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By Bruce W. Smith

Non-contacting, radioisotope density and level gauges are discussed. The characteristics of the more commonly used isotopes, the techniques of detection and the methods of presenting information are reviewed. The gauge parameters of accuracy, response time and long-term stability are tabulated with reference to calibration techniques and operating requirements. Automatic control systems, both pneumatic and electrical, are used in conjunction with density gauges on filter feeds, and in thickener underflow and heavy media processes. These systems are described. Procedures for installation, start-up and operator training are outlined, along with considerations of preventative maintenance and service requirements. Typical gauge system costs, including capital expenditure, installation, start-up and service, are presented, wherever possible, in order to provide a basis of comparison with more conventional systems.

Jan 1, 1964

By A. Khan, C. Ciriello

The purpose of this paper is to demonstrate the value of constraint modelling in optimization of mineral processing systems. This will be achieved by first understanding the overall concept of variation and constraints present in any system. Next, the value of using a Constraint Model in optimization is demonstrated through comparison of business cases. The benefit of understanding the severity of constraints and movement of the bottleneck within a mineral processing system will be understood through the use of a case study. Paper will conclude with a summary of all optimization benefits that utilization of a constraint model can bring.

Jan 1, 2015

By H. Miki, S. Wheatley

The addition of precipitated silica greatly enhances chalcopyrite leaching in the presence of sodium chloride at moderate temperatures (65-90°C) in acid media with ferric ions as the oxidant. The beneficial effect increases with the increase in chloride concentration and temperature. The addition of sodium silicate and silica sand has no significant influence. The analysis of solubility data in acid/salt solutions indicates that the solubility of silica as Si(OH)4 as the dissolved species is controlled by the activity of water, as expected from the hydration theory. Kinetic analysis shows the trends that copper dissolution from chalcopyrite in the presence of precipitated silica with sodium chloride follows a shrinking sphere model indicating a chemically controlled surface reaction. The effect of temperature on copper dissolution in the presence of both precipitated silica and sodium chloride was also larger compared to the results in sodium chloride alone. The SEM analysis shows that chloride and silica facilitates the precipitation of sulfur on the surface of the silica particles rather than the chalcopyrite particles which avoids the blockage of the mineral surface and thus improves the leaching kinetics.

Jan 1, 2014

By T. P. Johnson, A. Vathavooran

"Conventional mining operations can produce a wide range of wastes containing gold and other precious metals but which are less suitable for processing by traditional methods. There are also types of ore that do not fit easily into a traditional processing flowsheet, e.g. because the refractory nature of their minerology or the combination of valuable metals is less suitable for traditional processes. Nevertheless, these potential sources of valuable metals remain unexploited resources that have attracted growing interest in the metals and mining industries over recent years. The challenge is therefore to develop and use alternative processing methods that have the flexibility of operation to cope with a wide variety of material types and tonnages, whilst providing high recoveries for valuable metals. Tetronics’ DC plasma smelting technology achieves industry-leading recovery rates for precious metals from a wide range of input materials and initial precious metal concentrations, whilst generating an inert slag-based material as a by-product (even when starting from a hazardous waste input material), approved within the EU for use in construction applications. This paper describes how this technology can be used as a key part of an overall process for the recovery of precious metals from these interesting materials.INTRODUCTION The extraction of gold from its ores by various forms of cyanide leaching has been practised by the mining industry for over a century (Minerals Council of Australia, 2005) and it remains the primary extraction method in a wide range of mining operations. The ability of cyanide to extract gold efficiently and quickly from lower grade ores without extensive additional processing, coupled with well-known methods to recycle the cyanide for re-use within the process mean it is often both the most economically preferable and environmentally acceptable method for recovering gold. As a result, 88% of all gold produced from mines in the USA in 2014 was recovered via leaching of open heaps or dumps (UGGS, 2016). Nevertheless, there are occasions where certain combinations of mineralogy and other circumstances reduce the effectiveness of cyanidation techniques, so that ever more elaborate additional processing steps are required, with inevitable increases in operating costs (Swash, 1988). In these circumstances, which are likely to be more common in future as ore qualities diminish, other methods of extraction may offer better alternatives. Whilst much less commonly used for Au extraction at present, pyrometallurgical methods are amongst the longest-established of these alternative approaches and merit serious consideration in such cases."

