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By Rod Maclean, George Stewart

"This paper covers the planning, development, and mining of an underground pillar complex using a bulk mining method. To achieve the long-term goal of continually improving our operating processes, all cut-and-fill and undercut-and-fill workplaces at Thompson Mine have been evaluated for their conversion potential to the bulk method referred to as VerticalBlock Mining (V.B.M.).Since December 1979, conversion has occurred to the extent where 80% of the ore hoisted is mined using Vertical Block Mining (V.B.M.).Productivity and profitability have been substantially improved by converting to this bulk method, especially in pillar areas.IntroductionThompson Mine is a 6000 ton per day underground nickel mine located 3 miles outside the City of Thompson, 400 air miles north of Winnipeg . The mine has two shafts, T-l and T-3 (Fig. 1). The T-l shaft is 4427 feet deep with the deepest mining taking place on 4000 level. The T-3 shaft, which is the area of this presentation, extends to a depth of 2607 ft with the deepest operating level at 2400 ft. The two shafts, some 10 000 ft apart, are connected underground on numerous levels. The ore mined at T-3 is trammed on 2400 level to the T-I main ore pass and hoisted through the T-l shaft. Eight hundred and fifty thousand cubic feet of fresh air per minute ventilates the mine.The 1400 level 310 pillar complex is located in the T-3 mine area. There are six rib pillars, two crown pillars and one main pillar (boundary pillar between cut-and-fill stopes) within the complex (Fig. 2). The majority of the ore in this area has been mined using mechanized cut-and-fill techniques .Undercut-and-fill mining was the method originally planned to recover these pillars. It is slow, labour-intensive, and requires extensive use of timber during the mining cycle. The extraction drifts in the area are heavily timbered due to their proximity to the ore and the age of the facilities. Increasing drift maintenance costs and the successful mining of two main pillars with V.8.M. techniques provided the stimulus to review the mining plans for this area."

Jan 1, 1988

By M. Lytle

"The Corbin area of southeastern British Columbia has been a coal mining area since 1908. Byron Creek Collieries Ltd. Has operated its Coal Mountain Mine in this area from 1974 until the present. In February 1981, this company was purchased by Esso Resources Canada Ltd.Coal Mountain is structurally complex and standard computer algorithms are not applicable to model the overturned synclinal structures and faulted bedding surfaces. This paper discusses two approaches used by Esso Resources staff to model the geology of Coal Mountain.The first approach projects digitized cross-section data along trend to develop a large data base which correctly approximates the shape of the structure. The spatial orientation of the structure is corrected by merging the generated data set with drill-hole data. The second approach uses digitized cross-section and bench-plan geology to generate a block model of the coal reserve.HistoryThe Coal Mountain Mine, also known as the Corbin Mine of Byron Creek Collieries Ltd. is located 24 kilometres south of Highway 3 in southeastern B.C.In 1905, two American businessmen recognized the coal potential of the area during a horseback tour. The two businessmen, D.C. Corbin and E.J. Roberts, formed the Corbin Coal and Coke Co. to mine and market coal from their newly acquired 6075 hectares of coal licenses. By 1908, the town of Corbin was under construction, a 22.4-km rail spur was constructed from the mine to the main CPR line and the first underground mine began to produce coal. An open-pit operation was also developed at the 1828-metre elevation using a steam shovel loading into rail cars. The company operated continuously until 1935, when a lengthy strike forced suspension of operations.In 1943, the Consolidated Mining and Smelting Company Ltd. (now known as Cominco Ltd.) operated two surface mines to produce coal for its smelters at Kimberley and Trail, B.C. This operation ceased in 1948."

