013b), commercial-grade MgO was demonstrated to effectively immobilize lead and fluoride, and the immobilization effectiveness was indicated to last more than 100 years against the exposure to acid rain (pH 4.0). However, these studies focused on the behavior of contaminants. As a result, little is known about the behavior of MgO during the immobilization treatment. The lack of understanding of the behavior of MgO during immobilization treatment is one of the main concerns leading to relatively low public confidence in immobilization treatments."

Jan 1, 2016

By Guy Brouillard

A bow-tie analysis is a safety review methodology that uses a structured approach that can be qualitative or quantitative to document the potential risk of safety incidents. The bowtie diagram itself provides a powerful graphical representation of the threats barriers, events, and recovery measures which are readily understood by the "non-specialist". This presentation will discuss how mining operations can use this valuable tool within their operations to understand the risks and apply the appropriate safeguards toward reducing these risks to acceptable levels.

Jan 1, 2014

By N. Plint, D. Philips, J. Sweet, B. Durant

A pilot scale AG milling campaign was conducted at the AngloAmerican Platinum pilot plant in South Africa. Different blends of hard: soft (silicate: chromite) and coarse: fine particles in the AG mill fresh feed were tested. The effects of multi-component feed on the pilot scale autogenous grinding are presented in this paper, and can be used as a guideline for multi-component feed blends for AG mil

Jan 1, 2012

By Lisa J. Renaud

For generations, the mining industry has been committed to work toward developing new technology that can improve safety and increase production. Now with a more environmentally conscious society and tighter environmental regulations, a natural progression for the industry is to develop and take-on ?green? or environmentally friendly technologies. Not only could this improve the sustainability of operations, but could also reduce the long-term environmental impact footprint that is left behind. Algae represent a new frontier in research and development. As discussed specifically in this paper, algae, specifically microalgae, can be used for the production of biodiesel and other green chemicals by exploiting carbon dioxide and waste heat contained within process off-gasses. The potential positive benefits of this approach in terms of contribution to community and the environment are significant, and the focus of our research and development on microalgae production technology.

Oct 1, 2010

By P. E. Georghiou, S. Shafiei Zadeh, H. Hassan Nejad

Data are presented on the extractant behaviour on toxic metal removal from spent hydroprocessing catalyst, produced at the North Atlantic Refinery plant in Newfoundland and Labrador. Aliquat 336 was selected due to its potential capabilities for the separation of cobalt, molybdenum and nickel from the leachate extractant produced by aqua regia. The solvent extraction process was statistically modeled using central composite design (CCD), and the numerical optimization was conducted to achieve the optimum point for toxic metal recovery for the extractant.

Jan 1, 2014

By J. W. Merks

"The accuracy of a measurement on minerals and ores can be assured by applying suitable and unbiased procedures but its precision is a function of the number of primary increments and their mass, the number of lots per consignment or samples per shift, and the number of measurements on analysis fine samples.Experimental data will be used to show how the variance components for sampling, sample preparation and analysis contribute to the total variance on which precision statements for the final measurement are based. This type of experiment should not only form part of quality control programs at mines and smelters, but also underly the criteria on which the design of manual sampling regimes and mechanical sampling systems for bulk solids and slurries should be based.Sampling systems and regimes can only be adjusted and optimized if the variance component for each step in a quality evaluation process is measured. Knowledge of precision characteristics lies at the core of effective loss prevention and control programs."

Jan 1, 1985

By L. Freitag

"The Dollard oil field in southwestern Saskatchewan is a stratigraphic trap of irregular shaped perimeter. The reservoir is a low-angle monoclinal structure with a dip of approximately 100 feet in 5 miles from west to east across the long axis of the reservoir. Production of. 23° API gravity crude is obtained from a Jurassic sand referred to as the J-2-A, at an approximate depth of 4,500 feet. Reservoir studies and fluid analyses revealed that the crude is highly undersaturated, having a solution GOR of approximately 130 cubic feet of gas per barrel, that the reservoir has no definable water table, and that it appears to be of a closed-boundary type. Oil production was marked by a rapid pressure decline and it was soon evident that the greatest ultimate recovery would be best obtained if the natural driving energy of the reservoir were augmented by some artificial energy source. In support of a pressure maintenance programme, studies were conducted on flood-pot recoveries of large-diameter cores, and a potentiometric model study of the field was made. These studies indicated that a successful water flood would be obtained. The Dollard field was unitized in 1955 and pressure maintenance started in March 1956."

