Search Documents

Subsurface information from the "Upper Coal Measures" of the Sydney Basin is interpreted by means of structure contour maps, isopach maps and geological cross- sections. Particular reference is made to recent coal drilling operations by the New South Wales Department of Mines. The study is restricted to the onshore portion of the Sydney Basin.

Jan 1, 1972

By Chang TS, Suzuki K, Go H, Nakamura S, Kuwano Y

In 1979, a test operation of an experimental blast furnace was carried out to investigate the behavior of a sort of formed coke, which was used safely by 30% of total coke charge in No.2 B.F., Sakai works, NSC, in 1975". The Mashec-type formed coke of 60 x 60 x 40 mm in dimension was crushed and screened so that it had the same size range (1011,20 mm) as ordinary coke used in the base operation. Preceding to the operation, some experiments on the properties of the formed coke and the effects of crushing on them were performed.

Jan 1, 1981

By J C. Diaz, C R. Scherpenisse

Blasting represents one of the most relevant unit operations in the process of mineral extraction. The final objective of this operation is that of obtaining an adequate final fragment size distribution such that the combined costs of drilling, blasting, excavation and transport, and crushing/grinding, are minimised, while at the same time producing the minimum possible level of damage to the surrounding rock mass. The strong influence that drilling and blasting has over the subsequent processes involved in the operational cycle makes it imminently desirable to have access to experience and technology which make possible the evaluation and optimisation of this unit operation. The correct use of vibration monitoring techniques offers a number of benefits in terms of their ability to examine any blasting process in detail. In effect, the measurement of particle velocity levels that result from the detonation of each explosive charge offers a means by which it is possible to measure relative efficiency of each charge, interactions (productive and counterproductive) between adjacent charges, and a definitive indication of general performance of any given blast design and its implementation. In this way the monitoring of blast vibrations in rock due to the blast event, can be used as a diagnostic tool, given that the correct interpretation of the vibration traces allows the determination of the level of interaction between the design and operational variables of the blast event. This makes it possible to evaluate, for example, the presence of out of sequence detonations, statistical scatter in the detonation times of pyrotechnic delay detonators, deficient detonation of charges, instantaneous detonation of charges and sympathetic detonation of charges, as well as the general of vibration levels in terms of peak particle velocity, acceleration, and displacement. Another important use of such data is in the construction of a database relating vibration levels to charge weight, hole diameter, and distance, for any given rock type, enables the calibration of predictive vibration models which in turn make it possible to predict the damaging effects of blasting. Knowledge of both the vibration levels induced, combined with quantitative measures of the geomechanical competence of a rock mass make it possible to estimate the probability of producing blast induced damage. The high levels of vibration generated by some blast events may damage the rock mass, producing new fractures or extending and dilating existing fractures. The vibration in this context may be considered as a dynamic stress provoking strain in the rock mass. This paper describes the application of the vibration monitoring technique, particularly in the underground mining environment, and its importance in diagnosis, modelling, control, and optimisation of the development blasting process. The potential of the technique is assessed in the context of achieving substantial techno-economic improvements development blasting results, increasing output whilst minimising the operational costs of the mining process.

Jan 1, 1999

By Barnes R. G, Agostini A, Lewis P. C

The Mineral Resources Audit is a five-year Program established to produce a comprehensive and objective assessment of the mineral resources of New South Wales, including prospective resources. The goals of the Program are to improve planning and land use decision-making; attract exploration and minerals related investment; help the Department to identify and fill gaps in knowledge; and develop methods to identify and quantify resource potential and prospectivity. To achieve the goals of the Audit it is necessary to assemble and enhance a large amount of information and it is necessary to spatially analyse this information using computer-based Geographic Information Systems (GIS) which allow the collection, storage, transformation and display of large quantities of spatial data. An extensive range of both map-based and textual data can be employed in spatial analysis and resources and geoscience modelling. In order to use this information, data sets have to be corrected and standardised. Many data sets need to be classified. An objective of the Audit Program is the spatial analysis of the State, region-by-region, and the release of cleaned-up multiple digital data sets as packages which include upgraded mineral deposit information, 'seamless' geological map layers showing lithology, structures and stratigraphy, and processed and classified geophysical map layers. These regional packages are important reference sets for the mineral resources industry and will assist delineation of regional exploration targets.