Jan 1, 1982

By Yves C. Lizotte, Malcolm J. Scobie

Blast fragmentation is affected by the physical and mechanical characteristics of the rockmass as determined by geology as well as the explosive energy, the partition of this energy, the actual amount of energy transmitted to the rockmass, the blast geometry and the detonation sequence. This paper reviews studies of the influence of geology on blast fragmentation, particularly structure, i.e. the in situ or inherent fragmentation arising from rock discontinuities. Prior structural studies have mainly been limited to comparing equivalent diameters of the in situ blocks with the size distributions of the blasted material. No criteria exist to integrate structure into blast design. This paper reviews on-going studies of the blasted fragment shape and size observed in different rockmasses aimed at analyzing geological control over blasting. Digital photoanalysis was applied {o measure size and shape distributions, to correlate results with block size distributions and shape parameters of the inherent fragmentation. An integrated and comprehensive fragmentation assessment procedure which accounts for geological control is proposed. The potential of this research is to provide a greater understanding of the true contribution of explosives to fragmentation, the effects of fragment shape on system productivity and the reduction of blast-induced damage.

Jan 1, 1994

By C. Desmeules

"Carbon addition in the oxide pelletizing process is a big concern at the Sidbec-Normines pelletizing plant since 1976.Laboratory pot-grate testing carried out before the initial start-up of the Port-Cartier plant indicated that the nominal pelletizing grate capacity could be increased by fifteen per cent with a suitable carbon addition. Also an improved induration cycle offered the possibility of a significant energy reduction within the process with no adverse effect on pellet quality. A one-month plant scale program duplicated the lab test results and confirmed the anticipated cost saving by using these techniques. Since March 1980, Sidbec-Normines used coke addition as a current operation.This paper reviews briefly earlier laboratory and in-plant test work carried out to investigate the effects of adding carbon materials to the Fire Lake hematite concentrate, and presents operation techniques and plant results of carbon addition in the Port -Cattier pellet plant.IntroductionThe Sidbec-Normines pelletizing plant at Port-Cartier, Quebec, is designed to produce six million ton s per year of oxide pellet s. It is a Dravo-built two-line plant; one line to produce three million s tons per year of blast furnace grade pellets averaging 5.5 per cent silica, and another line of three million ton s to produce direct reduction grade pellets of about 2.0 percent silica.The laboratory pot-grate test program was conducted in 1977 at the British Steel Corporation Research Laboratories in England, with the assistance of J .E. Appleby, consultant to British Steel Corporation (overseas services) Limited.The purpose of that test program was to determine the optimum energy saving cycle and to study the physical and metallurgical effects on blast furnace and direct reduction pellets."

Jan 1, 1983

By I. H. Warren

"An analysis of form-coking processes is presented in terms-of their fundamental mode of operation and their relationship to other coking processes. Their possible future role in cokemaking is assessed. IntroductionAny consideration of prospects and possibilities for form coking must commence with the iron and steel industries-their likely future growth pattern on a world and regional basis and the potential direction of future developments in iron and steelmaking technology.From the numerous estimates which have been made of the future consumption of steel, it would appear that a growth rate of 3lllo between now and the year 2000 is likely. Radical changes in steel making technology are unlikely to be commercially adopted on any significant scale during the next twenty years . However, widespread commercialization inter alia of continuous casting and direct reduction, growth of electric furnace steelmaking and a decrease in coke rates will all contribute to a growth rate for metallurgical coke that certainly will be less than that of steel."