Jan 1, 2017

By S. W. Marcuson, P. J. Mackey

The 1973 Oil Embargo and succeeding disruptions in supply had a profound effect on energy costs and consumption patterns in the developed world. This was especially true in the USA where post World War II growth, fueled by low-cost imported oil, left the country dependent on uninterrupted oil shipments from the volatile Middle East. In this atmosphere, Professor H.H. Kellogg of Columbia University, convinced of the necessity of good environmental stewardship by the writings of the era’s leading environmentalists, developed a methodology for evaluating energy and process efficiency of metallurgical processes and wrote a series of papers describing and applying the techniques. One of these, "Energy Use in Sulfide Smelting of Copper" is recognized as a seminal work which both described the state of energy usage in copper smelting in the mid-1970’s and portended future developments. The background to these papers is examined and the current and past Cu-Ni matte smelting practices in Canada are examined in the context of the results. Data from early 20th century publications describing reverberatory and blast furnace operation is employed to show that energy consumption for much of the century was several multiples higher than that calculated for best reverberatory operation in the 1970’s.

Jan 1, 2015

By D. M. Maijer, S. L. Cockcroft, A. B. Phillion, P. Fan, C. Reilly, H. Khadivinassab

A combined experimental / numerical approach is proposed to investigate the bulk transfer of solute due to liquid metal feeding during shape casting of aluminum alloy A356 (Al-7Si-0.3Mg). A dumbbell-shaped experimental casting geometry has been developed, which promotes solute redistribution due to liquid metal feeding. The redistribution of solute in trial castings is evaluated based on the area fraction of eutectic phases. In the numerical model, silicon species segregation during solidification are calculated assuming the Scheil approximation, and are coupled with macro-scale solute transport due to Darcy flow in the mushy zone and feeding flow. The model has been implemented within the commercial CFD software, FLUENT, which simultaneously solves the thermal, fluid flow fields and species segregation on the macro-scale. The experimental and numerical results are compared and contrasted to examine the effects of liquid metal feeding in this casting.

Jan 1, 2014

By Eric Johnson

"IntroductionHistoricalCyanidation is a leaching process, in world-wide use, to extract gold (and silver) from ores and concentrates. The process has many inherent advantages on account of its adaptability:a. to any scale of operation;b. to a wide range of ore types and mineral associations;c. to a wide range of physical characteristics of the gold particle size, alloy (electrum) or mineral (telluride);d. to relatively simple plant controls and operating procedures;e. to simple marketing procedures and quick cash return.The basic idea for cyanidation was first described and patented by a German chemist, L. Elsner, in 1846. Some forty years later, J.S. McArthur, a metallurgical chemist and R.W. and W. Forrest, medical doctors, all of Glasgow, Scotland, came to realize the import of the discovery and accordingly, registered patents in Great Britain in 1887 and in the United States in 1889. The keystone of the McArthur-Forrest patent registration was the use of weak (0.05o/o) instead of strong (1.0%) solution.The years 1890-1910 saw much progress in equipment design and the advance from batch to continuous processing to increase efficiency and reduce operating costs.In later years, technological progress followed advances in materials of construction and control systems. Current innovations include large-scale equipment, high-capacity thickeners, belt type filters and Steller, candle-type filters for plants using zinc dust precipitation. As well, environmental protection is increasingly a major concern.The technology of gold adsorption from cyanide solution onto activated carbon has made rapid strides in recent years. This has followed the initial efforts of Potter, Salisbury, Zadra and their colleagues of the U.S. Bureau of Mines Research Station in Salt Lake City, Utah, and the field work of Homestake Mining Company personnel, in Lead, South Dakota."