Jan 1, 1995

By James S. E

Financial risk of environmental problems is the key to many important business decisions within the mining industry. Massive uncertainty makes it difficult to choose a strategy for managing environmental problems to reduce corporate financial exposure to environmental impairment. A correct and practical method exists to clarify the risks and help make decisions. A case study on an insurance problem illustrates the method.The approach used is to translate existing data on environmental problems into probabilistic expressions of financial risk, and organise the expressions to reveal alternative solution strategies for the insurance problem.

Jan 1, 1993

By D Lau

Traditionally X-ray diffraction (XRD) has not been significantly used by the cultural heritage sector, as the most commonly used technique, X-ray powder diffraction (XRPD), requires sample removal from the artwork or artefact, followed by grinding of the sample to a fine powder. With the development of micro-X-ray diffraction (micro-XRD) and other associated advances, non-destructive, in situ analysis of crystalline pigments on micro-areas of paintings and artefacts has become possible. This is illustrated with the application of this technique to the in situ analysis of propriety paints, paint cross-sections and small paintings. However, workers have noted that XRD can be insufficiently sensitive with pigment mixtures, due to matrix effects. This study obtained X-ray diffractograms of 17 single pigment preparations and determined relative amounts of crystalline content. The purity of single pigments was compared with Joint Committee on Powder Diffraction Standards (JCPDS) database diffractograms. The impact of pigments with high X-ray absorption coefficients on the detection limits of pigments with low X-ray absorption coefficients was further investigated by building on work done with the chromium oxide-zinc oxide series with the preparation of a second series of binary mixtures of zinc oxide (which has a high absorption coefficient and is almost fully crystalline) and ultramarine blue, which has a lower absorption coefficient but which is more crystalline. Semi-quantitative analysis, where baseline and absorption factor corrections are made, confirm detection limits as low as five per cent for chromium oxide and ultramarine blue when in a binary matrix with zinc oxide. However, this type of analysis is very time consuming. So in order to theoretically simulate issues that will be encountered with binary pigment mixtures, the single phase diffractograms were used to theoretically investigate the matrix effects of the three white pigments with the various coloured pigments. This illustrated that detection limits can be as low as five per cent or in non-ideal conditions, such as with partial peak clashes or where there are large differences in relative peak intensity, as high as 50 per cent. These results have significant implications for the analysis of painted surfaces on artworks or artefacts. It has been demonstrated that ideally this method is more suited to the investigation of surfaces where there is minimal mixing of pigments or where there is not a significant difference between the absorption coefficients of the mixed pigments.

Jan 1, 2008

By Wilkinson RDB, Van Der Meer FP

In order to overcome the statistical limitations imposed by the need to recover density tracers by hand, magnetic density tracers were developed to determine the efficiency of dense medium separators treating porous materials. The tracers were manufactured by extrusion of polypropylene ferrosilicon mixtures and subsequently coated with a distinctive paint to allow hand sorting according to density. Fifteen tracer batches were manufactured in the range 1.61 - 1.94 g/cm3. The tracer densities were determined by a hydrostatic method. The tracer method was applied to the dense medium separation of a Moroccan oil shale in a pilot scale Dyna Whirlpool separator. For each test, about 20,000 tracers were added with the plant feed and subsequently recovered from the products with a dry low intensity magnetic separator. The Tromp curve determined by conventional heavy liquid analysis was displaced towards lower densities compared with that determined by tracers, indicating that the porous shale particles absorb heavy liquid. It is concluded that for porous materials like oil shale and coal, the tracer method gives the most accurate results. In pilot scale testwork the tracer method is also much faster than the conventional heavy liquid analysis, as rather large samples have to be processed by the latter method to ensure Representativeness.

Jan 1, 1987

By Veal FL

Technological changes in Portland cement manufacturing during past years have reflected changes in the economics and availability of various types of fuel such as coal, fuel oil and natural gas. The industry consumes a sig- nificant quantity of both thermal and electric- al energy. The nature of the process and its chemical constraints does however permit the use of comparatively low grade fuels such as high ash coal and high sulphur oil. In striving for increased daily kiln outputs and conservation of energy, there is a worldwide trend towards the use of dry process plants. Wet process kilns of about 2 500 tonnes per day assume massive component sizes which present difficulties in manufacture, and transport to plant sites. Large capacity dry process units in excess of 8 000 tonnes per day are now in operation using precalcination techniques in which part of the fuel is introduced in the static preheater section ahead of the kiln while the balance is added to the kiln in a conventional manner. This technique has virtually doubled the potential output of any given single kiln.