Jan 1, 1980

By R. D. Studer

"The Snow Lake massive sulphide deposits are hosted by Aphebian volcanic rocks of the Flin Flon - Snow Lake greenstone belt, which in this area were deformed and metamorphosed to the amphibolite facies during the Hudsonian orogeny. All the known deposits occur in felsic rocks a short distance below the contact with an overlying mafic rock unit.The Stall Lake copper deposit occurs close to the top of an explosive felsic volcanic sequence. Rocks stratigraphically underlying the deposit have been hydrothermally altered by the mineralizing fluids. The sulphides were probably deposited from submarine volcanic vent(s) on the flanks of a felsic dome. The ore has been tightly folded, flattened and elongated parallel to the northerly trending lineation of the surrounding rocks during the several periods of deformation. Strike lengths of the lenses range from 60 to 300 feet and plunge-to-strike ratios are as much as 15:1.Ore lenses I to 4 typically consist of massive coarse-grained pyrrhotite, chalcopyrite and pyrite. A stratigraphically higher lens differs in that it contains fine-grained pyrite and chalcopyrite, with an increase in sphalerite toward its hanging wall. The No.4 orebody has a distinct footwall alteration zone characterized by brecciation and abundant chlorite-staurolite- garnet schist, with minor kyanite, anthophyllite, cordierite and anhydrite, as well as sulphide minerals. Chemically, the alteration zone is distinguished from the unaltered felsic rocks by Na20 depletion and Mg-Fe enrichment"

Jan 1, 1982

By L. Nutter, J. Clancy

"Barite is used extensively by the oil and gas well-drilling industry as a weighting agent. It is particularly well suited for drilling mud because of its qualities; it is non-abrasive, heavy, virtually inert chemically, easy to handle and inexpensive compared to other available heavy materials. Increased deep well drilling in Western Canada, and especially in the Arctic regions, could dramatically affect the demand for barite through this decade. Known deposits in northeast British Columbia are possible sources of incremental barite supplies, should the situation develop.IntroductionThe purpose of this report is to examine the opportunities for expanding barite production in British Columbia. Of primary interest will be the relationship between the projected future levels of production and consumption of barite in Western Canada and the extent to which increased domestic production could replace the need for imports in filling any expected supply shortages.After a brief overview of the nature and uses of barite and some of the relevant features of the barite supply industry, the discussion will turn to the supply gap in the Canadian market and the possibilities for import substitution.OverviewBarite is an industrial mineral which is used in large quantities by the oil and gas well-drilling industry. It is often an important component of drilling mud, a fluid circulated continuously in the well during the drilling process to lubricate and cool the drilling apparatus and to contain the high oil and gas pressures found at depth. Barite (BaSO4) is particularly well suited as a weighting agent for drilling mud because it is a heavy (specific gravity to 4.5) inert mineral which is inexpensive in relation to other materials having a high specific gravity. In the on-site use of drilling mud, ground barite is combined with numerous other solid ingredients and chemicals in the form of a slurry. Other advantages of barite include cleanliness, ease in handling and its non-abrasive character (hardness of 3-3.5)."

Jan 1, 1982

By Robert B. Parsons

"There is a widespread concern that certain of Finance Minister Michael Wilson's Tax Reform proposals will likely lead to a significant decline in flow through funding after 1988. This does not bode well for the junior exploration sector, which relies heavily on flow-through to finance exploration programs. The exploration industry is actively pursuing various solutions to the problems posed by Tax Reform, in order to ensure that flow-through has a future.IntroductionWhile the proposals contained in Finance Minister Michael Wilson's Tax Reform White Paper may not be as far-reaching as some people had expected, nevertheless the combination of the existing tax rules and proposed new rules offers sufficient complexity to keep pencils sharpened for many months. After having had an opportunity to study Tax Reform since June 18, 1987, the sharpened pencils are suggesting that the White Paper is not without its shortcomings and pitfalls. Insofar as the mineral exploration industry is affected, there is widespread concern that adoption of certain Tax Reform proposals could spell near disaster for mineral exploration in Canada. More specifically, there seems to be a consensus among the industry, as well as some federal and provincial government officials, that the announced phase-out of the ""mining exploration depletion allowance"" (MEDA) would reduce the appeal of flow-through shares to the point where only a fraction of exploration funding would be financed in the future by flow-through."

