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By Ltd Changsha Research Institute of Mining and Metallurgy Co., Shi Yunliang, Luo Yunbo, Chen Jun, Liu Miaohua, Xiao Jinxiong, Long Yan

"A refractory lead-zinc oxide ore located in Yunnan has hundreds of tons of metal reserves, which is hard to be recovered effectively by conventional oxide ore beneficiation methods. In this study, by sulfidation roasting of raw-ore, sulfide deposit is formed on the surface of the lead-zinc oxide ore, and then the roasted ore is processed with bulk flotation. The test results indicate that a bulk concentrate with grade of 7.85% lead and 34.24% zinc, recovery of 79.13% lead and 79.04% zinc, respectively, can be obtained by using conventional sulfide ore flotation method.The sulfidation process shows that pyrite in the raw ore releases S firstly, then S reacts with PbO and ZnO to transform into PbS and ZnS. When the mole ratio of sulphur:zinc is 0.59, the surface of smithsonite is covered with a layer of zinc sulfide. When the mole ratio of sulfu:zinc rate is 1.47, entire simthsonite particle is transformed into zinc sulphide. Thus the transformed particles can be recovered by flotation without complete sulfidation.INTRODUCTIONWith the increasing demand for zinc and decreasing of zinc resources, people pay more attention on development and utilization of zinc oxide ore. However, zinc oxide ore has wide range mineral kinds, complex mineral composition, disseminated fine-grained particle size, and high content soluble salt, so current study results about the zinc oxide ore with conventional flotation are not satisfactory. So far, process dealing with zinc oxide ore includes: sulfuration (Na2S)-flotation, direct flotation with fatty acids collectors, metallurgical methods, in which sulfuration flotation is the most widely used method. The basic principle of sulfuration flotation method is firstly roasting oxide ore with vulcanizing agent, and then recovering the sulfurated oxide ore with flotation, which is similar with recovering nature sulfide ore by using conventional collectors such as amines and xanthate."

Jan 1, 2016

By P. Maltais

Over the last 10 years, Computer Aided Design, Finite Elements Analysis and field testing of prototypes have enabled the cycling industry to grow and to significantly improve its products. However, today's cyclists have become more and more demanding, making these classical design approaches almost obsolete. Devinci understood that problem four years ago and fully revisited its design approach; to offer bicycle frames better suited to real life riding, one must fully know those real life conditions. In partnership with the University de Sherbrooke, Quebec, Canada, Devinci then developed a bicycle enabling them to measure the actual load applied on a bicycle frame in real-time for real riding conditions: the instrumented bike. Today, Devinci uses its instrumented road and mountain bikes, combined with virtual prototyping and laboratory testing capabilities to develop better bicycles, faster.

Jan 1, 2006

By S. Jordanov

The nature of processes that take place on top of copper bearing grains during the suppression of copper acid drainage from mine tailings was studied on a grain model. Cyclic voltammetry (C.V.) was employed as an experimental technique suitable for indirect measuring of copper leaching. Experiments were done in sulfuric acid (pH=2) at electrodes that progressively approach the real situation during acid main drainage, starting with Cu-metal, then with CuO and finally with CuO covered with CaSO4. Oxidation was found to be the only process that takes place on metallic copper electrode anodically polarized up to 2 V vs. Cu/CuSO4 reference electrode. Dissolution is intensive and reaches up to 50 mA.cm-2. When the same was repeated, but on CuO electrode, anodic currents were some 4 times lower than on the bare metallic surface. This indicates that the electrode material is not completely oxidized to copper(II)oxide and the Cu(O) or Cu(I) residues are oxidized during the anodic polarization. This explains the diminished dissolution. Dissolution is further restricted at electrodes covered with CaSO4. It is some 20 times lower than on the bare oxide electrode. When the second layer of CaSO4 was applied, anodic currents were another 15 times lower. Total decrease of anodic currents when transition is made from Cu-metal to CuO covered with 2 layers of CaSO4 reaches up to 7.500 times. C.V. measurements produced a proof that mechanical blockage is the way how lime prevents leaching of copper bearing grains in immobilization experiments referred elsewhere.