Jan 1, 1976

By Lorenzen L

In South Africa, as in many other countries, the young engineering graduate is promoted quite soon to a management position where he uses less technical skills and more people-oriented skills. In the standard undergraduate curriculum for engineering, little attention is paid to the non-technical issues of the profession. An undergraduate course in management techniques cannot be a substitute for a MBA or Masters degree in engineering management, but can at least create an awareness of the practical problems facing the engineering manager. The aim of this paper is to provide an outline of such a course structure at the University of Stellenbosch. A survey is also presented on management training in the South African and Australian mineral industries. Feedback from students and graduates indicates that the fresh graduate does not fully appreciate the value of such a course until he/she achieves a position of responsibility after two or three years. Nevertheless, the management course appears to be successful in widening the perspectives of the engineer. As explained frequently in management journals, the technically oriented person (the engineer) has a convergent thought pattern, which could be in conflict with the more divergent thought pattern of the top, personnel or marketing manager. It becomes increasingly imperative for the young minerals engineer to be externally oriented instead of the traditional internal focus of engineering. The engineer should not only be aware of environmental issues in the technical design and operation of plants, but should also understand the inter-relationship between public relations, political pressures and environmental perceptions vis-d-vis technical facts.

Jan 1, 1993

By Dimitrakopoulos R

Ore textures in base metal deposits are an important factor in the liberation of the economic components of the ore, metal recovery and reagent consumption during beneficiation. Optimising the mine profit requires knowing the relationship between ore texture and mineral processing behaviour, and the ability to predict the metal grade and the ore texture at a suitable scale. A new method that generates distributions of mesotextures for any mining block size or shape is proposed and includes: I . establishing a protocol for acquiring mesotexture data: 2. measuring the mesotexture spatial correlations using a multi-texture variogram; 3. generating multiple simulations of mesotextures; and 4. upscaling the simulations to generate the expected mining block/stope mesotexture distributions. Models of the ore textures built using the proposed methodology can be used to assess resources and reserves, enhance ore/waste discrimination and predict the metallurgical behaviour of parcels of ore.

Jan 1, 1997

By I Brunton

Blast fragmentation can have a significant impact on the profitability of a mine. An optimum run of mine (ROM) size distribution is required to maximise the performance of downstream processes. If this fragmentation size distribution can be modelled and controlled, the operation will have made a significant advancement towards improving its performance. Blast fragmentation modelling is an important step in Mine to MillTM optimisation. It allows the estimation of blast fragmentation distributions for a number of different rock mass, blast geometry, and explosive parameters. These distributions can then be modelled in downstream mining and milling processes to determine the optimum blast design. When a blast hole is detonated rock breakage occurs in two different stress regions û compressive and tensile. In the first region, compressive stress waves form a æcrushed zoneÆ directly adjacent to the blast hole. The second region, termed the æcracked zoneÆ, occurs outside the crush one. The widely used Kuz-Ram model does not recognise these two blast regions. In the Kuz-Ram model the mean fragment size from the blast is approximated and is then used to estimate the remaining size distribution. Experience has shown that this model predicts the coarse end reasonably accurately, but it can significantly underestimate the amount of fines generated. As part of the Australian Mineral Industries Research Association (AMIRA) P483A Mine to MillTM project, the Two-Component Model (TCM) and Crush Zone Model (CZM), developed by the Julius Kruttschnitt Mineral Research Centre (JKMRC), were compared and evaluated to measured ROM fragmentation distributions. An important criteria for this comparison was the variation of model results from measured ROM in the fine to intermediate section (1 mm to 100 mm) of the fragmentation curve. This region of the distribution is important for Mine to MillTM optimisation. The comparison of modelled and Split ROM fragmentation distributions has been conducted in harder ores (UCS greater than 80 MPa). Further work involves modelling softer ores. The comparisons will be continued with future site surveys to increase confidence in the comparison of the CZM and TCM to Split results. Stochastic fragmentation modelling will then be conducted to take into account variation of input parameters. A window of possible fragmentation distributions can be compared to those obtained by Split. Following this work, an improved fragmentation model will be developed in response to these findings.