Jan 1, 1987

By Ron Jessulat

"IntroductionBrunswick Mining and Smelting Corp. Ltd. is a IO 500 tid base metal producer. Development is carried out by Jarvis Clark MJM-21 3-boom development jumbos, using Tamrock E400, 410 and 550 pneumatic drills. Typical drift size is 13 ft by 18 ft with a 12-ft advance per round. Blast holes are 1 ½ in. in diameter while reamed holes are 3 in. in diameter. AN/FO is the principal blasting agent, being loaded by C-I-L model60R intermediate loader. The detonators are NONELS and DETINELS. Sulphide dust explosions occur during blasting when dusts from certain minerals such as pyrite and pyrrhotite are ignited by name from the detonating shots. The result is a secondary unwanted explosion with a characteristic shock wave and name front that are very destructive to mine services such as ventilation ducting, electrical cable, and ventilation control doors.A typical reaction in the Brunswick orebody occurs according to the chemical formula:4FeS 2 + IIOs-2Fe2O3 + 8SO2 + 3458--(Enright , 1988)The hematite (FeO3) is deposited as a red dust in the blast area while the toxic sulphur dioxide gas (S00 contaminates the underground workings . The presence of S02 gas disrupts production until it is purged from the area by the mine ventilation system or dissipates slowly in those areas where the vent ducting has been melted by the name front or torn down by the shock wave.Sulphide dust explosions exact a high economic toll. Direct costs in damaged materials and wages are probably exceeded by the value of lost production and disruption to the mining cycle. In addition, the health and safety concerns associated with sulphide dust explosions cannot be ignored."

Jan 1, 1993

By Tim Watson

Andacollo Hypogene Project ?Overview Project description: Sulphide copper concentrator Throughput:55,000 tpd Location: Approximately 50 km from La Serena Elevation: Approximately 1,000 m ASL Start feasibility study: July 2005 Start of construction: May 2007 Construction completion: December 2009 Final cost(1,2,3):435 Million US $ (1) Excludes third party costs, 220 kV power line (2) Cost is based on a Chilean Peso to US Dollar foreign exchange rate of 535 to 1 (3) Does not include US$40.3 million for the Elqui River Pipeline Project or US$8.0 million for the stock pile cover

May 1, 2010

By J. Boulton

"Nuclear energy is an established and proven energy source. Today, CANDU-PHW nuclear-electric generating stations produce over one third of Ontario's total electrical supply: safely and economically. In many parts of Canada, where economic hydro resources do not exist or are fully developed, coal and nuclear energy are the only alternatives for future large-scale electrical generating capacity.Recent analyses have suggested that, in the f ace of increasing energy demands and decreasing reserves of hydrocarbon fuels, Canada must depend on electricity to provide an expanded fraction of its energy budget. Nuclear energy is likely to play an increasing role in the generation of electricity; there are also potential applications as a supplier of process heat in industry and in the in-situ recovery of bitumen fro m tar sands.The future supply of nuclear fuel, reactor safety and radioactive waste management are briefly discussed. In each case, the benefits to be gained from a controlled expansion in the use of nuclear energy outweigh any uncertainties which may exist."

Jan 1, 1981

By W. G. Brown

"Review of prototype testing of two types of three-phase, argon stabilized reactor/furnace indicates specialized advantages for both, as compared with existing metallurgical furnace technology. They are: the direct-arc, plasma-torch furnace (Knipp); and the indirect, plasma extended-arc reactor (PEAR), developed at the University of Toronto.IntroductionA unique type of three-phase AC, plasma extended-arc reactor, (PEAR), shown in Figure la with gravity feed, has been undergoing development at the University of Toronto, during the past fifteen years: argon gas, introduced axially through drilled-holes in ordinary graphite electrodes, increases the length of indirect arcing and improves electrical stability while decreasing electrode consumption as compared with the performance of AC electric arc furnaces (EAF 's). Meanwhile and independently, a three-phase, transferred arc plasma furnace (Fig. 1b) has been developed by the Krupp Research Institute in Germany, using argon-stabilized, water- cooled plasma-torches with thoriated tungsten electrodes.Accordingly, the two types of furnace are similar as to both three phase and stabilized operation, but otherwise they differ in several respects, ranging from indirect versus direct-arcing to principal intended application and current state of practical development. Between them they raise questions: (I) of their present or fore seeable economics in comparison with existing processes they are intended to replace , (see Heinke and Neuschutz, 1986, for a review of the merit s of AC and DC plasma-torch furnaces); and (2) of the state of development and accessibility of their plasma theory-in-common."

