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By P. L. Schwartz

The present method of shipping potash to the myriad of consumers is inefficient, not only because of the extreme and unpredictable nature of seasonal demand, but also because railway car turnaround times are very lengthy. The Floating Train system employs unit trains of potash operating from Saskatchewan mines to distribution warehouses located throughout the six corn-belt states of Minnesota, Iowa, Wisconsin , Illinois, Indiana and Ohio, transshipment points at Thunder Bay and the U.S. waterway network, and, where applicable , large consumers. These unit trains would "float", meaning that they would not originate at the same mine nor terminate at the same warehouse on each trip . They would " float " freely among the origins, destinations and participating railways. The potash would be shipped uniformly throughout the year and usually stored in warehouses located within the six states. It would be subsequently delivered to consumers within a 75-mile radius. Distribution warehouses and rolling stock would be provided by a new company, Potash Distribution Limited, consisting of major potash producers and the Canadian railways. Potash Distribution Limited would be responsible for the distribution of potash from the origin through the warehouses to the final consumer. The additional costs of providing warehouse space and outbound delivery will be offset by the reduction in both rail rates and "peaking" expenses.

Jan 1, 1978

By A. Jordens, Y. Zhiyong

"IMBSRE, one of the largest rare earth element (REE) producers in China, produces a rare earth oxide (REO) concentrate as a by-product by floating the middlings stream from a low intensity magnetic separation step in the main iron ore processing stage. As the mine depth has increased, flowsheet changes in the main iron ore circuit have reduced the REO grade and increased the magnetite to REO ratio in the middling product used as flotation feed for the REO circuit. Extensive laboratory work was carried out and identified a new modified hydroxamic acid product, Florrea 8920, that could provide better metallurgical results over the standard hydroxamic acid used as the main collector. This paper briefly reviews the use of hydroxamates in the flotation of oxide minerals, provides detailed information on the different hydroxamates available from Florrea and then provides a case study of the successful implementation of the Florrea 8920 product in a commercial Chinese REE flotation plant. The case study consists of a one year program of pilot plant testing and industrial trials to confirm the results of laboratory tests. The implementation of the new collector resulted in an improvement in grade and recovery to 61% and 64% respectively. The new collector also provided significant economic and environmental benefits.INTRODUCTIONThe flotation of rare earth element (REE) bearing minerals is a topic which has been dominated in the English language literature by the work conducted on the Mountain Pass bastnäsite deposit (Pradip, 1981; Fuerstenau, Pradip, Khan, & Raghavan, 1982; Pradip & Fuerstenau, 1983, 1985, 2013; Fuerstenau & Pradip, 1991; Fuerstenau, Pradip, & Herrera-Urbina, 1992; Herrera-Urbina, Pradip, & Fuerstenau, 2013). By far the most important collector type used for the flotation of rare earth minerals (REM) is hydroxamates. These reagents were initially extensively described as REM collectors in the English literature by Pradip (1981) however they have been successfully applied to numerous other minerals such as: cassiterite (Sreenivas & Padmanabhan, 2002); pyrochlore (Gibson, Kelebek, Aghamirian, & Yu, 2015); hematite, chrysocolla, rhodonite, hubnerite and pyrolusite (Fuerstenau, 2005); and malachite (Lenormand, Salman, & Yoon, 1979) amongst others."

Jan 1, 2016

By R. P. Kofluk

The nickel-cobalt sulphides produced from limonitic laterite ores by Moa Nickel S.A. in Cuba are refined at the Corefco nickel-cobalt refinery in Canada. Significant economic implications are associated with the refining of precipitated sulphides containing elevated iron contents. The Moa Nickel S.A. operations encompass laterite mining, high pressure acid leaching (H PAL), and ultimately, precipitation of a mixed sulphide product. These processes are reviewed as they pertain to the control of iron and the formation of a mixed sulphide containing nominally 55% Ni, 5% Co and 1% Fe. The contributors to the iron content of the mixed sulphide product are reviewed; the major contributors are the HPAL operation and sulphide precipitation. The precipitation of iron during sulphide precipitation is influenced by the solution acidity, the iron and copper concentrations in the feed solution, and the presence of laterite leach solids. The significance of the copper concentration of the sulphide precipitation solutions is manifested by both physical and chemical modifications of the sulphide precipitates, presumably through the formation of fine copper sulfide seed particles.