Jan 1, 2001

By D Thornton

Geologists use large data sets and spend many hours and much computing time modelling the distribution of minerals throughout a rock mass. Significant investments in drilling, assaying and quality assurance and quality control (QA/QC) are made before sophisticated geostatistical techniques are applied to the collected data. A large amount of research has been done in this field such that the ore control model is a reasonably accurate reflection of the mineral that is actually in the ground. However, after all this effort, the mining engineers then work just as diligently to blast the in situ rock mass to a particle size that can be efficiently handled and further reduced by downstream comminution processes. In open cut mines, this invariably requires large amounts of explosive energy that displaces the ore boundaries from where the geologists originally defined them. Failure to accurately account for blast movement will result in misclassification, whether that is ore to waste; low grade to high grade; sulfide to oxide; or other contaminates û collectively referred to as ore loss and dilution. The financial consequence of getting this wrong is substantial and not well quantified. This diminishes all of the good geological QA/QC done in defining the ore. This paper discusses various technologies used to physically measure blast-induced orebody movement and the difficulties in modelling this with a purely theoretical approach. Rock mass structure, blast energy, design and timing contours all have significant and interrelated effects on blast movement vectors. Measured blast movement has a large variance due to the uncertainly of many of the controlling parameters û arguably dominated by the heterogeneous nature of the rock mass. Although there have been significant advances in blast movement modelling capability in recent years, this unpredictable blast movement limits their use in the context of production ore control. Certainly, without physical field measurements, accurate predictions of movement are near impossible.Limitations of traditional surface markers in determining three-dimensional (3D) blast movement within the orebody are also reviewed, and advancements in accurately measuring these vectors within blasted ore discussed

Sep 26, 2011

By Baguley PJ, Napier-Munn TJ

This paper presents preliminary resu]ts from field studies which were conducted to establish, among other things. the influence of medium viscosity on the partitioning behaviour of dense medium cyclones and drums in mineral applications, using frrrosilicon- ba_sed media. The medium vicoosit.y- was measured on-line, and partitioning behaviour was determined using ore sampling and density t r acers . The results demonstrate that viscosity is an important. operating variable, influencing ,eparat.ing density and efficiency under certain conditions. The implication is that metallurgical performance can be optimised by manipulating viscosity, either by appropriate selection of medium' characteristics or by automatic alarming and/or "ontroi using signals from the on- 1. i ne viscometer.

Jan 1, 1987

By Irving R. C

THE objective of the iron smelter is naturally the production of high quality iron at the lowest practicable cost. To enable this, large tonnages are put through the blast furnace, and, at the same time, the quality of the iron must be under definite control.The modern blast furnace enables these objectives to be attained. The description whieh follows sets out the general details of construction of such furnaces, and the operation at thc Broken Hill Proprietary Company's blast furnaces at Newcastle, New South Wales.The occurence of iron in many forms is so well known as to need no description. Modern civilisation may be said to be built on a foundation of iron, and, today, the production of iron and steel has beeome one of the world's industries.A short historical introduction will serve to show the evolution of the processes and apparatus since iron production assumed importance.There is no definite date fixed as to when iron was first made, or by what means it was first discovered. Perhaps prehistoric man threw iron bearing stone on to his fire, and these became reduced, Ieaving a soft metal behind, or more probably the first iron was of meteoric origin.There is evidence, however, to prove that it has been known for a period of 6000 years. Iron has been found in the Pyramids and its use was known to the early Eqyptians and later to the Hebrews, Assyrians, Greeks and Chinese. Following the Greeks, the Romans excelled in its extraction and uses in the manufacture of their instruments of war, and to this fact can largely be attributed the success of their many wars of conquest. As the Romans overran the rest of the then known world they carried the art with...