Jan 1, 1991

By J. Erik Scheel

Overview ? About Hard Creek Nickel ? Turnagain property ? Proposed power line ? Recent Preliminary Assessment ? Favourable economics ? Property Geology ? Mineralization and metallurgical characteristics of major lithologies ? Development of the acNi (ammonimum-citrate H2O2) technique ? Overview of necessary steps ? Results of the technique ? Conclusions

May 1, 2008

By J. A. Pigott, R J. Hall

The International Nickel Company of Canada, Limited operates five underground mines on the rim of the Sudbury Basin in the northern part of the Province of Ontario. Four of the mines, the Frood-Stobie, Creigh-ton, Murray and Garson, are located on the south range of the basin with-in a radius of IO miles of the centre of the city of Sudbury. The fifth mine, Levack, is on the north range about 30 miles northwest of the city. The ores are mined primarily for nickel and copper, and the principal minerals are pentlandite, chalcopyrite and pyrrhotite. In 1960 the total ore production was in excess of 16 mil-lion tons, 95 per cent of which was produced from the five underground mines and the balance from the Frood-Stobie Open Pit. Mining at this open pit is nearing completion and underground production has been expanded to replace the open pit tonnage.

Jan 1, 1961

By K. H. Concannon, K. I. Hindle

"The use of simulation modeling in the primary metals industry (including mining, smelting, and metals processing) is expanding as significant cost-benefits can be realized by companies employing capital intensive processes. The economic scale and complexity of operations found in this industry is well-suited to applications using this ""what-if' computer modeling technique, ranging from proof-of-concept projects to testing facility design or configuration, and determining resource requirements. More recently this technique is being used to support on-going planning and scheduling for operations using the simulation as the engine to derive the best schedule. With increased computer processing capability, deterministic models are now being developed to capture the workings of a production system or conversion process, allowing real-time monitoring and scheduling of these operations. This paper presents a sample of some recent discrete-event simulation modeling applications that demonstrate the capability and benefits of this technique in the primary metals industry. These include the use of simulation to support the long-range planning of underground mining operations; the modeling of a metals supply chain network that employs a multi-modal distribution system; the scheduling of a metals coil finishing process using a deterministic simulation model; and a more detailed description of the use of simulation to model furnace and converter aisle activities within a smelter operation in Northern Canada."

Jan 1, 2007

By D. R. Boyle

"The Murray Brook precious metal (Au, Ag) gossan deposit is one of nine supergene mineral deposits that have developed over polymetallic massive sulfide deposits in the Bathurst Camp of New Brunswick. Reserves consist of 1.9 Mt of gossan containing 1.53 g/t Au and 65.9 g/t Ag. The supergene zone at Murray Brook consists of six distinct units: a) altered massive sulfide, b) pyrite-quartz sand, c) massive sulfide gossan, d) disseminated sulfide gossan, e) ferruginized wallrock, and f) leached bedrock. The massive sulfide gossan constitutes the main body of economic mineralization and consists of goethite, primary quartz, secondary amorphous silica, K-Fe-Pb-As- Sb-Ag hydrated sulfate and oxide minerals (beudantite, plumbojarosite, jarosite, bindheimite, scorodite), trace cinnabar, and cassiterite of primary origin. The order of stability of sulfide minerals during oxidation was pyrite _ arsenopyrite _ galena _ Bi-Sb sulfosalts _ chalcopyrite _ tetrahedrite group _ sphalerite.Two mass balance techniques (isovolumetric and conservative element) indicate elemental depletion in gossan relative to primary ore in the order: S>Cd=Zn>Cu=Mn>Na=Ca>Fe=Al=V> Mg= K=Se=Hg>Pb>Ti>Ag>Mo=P>Ba; and enrichment in the order Au>As>Sb>Si>Bi. Tin, as cassiterite, is conservative.Mineralogic and paleomagnetic data suggest that the gossan deposit formed under a warm temperate climate throughout the Pliocene. The rate of oxidation and the compositional nature of the ore was significantly influenced by: a) the position of the primary sulfide zone in a downward moving hydrological system, b) primary sulfide composition and zonation that promoted the development of a strong electrochemical oxidation system, and c) pronounced intercalation of carbonate and sphalerite mineralization in sulfide zones, which promoted rapid development of secondary porosity, permeability and downward flow of oxygenated groundwater.During progressive oxidation and physico-chemical erosion of the gossan zone, Au was transported downward in groundwaters, probably as a Auo colloid complex, to be concentrated in the lower horizons of the gossan profile. The precipitation of Au was greatly increased in the pyrite/arsenopyrite zones. Gold concentration was multi-cyclic with continual dissolution and nucleation of the metal until final concentration in the void structures of the gossan. Leaching experiments and microprobe analyses indicate that Au is present in the gossan as submicron composite sols of Au-Ag-silica."

