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By Y. M. Shneerson, I. V. Fomenko, M. A. Pleshkov, E. A. Ospanov, A. A. Shakhalov, S. S. Naboychenko

Low-grade copper concentrates (with copper content less than 20%) often contain impurities such as arsenic, zinc, lead, mercury, antimony and bismuth. The pyrometallurgical treatment of such concentrates is associated with several problems, which will ultimately affect the cost and the quality of copper cathodes as well as by-products. SRC Hydrometallurgy proposed a complex hydrometallurgical technology which allows the removal of impurities and the enrichment of low-grade copper concentrates to a quality which will be more suitable for pyrometallurgical processing. Laboratory batch tests and pilot plant results for the pressure leaching steps are shown in this paper. The key parameters of the leaching steps were determined and optimized. The quality of possible by-products were also determined. The developed flowsheet includes two pressure leaching steps: pressure oxidation (POX) and hydrothermal alteration (HTA). Both operations are carried out at 170°C with subsequent flotation of POX and HTA residues and recovery of copper, zinc and lead into separate concentrates for further processing. The development of the flowsheet was based on the Balkhash Zinc Plant (Balkhash, Kazakhstan), which had been non-operational since 2009. The developed flowsheet for processing of low-grade concentrates will utilize 80% of the existing equipment of the Balkhash Zinc Plant, thus leading to a significant reduction in required capital expenditure. INTRODUCTION As the age of copper mining operations advance, copper grades continue to diminish and impurity levels increase. Therefore, copper producers are forced to look for new innovative hydrometallurgical technologies which are able to handle low-grade raw materials and solve problems associated with impurities in an economically justifiable way. New technologies allow to extract valuable components selectively and to process low-grade concentrates which had previously been marked as non-technological and economically unviable. Hydrometallurgical technologies for processing of copper-containing materials can be divided into two main categories: chloride and sulfate (atmospheric, autoclave and bacterial) based technologies. Since the 1970s, many autoclave techniques for the processing of copper-containing materials have been developed and implemented (Naboichenko, 2002; Dreisinger, 2005; Habashi, 2009; Shneerson, 2011). The mineralogical composition of the ore (or concentrates), geographical location of the deposit, distance from industrial areas, availability of existing treatment facilities, availability of skilled labor, cost of electricity and cost of neutralization are some of the factors which are usually considered when the appropriate technology is selected (Halbe, 2002).

Jan 1, 2019

By E. Lehtila, J. J. Talja, R. Jahila

Kopar Oy is acknowledged for engineering and manufacturing of robust systems for bulk material handling, especially at power plants and non-ferrous smelters. We have over thirty years of experience with systems specifically designed for hot and abrasive conditions, aiming at low cost of ownership, low operational expenses and high availability. Although Kopar has numerous applications in mechanical conveying, there is an increasing number of pneumatic conveying applications at copper smelters. They relate to conveying of concentrate, and primary and secondary flue dusts. Challenges of pneumatic conveying for concentrate are mechanical and do relate to broad particle size distribution and high abrasivity of the concentrate and the silica. Therefore, special attention shall be paid to system design and ceramically lined bends in the pipeline. Challenges of pneumatic conveying of primary flue dust relate predominantly to material stickiness and poor flowability which are mainly due to fine particle size and formation of sulphates and furthermore, crystalline water. Additional challenges of secondary dust, the white converter dust, are primarily due to the extremely fine 0.1–1.5 µm particle size and problems which come with this. Effect of material characteristics like size distribution, morphology and chemical composition in pneumatic conveying are discussed in detail. INTRODUCTION Fine materials like concentrate, feed mix, flue dusts (from waste heat boiler and electrostatic precipitator) and secondary dusts need to be conveyed at smelters. Both horizontal and vertical conveying and combination of those are used. For the purpose, both mechanical and pneumatic conveying are applied. Most widely used equipment are drag chain conveyors and various combination of pneumatic systems, e.g. air lift, dense-phase and dilute phase pneumatic conveyors. Kopar has 30 years’ experience with multiple material handling systems. Furthermore, acquired companies like Elmomet Oy and SITE Oy (both currently fully merged and integrated into Kopar Oy) have even longer history, especially in pneumatic conveying. It is commonly known that the finer the dust the more difficult it is to be conveyed pneumatically. Sulfates with crystal water makes it all even more difficult, if not ineligible. Challenges related to pneumatic conveying of various fine materials is discussed in detail in the paper.

