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By L. C. Bird, A. I. A. Salama, M. W. Mikhail

"A program of sampling in Canadian washeries was carried out by the Coal Research Laboratory (CRL) over a period of two years to evaluate the performance of various density separators in these operations(1). Operating data on quality and recovery of products, separation efficiencies and cutpoints for each separator type are compared with data predicted using computer models developed from previously existing data.The Heavy Medium Cyclone (HMC), Heavy Medium Bath (HMB) and jig models give predictions of recoveries and qualities of products for sizes coarser than 10mm with absolute value of error mean less than 7 per cent, whereas predictions of the Water Only Cyclone (WOC) model for -10mmfine coal are with absolute value of error mean less than 8 per cent. Although less accurate for -10 mm fine coal, the HMC and jig models produce predictions of recoveries with absolute value of error mean less than 2 per cent and quality of products predictions with absolute value of error mean less than 28per cent which are generally acceptable because more liberation in the fine fractions appears to compensate for any difference in the accuracy of separation, resulting in good prediction of the clean product. However, ash content of the actual fine refuse was lower than predicted. The difference is attributed to the highly friable nature of Canadian coals which tends to cause an excessive loss of coal fines to the fine refuse.A comparison study based on quality and recovery of products is made between the Dutch State Mines (DSM) models and the recently modified models, both produced comparable predictions."

Jan 1, 1985

By A. Torkian

Copper mining operations have increased in Iran in the past decades due to price increases and potential for creating jobs in developing countries. Iran consists of many copper mines. The mining operations have a positive economic impact on the region, but may also be the cause of adverse environmental effects. Environmental aspects and the health impact of respirable particulates on the communities and agricultural production in the immediate vicinities have been under scrutiny by the regulatory agencies to ensure sustainable development. The impact of an open-pit mine on the air quality and extent of particulate pollutant dispersion in different directions and times is the focus of this paper. The results of the modeling have been validated through ambient air monitoring. Monitoring stations were installed in different areas within the mine unit operations and around it including background areas where PM10 values were 7 µg/m3. Outside the Complex, particulate concentrations were monitored in 9 different stations and up to 25 km distance. Modeling of point, area, and volume sources was conducted using a 9- year meteorological database. The results showed that particulate quantity decreases rapidly below local standard value of 150 µg/m3 at 2.5 km around the mine and the main pollution is due to the crusher and tailings dump areas. Model outputs were compared to the actual values measured by the air quality monitoring network including villages and crop fields. High overall correlation of about 76% was obtained for most of the locations but lower values were reported for more complex terrain in the region. Remedial actions recommended included road water spraying and better management practices to avoid overloading trucks.

Aug 1, 2013

By Tobias Riedel, Peter Ay, University of Applied Sciences, Bianka Bade, Nicole Pausch, Bernhard Gemende, Florian Logsch, Matthias Leiker, Satyanarayana Narra, Claudia Glaser

This study focusses on the production of micro-structured agglomerates with high porosity from iron (III)-hydroxide-containing materials as adsorbent. A fractal-like structure of the agglomerates was created through a two-stage agglomeration process. Developing porous structures was necessary to increase the adsorption capacity. Various materials were used for the agglomeration experiments: i) filter cake (dry matter content 23 to 27 wt.-%); ii) FerroSorp®DGµ, a product which is already being used commercially for various applications in water cleaning. These materials in the pristine state have different characteristics such as dry matter content and particle size distribution. The desired optimised agglomerates can be achieved with the help of additives or binders, respectively. Additionally, the agglomeration process parameters play a vital role. In order to produce agglomerates with high porosity, the process was carried out in two steps. Firstly, FerroSorp®DGµ (d90 < 30 µm) was agglomerated jointly with the aforementioned filter cake in an Eirich intensive mixer (particle size range 125 µm < d90 < 500 µm). The second agglomeration step post drying was carried out in a pelletisation disc or in an Eirich intensive mixer with the addition of polymeric binders (up to particle sizes ranging from 2 to 4 mm). Agglomerates were characterised both in short and long term loading tests using phosphate as model ion. Contact times were less than 10 min, similar to practical application in percolation columns, or more than 7 days, respectively. The results show that the agglomerates produced in the two-stage pelletisation process have more advantageous properties like better accessibility of the active sites obtained by specificly influencing the particle size distribution during the two-stage pelletisation process.