Jan 1, 1989

By Ahmad Ghahreman, Lin Li

"In this study, the Fe(II)/Fe(III) redox reaction kinetics on the surface of pyrite, have been investigated in a 0.5 mol L-1 sulfuric acid solution for a temperature range of 22 to 65°C. Based on mixed potential theory, chronoamperometry is introduced to study the Fe(II)/Fe(III) kinetics by subtracting the current density of pyrite oxidation in an iron-free acidic solution from that in an iron-containing solution at the same applied polarized potential. Tafel behavior was established by this method to analyze the kinetics of the Fe(II)/Fe(III) redox reactions. The results showed that exchange current densities increased slightly with temperature, however remained on the order of 10-5 A cm-2. The activation energy for Fe(II) oxidation and Fe(III) reduction on the pyrite surfaces was calculated to be 102.0 and 32.7 kJ mol-1, respectively. Anodic transfer coefficients also increased, from 0.24 to 0.39, with increasing temperature, which indicates a weakened n-type semiconductor property at higher temperatures. Electrochemical impedance spectroscopy measurements have indicated that at lower anodic over potentials the charge transfer is the rate determining step of pyrite oxidative dissolution in sulfuric acid solution. In the presence of Fe ions, the major contribution of the total current density comes from the Fe(II)/Fe(III) redox reaction. INTRODUCTION Pyrite, an abundant sulfides mineral in the nature, is commonly considered a valueless gangue mineral frequently associated with other valuable sulfide minerals such as chalcopyrite, or metals such as gold, or coal (Lin & Say, 1999). Pyrite oxidation has been the subject of extensive research in view of gold metallurgy, as oxidation of pyrite is the initial step to break down the pyrite lattice and expose the encapsulated fine gold particles (Gasparrini, 1983). Fe(III) ion and dissolved oxygen (DO) have generally been considered as the two most important oxidants with respect to pyrite oxidation, having been studied extensively in previous research (Zheng, Allen, & Bautista, 1986; King Jr & Lewis, 1980). The process of pyrite oxidation can be viewed as a series of reactions amongst pyrite, ferrous, ferric and oxygen in which pyrite is initially oxidized by the dissolved oxygen in water forming ferrous (Eq. 1), and then the ferrous also is oxidized by he dissolved oxygen to form ferric (Eq. 2). The ferric, produced by reaction 2, then could potentially oxidize pyrite (Eq. 3) and convert to ferrous."

Jan 1, 2017

By Louis M. Perlman

CAN PRESENT TRENDS CONTINUE? Can population growth in the world keep going at the average rates of the last few decades, till, say, the year 2000? And beyond? At the same time, can we expect steady increases in mineral consumption per head, all over the world, as the living standards of many nations converge toward the living standards of North America? If they do converge? Does the total fund of world resources extend, with foreseeable techniques, to supplying the consequent demands for metals, non-metallic minerals and energy? Do we have the requisite economic and scientific techniques available to answer these questions? Certainly, we cannot forecast over decades with any certainty. There are many, of course, who seem to believe that by the simple fitting of trends, they can tell us something about the world and resource constraints in the year 2000, twenty-three years from now. It is significant that many studies of this sort have added sustenance to the 'doom-watching' fraternity of commentators. The reason is simple. The extrapolation of exponential trends into the distant future frequently leads to the most astounding and impossible scenarios. Another feature of exponential growth is the suddenness with which certain fixed limits are approached. It took world population two hundreds years to increase by 1/2 a billion, from 1650 to 1850. Yet some U.N. estimates suggest that the net addition to human population will be over 2 billion between now and the end of the century. Thus, the present world population would increase from a little under four thousand million today to rather over six thousand million in the year 2000.