Jan 1, 2019

By C. Chongo, L. Little, Q. Mclennan

Since commissioning in 2005, First Quantum Minerals’ Kansanshi Mine in Zambia has produced over three million tons of copper and 1.8 million ounces of gold from a deposit with highly varied copper mineralization. The processing plant is complex with three independent flotation circuits, gold gravity concentration, atmospheric and high pressure leaching, solvent extraction, and electro-winning. For the first ten years of operating the plant, copper mineralogy was inferred from total copper and acid soluble copper assays, and various misconceptions developed about the mineralogy which impacted operational strategy and project decisions. In 2015, an on-site mineralogy section was set up with an Automated Scanning Electron Microscope, the Zeiss MinScan. This instrument has provided detailed mineralogical data that have debunked some of the mineralogy myths that had developed, highlighting the key underlying issues affecting processing performance. This has enabled the development of projects targeting losses of specific copper minerals in defined size classes, unlocking significant value. This paper describes some of the early misconceptions around mineralogy at Kansanshi processing plant, outlining projects that have benefitted from understanding copper mineral distribution. Learnings from Kansanshi are to be applied at other FQM sites, with a similar mineralogy program being set up at the Cobre Panama project. INTRODUCTION The deposit Kansanshi Mine is located in the North Western Province of Zambia, and it has been the largest copper producer in Africa for over a decade. The deposit occurs within a broad northwest trending antiform that can be traced for 12 km, hosted in a zone of complicated faulting, abundant vein injection, breccia development and down-dropped rock units that lies within Kansanshi’s mining license. The copper mineralization within the deposit is predominantly vein-hosted, although some is strata-bound, occurring in thin bands and veinlets parallel to foliation, and some is disseminated associated with albite-carbonate alteration (Gray, 2015). Supergene enrichment has led to significant variety in the copper mineral speciation. This alteration is complex, and has not followed the text-book principles with a neat layer of supergene mineralization overlying fresh hypogene ore. Rather, the occurrence and extent of oxidation and supergene enrichment is highly irregular throughout the deposit, sometimes occurring at significant depth in localized pockets and along fault lines. Gold mineralization tends to follow the copper within the deposit, but it is dominated by coarse-grained, free-milling native gold. The extent of copper oxidation – measured as the fraction of total copper that assays as acid soluble – is used to classify ore into three main ore types, named Sulphide, Mixed, and Oxide, which are then fed to three different primary crushers for processing in independent circuits.

Jan 1, 2019

By V. Itkin

"Three methods were tested for the beneficiation of aluminum scrap, generated by heavy medium separation of non-ferrous automobile scrap residue. These were: crushing in a shredder followed by screening; grinding in a ball miff followed by screening; and eddy current separation. The best results were obtained with the grinding-screening method. IntroductionThe usual method of aluminum alloy reclamation from non-ferrous automobile scrap residue consists of a two-step heavy medium separation to remove materials lighter than and heavier than aluminum. The resulting aluminum scrap still contains over 15% impurities such as stones and glass, heavy rubber, insulated copper wire , plastics and heavy metals entrapped by macerated aluminum piece s, composite fragments, etc.(2). Upon melting, these impurities create difficulties and yield a low ingot recovery-65% to 70%, hence small foundries avoid this material.There are a number of ways to improve the quality of aluminum scrap such as:(1 ) crushing of the scrap, which powders the brittle content , a major impurity component, followed by screening out of the dust(2) eddy current separation , which removes metals from the material flow, and(3) implement better methods for density separation.The eddy current separation and two variants of the comminution-screening technique were studied by Intermetco Ltd., Hamilton , Ontario."