Jan 1, 2016

By A. Ghahremaninezhad, E. Jorjani, A. Riahi, Islamic Azad University, B. Nazari, H. Hani, Z. Manafi

The presence of a high iron concentration, 9.1 g/L, in the raffinate of the Sarcheshmeh copper heap bioleach process led to the formation of various types of jarosite, (K,Na,NH4,H3O)Fe3(SO4)2(OH)6, on the heap mineral surfaces. This study probes iron removal from the raffinate using a bio-oxidation process based on A. ferrooxidans bacteria in the presence and absence of jarosite seed. The jarosite seed was biologically synthesized using A. ferrooxidans bacteria. The effect of solution pH (1.5 to 2.5) and jarosite seed dosage (0 to 15 wt.%) on iron removal was examined. It was demonstrated that the concentration of iron ions present in the raffinate decreased from 9.1 g/L to 2.5 g/L with the addition of 10 wt.% jarosite seed at pH 2 and 130 rpm mixing rate at 32°C. Three different types of raffinate including (1) native raffinate containing 9.1, 3.4, 5.7 g/L of total, ferric and ferrous iron, respectively, (2) bio-oxidized raffinate in the absence of the jarosite seed containing 8.5 g/L total iron (mainly ferric with negligible ferrous), (3) bio-oxidized raffinate in the presence of jarosite seed containing 2.55 g/L total iron (mainly ferric with negligible ferrous) were used in mesophilic, moderate thermophilic and thermophilic bioleaching processes. The results of the flask tests showed that the highest copper bioleaching recoveries of 9.4, 49.4 and 90.8 % were achieved using raffinate (3) with mesophilic, moderate thermophilic and thermophilic bioleaching processes, respectively.

Jan 1, 2016

By P. Tukkaraja, K. Katzenstein

"Block caving is one of the most economical and efficient underground mining methods and has gained popularity around the world especially for extracting low grade and massive ore bodies. However, during the extraction of ore from the draw bells, gases trapped inside the cave could emit into the working areas; hence, ventilation plays a key role in operating block cave mines successfully where gas emission is a concern. To design an effective ventilation system for a block caving mine, given the dynamic nature of the caving process, it is necessary to develop airflow characteristic curves (P-Q) for a given cave. This study uses a 1:100 scale physical model with an exhaust fan system, and a Computational Fluid Dynamics model of a block cave to investigate the airflow behavior through the cave filled with broken rock material. From this study, it was observed that the cave airflow resistance increases with the decrease in cave porosity and the particle size.INTRODUCTIONThe block cave mining method is gaining popularity owing to its low cost and high productivity. This study considered a case where this bulk mining method is used for the extraction of an orebody that contains uranium mineralization. During the extraction of broken ore from the draw bells, radioactive gases trapped in the cave zone could be released into the production drifts and could create unsafe working conditions in the mine. Mine ventilation systems play an important role in regulating the migration of radon in working areas. One of the strategies to control radon migration in a block cave mine is to exert negative pressure on the cave zone by using an exhaust fan above the cave zone. In order to select an appropriate exhaust fan system, it is necessary to study the airflow resistance of the cave zone (Loring & Nelson, 2006).Extraction of broken ore via drawpoints creates a void volume inside the cave called the air gap. Air gaps with larger heights can lead to air blasts in a block cave mine should the cave collapse. Besides that, the air gap can also lead to decrease in ventilation system efficiency due to recirculation of air flow and associated shock losses. Air gap height can also have a profound effect on the variation of cave airflow resistance (Erogul et al., 2015, 2017). The knowledge of cave airflow resistance is also important for predicting the intensity of an air blast. Cave airflow resistance is a function of cave properties such as broken rock size, air gap, and porosity inside the cave zone (Baysal et al., 2017). Initially, a scaled experimental model with a forcing system was developed to investigate the airflow behavior through the cave, however, this model couldn’t provide an observable change in the airflow resistance when the cave properties were changed (cave porosity, and airgap) This was attributed to the difficulties associated with forcing system in terms of achieving lower porosity values with the available material (lightweight shipping boxes) for simulating broken rock inside the cave zones, and controlling air leakage from the model (Ajitha et al., 2018)."