Jan 1, 1977

"The successful commissioning and ramp up of the Albion Process™ at the GPM Gold Project relied on the successful scaling up of the process from batch and continuous pilot plant campaigns (Voigt et al., 2015). Critical information about reaction kinetics and residence time, grind size and pulp density were determined at the laboratory scale and successfully applied to the commercial scale. A limitation of small scale testwork, is that some parameters cannot be measured reliably and scaling up is a function of the physical size of the equipment which isn’t possible to test with laboratory scale equipment. Oxygen mass transfer rate is one such parameter since this is a complex interaction of many factors including slurry temperature, solution and slurry chemistry, slurry viscosity, agitator type, dimensions and power, oxygen bubble residence time, oxygen purity, tank geometry and oxygen injection technique. Oxygen generation represents an important operating cost for the Albion Process™. Pivotal to the Albion Process™ operating economically at atmospheric pressure is the capability to efficiently transfer oxygen while utilising as much oxygen injected to the process as possible. To respond to this Glencore Technology developed the HyperSpargeTM supersonic gas injector. This paper compares the HyperSparge™ against other sparging techniques to quantify the benefits of oxygen injection via a supersonic gas jet on scale up of the oxygen mass transfer system. The paper then examines plant survey data from the GPM Gold Project to demonstrate the very high oxygen utilisation that can be achieved with a correctly designed oxygen mass transfer system.INTRODUCTION One of the main challenges in chemical reactor design is the scale-up of processes from the laboratory to industrial scale. Processes which cannot be faithfully simulated with an experiment at the laboratory scale face challenges due to the physical dimensions and complexity of full scale operation. One example of this is the design of oxygen mass transfer systems in atmospheric oxidative leaching circuits such as the Albion Process™. A number of constraints associated with the use of laboratory scale equipment to design full scale circuits are involved in gas mass transfer processes in agitated slurries such as the Albion Process. Chiefly, typical laboratory and pilot size equipment lacks the required volume to provide useful design data without relying on empirical correlations: the specific agitator power input is artificially high, the bubble residence time in the vessel is artificially low, the oxygen partial pressure at the base of the vessel is artificially low and the oxygen delivery method may differ significantly to the industrial process. Further, the dynamic nature of the process introduces additional impacts on gas mass transfer, including the presence of solids, recycle streams and minor elements, plus the variances within the reality of a process plant such as disruptions or variance of feed quality."

Jan 1, 2017

By A. Sutherland Brown, Stuart S. Holfand

"The Northeastern part of the Cariboo district lies in the big bend of the Fraser River between Quesnel and McBride. The area shown on Figure 1 extends from just west of Wells to Isaac Lake, about 30 miles across the regional strike of beds.Topographically the area extends from the moderately well dissected Interior Plateau in the west through a transition zone to the fully dissected Cariboo Mountains in the east.The area is an important source of lode and placer gold. The Cariboo Gold Quartz and Island Mountain lode-gold mines have produced more than 32 million dollars in bullion since 1932. Placer-mining has probably produced an equivalent or greater amount, although only 15 million dollars is officially recorded because accurate statistics. were not kept until fourteen years after the origiiaal gold rush of 1860.The regional structure of the Barkerville district was summarized by Lang in the Jubilee Volume (1948, pp. 141-149). Since then a large amount of detailed and areal mapping by the writers has expanded the information available and made necessary a complete revision of the regional geology. Much of the information summarized in this paper, together with a full discussion of the revisions, may be found in British Columbia Department of Mines Bulletins, Nos. 34 and 38, but other information is as yet un-published.Rocks of the Kaza group are exposed in the core of the Lanezi anti-clinorium between Spectacle and Isaac Lakes. The main part of the group is composed of greenish micaceous greywacke and greenish schist with knots of garnet, biotite, or both, and minor amounts of pebble conglomerate. The upper 1,000 feet is composed of white to brown quartzites and brown phyllites. Altogether, about 6,000 feet of the group is exposed. 1t is of latest Precambrian, i. e. Windermere, age."

Jan 1, 1949

By E. C. Sanford

A laboratory-scale batch extraction unit and operating procedure for studying the hot-water separation of bitumen from Athabasca tar sands are described. The extractor evolved from earlier units and has been in use by Syncrude Research for the past 10 years. By using a unit such as this, it is possible to study tar sand feed quality and the effects of chemicals on the hot-water extraction process, while process variables are held constant. Data are presented to demonstrate the importance of surfactants to the process and the interrelated role of inorganic bases and surfactants.

Jan 1, 1979

By L. Bichler

Utilizing thermal analysis techniques, pioneering research into the solidification mechanism of a popular magnesium alloy AZ91E cast by the Lost Foam Casting (LFC) process was carried out, Foam characteristics, section thickness and application of vacuum were seen to have profound effect on the cooling rate, thermal gradients and casting temperature profiles.