Jan 1, 1986

By Jürgen Antrekowitsch, Gerardo R. F. Alvear Flores, Mehmet Ayhan, Christoph Zschiesche

Synergies between copper and lead extractive metallurgical processes enable the processing of a broad range of polymetallic materials. However, this complexity also brings some challenges expressed in terms of complex intermediates and final products. For instance, based on the limited solubility of Cu and Ni in crude lead bullion additional phases will appear during the crystallization of the melt. Beyond the need for continuous optimization of metallurgy the control of phase solidification is a further important pillar to achieve a more efficient process by minimizing the amount and cycles of reverts. This paper describes the microscopy study of one of the most relevant intermediate in the Cu and Pb metallurgy, the Cu based alloy and highlights the importance of applying a well-controlled cooling sequence to improve the overall process efficiency. INTRODUCTION One of the key aspects in Aurubis’s 2025 vision is to move towards the implementation of a multi metal recovery strategy. The implementation of this new multi metal vision is supported by the long tradition of the company, founded in 1866 as Norddeutsche Affinerie, and further developed by adopting modern copper smelting and lead smelting technologies for the processing of primary and secondary materials. The combination of these assets have already build the basis for processing of complex materials in the copper and lead circuits implemented in Aurubis’s facilities. The addition of a new smelting facility, will enhance these capabilities. Aurubis current flowsheet combines Cu, Pb and Zn metallurgy. This includes primary smelting of copper concentrate, processing of secondaries (residues, slimes, slags) and recycling materials (scrap, shredder material, e-scrap). These broad range of materials contain not only the mentioned base metals but also a number of minor metals that requires to be properly managed to ensure efficient recoveries and quality of the targeted metals.

Jan 1, 2019

By J. P. Harrison, K. Gao

It is well known that in situ stress measurements at a given site will generally display significant variability. However, it appears that a robust analysis of such measurements – i.e., one that is faithful to the tensorial nature of the data – is not available. Despite the fact that stress is a tensor, stress magnitude and orientation have long been analyzed separately using classical statistics. In earlier work we demonstrated the applicability of tensor statistics to the analysis of stress variability. Here, we investigate further the difference between tensor and classical statistics with respect to the stress tensor correlation matrix. Our analysis commences with the selection of a series of valid correlation matrices. Then, assuming that standardized tensor components follow the multivariate standard normal distribution, these correlation matrices are used to generate marginal probability distributions of the eigen-parameters (i.e., principal stress magnitude and rotation angle). From these, random stress tensors are generated, their eigenparameters determined, and the probability density distributions of these obtained using both classical and tensor statistics. Our results indicate that, for all correlation matrices, both methods give practically identical distributions for principal stress magnitude. However, the discrepancy between the two methods with regard to probability density distribution of rotation angle is highly dependent on stress component correlation. This discrepancy is usefully quantified in terms of the integral, with respect to orientation, of the difference between the two probability density distributions. This parameter, which we term Area Difference, is closely linked to the magnitude of the correlation matrix determinant, which itself is related to the normal stress correlation coefficient (i.e., ?x ,?y ??). Assuming that Area Difference should not exceed 0.1, we identify the critical determinant for any particular value of normal stress component correlation coefficient. Thus, using published in situ stress data and the obtained critical determinants, we show that for a specific normal stress component coefficient, when the correlation matrix determinant is less than its critical determinant, the more precise tensor statistics should be used to calculate the distribution of rotation angle. These results demonstrate that the customary analysis of stress measurement data may lead to erroneous results, and that tensor statistics appears to be preferred approach.

Jan 1, 2015

By Andrew Thrift

Overview ? Problem ? Research question ? Literature review ? Methodology ? Results ? Discussion and recommendations ? New developments Problem ? Increasingly higher expectations ? Inadequate consultation leads to conflict rather than collaboration ? Consultation practice is often weak on decision-making ? Influence of consultation on planning is Unclear Research question ? Are Structured Decision Processes (based on decision analysis) an effective methodology for involving stakeholders in consultative decisionmaking in the mining industry?

May 1, 2006

By J. I. Jr. Moore

Many articles have been written about the various operations of Britannia mines and mill, as well as treatises on the geology and ore deposits. A partial list of these papers is given below. Most of these papers have covered well the history of Britannia, and have included a thorough discussion of the geology and ore deposits; therefore, in this paper, no account of these subjects. is necessary. However, a short description of the ore deposits will be given as an aid to a clear understanding of the descriptions of the various mining methods. The Ore Deposits The ore deposits at Britannia occur along a shear zone and are five in number, named for the claims in which they lie, as follows: Jane, Bluff, Fairview, Empress, and Victoria. Each of these deposits is called a mine, as they are separated by 500 to 1,000 feet of barren ground. The Jane mine, although the first producer of the Britannia group, has not been in operation for a number of years. The deposit is a silicified replacement in sediments; with very little evidence of shearing. The Bluff deposit is a highly silicified replacement in porphyry, massive and irregular, very hard in the upper 600 feet with practically no shearing, and softer within chlorite schist in its lower 1,000 feet . The Fairview deposit consists of a series of twelve distinct veins or lodes, rather lenticular in shape, and occasionally merging.