Jan 1, 2019

Some examples of the results of research projects, conducted in the KOMAG Institute of Mining Technology are presented. Special attention is paid to mining machines and equipment, and improving work safety and comfort of miners in underground workings. From numerous scientific and technical achievements of the KOMAG Institute within the last 2 years, a few design solutions have been selected for a presentation. Some results of European projects on innovative solutions are described as well, highlighting KOMAG?s role in the national and international research area.

Aug 1, 2013

By S. Jordanov

The nature of processes that take place on top of copper bearing grains during the suppression of copper acid drainage from mine tailings was studied on a grain model. Cyclic voltammetry (C.V.) was employed as an experimental technique suitable for indirect measuring of copper leaching. Experiments were done in sulfuric acid (pH=2) at electrodes that progressively approach the real situation during acid main drainage, starting with Cu-metal, then with CuO and finally with CuO covered with CaSO4. Oxidation was found to be the only process that takes place on metallic copper electrode anodically polarized up to 2 V vs. Cu/CuSO4 reference electrode. Dissolution is intensive and reaches up to 50 mA.cm-2. When the same was repeated, but on CuO electrode, anodic currents were some 4 times lower than on the bare metallic surface. This indicates that the electrode material is not completely oxidized to copper(II)oxide and the Cu(O) or Cu(I) residues are oxidized during the anodic polarization. This explains the diminished dissolution. Dissolution is further restricted at electrodes covered with CaSO4. It is some 20 times lower than on the bare oxide electrode. When the second layer of CaSO4 was applied, anodic currents were another 15 times lower. Total decrease of anodic currents when transition is made from Cu-metal to CuO covered with 2 layers of CaSO4 reaches up to 7.500 times. C.V. measurements produced a proof that mechanical blockage is the way how lime prevents leaching of copper bearing grains in immobilization experiments referred elsewhere.

Jan 1, 2007

By Zhenyu Han, Dion Weatherley, Ruslan Puscasu

"This study aims to demonstrate the capacity of the Discrete Element Method (DEM) to model and simulate fracture in brittle rock, capture the crack propagation process and determine crack propagation rates for various levels of external loading. In the numerical experiments reported here, a macroscopically homogeneous body of brittle rock, containing a single pre-existing crack, was subjected to tensile stress loading. Simulations concerned with model I crack growth process in 3D were carried out. The process of fracture has been observed under various steady state and dynamic conditions. The numerical results obtained reproduce qualitatively and quantitatively a variety of observed fracture phenomena. Specifically, this study examined the onset of cracks, single dominant cracks that grow across the specimen, crack bifurcations and branching. The density of fractures that can be nucleated and grow to a significant size with and without arresting each other, crack growth speed and stress distribution, all have been consistently and systematically analyzed. Suggestions on potential future developments are made and discussed.INTRODUCTIONFracture and failure mechanics are very important in mining, manufacturing, materials processing, mineral processing, civil and mechanical engineering, and many other disciplines of science and engineering. Yet, due to the complexity of fracture phenomena, no theoretical models of broad applicability are currently available (Bieniawski 1967). The simulation of crack propagation is therefore considered an open question in numerical rock mechanics. Although, a significant body of experimental research on fracture of materials was carried out since the early days of fracture mechanics (circa 1940s) (Poncelet 1946, Mott 1948), often in parallel with the development of fracture mechanics theories as well as with the development of experimental and observational techniques themselves, the experimental results were often done on particular classes of material such as glasses and other very brittle materials. Indeed, a number of specific experimental observations on the behavior of growing cracks in brittle materials were made in the 1940s for which generally accepted explanations based on physical principles are still lacking. Likewise, quantitative numerical modeling, based on both continuum and discrete methods, as a basis for understanding dynamic crack growth is still in a preliminary stage."