Jan 1, 2005

By R. Hans

Removal of toxic anions from aqueous solution was studied using a Magnetic Ion Exchange (MIEX) resin which is a polyacrylic, strong base resin. Gravity based settling is made more efficient due to the magnetic nature of the resin which is advantageous over conventional ion exchange resins. In addition, the magnetic microspheres of MIEX have larger surface area in comparison to conventional ion exchange resins. Over the years MIEX has been successfully used and has gained significant popularity for efficiently removing dissolved organic matter from wastewater and groundwater. In the present study the efficiency of the MIEX resin was tested for the removal of chromium(VI), molybdenium(VI), vanadium(V) and arsenic(V) anions. Effects of pH (2-10) and temperature (25oC-55oC) were examined. In general, low solution pH values were favorable for anion uptake by MIEX. Except for chromium(VI), the metal ion uptake was significantly increased by the increase in solution temperature. The adsorption data were analysed on the basis of chemical speciation and heterogeneous kinetic models.

Jan 1, 2014

By A. J. DeArdo

Linepipe steels have come a long way in the past forty years. In fact, modern, high strength steels for large diameter linepipe applications represent one of the seminal accomplishments in metallurgy of the past half-century. The synergy of advanced steelmaking, alloy design including microalloying, hot rolling, and interrupted accelerated cooling has led to the marvelous steels being used today. The drive for higher performance pipelines has been motivated by the energy sector of our global economy who wanted both higher throughput capacity, i.e., larger diameters and higher pressures, and lower material cost, i.e., relatively thinner gauge wall thicknesses. These requirements led to new steels with higher strengths, better toughness and improved weldability. The goal of this paper is to trace the evolution of linepipe steels from the X60 grades of the small diameter pipelines of the 1960s to the (X80 - X120) grades used in the large diameter pipelines of today. The metallurgical triumphs permitting this success story, e.g., clean steel practices, controlled rolling, microalloying with Nb, and using IAC to obtain low temperature transformation products, will be highlighted and discussed.

Jan 1, 2005

By L. Tong, D. Robinson

"The stirred milling of nickel laterites offers possibilities for improving liberation and selective size reduction of soft nickel-bearing minerals in laterites. Batch grinding tests were performed in a netzsch™ lME4 stirred mill on siliceous goethitic, goethitic, and saprolitic nickel laterites. Tests on the -2,000 µm sample displayed the effects of selective comminution. The -38 µm product of grinding the -2,000/+38 µm feed confirmed the effects of selective grinding and nickel upgrading. Size classification followed by stirred milling is recommended for nickel upgrading. The energy requirement in the stirred milling was also investigated.RÉSUMÉ le broyage par billes de latérites comportant du nickel offre des possibilités d’amélioration de la libération et de la réduction sélective de la taille des minéraux nickélifères tendres dans les latérites. Des essais de broyage en vrac ont été effectués dans un broyeur à billes netzschMD lME4 sur des latérites nickélifères à goethite siliceuse, à goethite et saprolitiques. Des essais sur l’échantillon -2000 µm présentaient des effets d’une comminution sélective. le produit -38 µm de l’alimentation -2000/+38 µm confirme les effets d’un broyage sélectif et du rehaussement de la teneur en nickel. Pour améliorer la teneur en nickel, il est recommandé de classifier le minerai en fonction de sa granulométrie, puis d’effectuer un broyage à billes. l’énergie requise pour le broyage à billes a aussi été étudié."