Jan 1, 1928

By D. B. Dreisinger, M. R. Tavakoli

Vanadium has been produced from a variety of sources. This metal is known to make aqueous solutions of complex speciation as a function of vanadium concentration and pH. Considering the method of leaching, the impurities in the PLS and the planned vanadium product, different extractants and flowsheets can be applied for solution purification. In this paper, purification of vanadium leaching solution using organophosphorus, solvating and amine extractants will be reviewed. This review will be focused on vanadium separation from iron, molybdenum and uranium which are often present in vanadium resources including primary ores, fly ashes and spent catalysts.

Jan 1, 2014

By Anthony McDonald, Dominic Verhelst

"Hudson Bay Mining and Smelting Co. Ltd. (HBM&S) started up a zinc plant and smelter in late 1930, employing technology of that period. The zinc plant has since converted from a roast/leach operation to a two stage pressure leach operation to eliminate sulphur dioxide emissioms. The smelter, however, is still continuing with much of the original roaster/reverberatory furnace technology. This paper reviews the process flow of the copper smelter, with some comments on past and recent changes.Smelter FlowsheetPrior to July 1993, the HBM&S smelter operation consisted of seven areas, namely feed preparation, roasters, reverberatory furnace, converters, anode casting, fuming plant, and dust collection. A simplified smelter flowsheet is shown in Figure 1. The data for tonnage of materials moving through the circuit are presented in Tables I to 4, and are representative of the time period from July 1992 to June 1993. A change in the zinc plant technology in 1993 resulted in the elimination of a zinc-bearing sulphide leach residue from the smelter feed blend, thereby greatly reducing the zinc content of slag produced in the smelter. Consequently the fuming plant and ancillary equipment, such as the drying plant, were shut down. These areas will, however, be described. With the closure of the zinc fuming furnaces all the slag from the reverberatory furnace is now discarded to stockpile.The over-all smelter metal recoveries are 96% for Cu and rn.5010 for Au and Ag. Figures 2 and 4 indicate historical production numbers of copper, silver and gold, respectively. A review of the minor element distribution in the smelter can be found elsewhere."

Jan 1, 1994

By Y. Wang

In this paper, the tribological and electrochemical corrosion properties of Al2O3/polymer nanocomposite coatings were studied using a micro-hardness test, a single-pass scratch test, an abrasive-wear test, and finally an electrochemical technique such as potentiodynamic polarization measurement, The coatings containing Al2O3 nanoparticles showed improvement in scratch and abrasive resistance compared with polymer coatings; this improvement is attributed to the dispersion hardening of Al2O3 nanoparticles in polymer coatings, Corrosion test results showed that the embedded Al2O3 nanoparticles in the polymer matrix do not sacrifice the corrosion resistance of the polymer itself.

Jan 1, 2005

By D. Mark Richards

Highland Valley Copper is a large open pit copper mine in the southern interior of British Columbia. Machine guidance technology using the Global Positioning System (GPS), was first implemented at the mine in late 1996 for blast hole drill navigation. The purchase of a third BE49R drill in 1998 completed the change to GPS navigation for all the mine?s drilling. The acceptance of this technology was almost immediate at both the operator and management levels. With the purchase of a new P&H 2800 shovel in 1997, the opportunity was taken to extend GPS navigation to a shovel. Due to communication restrictions, this was not as successful as envisaged. In late 1999, following a cost benefit analysis, a three-shovel trial of Caterpillar?s Computer Aided Earthmoving System (CAES), was initiated. The trial was successfully concluded in June 2000 and a further two shovels were equipped. Acceptance of this system has been very good at all levels, which has undoubtedly contributed to its success. In September 2000, CAES was extended to the dozer fleet with the purchase of a new track dozer. The CAES equipped dozer is used for pit production and project work. It is planned to extend CAES to the rest of the shovel fleet in 2001, along with a production front-end loader and one or two more track dozers.