Jan 1, 2015

By P. Hajiani

"Feasible and sustainable separation of lanthanides outside of China has been a dilemma for the past few years. The present technique uses REE electrophoretic mobility (Ui) variation in an electrical field to separate them. The present invention relates to a system and a method to separate and refine rare earth elements/compounds produced in hydrometallurgical processes while they are dissolved in an acidic medium, without any intermediate precipitation step. This process uses free-flow electrophoresis to isolate REE from the concentrate simultaneously without any pre-treatment or intermediate steps related to the nature of elements.INTRODUCTIONRare earth elements (REE) invariably occur together in nature, and any given mineral contains several or most of them. Production of high purity individual rare earth (RE) elements/compounds from their ores generally requires two stages of processing, including mineral processing and hydrometallurgy.Depending on the ore, mineral processing and hydrometallurgy treatment of the ore before REEs purification is relatively simple and quite achievable though conventional methods. However, producing individual REE from mixed REs compounds is tremendously tedious. RE processing often requires dozens of steps, each resulting in minute improvement in the complex RE streams. Separating and extracting a single REE requires a great deal of time, resources, and expertise. Today, advanced RE refinery facilities cost hundreds of millions of dollars to build. The high purity RE concentrates are separated into individual REE using solvent-based or ion exchange methods. Although there are several techniques to separate REEs, most of them suffer from different types of drawbacks. For instance, solvent extraction requires a great number of steps to achieve high purity REEs. The process which uses ion-exchanger for separation and refinery operates with low REE concentration in solution which leads to very large liquid volume quantity, bulky tanks, dehydrators, pumps, etc. The low concentration will adversely affect the water consumption as well as other chemicals. Similar chemical properties of those three valent elements do not allow them to be isolated easily one from one another using conventional separation techniques. Solvent extraction has been successfully applied for rare-earth refining (lanthanide, scandium and yttrium) for the past few decades in China. Since then, efforts have been dedicated to develop other techniques which could be applied industrially around the world."

Jan 1, 2016

By R. Laucournet, E. Billy, M. Joulié

Today Li-ion batteries are considered as one of the most attractive available energy storage solutions. However in order to overcome environmental, legislative and economic issues, the management of used batteries has to be considered and mainly the recycling. The present paper deals with the recycling of used Li-ion batteries and the recovery of high value metals from active materials of electrodes. Lithium nickel cobalt aluminum oxide (NCA) and lithium manganese nickel magnesium oxide (LMNM) cathodes, which contain most of valuable elements typically used in the composition of active materials for Li-ion batteries are investigated by a hydrometallurgy route. The process is divided into two steps: the materials leaching and the elements recovery by a selective chemical separation. Some experimental parameters (acid nature, concentration, time and temperature) are studied to determine the most efficient conditions of dissolution. Then, the valuable elements such as nickel, cobalt and manganese are selectively recovered with a high efficiency close to 100 % and with a high purity by precipitation. By this study, an adaptable hydrometallurgy process can be defined according to the composition of Li-ion batteries to recycle.

Jan 1, 2014

By W. A. Alexander

Introduction In the course of a programme of research on beryllium in progress in these laboratories, knowledge of the recrystallization temperature became necessary. As the information is not available in the literature, the determination of this temperature for metallic beryllium was undertaken. By the reduction of grain size through working and recrystallization and the probable simultaneous induction of preferred orientation, it was hoped to improve the working properties of beryllium at lower temperatures. The recrystallization temperature is usually determined by observing the lowest temperature of annealing at which new crystals are formed in severely cold-worked metal or alloys. This temperature is profoundly influenced by the following factors: the purity of the metal, in the case of an element, or the composition of the alloy; the degree of straining or working; the temperature of straining; the original grain size; and the time held at the annealing temperature. The observed temperature is lowered by higher purity, more severe straining, lower temperature of working, smaller original grain size, and longer time of annealing. Beryllium presents special difficulties in that the percent elongation in tension is effectively zero, so that ordinary squeezing or rolling was not possible. A possible means of straining was suggested by the fact that indentation hardness tests could be made. It was known from earlier work that the metal could be worked at elevated temperatures, so that working at the lowest feasible temperature and quenching might also be a means of producing strain. The purity of the metal is also a point of some uncertainty in the case of beryllium. Losano has prepared 99.96% Be which appears to be the best reported. Distilled metal used in the present work approached this purity. However, by analogy with other metals, residual impurities may have a pronounced effect on the recrystallization. Further purification of beryllium would evidently entail considerable difficulties due to the highly reactive nature of the metal, and was not attempted.