Jan 1, 2007

By Laura Kelsey

Contaminant Robust In Situ Water Extractor CRIWE Nafion-based water clean-up Extract purified water from natural extraterrestrial sources In situ water processing for downstream electrolysis Chemically resistant to process contaminants such as acid

May 1, 2013

By A. Klingberg, M. Svensson, N. Smolko Schwarzmayr

"Removal of silicates and carbonates from sedimentary phosphate ores by the use of new synthetic collector/formulations was investigated in a comparative study with traditionally used collector systems as references. In the direct carbonate flotation the new formulations showed higher efficiency, contributed to an improved balance of P2O5 recovery and P2O5 enrichment in the recovered material. Efficiency of the new formulations containing synthetic surfactants was 1.5–2 times better than potassium salt of fatty acid sulfonate based formulations that are traditionally used for that purpose. The new formulations also provided up to 7% increase in P2O5 recovery at the same P2O5 grade. The new synthetic collectors for removal of silicates showed extremely good selectivity towards silica bearing minerals. The selectivity factor for the flotation tests when new formulations were used was 32–52 and for the flotation tests with the traditional collectors: 20–32. The ratio between distribution of an amount of silicates (as SiO2) and distribution of phosphate in the froth (waste) is defined as the selectivity factor. The new formulations provided more than 2% decrease of the amount of SiO2 at the same P2O5 recovery.INTRODUCTIONPopulation growth and decrease of arable land are the main reasons for constant increase of consumption of apatite (phosphate ore) in the fertilization field (Lannefors, Gorochovceva, Klingberg, Lima, & Gustafsson, 2015). Fertilizers play a key role for farmers to produce more with less land. The phosphate component of the fertilizer is vital for producing healthy and large amount of crop. As a result the demand for phosphate rock is growing.The largest producers of phosphate rock are the Unites States, Morocco, Tunisia, China, Russia, and Brazil. The term “phosphate ore” includes all phosphate-bearing minerals and rocks, but only two of them are of industrial interest: apatite (igneous origin) and sedimentary phosphate (Peres, Araujo, El-Shall, Zhang, & Abdel-Khalek, 2007). The majority of the world’s phosphate deposits are of the sedimentary type. There are two different types of sedimentary phosphates: siliceous and carbonaceous which are categorized based on gangue minerals (such as quartz, carbonates, mica, and clay)."

Jan 1, 2016

By L. Becze, B. Pierre, S. Di Carlo, G. P. Demopoulos

From January to June 2007, the autoclave production at the Kidd Metallurgical Site was severely affected as a result of plugged discharge lines and extensive precipitation/crystallization of sulphates that caused massive scaling in different autoclave compartments. Work was performed at McGill University to understand the root causes. The crystallization of zinc and ferrous sulphate salts was investigated in terms of solubility measurements. Scale samples were characterized using chemical and mineralogical-spectroscopic analysis. In this paper, following a description of the Kidd zinc pressure leach operation, highlights from this investigation are presented and solutions used to overcome the problem are outlined.