Jan 1, 2015

By The Staff

Development of the Eldorado Mine THE pitchblende-silver deposits of Great Bear lake, Northwest Territories, were discovered by Gilbert LaBine in 1930. The property owned by Eldorado Gold Mines, Limited, consists of 53 claims situated, for the most part, on LaBine point, on the northeast shore of the lake. The Company also holds a group of 10 claims on Dowdell point, 7 miles to the southeast of the main group and across Echo bay. The fractures traversing the ridge on LaBine point can be readily seen from the air. Lack of overburden and the scantiness of vegetation leave rock exposures which are visible for miles. The years 1931 and 1932 were spent largely in staking, prospecting, and examination of the outcrops. A small Diesel plant was shipped to the property in 1932 and underground operations were started. Entry was made into the ore-body by means of an adit. A 20-ton mill was completed in the winter of 1933-34, and since then operations have been continuous, except for temporary shut-downs for additions to the mill. TRANSPORTATION The mine is situated 28 miles south of the Arctic Circle and is reached by an air route of 1,140 miles from Edmonton. The water route follows the course of the Mackenzie River system from Waterways, Alberta, the end of steel, and is approximately 1,450 miles in length. Two portages, at Fort Smith and on the Bear river, respectively, are necessitated by the occurrence of fast water. Transportation was one of the major problems to be solved, and Eldorado Gold Mines, Limited, found it necessary to embark upon both water and air freighting on its own account. The Company now operates a Bellanca 'plane with a payload of 4,400 pounds, and a complete water transportation system. The latter was established some years ago by the Northern Transportation Company and it is still operated under that name, but the Company is now a subsidiary of Eldorado. Modern steel boats, oil tankers, and barges were added to the fleet this season. The greater part of the ore shipments are made by water, aircraft being used for this purpose only when occasion demands. Freight rates have been greatly reduced by direct ownership of carriers. For example, water-borne freight is now quoted 'to the mine at $ll0 per ton, as compared with $240 per tan four years ago.

Jan 1, 1938

By Yihan Liu, Jintao Zhang, Chen Xiao, Xiaomeng Zhao, Guanglei Song

To estimate the performance of the inert anode materials based on NiFe2O4 spinel ceramic during it used for aluminum electrolysis, we investigated the wetting process of cryolite molten salt which is in composition of industrial aluminum electrolysis with carbon anode and NiFe2O4 based cermet materials, by means of determination the interface wetting angle between the molten cryolite electrolyte and the solid anodes interface. The results show that the wetting angle between the electrolyte and carbon anode is larger than 90 angulation, this means that they basically can not wetting; however the nickel ferrate spinel ceramics behaves much better. In regard to the NiFe2O4 matrix materials, their initial wetting angles is 76.9. The initial wetting angles for 1.0wt%MnO2, 2.5wt%TiO2 and 0.5wt%V2O5-doped samples are respectively 56.86°, 52.98° and 51.93°. However, after 50s later, all the wetting angles came down below 15°.

Jan 1, 2015

By F. Tanaka

Copper losses to discard slag have long impacted on the profitability of copper smelters. Businesses based on the treatment of secondary materials have also revealed that copper losses are indices of precious-metals losses. Many custom smelters are thus required to obtain more reliable controls for reducing copper losses than ever before. Mitsubishi Materials Corp. has cooperated with academic research institutes in conducting research projects on the pyrometallurgical fundamentals of copper smelting systems, including mutual evaluation of magnetite behavior between synthetic and industrial slags. The state-of-the-art pyrometallurgy has subsequently been introduced to Naoshima smelter for controlling the Mitsubishi process. The revised controls function successfully and the operational results demonstrate that avoiding the discharge of solid magnetite from the S-furnace is quite effective to reduce copper losses. Magnetite behavior has been controlled over the Mitsubishi process so as to reduce copper losses while satisfying the needs of recycling businesses growing in Japan. In-situ estimation of magnetite behavior using the absorbed heat from the melts to cooling water will also be discussed.

Jan 1, 2007

By Alex Matheson, Nick W. D. Massey, Peter T. Bobrowsky

Crowing pressures on aggregate resources include diminishing reserves, high transportation costs, sterilization and land use conflicts. In the absence of detailed resource knowledge for a particular region, aggregate resource potential maps provide the best "first approximation" regarding the surficial distribution of sand and gravel. The 1:50 000 scale Level Ill aggregate potential map integrates several important factors which influence the management of sand and gravel. Data used to generate this type of thematic map is readily available in most areas, fieldwork required is minimal, there is a logical quantitative evaluation of the data layers and integration is easily accomplished on a desktop PC-based platform. Also the aggregate potential map, with its focus on identifying areas of potential future aggregate exploitation as well as present inventory, provides a useful tool for the aggregate explorationist.

Jan 1, 2001