Jan 1, 1959

By J. F. Shirley

"Very seldom, if ever, is a molybdenite by-product plant operated exactly the way the process design engineer visualizes it. The best thing the design engineer can do is provide a sound, basic circuit with enough room and flexibility in order that the operating staff can make the necessary modi fi cations to optimize the process. The plant, with minor modifications, should be capable of handling more than one process. This is especially true when the client is having the plant designed for a new process.The writer would like to propose the following ten ""rules-of thumb"" for designing by-product molybdenite plants where the molybdenite is floated out of a copper concentrate. The term rules-of-thumb is used, because there are probably valid reasons for not using one or more of them in a particular plant design. In fact it was 1980 before the writer was all owed to start up a plant where all of these rules were honored in the plant design. This was after 19 years of experience in the design of molybdenite by-product processes and plants. The main reasons for not following the rules are available capital, available space, and the client's experiences based on pilot plant and laboratory test results."

Jan 1, 1981

By K. Adham, C. T. Harris

Arsenic is often associated with copper, nickel and gold in sulphide deposits. This paper describes a two-stage high-temperature fluid bed reactor for the removal and fixation of As from ores and concentrates. The first (bottom) stage of reactor removes the As through a neutral roast, by volatilization as mostly sulphide species. The second (top) stage of reactor captures the As from the gas phase through oxidative fixation, as a stable iron arsenate, by reaction with an appropriate iron source (sulphide or oxide). The second stage is placed on top of the first, so that their combined function can be achieved in a simple two-stage fluid bed arrangement, with the bottom stage off-gas providing the top stage fluidization.

Jan 1, 2014

By Malcolm Scoble

School Values ?? Each other; ?? Students, & helping them develop intellectually, personally & professionally; ?? Freedom to pursue educational & research opportunities; ?? Home-work-life balance; ?? The geographic-business community in which we operate ; ?? The pursuit of excellence; ?? Our contribution to society; ?? Creativity & innovation; ?? Teamwork & collaboration; ?? Career development, achievement & reward.

May 1, 2008

By M. Moghadami

Design and construction of underground openings are associated with many uncertainties with regard to input data. In the construction process of underground openings various levels of risks exist and these affect the safety and profitability of the project. The development of underground openings can be broadly categorized into three major phases of data collection, design, and construction. A significant level of uncertainty is associated with some of the key parameters involved in the aforementioned development phases. Moreover, it is very difficult to evaluate and quantify the effects of uncertainties on the underground project construction process. Additionally, the interactions between important risk elements are typically not well understood. The intention of this study is to develop a general risk model for underground opening projects located in soils and weak rock masses. The goal of the research is to identify and quantify important geotechnical risk elements. Moreover, a weighting procedure will be proposed for the identified risk elements. Finally, all important risk elements will be assembled into a general model with emphasis on geotechnical parameters. The final objective of this study is to apply the proposed model to a real underground project scenario and verify it for actual field conditions. The proposed model, once calibrated properly, will provide a useful support tool for the decision making process.

Aug 1, 2013

By C. Bazin, D. Hodouin, M. Ounpuu

Sensors are now available in mineral processing circuits to monitor pulp flowrate and density, as well as ore characteristics and other process variables. The amount of information provided by these instruments is considerable but in many cases poorly exploited. This paper gives the results of the application of time series analysis techniques to signals generated by the sensors installed on an industrial Pb dezincing flotation circuit in New-Brunswick. Autocorrelation and cross correlation functions appear to be interesting tools for a preliminary circuit analysis, however the calibration of single input single output discrete transfer functions using collected sensors signals leads to conflicting results. For this reason a phenomenological approach, based on the kinetic and transport properties of the flotation process, is also considered. It has several advantages over the empirical transfer function modelling but also limitations in its applicability to industrial processes. A combination of the transfer function and kinetic modelling approches appears to be a promising avenue for better process modelling and control.