Jan 1, 1995

By M. E. Sirkka

"INTRODUCTIONInco Ltd. has ten operating mines in the Sudbury district. Over the last ten years mining methods have changed at Inco with special emphasis on the introduction of bulk mining replacing conventional mechanized cut-and-f ill and undercut-and-fill methods. At the same time, the technology and size of LH D equipment has also progressed to meet the demands of bulk mining. This paper will concentrate on various aspects of the introduction and operation of electric LHD equipment a t Inco Limited, Ontario Division. BackgroundInco Limited received its first electric 2 cu. yd capacity LHD in July 1975 at Creighton Mine. The unit was tested pulling shrinkage stope muck and then was moved to a mechanized cut and- fill complex on 6600 Level. The electric scooptram received quick acceptance from the operators, due to its quiet operation and low heat generation, in a relatively hot operating environment. Although there are only two of these units operating a t present, this initial favourable experience, both in cost and efficiency, led to the development and purchase of electric scooptrams of the 5 cu. yd size. There are currently eleven 5 cu . yd electric LHDs in operation.The most recent development a t Inco is the move to yet larger electric LHDs in the 8 cu. yd size. The first electric ""Eight"" has now been in operation at Copper Cliff South Mine for over a year. This unit has the distinction of being the first one of its kind in service in North America. At the time of writing, there were ten 8 cu. yd electric ma chines operating in Inco's Ontario Division Mines, with three on order."

Jan 1, 1989

By C. H. Bertoni

"The Superior Province of the Canadian Shield is the largest gold producing area within Archean greenstone rocks in the world, with total production of over 140 million ounces of gold. One hundred and fifty-five mines have individually produced more than 8,000 ounces, although only a relatively limited number of deposits (33) produced more than one million ounces of gold. The output from these 33 deposits accounts, however, for 85% of total gold production. The majority of grades (68%) ranges between 0.10 and 0.30 ounce per ton, and there is no linear relationship between grade and tonnage.Development of new gold mines reflects the history of gold prices. However, the response to the latest increase in gold prices was not as marked. It is concluded that gold deposits are becoming increasingly more difficult to find and new exploration techniques are urgently required.IntroductionWith most of its production coming out of the Superior Province, the Canadian Shield is the largest producer of gold from Archean greenstone rock s in the world. In total gold production, the Superior Province is surpassed only by the paleo-placers of Witwatersrand and the placers of the USSR (Anhaeusser, 1976). There has been no attempt so far to compile the historical production of the Province as a whole in a single document. The aim of this work is to fill this gap, not only for the convenience of having a complete list of gold producers, but, more importantly, as a basis on which to study the tonnage and grade characteristics of these deposits."