Jan 1, 1947

By G. Guzman

In the framework of the optimization of Teniente Converter operation the new system of automatic flux feeding through gar-gun was implemented in the Potrerillos Smelter, Codelco Chile, Salvador Division. The control algoritm based on simple iron and silica balance adjusted by empirical coefficients was incorporated in the logical programmer. The programmer works in real time gathering information from the plant instrumentation events and introduced chemical assays of concentrate, slag and flux. Through the auto-tuning of the automatic operation the criterions of optimal flux dosage were determined. Four month of operation of the automatic flux feeding system demonstrated the stabilization of magnetite content in the slag in the narrow range from 18 to 20% and the decrease of flux consumption, corresponding to annual savings US$ 340,000. Additionally, the automatic system helps operators in the control room in fast determination of optimal fluxing and avoid the errors in flux dosage affecting the slag quality and its impact on refractory wear.

Jan 1, 2007

By X. -P. Zhang, L. N. Y. Wong

Shale gas exploitation initiated in North America has rapidly extended worldwide. Hydraulic fracturing is an emerging field technique for stimulating the gas reservoir. The study of cracking processes, particularly crack coalescence, is vital for a successful hydraulic fracturing to enhance the gas exploitation. Experimental studies have observed that the size effects of the constituent particles are significant on the cracking behavior of the rock specimens. To further investigate the size effects, the bonded-particle model (BPM), which is based on the discrete element method (DEM), is adopted in the present research. In flaw-containing specimens, by varying the crack resolution (?= a/2R), which is the ratio of half flaw length (a) to particle size (2R), the size effects on cracking behavior under compressive loading are studied. By keeping the flaw length constant, the particle size is varied independently in the BPM analysis. Decreasing the crack resolution increases the first crack initiation stress, but it has no obvious effects on the uniaxial compressive strength. The trajectories of the first cracks and secondary cracks hence generated have a higher resolution and are well-defined in those specimens possessing a higher crack resolution. On the contrary, in lower crack resolution specimens, the macroscopic first cracks appear to be wider and less continuous. These findings from numerical simulation clearly demonstrate particle size effects on cracking behavior. Special attention should be paid to these effects in future numerical study using the bonded particle model.

Jan 1, 2015

By H. Aminian

Gold powders have many important industrial applications. In this paper the available processes for the preparation of gold nano and micron sized powders are described. The attention has been given to hydrometallurgy route and the recent works and achievements in controlling the powder morphology are highlighted.

Jan 1, 2011

By R. J. Fruehan

Oxygen steelmaking (OSM) is not only the dominant steelmaking process but defines the structure of the industry. There are a number of myths regarding the future of OSM, which are false. These myths include that the EAF will become the dominant process in the near future, it is less costly to produce steel in an EAF and OSM is a mature technology and no new developments are occurring. These myths are shown to be false. Selected new developments are discussed such as post combustion, recycling of waste oxides, slag splashing and sensors.

Jan 1, 2004

By Peter Moser, Thoma Oberndorfer

"Within the research project “Mine Development” (Fettweis and Moser, 1990) a PC-based mine database has been built up since 1991 and so far includes detailed technical and economic data of about 150 under-ground hardrock mines in industrialized countries worldwide. These data represent about 50% of the underground hardrock mines in west and central Europe, Scandinavia, United States, Canada and Australia (Fig. 1). The mining operations included in the database have been visited directly and analyzed with respect to their deposit conditions, their general design and layout and also their operational and economic performance.The main aim of the Mine Database is to make a contribution to an improved planning of new underground hardrock mines. An analysis of current mine planning practices shows, that both personnel and company experience is still a dominant factor in planning new underground hardrock operations. Through the information included in the Mine Database the experience of a single per-son or company is supplemented by the experience of a wider group of people. The Mine Database makes the huge amount of experience that is available worldwide in the field of under-ground mining accessible for new mining projects. From that a contribution to a more reliable mine planning procedure based on the performance of existing mining operations is expected.In addition to its use in planning new mining operations, the Mine Database can con-tribute to the exchange of technical data among different mining operations, especially on equipment performance, etc. Such an information service is offered by the Department of Mining Engineering & Mineral Economics in Leoben and is already being used by different mining companies. To respect proprietory information, company specific information is not released under any circumstances.The cost of building up the Mine Database, so far, is about US$500.000 — two thirds of which is labour, and one third, travel."