Jan 1, 2006

By V. G. Papangelakis, G. A. Moldoveanu

The use of anhydrite (AH) seed, control of acidity levels and ageing were assessed as means to promote the conversion of freshly produced metastable gypsum generated in-situ to the less soluble anhydrite phase and force deposition of calcium sulphate on seed as opposed to on equipment as scale, while achieving lower terminal aqueous calcium concentration as well. It was found that moderate sulphuric acid levels (0.25M) and ageing in the presence of AH seed accelerated the gypsum-AH conversion, achieving 100% transformation of the metastable gypsum generated in situ to the more stable, less soluble AH in 6-7 days, while lower/nil acidity did not promote more than 30% AH conversion for 10 days, even in the presence of AH seed. These findings indicate that anhydrite seeding, ageing and incomplete neutralization are beneficial for scale control as well as achieving lower calcium levels, thus rendering the resulting solution more amenable for recycling.

Jan 1, 2015

By E. Eccleston, E. Gardner, F. Letarte, R. Schonewille

"In 2005, after nearly a decade of process development and feasibility work, the commercialization of the Falconbridge Nickel Smelting Technology (NST) began in earnest with the design and construction of a grassroots ferronickel plant at Koniambo Nickel in New Caledonia. The NST process was developed as an alternative to the conventional Rotary Kiln-Electric Furnace (RKEF) process for production of ferronickel from saprolitic nickel laterite ores. The NST process promised environmental and energy efficiency advantages over the conventional route. A key step of the NST process involves fluidized bed pre-reduction of calcined laterite ore using direct injection of pulverized coal as the reductant. Two parallel fluidized bed reduction roasters (FBRs) were installed at Koniambo Nickel, each designed for a maximum capacity of 4,200 MTPD of calcined nickel laterite ore. This paper describes the process development and scale-up of the fluidized bed pre-reduction process, the design challenges associated with the prototype commercial units, and the current status of the FBR operation at Konaimbo.INTRODUCTION In the mid-1990s, Falconbridge began to develop a new flowsheet for production of ferronickel from nickel laterite ores. The process that developed came to be known as the Falconbridge Nickel Smelting Technology (NST). The flowsheet, which is particularly appropriate for saprolitic ores, involves several major unit operations, including: drying in a hammer mill-flash dryer, calcination and preheating in a flash calciner, pre-reduction in a fluidized bed reactor, and smelting in a DC arc furnace to produce the ferronickel product. This paper focuses on the fluidized bed pre-reduction step of the process and provides an overview of the process chemistry, laboratory and pilot plant development work, scale-up and commercialization of the pre-reduction step, and the results obtained in the prototype commercial units."

Jan 1, 2017

By F. K. McKean

THE task of establishing a new corrosion testing laboratory is more difficult than it need be because there is very little information on the subject available in the literature. Many articles describing tests and results may be found, but a wide search will unearth only passing remarks on the different types of equipment that may be selected for accelerated corrosion tests. An article describing some of the apparatus needed in a corrosion laboratory should be of help to those interested in building a new unit or in making additions to an old one. In May of this year, the writer was given the assignment of equipping a laboratory for general corrosion testing, to form a part of the new Physical Metallurgy Research Laboratories of the Department of Mines and Resource~ at Ottawa. With the help of senior members of the staff, along with what could be gathered from other sources, a list of necessary equipment was compiled and a plan for arranging it in the rooms was decided upon. Where possible, the apparatus was constructed in the excellent machine shops at the disposal of this Department, while the rest was placed on order with the manufacturers.

Jan 1, 1945

By K. E. Waters, E. R. L. Espiritu, G. R. da Silva

"Rare earth (RE) elements are essential components of emerging green technologies. The increase in demand for these applications have driven the search and development of new rare earth deposits such as the Niobec project in Quebec, Canada. This deposit consists primarily of dolomite with significant amount of RE minerals bastnäsite and monazite, the primary sources of RE elements. Due to the minerals’ fine liberation sizes, flotation is commonly used as a concentration method. To develop an efficient process, the electrokinetic properties of the minerals must be understood. In this study, the surface properties of bastnäsite, monazite (RE minerals) and dolomite (a common gangue mineral) were investigated by zeta potential measurements. These measurements are affected by various ions present in solution; for bastnäsite, monazite and dolomite, some of these ions are H+, OH-, PO43- and CO32-. Dolomite, being a sparingly soluble mineral and a primary component of the ore, may be the greatest contributor of these ions in solution in the form of CO32- ions. Thus, different sources of CO32- ions (from dolomite dissolution and from Na2CO3) were investigated. The research work aims at elucidating how these reagents may influence the minerals’ surfaces. The results have shown that dolomite supernatant and sodium carbonate greatly affect the electrokinetic properties of each minerals. The addition of dolomite supernatant have resulted to relatively similar zeta potential of the minerals; while, sodium carbonate have affected them differently. These observations could be useful in efficient flotation of bastnäsite and/or monazite from bastnäsite-monazite-dolomite system.INTRODUCTIONThe increase in the demand for rare earth (RE) elements has driven the search and development of new deposits. Out of 53 rare earth projects in the world, 19 can be found in Canada (Hatch, 2015). These include the Niobec project of Magris Resources Company in Quebec. This deposit contains a significant amount of rare earth minerals (such as bastnäsite and monazite), with carbonates (such as dolomite) as the primary gangue minerals."