Jan 1, 2008

"HPGRs operate in a wide array of applications in mining and minerals. These range from relatively coarse crushing of copper and gold ores at one end of the spectrum to the processing of fine iron ore pellet feed and fine industrial mineral products at the other. Traditionally these circuits involve the treatment of relatively moist materials in pre-grinding circuits; using single stage HPGRs in open circuit or as a closed circuit operation with screening or partial product recycle. More recently, HPGR is increasingly deployed in dry grinding in combination with air classification. The high throughput demonstrated by larger HPGRs has stretched the application towards coarser size reduction duties for a number of new projects. At the same time, the basic principle of inter-particle crushing for generating a product with a high fines proportion gives ground to investigate applying the technology further towards finished product duties. The advantages that HPGR brings are clear. Multi Stage grinding enables energy efficient size reduction across more of the comminution circuit. Primary HPGR serves for a coarse grinding duty, whereas a secondary HPGR is geared towards generating a fine product for downstream processing or even a finished product. This publication summarizes some of the features of staged HPGR circuits and discusses some examples of operating and projected applications.INTRODUCTION In most HPGR applications, the grinding units are used as a single process stage, either in open circuit, such as for pebble crushing [Rose 2002, Westermeyer 2000, Van der Meer 2015] or in closed circuit with classification [Van der Meer 2009, 2012] or product recycling [Van der Meer 2010]. Where a higher plant capacity is required, the HPGRs are commonly installed in multiple lines in a parallel arrangement [Parker 2005, Koski 201, Vanderbeek 2006]. HPGRs can take a wide range of feed size distributions, and grind this down to a product with a high fines content. In general view, there is a limit on the size reduction range that even an HPGR can provide. Grinding down from a very coarse ore (e.g. 70-100 mm) to a very fine product (e.g. 100 microns range) is stretching the ability of a single stage HPGR circuit. Fine grinding generally requires a classification stage that returns the classifier oversize to the head of the HPGR circuit. From one point of view, it can be demonstrated that when recycling a large proportion of fines and middlings back to the HPGR feed results in an effective feed with an overrepresentation of middlings and fines, which will eventually reduce the grinding efficiency and consequently result in an increased recirculation mass flow [Van der Meer 2014]. From another point of view the large recycling mass puts a strain or even a limit on the capacity of present-day conveyor capacity."

Jan 1, 2018

By Yongjie Bu, Wei Sun, Zhiyong Gao, Yuehua Hu, Hongbiao Tao, Runqing Liu, Central South University

"The flotation behavior of O-isopropyl-N-ethyl thionocarbamate (IPETC) and pH for chalcopyrite and galena was studied through pure mineral test, adsorption quantity determination, solution chemistry calculation and Materials Studio simulation. The results show that the recovery differential value of chalcopyrite and galena is about 20% when pH of the pulp 9.5 and IPETC is 7×10-4 mol/L, the flotability differences of the two minerals is significant. There is competitive adsorption between OH? and IPETC on mineral surfaces, it lead to galena flotability is lower than chalcopyrite flotability. IPETC can remove the hydration layer on mineral surface and adsorb on active sites for collector adsorption, minerals have a better hydrophobicity.INTRODUCTIONCopper and lead are two of the most widely used metals in industrial and living, their applications include building construction, various metal alloys, heat and electricity, machine manufacturing (Zhang et al., 2014). Chalcopyrite and galena are the major source of copper and lead, normally they associated with each other. With the growing use of these resources, high grade and dissemination large particle sizes minerals are less and less, the use of low grade and complex dissemination minerals have to be paid more attention (Chen, Ye, & Li, 2010; Liu, Sun, Hu, & Wang, 2009). As the special properties and complex composition of copper-lead sulfide ore, flotation separation of chalcopyrite from galena effective is a research emphasis and difficulty point in mineral processing (Bruckard, Sparrow, & Woodcock, 2011).In the separation process of chalcopyrite and galena, it is rather important to choose effective collector (Huang, Wang, & Liu, 2014). Enlarging and using the two mineral flotability will be a good basis and start in flotation (Reyes-Bozo et al., 2014). Qin et al. (2013) made a great deal of research on flotation separation of copper/lead concentrate, collector O-isopropyl-N-ethyl thionocarbamate (IPETC), butyl xanthate (BX) and ammonium dibutyl dithiophosphate (ADTP) were investigated, BX and ADTP floated both chalcopyrite and galena well, specific adsorption appeared in the surface of mineral, the problem was the collectors were not selective enough, however IPETC showed better selective."