Jan 1, 1985

By S. Hussien, P. Somasundaran, P. Patra

"Rare earth elements (REEs) are essential for many applications in electronics, energy harvesting, and defense. The common resources for economic extraction of REEs are oxides such as bastnaesite and monazite, which are scarcely available in the earth’s crust. On the other hand, REEs are available in many clay and phosphate ores where REEs substitute Ca or Si in the mineral lattices or as physically adsorbed cations at negatively charged sites on the clay surface. While REE oxides readily dissolve in acid, making the chemical leaching of REEs an economically viable option, adopting a similar approach for leaching of silicates and phosphate ores is unfeasible because of significantly low REEs content in these ore deposits. Bio-leaching approaches are environmentally benign and economically viable. We investigated the bio-leaching (Acidothiobacillus ferrooxidans (Af) and the fungal Aspergillus niger (An)) of REEs from a phosphate ore, and examined the factors governing the leaching processes. Based on the shake flask leaching studies, an increase in surface area combined with an increase in pulp density (1-15 wt. %) was found to lead to an increase in the amount of REEs leached. In contrast, an increase in the surface area by reducing the particle size from 75 to 35 led to a decrease in the amount of REEs leached. These differing attributes are proposed to be due to the poor bacterial growth/activity with high F- ions in the leaching media, F- released from the edge-sites of the smaller particles. On the other hand, several advantages that associate with the Af bacterial bio-leaching processes relate to the media composition (Mg2+ and (NH4)+) and phenomena occurring at the electrical double layers of the mineral and bacterial- water interfaces. These studies suggested that leaching of particles occur in a layer-by-layer manner.INTRODUCTIONRare Earth Elements (REEs) are essential for many important applications, such as in electronics, energy generation, and defense. The common resources for economic extraction of REEs are typically carbonates such as bastnaesite and monazite, which are scarcely available in the earth’s crust (Y. Kanazawa and M. Kamitani, 2006). REEs are abundantly available in many clay and phosphate ores where REEs substitute Ca or Si of the mineral lattices. Conventional acid leaching of REEs from oxides is not economically feasible for clay and phosphate ores because of significantly low REE content (parts per billion) in these ores (Tian, J., Chi, R., Yin, J., 2010a; Moldoveanu G. A. and Papangelakis V. G., 2013; WK Goyne, LS Brantley and J Chorover, 2010). In some cases, REEs could be extracted from these ores via chemical leaching routes as they constitute reasonable amounts of REEs (0.1 - 1% REEs). A major challenge faced in general in chemical leaching processes (Chi, R., 1988) is the loss of REEs in the phosphate/gypsum precipitates/crystals, which are overcome in a step-by-step manner by sequentially removing impurities such as fluorine and calcium, including steps carried out at elevated temperatures. On the other hand, bio-leaching approaches provide environmentally benign and economical alternatives. Acidophilic bacteria are currently being used for industrial scale bio-leaching of Au/Cu/Ni from low grade ores. Studies on bioleaching of REEs from red mud (Al2O3) using Penicillium tricolor and Aspergilus niger (An), and, of bio-leaching (lab-scale) of phosphate rocks using Acidithiobacillus ferrooxidans (Af) have been reported (Boon, M., Heijnen, J.J., 1993; Qu, Y. and Lian, B., 2013). We conducted bacterial (Af) bio-leaching of REEs from a phosphate ore in shake flasks and columns, while examining the key factors that govern leaching kinetics."

Jan 1, 2016

By Carlos Antônio de Morais, Renata Dias Abreu

The present work describes a study of the separation of terbium and dysprosium from heavy RE concentrate through a solvent extraction circuit in a counter-current system. As the efficiency of the REE extraction by acid extractants rises with the increase of the atomic number of the element, the aim of this work is to extract the elements with higher atomic number maintaining Tb and Dy in the aqueous phase. Thus, terbium was separated first with subsequent separation of dysprosium. The experiments were carried out by using IONQUEST®801 as the extractant and a REE-hydrochloric liquor as feed solution. The optimum operational circuit in terbium separation was comprised of 37 stages: extraction, scrubbing, stripping, and solvent washing. For the dysprosium separation 39 stages were required. Terbium separation over 92% with over 95% purity and a Dy separation over 97% with over 95% purity were obtained.