Jan 1, 2016

By J. H. Parliament

"The 15,000-tpd Similkameen open-pit copper mine, 10 miles south of Princeton, B.C., started production during 1972. The two main ore zones are separated by the deep canyon of the Similkameen River, with the Ingerbelle or western deposit being mined first. The location, design and construction of the plant were complicated by the steep terrain and the situation of the orebodies. Mining, utilizing 10-cu.yd electric shovels and 100-ton electric-wheel trucks, is conventional. Closely integrated with the preproduction mining was the construction of a 4-mile section of main highway to bypass the Ingerbelle pit. This entailed a very large fill, placed with mine equipment. Ore is crushed to minus 9 inches, stockpiled and reclaimed for direct delivery to three 32-ft-diameter by 14• ft single-stage autogenous grinding mills, each driven by two 4000-hp motors. Because of the friable ore in the upper part of the mine, 4-inch balls are added, with higher than design throughput attained. Classification is by 91>-inch spiral classifiers and cyclones. The flotation section comprises three parallel lines of ten 400-cu.ft rougher- scavenger cells and a single line of 100-cu.ft cleaner and recleaner cells. Concentrate is transported in end dump, closed trucks to Vancouver for dockside storage prior to shipment to the smelter. Tailings are piped across the canyon on a suspension bridge and through a tunnel to an empoundment area. Water is reclaimed and returned to the concentrator, forming a closed system. Dams are raised with cycloned ands, with the downstream section compacted."

Jan 1, 1973

By P. Mišcevic, B. Kavur, I. Vrkljan, N. Štambuk Cvitanovic

It is known from earlier and recent research that mechanical properties of intact rock like uniaxial compressive strength (UCS), Young's modulus (E) and Poisson's ratio (?) are influenced by shape deviations of test specimens as deviations from the ideal cylinder. That impact can be significant at certain level of inaccuracy of specimen preparing, and it should be objectively evaluated and controlled in testing. The effects of intact specimens side straightness, ends flatness, ends parallelism and perpendicularity to the specimen axis, on UCS, E, and ?, measured in several actual ways during laboratory compression tests, were determined by previous research on 90 homogeneous specimens of limestone. In this paper, we subject these new experimental results to Response Surface Methodology (RSM) to model the mentioned dependence, to identify significant connections of variables and to evaluate the conclusions obtained directly from experimental phase. This study indicates how the responses of the model (outputs) – parameters UCS/E/??of limestone rock depend on factors (inputs) – parameters of specimen shape deviations like flatness R, parallelism P and perpendicularity O, assuming modern test machines with spherically seated upper platen. Starting from general RSM model with three factors (R, P, and O), we investigated the multiple linear regression models of specific mechanical property (UCS, E, and ?). Using the NCSS program ("NCSS 2004 and PASS 2005") in several steps, final models with very high coefficients of determination were developed for properties with the most evident effects of specimen shape deviations: nine models for strength UCS and UCS50 (equivalent UCS for specimen with 50 mm diameter), and three models for ?L (Poisson's ratio calculated from axial deformations measured on the entire specimen length). These statistical models with their response surfaces further strengthen and confirm the results and conclusions from the experimental phase. The critical values of R, P, and O are established using an additional statistical analysis to determine the lower and upper engineering limits. These findings set the basis for the new eligibility criteria for specimens of limestone (and similar rock with UCS about 100-150 MPa) in further testing of strength and deformability.