Jan 1, 2016

By Philippe Henry

HYDROMETAL is using suitable technology to reintroduce lost metal units into the industrial cycle, thereby saving resources and energy while keeping the environment cleaner. Hydrometal is treating on average 60000 t per year of complex materials through a unique hydrometallurgical recycling concept. Zn, Cu, Sn, and Pb are the most important in volume, but in the last 15 years, Hydrometal has also developed a few specific recycling treatments for the minor metals including Ge, In, Co, etc. In 2010, Hydrometal commenced the recycling of RE (Rare Earths) from wastes generated by the RE refining industry in Europe and has decided to initiate new recycling projects for the RE recovery from the magnet or glass industries. Two case studies of recycling of materials in our integrated hydrometallurgical facility (Hydrométal) in Belgium are discussed: recycling of cerium from polishing sludges; and recycling of Ni- Co from cement produced in the zinc industry.

Jan 1, 2014

By O. S. Perry, G. H. Charlewood, K. Griffin, S Ogryzlo, H. Hopkins, G. MacIntosh

"The gold mines of Kirkland Lake are in Teck township, Timiskaming district, Ontario, latitude 48°9'N. and longitude 80°3'W., at an elevation of 1,038 feet above sea-level.There are seven contiguous producing mines in a length of 3;1/2 miles along the general east-west strike of the deposits. The seven mines are, in order from west to east, Macassa, Kirkland Lake, Teck-Hughes, Lake Shore, Wright-Hargreaves, Sylvanite, and Toburn.The first discovery of gold in the zone was made by W. H. Wright in 1911 on the east claim of the Wright-Hargreaves property, and the following year the Tough brothers and H. Oakes found gold in what is now the No. 1 vein_ at the Toburn. Production began at the Toburn in 1915, followed by Teck-Hughes in 1917, Lake Shore in 1918, Kirkland Lake Gold in 1919, Wright-Hargreaves in 1921, Sylvanite in 1927, and Macassa in 1933.To the end of 1946, 31,938,350 tons of ore had been milled at the Kirkland Lake mines, from which 16,132,700 oz. gold, having a value of $498,517,600, were recovered. The bullion varies from mine to mine between 800 and 900 fine, the average for all the mines being 853. The average fineness of the native gold is 941.The workings of some of the mines are more than 6,000 feet deep and sinking to depths below 7,000 feet is now in progress.GENERAL GEOLOGYThe regional structural geology of the area in which the mines of Kirkland Lake occur is described in a preceding paper in this volume by J. E. Thomson."

Jan 1, 1954

By W. H. MacLean, S. Liaghat

The Key Tuffite is a thick (0.3 m to 6 m) and laterally extensive (-10 km) cherty, sulfide-bearing tuff unit in Archean greenstones in the Matagami mining district in northwestern Quebec. It lies at the contact of the Watson Lake Group and overlying Wabassee Group volcanic rocks, and is host to major Zn-Cu volcanogenic massive sulfide deposits. The tuff component is highly altered and its volcanic precursors are not identifiable by petrographic means. The tuff is mixed with a volcanic exhalative component comprising chert, carbonate and sulfides (pyrite, pyrrhotite, and minor sphalerite and chalcopyrite). The normative mineral composition of the Key Tuffite is 33% quartz, 28% sulfides, 16% sericite, 8070 carbonate, 6% chlorite and 9% other minerals. In the vicinity of the Bell Allard and Orchan mines, the precursor tuff components are identified using immobile major and trace elements, as Watson Lake tholeiitic rhyolite (Zr/Y = 1.5 to 3.5, LaN/ybN = 1.7 to 2.8, SiO2 = 72.5 ± 1.2 wt %, and Wabassee calc-alkaline andesite (Zr/Y = 9, LaN/YbN= 4 to 8, SiO2 = 56% to 65%). Immobile element computation techniques were used to calculate mass additions and losses in the conversion of the tuff to the Key Tuffite. Average net amounts of FeP3 (27% total iron), Si02 (14%), Cao (8%), S and K2 (+ 2%), were added, Nap was removed (-2.8%), and MgO was over-all unchanged. Total net mass change was +63%, which comprises mainly exhalative additions, but also includes changes owing to hydrothermal alteration of the tuff component.