May 1, 2001

By Wengui Su, Qi Zhang, Junce Wang, Zhijun Ma, Xingyuan Weng

"Mesoporous materials with large specific surface area, pore size, and pore volume have been widely used in many fields such as ion exchange, gas separation, adsorption, and catalysis. Mesoporous materials prepared using natural zeolite have the advantages of both acid and alkali resistance. In this work, mesoporous materials were prepared using natural zeolite as the starting material and diethylenetriamine (DETA) as a template. The resulting samples were characterized using scanning electron microscopy (SEM), X-ray diffraction (XRD) and N2 adsorption-desorption experiments. The influence of the crystallization temperature and crystallization time on the specific surface area, pore volume, pore size, and morphology of the resulting mesoporous materials are also discussed. Our results show that for an increase in both the crystallization temperature and time, the average pore size first increases then decreases, while the specific surface area first decreases then increases. Based on this work, we concluded that the optimal crystallization temperature was 2003 and the optimal crystallization time was 60 h. These conditions gave an average pore size of 17.93 nm, a pore volume of 0.048 cm3g-1, and a specific surface area of 16.48 m2g-1.INTRODUCTIONMesoporous zeolite, as the name implies, is a highly porous crystalline zeolite. This material is of interest due to its high hydrothermal stability, its adsorption and diffusion properties for macromolecules, and its excellent selectivity and activity as a catalyst. In recent years, it has become a hot spot among research of porous catalytic materials and has been widely used in petroleum and natural gas processing, fine chemical processing, various adsorption and separation tasks, and other uses (Carvalho & Urquieta- Gonzalez, 2015; Teh, Triwahyono, Jalil, Mukti, Aziz, & Shishido, 2015)."

Jan 1, 2016

By J. H. Rickard, D. H. Watkinson

"Abstract - Detailed petrographic and quantitative (electron microprobe, SEM-EDS) mineralchemical analyses of sulfide ore from the 100 orebody at the Copper Cliff North mine, Copper Cliff, Ontario, reveal numerous stages of ore development. Sharp contacts between weakly mineralized quartz diorite and blebby to massive sulfides indicate multiple intrusive events within the Copper Cliff offset dike. A spatial association of sulfides and hydrous minerals, such as amphibole, biotite, chlorite and epidote, suggests that most primary ore has been affected by later hydrothermal fluids. Sulfides are often enclosed or bordered by these secondary silicate phases. The ore consists primarily of pyrrhotite, pentlandite, chalcopyrite, with trace michenerite, cobaltite/gersdorffite, irarsite, hessite, tsumoite, and bismuth tellurides.Geological and petrological comparison of the 100 orebody and the adjacent 900 and 890 orebodies has revealed distinct similarities in ore distribution. Data show that the 100 orebody is depleted in platinum-group elements (PGE) relative to the 900 orebody. Platinum-group elements from the 100 orebody may have been hydrothermally remobilized and partly emplaced in the 900 orebody, in adjacent veins, or in magmatic breccia. Analysis of Cu, Ni, and PGE assay data of ore samples has characterized their distribution among the eight different ore textures in the orebody. There is a strong association between Pt and interstitial sulfide, and to a lesser extent massive sulfide, but little correlation between chalcopyrite-rich ore and PGE in the 100 orebody, unlike many other deposits in the Sudbury region."

Jan 1, 2001

The total current inventory of mature fine tailings is estimated to be nearly 850 million m³. Pressure has come to bear on the industry to accelerate its tailings management practices and prevent this inventory from steadily growing. The present paper describes the treatment, management and reclamation of fluid fine tailings. New technologies being evaluated include: i) Thin layered - fines dominated deposits, ii) Deep - fines dominated deposits, iii) Fines enriched sand deposits, and finally iv) water capped disposal in end pit lakes. A brief overview for each of the methods of treatment and disposal for fluid fine tailings is provided.