Jan 1, 1996

By K. Kudo

Magnesium rods of 99.95% purity and approximately 6 mm in diameter were continuously cast at rates of between 15 and 25 mm/min by a heated mould process and their mechanical properties evaluated. It was found that rods cast at 15 and 20 mm/min consisted of a single crystal, while rods cast at a speed of 25 mm/min were multi-crystalline and showed a unidirectional structure. Although room temperature tensile ductility to fracture varied widely, it was found that with an appropriate crystal orientation, cast rods can exhibit elongation by as much as 215%.

Jan 1, 2006

By M. Hekmati1

SAG/AG mills have been most common choice in grinding circuits last decades. In the most cases, at the discharge of SAG/AG mills, a trommel screen is used that is equipped with baffles to provide appropriate residence time and improve separation efficiency. Using baffles, with the resultant maintenance requirements could lead to decrease in mill availability. In this research, an innovation in the structure of baffles of a trommel is presented. The results show that using new baffles led to 67% decrease in SAG mill downtime due to problems of baffles and 80% decrease in fine particles on recycle conveyor.

Jan 1, 2012

By J. Budac, R. Kofluk, S. Mankasingh

Stainless steels such as 316L or 304 are normally relatively resistant to attack by nitric acid. However research at Sherritt International’s Fort Saskatchewan Operation reveals that when the stainless steel is immersed in an aqueous system in which nitric acid is used to dissolve metals such as cobalt or nickel, the steel can be seriously corroded. Sherritt is patenting a simple process for arresting the corrosion via the use of copper. This process is expected to substantially eliminate corrosion in processes where nitric acid is used to dissolve metals attached to a stainless steel substrate.

Jan 1, 2014

By A. R. Farkoosh, J-P. Fortin, M. Pekguleryuz, S. Bagherpour

"Titanium aluminides are structural intermetallics which offer an attractive combination of high temperature strength and light weight. For such properties, these intermetallic alloys have become front-runners in replacing nickel-based superalloys used for several high temperature applications. These alloys are produced from metallic titanium, aluminum and master alloys involving an expensive and difficult process. A low cost alternative to current industrial production method is the new modified aluminothermic process which directly reduces titanium oxide (TiO2) to titanium aluminides. Nevertheless, this process has itself significant challenges in achieving alloys free of oxide inclusions; the close densities of the slag and the titanium aluminides makes slag/molten metal separation a challenging task. Usually, the alloy produced requires a second refining step. In this study, thermodynamic calculations based on CALPHAD method were performed to determine the solidification path and an attempt has been made to develop a criterion to increase the density deference between the slag and the alloy by alloying with appropriate elements. Furthermore, scanning electron microscopy (SEM) and x-ray diffraction (XRD) techniques were utilized to examine the microstructure and phase selection of three Ti-Al alloys produced by the aluminothermic reaction, including the as-cast, refined in a controlled atmosphere and inert-gas-refined alloys. The composition range of the alloys studied was restricted to the a2-Ti3Al + ?-TiAl phase field (Ti-30Al) in the binary Ti-Al phase diagram leading to a lamellar structure with different complex intermetallics as shown in Figure 1.INTRODUCTIONTiAl based alloys are promising structural materials for high temperature aerospace and automotive applications. This is due to some attractive properties such as low density, high specific strength, high specific stiffness and high temperature strength retention (Wen-bin, Xue-wen, Hong-fei, & Yong-feng, 2011). These alloys have become leading candidates to replace Ni-based super alloys in gas turbine engines. Replacement of Ni-based super alloy parts with titanium aluminides is expected to reduce the structural weight of high performance gas turbine engines by as much as 20–30% (Kothari, Radhakrishnan, Sudarshan, & Wereley, 2012)."

Jan 1, 2016