Jan 1, 2015

By A. Ansari

Standard depressants used in the selective separation of copper and molybdenum sulfides by flotation pose environmental and health hazards. In this investigation, the floatability of chalcopyrite and molybdenite in the presence of six well-characterized lignosulfonates was studied through Hallimond tube flotation and adsorption tests. The results define the physicochemical conditions (lignosulfonate type and dosage, pH, presence of ions) for possible selective separation of molybdenite from chalcopyrite. Dissolved polyvalent cations, especially calcium, appear to serve as "activators" for lignosulfonate adsorption on both minerals. From this point of view, the use of lime as a pH modifier is not always appropriate for optimum selectivity since high dosages of lime to produce high pH tend to indiscriminately depress both sulfides.

Jan 1, 2006

By G. P. Gu

The in-service 90/10 cupro-nickel tubes in a water-chiller system suffered from severe corrosion damage during their relatively short service life causing unexpected down time. In addition to downtime, the environmental risk associated with losing refrigerant was also a concern that initiated this investigation, Microstructural investigation using SEM and electron microprobe indicated that pitting corrosion had resulted in local nickel depletion, During the corrosion process, copper appeared to have re-deposited around the corrosion pits accelerating the local corrosion.

Jan 1, 2005

By S. Shrestha

Magnesium-based alloys are of growing interest for many industrial applications due to their favourable strength-to-weight ratio and excellent castability. Mass reduction has advantages in many industrial sectors for example, in automotive, a reduction in mass improves fuel economy and can lead to more efficient mechanical systems by reducing the weight of moving parts like wheels, gears, pistons. However, the relatively poor corrosion and wear resistance limits the use of magnesium and its alloys in many potential applications. The patented Keronite® plasma electrolytic oxidation (PEO) process enables manufacturers to overcome such problems and, in its latest generation equipment has been developed to industrial realisation for high volume production. This paper presents microstructural characteristics and corrosion performance of two most widely used high pressure die-cast magnesium alloys AZ91D and AM6OB with a duplex corrosion protection coating system that comprised a thin Keronite pre-treatment followed by a subsequent automotive grade final powder coat.

Jan 1, 2006

By E. Burdukova

Rheological measurements have found a wide array of applications in mineral processing research. Rheological properties of mineral suspensions are highly dependent on the mineral surface properties as described by DLVO theory, and the relationship between these properties and inter-particle interactions is well established. In this paper, rheological properties of mineral suspensions are used to study the differences in behaviour of isotropic talc and anisotropic zirconia minerals as a function of varying properties of the suspension medium, such as pH and polymer dosage, specifically carboxymethyl cellulose (CMC). It was found that the rheological tests when carried out in parallel with electrophoretic or point of zero charge measurements, clearly reveal differences between behaviour of the suspensions of isotropic and anisotropic minerals. These differences are further accentuated with the addition of carboxymethyl cellulose (CMC).

Jan 1, 2006

By J-L. Tang

A new rhcoforming processing of Al alloys with component shaping systems apart from slurry preparation systems is experimentally exploited, using the reversible multilevel-speed electromagnetic stirrer, the slurry transfer tool and its coating, the thin plate sample with five steps and rheocasting mould, all of which are independently developed. The results show that semi-solid A356 alloy slurry with shape factor of about 0.85 and particle size of 70~80 µm (under air-cooling condition) could be prepared in 20~25 s, fully meeting the production rate of high pressure die casting. The slurry could be smoothly transferred from the slurry preparation equipment to the rheocasting shot chamber while the slurry temperature of slurry decreases by no more than 3 . The tensile strength and elongation of the semi-solid rheocasting samples could be respectively increased by 11.6~18.2 % and 42.5~50 % compared with the traditional liquid die casting ones, and the rheoforming processing has close affinity with the traditional hot working processes.

Jan 1, 2007

By S. E. Jackson, L. J. Cabri

Quantitative determination of gold at sub-ppm concentrations in sulphide minerals is an important component of deportment studies for sulphide-gold deposits. Laser Ablation Inductively Coupled Mass Spectrometry (LA-ICP-MS) analysis is preferred for this application because it rapidly and cost-effectively provides spatially resolved (<20 pm), low ppb concentration data for gold and other elements in mineral grains. Recent advances in LA-ICP-MS analysis include the development and application of elemental mapping. Raw signals from multiple line scans or lines-of-spots are deconvoluted and calibrated to generate elemental maps which provide detailed information on spatial variations of gold and other elements within and between grains.

Jan 1, 2011

By P. Shibley, P. R. Clarke

Since this was an interim report of the initial operation of a long term project it is not available for publication. It is expected when the project is completed a full report of the work will be published.