Aug 1, 2013

By Arthur Brant

STEEPROCK LAKE (Figure 1) lies about two miles north of Atikokan, a village approximately one hundred and forty miles west of Fort William and one hundred miles east of Fort Frances on the Canadian National railway. The possible presence of hematite beneath the waters of Middle arm was inferred by early geological investigators (1890-1903) from the dense hematite float found on the southerly shores of this portion of the lake (1). A dip-needle survey of Middle arm, undertaken in the winter of 1930-31 by J. G. Cross, indicated two areas of high magnetic attraction which Mr. Cross thought might be due to magnetic iron oxides associated with possible hematite bodies. Bedrock could not be reached by the ineffectual hand-drilling so courageously attempted, and further work was abandoned. It was not until 1937 that Mr. Jos. Errington, of Toronto, convinced of the possibilities, determined to support Mr. Cross to the extent of several thousand feet of drilling. During the winter of 1937-38, holes Nos. 1, 3, 4, 5, and 13 were put down (see Figure 1). The first four of these holes demonstrated that the areas of magnetic attraction outlined by the dip-needle survey east of the Narrows and southwest of Elbow point were due to ash rock (2). As a result, Mr. Cross decided to investigate the bordering areas of low magnetic attraction and selected a location near the high ferruginous lime (3) point in the northeast of Middle arm. Dense, hard hematite beneath approximately 350 feet of water and clay was struck in the first hole, and, before the end of the winter's drilling, hematite had been encountered in holes Nos. 6 to 13 along a straight line 700 feet in length (see Figure 1). In the meantime, the Steerola ( 4) Exploration Company had been formed to continue development and already, in the spring of 1938, W. D. Neeland, the Company geologist, had come to the conclusion that the most probable location for possible hematite was at the ash-lime contact. Accordingly, during the summer, drilling was continued off-shore in holes Nos. 15, 25, and 27 (see Figure 2) toward possible hematite bodies inferred by Mr. Neeland.

Jan 1, 1940

By A. Yousefpour, M. Hojjati, G. Chouinard

In recent years, high performance thermoplastic composites such as PEEK and PEKK have been developed for aerospace applications. These materials offer, among the other properties, high toughness and damage tolerances. These are semi-crystalline materials and their processing can lead to different crystallinity that in turn have some impact on the final properties. The effect of cooling rate on degree of crystallinity of PEEK is studied to identify the processing window for manufacturing. Samples were heated at the constant heating rate of 20°C/min up to 375°C (above melting point) and held for 10 minute. The enthalpy of the crystallization was measured at different constant cooling rates of 0.5, 1, 2, 5, 10, 20, 30, and 40°C/min. After cooling, the samples were heated at constant heating rate of 2°C/min using modulated DSC. At temperature between 90°C to 375°C, two endotherm peaks were observed. Results suggest that endotherm peaks are related to a melting and recrystallization phenomenon of one crystal morphology. However, the second endotherm peak could be associated with another crystal structure or morphology.

Jan 1, 2006

By B. McFadzean, I. Achaye, T. Chidzanira, J. Wiese

"Froth stability has an overriding effect on metallurgical recovery and grade for many ore types. Froth recoveries of less than 10% are common for low stability froths such as those in sparsely mineralized ores or in cells at the back end of flotation circuits. It is well known that, aside from chemical factors such as frothers and electrolytes, the mineral particles themselves have the dominant influence on froth stability. The particle properties of size and hydrophobicity are expected to have the greatest effects on froth stability. The aim of this study was to understand the effects of particle size on froth stability and to quantify these relationships.The study compared a synthetic ore of pyrite and quartz, with carefully controlled size ranges and hydrophobicity, with conventionally milled platinum-bearing UG2 ore and the bulk reverse flotation of hematite ore. A novel bench-scale continuous column flotation cell and continuous mechanical hybrid cell with large relative froth volumes, as well as a three-phase froth stability column were used to characterize the froths.It was found that froth stability could be related to the concentrate particle surface area by a Langmuir-type relationship. This is indicative that the mechanism by which particles stabilize the thin films in froths is similar to the mechanism by which surfactants lower surface tension. Different froth stabilities were found for different ores and this was thought to be the result of different particle sizes and distributions, which resulted in different packing densities in the thin films and Plateau borders. Interestingly, there was a clear relationship between the feed particle size and the froth stability even though froth stability was dependent on the concentrate particle surface area. It seems that the feed particle size is a good predictor of the surface area of particles in the concentrate. Concentrate particle size did not show a clear relationship with froth stability since it was already shown that it is both the size and the amount of the particles in the froth that contribute to the stability.INTRODUCTIONThe stability of the froth in froth flotation is important to the recovery and grade of the valuable mineral. Too stable a froth and the grade is reduced; not stable enough and the recovery may be compromised. Platinum-bearing ores with fragile, poorly mineralised froths are known to have froth recoveries that are routinely less than 10% (Crosbie et al, 2009). There are a number of chemical, physical and operating parameters that can affect froth stability, including reagent dosages, air flow rate, pulp density and particle properties. Arguably, the largest contribution to froth stability is from the particles that stabilise (or destabilise) the thin films in froths. Particle size, hydrophobicity and shape all affect froth stability to some extent."