Jan 1, 1983

By J. Lebl, S. Bharti, D. J. Cornett

"This paper presents the design and application of blasthole mining to an area at Strathcona Mine previously employing post pillar cut-and-fill. Extensive mining in the area had led to gradually deteriorating ground conditions and post pillar stoping was no longer considered acceptable. Alternative methods had to be investigated.Conventional methods for mining in poor ground were rejected because of the high cost. Blasthole mining was selected because iI offered good productivity and safety with acceptable costs. The design of this approach involved field investigations and the use of numerical modelling to simulate the different blasthole options and their impact on ground stability. The blasthole design incorporated reinforcement with cablebolts, use of a radio-controlled remote LHD unit, large-diameter holes, blast design and wall control. Potentially unstable areas were outlined during mining with ground monitoring instruments and the results used to modify mining plans during the production phase.IntroductionIn underground metal mines there is a need to improve safety and productivity and lower mining costs in order to maintain reasonable rates of return on investment. This requires the application of good engineering design to both mine planning and ground control in order to optimize production and costs and to forecast potential problems during mining. The task becomes more important when extensive mining leads to gradually deteriorating ground conditions, making existing mining methods and techniques no longer acceptable from a safety point of view. Alternative mining methods must, however, be sufficiently productive to ensure profitability. This paper presents an example of the engineering design and operating approach used by Falconbridge in dealing with such a situation at Strathcona Mine."

Jan 1, 1983

By D. R. Boyle

"Abstract - The Murray Brook precious metal (Au, Ag) gossan deposit is one of nine supergene mineral deposits that have developed over polymetallic massive sulfide deposits in the Bathurst Camp of New Brunswick. Reserves consist of 1.9 Mt of gossan containing 1.53 g/t Au and 65.9 g/t Ag. The supergene zone at Murray Brook consists of six distinct units: a) altered massive sulfide, b) pyrite-quartz sand, c) massive sulfide gossan, d) disseminated sulfide gossan, e) ferruginized wallrock, and f) leached bedrock. The massive sulfide gossan constitutes the main body of economic mineralization and consists of goethite, primary quartz, secondary amorphous silica, K-Fe-Pb-As- Sb-Ag hydrated sulfate and oxide minerals (beudantite, plumbojarosite, jarosite, bindheimite, scorodite), trace cinnabar, and cassiterite of primary origin. The order of stability of sulfide minerals during oxidation was pyrite > arsenopyrite > galena > Bi-Sb sulfosalts > chalcopyrite > tetrahedrite group > sphalerite.Two mass balance techniques (isovolumetric and conservative element) indicate elemental depletion in gossan relative to primary ore in the order: S>Cd=Zn>Cu=Mn>Na=Ca>Fe=Al=V> Mg= K=Se=Hg>Pb>Ti>Ag>Mo=P>Ba; and enrichment in the order Au>As>Sb>Si>Bi. Tin, as cassiterite, is conservative.Mineralogic and paleomagnetic data suggest that the gossan deposit formed under a warm temperate climate throughout the Pliocene. The rate of oxidation and the compositional nature of the ore was significantly influenced by: a) the position of the primary sulfide zone in a downward moving hydrological system, b) primary sulfide composition and zonation that promoted the development of a strong electrochemical oxidation system, and c) pronounced intercalation of carbonate and sphalerite mineralization in sulfide zones, which promoted rapid development of secondary porosity, permeability and downward flow of oxygenated groundwater.During progressive oxidation and physico-chemical erosion of the gossan zone, Au was trans- ported downward in groundwaters, probably as a Auo colloid complex, to be concentrated in the lower horizons of the gossan profile. The precipitation of Au was greatly increased in the pyrite/arsenopyrite zones. Gold concentration was multi-cyclic with continual dissolution and nucleation of the metal until final concentration in the void structures of the gossan. Leaching experiments and microprobe analyses indicate that Au is present in the gossan as submicron composite sols of Au-Ag-silica."

Jan 1, 1995