Jan 1, 2014

By George Dogbe

Open pit optimization forms the basis of mine design, production planning and construction of mine facilities. The negative effects of this phase may include substantial reductions in ore recoveries, relocation of waste dumps and surface infrastructure, extraction of unwanted waste, with a cumulative effect on mine value reductions. As a result, this area has received significant research focus using linear and dynamic programming, heuristic, genetic and stimulation algorithms and the graph theory. These algorithms are derived from rigorous mathematical models, but they are built on the assumption that all the periodic production capacities are extracted at the time of analysis. This assumption weakens the models because mining occurs over significant time period. In order to develop a comprehensive model that accounts for the timing of material extraction, the current models, which are built on the economic block value (EBV) concept, must be modified to account for time. In this paper, the authors develop a model of the optimization problem using the 2-D Lerchs-Grossmann?s optimization algorithm. This model is used to investigate the effect of periodic discounting on the optimal pit layout design by designing an integrated pit optimiser (IPO) that incorporates ?production scheduling?. IPO uses the ensuing discounted economic block value (DEBV) as a basis for the pit optimisation process. The time-dependent model is compared with a time-independent model. The results show that discounting has no effect on the optimal pit contour although the reported pit value is overstated if the EBVs are used instead of the DEBV. The authors, however, believe that this conclusion may not be general and could have been influenced by the nature of ore body geometry and the proposed mining strategy.

May 1, 2004

By J. R. Shore, F. G. M. Gillett, E. J. Zickar

"The addition of fines to rod mill feed has been employed at Inco Metals' Frood-Stobie Mill since 1973. The fines, which act as a ""lubricant"", causes an increase in the pulp fluidity and assists the flow of feed through the rod mill. Fines addition was one of the main factors which led to improved rod mill performance and the elimination of rod mill tangles.This paper outlines the testwork performed in evaluating the addition of fines, and summarizes the beneficial effects on rod mill grinding efficiency, throughput rates, power consumption and noise level. INTRODUCTIONFrood-Stobie Mill is situated within the Frood-Stobie mining complex, on the southern rim of the Sudbury Basin. The Mill commenced operations in November, 1967, and has since processed in excess of sixty-five million tons of ore. Minus 8-inch ore is delivered to the Mill's coarse ore bin by two surface conveyor belts from the Frood and Stobie Mines, while Little Stobie ore is transferred by underground conveyor and hoisted directly into the coarse ore bin a long with additional Stobie Mine ore."

Jan 1, 1981

By L. Sun

In this work, strontium doped lanthanum ferrite (LSF) and their composite cathodes were fabricated by screen printing on yttria-stabilized zirconia (YSZ) electrolytes. Their electrochemical properties were evaluated by using electrochemical impedance spectroscopy and steady-state polarization methods. All the cathodes were screened by comparing their total polarization resistances before and after activation processes at different temperatures. The improved LSF composite cathodes were also screen-printed on YSZ/NiO half cells to fabricate solid oxide fuel cells (SOFCs), which have reached the output power densities of 170 mW/cm2 at 650 °C, 230 mW/cm2 at 700 °C, 304 mW/cm2 at 750 °C and 388 mW/cm2 at 800 °C.

Jan 1, 2005

By Ben Cottrell

In this paper technical drilling is referred to as the process of collecting engineering and metallurgical parameters for subsequent mine design considerations. Throughout the development of a mineral exploration property there are various opportunities to ?piggy-back? technical drilling onto the routine exploration drilling process, helping to reduce future costs and delays associated with re-drilling and missing information. This article is written from the engineers and metallurgists point of view, to outline some best practices for exploration borehole planning and technical data collection requirements.

Aug 1, 2013

By Paivi Suikkanen, Kari Hietala, Kaarlo Haavanlammi

"Processing of high-magnesia concentrates, the recoveries of nickel and copper, as well as those of platinum group metals (PGM’s) and cobalt are key issues of the Nickel Smelting technologies. PGMs are typically found in association with each other, but also importantly with nickel and copper. A challenge of producing saleable concentrates at acceptable recovery degrees, an increasing focus on the sustainable use of metals and recent decreases in the value of nickel has increased the interest to find a reliable route from Cu-Ni-PGM bulk concentrates to product. According to studies, most efficient process for Ni-Cu-PGM concentrates is flash smelting using DON process20 years ago, in 1995, Outokumpu commenced at Harjavalta a new Nickel Flash Smelting technology based on the Direct Outotec Nickel (DON) Smelting Process. The DON process enables production of high-grade nickel matte with low Fe-content directly in the Flash Smelting Furnace (FSF) without subsequent converting. Metal values from the smelting slag are recovered in the Electric Furnace (EF) as iron containing Ni-matte. Matte refining is based on atmospheric pre-leaching and total pressure leaching. Nickel, cobalt and iron are leached leaving a leach residue containing small amount of gangue minerals and PGM’s. Iron is removed from the leach solution in and nickel will be recovered with standard methods. Overall > 95% metal recovery can be expected with low energy consumption and low environmental impact."

Jan 1, 2014