Jan 1, 2016

By Jiahao Xu, Namsoo P. Kim, Guikuan Yue

Iron (ferrous ions and ferric ions) plays an important role in the heap leaching of copper sulfide minerals and copper electrowinning. In our previous study, a novel oxidation-reduction potential (ORP) equation only based on the variables of temperature and nominal ferric/ferrous ratio was developed to predict the redox potential of the quaternary H2SO4-Fe2(SO4)3-FeSO4-H2O system, and its applicability was also extended to more complex acidic iron sulfate solutions, especially those generated during the acidic leaching and bioleaching of Printed Circuit Boards (PCBs) to recover copper. In this work, the broader range of applicability of this equation to other complicated acidic iron solutions containing copper ions has been extended and determined. Specifically, synthetic iron-containing solutions with copper ions according to the conditions of industrial electrolyte during copper electrowinning and heap leaching have been used to measure the ORP and test the developed equation. It seems that this equation can still be employed to predict the redox potential of the Fe3+/Fe2+ couple for the simulated solutions under conditions related to copper electrowinning and pregnant leaching solution generated during heap leaching over a wide range of solution concentration, nominal Fe3+/Fe2+ ratio and temperature. It has shown that the prediction and measurement of redox potential is highly useful to estimate and understand the iron chemistry of industrial leaching and electrowinning processes. INTRODUCTION It is well-known that iron (ferric or ferrous) ions are widely involved in the hydrometallurgical production of non-ferrous metals such as Cu, Au and Zn, mainly in the form of acidic iron sulfate solutions. As far as Cu is concerned, in a typical leaching-solvent extraction-electrowinning process, ferric ion plays a central role in the heap leaching process and is reduced to ferrous ions in the pregnant leaching solution. Ferric ion is the most important surrogate oxidant and the dissolved ferric/ferrous couple plays an important catalytic role in accelerating the leaching rate with oxygen as an oxidant (Peters et al., 1986; Schlesinger, King, Sole, & Davenport, 2011). In addition, during the traditional electro-winning process, oxygen is evolved at the anode, and copper is reduced at the cathode. A common idea is that iron in the electrolyte in copper electrowinning cell (with total iron of 1–4.4 g/L) plays an important role in reducing the current efficiency. According to the published results (Winand et al., 1975; Dew et al., 1985; Moats et al., 2009; Khouraibchia et al., 2010), thecurrent efficiency decreases linearly with increasing ferric ion concentration and the energy consumption increase was mainly caused by the decrease in current efficiency.

Jan 1, 2019

By Robert B. Parsons

"The mining industry is adjusting its sights to take a shot at the rising level of non-profit taxes which threaten to handicap the industry 's competitive advantage. In the case of this particular expedition, the industry evidentally has a strong ally - the country's mines ministers. It appears that an initiative is under way to assess the impact of non-profit taxes on mining in Canada as compared to other mining nations.IntroductionSeventy-five years ago, Canadians were unceremoniously introduced to something called income tax. Since then, income tax has been identified as the source of countless evils ranging from the common cold (attributed to stress) to the demise of the economy. Some years later, the provinces jumped on the bandwagon with their own income taxes, and later on with mining taxes. These profit-based taxes had some appeal to elected officials and to a segment of the populace. The onus of the taxes varied directly with the ability to pay (in theory, at least). Previously, the principal sources of government revenues had been property taxes and customs duties, which were viewed as possibly being somewhat regressive in nature.The mining industry has always had concerns about different aspects of income and mining taxes - the tax rate is too high or the depreciation rate is too low, and so on. Recently, though, the industry has turned its sights on the expanding array of taxes which are not based on profit, including payroll taxes, capital taxes, water taxes, sales taxes, fuel taxes, property taxes, environmental levies and user fees. The industry is seriously concerned that the rising level of non-pro fit-based taxes is not only hampering the industry 's ability to reinvest in Canada, but is also placing Canada at a disadvantage in terms of trying to attract new investment capital."

Jan 1, 1992