Jan 1, 1968

The paper will cover the basic reasons for alkaline leaching, a brief description of the circuit and the reasons for the flowsheet used. Changes made to the flowsheet, including the use of mechanical agitation of pachuca slurry, the use of oxygen and its effect on extraction, the use of lime and its effect on process economy, and the environment, will be described. A brief description of a unique semi-autogenous mill and future circuit changes will be included.

Jan 1, 1979

By T. Plikas, T. Porretta, M. Al-Dojayli, B. Pretorius, J. Woloshyn, H. Ghorbani

"Water-cooled ducts represent an integral part of high temperature off-gas systems in metallurgical processes. Typically, off-gas enters these ducts at significantly elevated temperatures; therefore, water cooling may be required to maintain the duct skin temperature within allowable design limits. These off-gases are typically of high mineral content that could lead to dust buildup, and there is a possibility of slag buildup / molten metal splashing. Therefore, dust cleaning provisions may be necessary in order to remove or minimize accretion on the duct wall, which could otherwise impact the water cooling and the system process efficiency. These ducts may have complex geometry and experience a wide range of loading, including gravity loads, water and gas pressures, cyclic thermal loading and dynamic impact forces. Consequently, the thermo-mechanical assessment of such water-cooled ducts is critical and requires consideration phenomena such as high temperature gradients, potential nucleate boiling, thermal ratcheting and fatigue failures. Such assessment is not comprehensively covered by design-by-rule design codes and guidelines due to its complexity. This paper presents a successful implementation example of design-by-analysis methodology to improve the design and extend the life of a water-cooled furnace transition duct using Computational Fluid Dynamics (CFD) and Finite Element Analysis (FEA).INTRODUCTION Water-cooling represents an important part of high temperature off-gas systems in metallurgical processes. Typical temperatures of the off-gas in the furnace uptake are in excess of 1400°C, and thus there is a need to maintain the water-cooled duct and jacket skin temperatures within their material allowable design limits. Water-cooled channels have been used effectively in arc furnace roof design (Sosonkin et al., 1972; Smolyarenko and Khainson, 1988) and other furnaces as well as in furnace fuming jackets (Scholey et al., 1994). The design of these systems was based on one-dimensional analysis to ensure sufficient cooling is available under extreme furnace conditions (Smolyarenko and Khainson, 1988; Scholey et al., 1994). With advancement in furnace and fuming system designs, water-cooled duct designs have become more complicated in geometry. Numerical techniques, such as three-dimensional fluid flow and heat transfer modeling, are therefore needed to more accurately calculate water velocity, temperature and convective heat transfer coefficients in the water-cooled channels (Haywood et al., 2002; Henning et al., 2010). This is of particular importance around geometric corners where stagnant water flow may lead to local nucleate boiling at the critical heat flux, causing hot spots (Bergman et al., 2011). High wall skin temperatures increase the risk of failures due to thermal stresses as well as increasing corrosion rates (Gelfi et al., 2012), leading to costly equipment downtime and potential safety risks."

Jan 1, 2017

By N. Musee, N. Kornelius

This study presents a neural network approach to modelling the liberation of gold bearing ores. A complete mineralogical analysis of unmilled and milled ores, including gold deportment and gangue content are used as inputs to a self-organising neural net which generates order preserving topological maps. The arrangement and shapes of these clusters are coupled to unmilled free gold data to predict gold liberation in milled ores (absolute error: 4.2%). Moreover, the self-organising maps were diagnostic of the quality of data used, indicating that the relationship between particle size and gangue material content requires further investigation.

Jan 1, 2005

By Mory Ghomshei

Pebble Creek Geothermal Power project is associated with a massive recent volcanic eruption in Southwestern British Columbia Canada. Slim holes drilled to depths 1100 m in the prospect area, show very high temperature gradients around 80?100?C/km. The temperature and chemistry of the Pebble Creek hot springs indicate the possibility of a steam reservoir in the prospect area. In addition to high temperature gradients, presence of host rocks with high permeability, along with abundance of recharge waters (from the Lillooet River) provides clear signature of a high-grade geothermal power reservoir at depth 2000 to 3000 m. Data show that over five hundred Megawatt of green power can be generated from the prospect area in a commercially viable manner. The generated power will be base-load, which in comparison with large hydro has the advantage of lower capital costs and a significantly smaller footprint. The final hurdle to overcome, before starting the development phase, is deep exploratory drilling for resource confirmation. This paper is a summary of the data available on the Pebble Creek geothermal power prospect, presented in the context of viability of the resource for large-scale commercial power generation.

Aug 1, 2013