Jan 1, 1992

By Greg Gosson

"Early efforts to develop formal reporting systems to quantify and classify mineral deposits date back over 100 years. (e.g. Hoover 1909: “Proved, Probable, Prospective Ore”). This was at first driven by mine operators’ need for reliable estimates of what their mines could produce. Disruption of transportation routes by world wars prompted western governments to recognize the need for assessments of strategic sources of metals and minerals that could support domestic industry during times of crisis. Categories were created to quantify mineral potential which were additional to those of mine reserves. Terms such as hypothetical and undiscovered resources entered the lexicon. Capital markets serving the mining industry were traumatized during the latter part of the 20th century by undisciplined and fraudulent disclosure by exploration companies of mineral deposit potential. Government securities regulators pressed for the development of credible reporting codes (e.g. SEC Industry Guide 7: 1981; JORC 1989; SAMREC 1994, CIM 2000). Representative organizations from the major western mining countries generally agreed that there should only be three categories of mineral resources (measured, indicated, and inferred) and two categories of mineral reserves (proven and probable). This was formalized in 1997 with the “Denver Accord”. Acceptance of the standard terminology may have been the easy part, because the challenge for the 21st century is to get general industry acceptance and agreement of the principles behind the definitions of each category. There has been noticeable movement towards this objective in the last few years. This is reflected in part in the updated reporting codes by JORC 2004, CIM 2005; SAMREC 2007; SME 2007; and PERC 2008, and the development of the CRIRSCO International Reporting Template 2007."

Jan 1, 2003

By A. Sokolov, E. Hasikova, V. Gostilo, V. Titov

Introducing online X-ray fluorescence (XRF) analyzers in the mining and processing industries can lower costs and improve the representativeness and speed of analysis. The applicability of the CON-XTM industrial conveyor XRF analyzer for continuous measurement of potassium content in process materials was demonstrated at various stages of potassium muriate (MOP) production. The CON-X analyzer produced reliable and accurate results for sylvinite ore (27–36% KCl), MOP cake after flotation (88–97% KCl), and NaCl residue (1.5–5% KCl). Tests of the analyzer at an MOP-producing plant showed a < 0.5% difference between online and laboratory results.

Jan 1, 2014

By M. R. KEYS

"The property is about 120 miles north of Red Lake in the Favourable Lake area, district of Kenora ( Patricia part) , Ontario. The original discovery was staked by K. Murray in December, 1927. The first development work was done by the Favourable Lake Mining and Exploration Company. In 1936 Newmont Mining Corporation acquired control of the property and developed it to production by September, 1939. Production to the end of 1945 had a value of $7,534,656 from 441,457 tons of ore, an average value of $17.04 a ton . This production was mainly from gold and silver, with lead and zinc of subordinate importance.The rocks in the vicinity of the mine trend in a north-south direction. From east to west the sequence is: (1) A dark-coloured, massive rock, presumably a flow, composed mainly of quartz and biotite. ( 2) A buff- coloured, scricitized rock locally containing quartz phenocrysts and black hornblende. This is an alteration product of the dark variety and is later than the folding. It occurs mainly within the dark rock. (3) A series of sediments comprising thin beds of greywacke, grit, quartzite, conglomerate, and iron formation. ( 4) A gabbro sill, now largely altered to amphibolite.With the exception of the buff type, these rocks dip 80°E. The buff rock has a very irregular outline in comparison with the other rocks and appears to dip somewhat more flatly east. Felsite and diorite dykes are also present. These have a general strike of S.60°E. and dip 65°S .W. A post-ore diorite dyke trending N.15°E. occurs about 2,000 feet east of the mine area."

Jan 1, 1954

By S. Duvah Pentiah

The transformation of an open pit coal mine to a horizontal-punch underground mine is subject to a number of challenges. These include scheduling the operation of various sizes of trucks over a long period, as well as updating delivery routes and dump site locations as the mine transformation progresses. In this process, rock is excavated from a quarry through earthworks. The bulk earthwork and quarry material delivery were initially drawn from traditional planning and experienced issues in their early phases. As a result, a traffic simulator was developed in order to validate schedules and predict achievable throughput, likely delays or blockages in the long term. The dynamic traffic simulator was also used to provide traffic density and vehicle arrival data at selected intersections in order to identify possible safety and efficiency issues.

Aug 1, 2013

By S. Shairp

At the Hudbay zinc pressure leach plant, filtration and washing of the second stage leach slurry takes place on a vacuum belt filter prior to disposal to tailings. Due to periods of poor filterability, laboratory studies were undertaken to investigate the effect of temperature of the filter feed slurry, and to compare filterability to the resulting cake particle size distribution.

Jan 1, 2014

By Shin-Kun Ryi

The world nowadays faces many challenges associated with excessive utilization of fossil, fuels, such as poor air quality and greenhouse gas emissions. Hydrogen appears to be an attractive alternative to the conventional, fossil, fuels with better energy efficiency and less environmental, impact. Pd and Pd-based alloy are the most often used membranes for hydrogen separation due to their superiority over other membranes. However, the stability of the commonly-used thin Pd-based composite membranes at high temperatures still, remains a big challenge. In this presentation, we will, report our progress on thin Pd-Ru alloy composite membrane by electroless plating high temperature applications.

Jan 1, 2010

By Q. G. Reynolds, R. T. Jones

"Residence time distributions are well defined for batch and continuously stirred reactors. However, there exist many smelting furnaces that do not fit either of these classifications. A mathematical description is presented for the case of a furnace that is fed continuously, but where the liquid slag and metallic products are tapped intermittently. The effects of slag and metal tapping intervals and the fraction of liquid retained in the furnace, are shown to have a significant effect on the residence time distribution.INTRODUCTIONThere are some processes in which the time spent by the feed material in a smelting furnace plays a significant role in determining the extent of the reactions between metal and slag and influences the degree of settling of metal droplets from a molten slag.Residence time distributions are well defined for batch and continuously stirred reactors. However, there exist many smelting furnaces that do not fit either of these classifications. Here we will focus on producing a mathematical description for the case of a furnace that is fed continuously, but where the liquid slag and metallic products are tapped intermittently. The effects of slag and metal tapping intervals and the fraction of liquid retained in the furnace, are studied.Previous work (Jones, la Grange and Assis, 1997) has studied the effect of retention time on the degree of cobalt recovery achieved in a slag reduction process. In that work, a method was proposed for the calculation of the mean residence time of the contents of a pilot-plant furnace. That approach is to be extended here for the purposes of providing a more general design or scale-up tool.The maximum allowable depth of molten material in a given furnace is affected by such factors as the desired batch size (or the size of the ladles) and the pressure of the molten material that the tap-hole and surrounding system can withstand. Within these constraints, there might be some scope for choice of taphole position. The effects of this choice need to be understood mathematically."

Jan 1, 2012

By M. A. Vos

"Aggregates are the low-cost mineral raw material of building construction. Large volumes of aggregate are consumed each year. The availability of aggregates in southern Ontario is discussed in the context of the geological formations in which they occur. Sand and gravel are abundant in glacial deposits and in recent sediments. A knowledge of the glacial history is important for their discovery. Bedrock formations provide a variety of aggregates in Ontario. Knowledge of the rock types involved and of the depth of overburden are important for evaluation of the aggregate potential of bedrock resources in an area. Utilization of available resources intensifies as the population increases. Urban development makes it progressively more difficult to satisfy the demands of the construction industry. The effects of urban development on the aggregate resource base of an area are illustrated by developments and consumption statistics in the Toronto- centred region. There is an obvious need for a comprehensive survey of available resources in urban areas to serve as a guide in land-use planning. To fill this need, staff members of the Industrial Minerals Section, Geological Branch, Ontario Department of Mines and Northern Affairs, are engaged in mapping projects and mineral resource studies in southern Ontario as well as in some urban areas of northern Ontario."

Jan 1, 1972

Background ArcelorMittal?s (formerly QCM?s) Port Cartier iron ore pelletization operations 2 side-by-side induration furnaces each producing 578 t/h of cured pellets Firing No. 6 fuel oil and coke breeze (in bed) Very large heat losses to be addressed primarily by gas recirculation

May 1, 2011