Jan 1, 1930

By Vanderberg B

A 3D, PC based computer program is currently under development by Blasting Analysis International, Inc., to analyze the kinetics of full scale blasts with two or more high-speed motion picture cameras. Todays common approach of utilizing only a single camera system can, in some cases, lead to great errors and erroneous conclusions when motion is assumed to be in a predefined plane of motion. CMe phrase, "What you see is what you get, it no longer true in 3D."). This is especially true in blasting environments which exhibit complex and/or predominant structural geology. The 3D system eliminates this problem, and includes automatic corrections for vertical and horizontal camera optic axis orientation, dimensional controls, lens distortion, field set-ups, projection imaging and digitized inputs. The only information required is the surveyed or known coordinates of at least six non coplanar points in the field of view. Motitn from each camera view is then digitized, transformed through a direct linear transformation, and processed with the 3D software, which also automatically time matches the data, even when the high-speed cameras are operated at different speeds. Eleven calibration constants are generated using an overdetermined system of linear equations to output the true 3D coordinates of motion in the time domain. Applications for this 3D approach are not restricted to just analyzing the kinetics of a blast. The system is sufficiently flexible to allow an accurate, quick and economical method of bench face profile analysis, generate muck pile profiles and estimate volumetric calculations. The recording systems for these applications can be common 35mm still photography and/or video equipment. It is envisioned that this system will soon replace expensive laser surveying systems at a fraction of the cost in the near future. It is also an excellent system to accurately quantify drill pattern layouts and the spatial locations of each blasthole. This information is required for generating single hole based synthetic seismograms to accurately predict the vibrational outputs of full scale blasts. In terms of litigation concerning claims resulting from blast induced ground vibrations to structures, the system is proving to be an excellent and economical method of performing pre-blast surveys where differential settlement is suspect.

Jan 1, 1990

Driefontein Gold Mine together with Kloof Gold Mine and Beatrix Gold Mine forms part of Gold Fields South Africa. Driefontein Gold Mine is situated near the town of Carletonville, 50 km south of Johannesburg, in the Gauteng Province. The 4 Shaft East complex comprises of the 4 Main Shaft and the 4 Subvertical Shaft. The main shaft is 9150 m in diameter and was sunk in 1984 to a depth of 2000.5 m. The 4 Subvertical Shaft is 7320 m in diameter and was sunk during 1985 to a depth of 3006 m. Full production was, however, only reached during 1988. Intensive mining is currently being done between levels 28 to 42. In 2002 a decision was made to start mining the shaft pillar, situated between 32 and 33 level in the subvertical shaft. Intensive studies showed that with selective mining scheduling the total mineÆs life could be lengthened by nine years if accessed timeously. The higher grades present in the shaft pillar can be mixed with lower grades from the same reef band presently mined 1500 to 2000 m away from the subshaft pillar area. The shaft pillar comprises 50 per cent of the remaining ore resources available. However, no provisions were made in the initial phases of the shaft development to extract the shaft pillar. Grades between 4300 cmgt to 2500 cmgt relating to 23 and 14 g/t are present in the shaft pillar and an estimated 50 tonnes of gold can be produced from this pillar in the period from 2007 to 2015. The pillar extraction is the key to DriefonteinÆs long-term gold profile. Every geological feature possible is represented in this to-be-mined pillar area. The pillar around the shaft is a complex structure featuring hard and soft lava, sedimentary structures/plane parting that moves against each other, quartzite capping, etc. Replacement of services and secondary support systems were designed, modelled and put in place. The original steelwork was not designed to cope with the various stresses and movements, which are expected once the extraction process is started. Existing shaft steelwork was used as far as practically possible. The principal behind the design was that the steelwork would be totally disconnected from the shaft lining over its total length of 132 m in the area of the reef intersection. This will allow the steelwork to move independently from the geological structures surrounding it, allowing a certain degree of distortion of the shaft lining, moderate twist and tilt to take place without interfering with hoisting operations.

Jan 1, 2005

By Corbett GJ, Leach TM

A continued exploration programme has further defined the geology of the Tolukuma vein system, verified the resource indicated by Newmont, and identified potential for additional mineralisation. The resource at Tolukuma Hill, designated as zone C, is a mine recoverable 432,000 t at 18.1 g/t Au & 46 g/t Ag. Mining will be by a combination of open pit and underground at a rate of 100,000 t per annum. Processing will be by SAG mill, gravity circuit and CIL plant. A diatreme breccia, localised at an intersection of structures and a relationship of gold to base metal sulphides, are indicative of a strong porphyry association. Typical epithermal features such as crustiform banded quartz and quartz pseudomorphing platy calcite are also present and locally contain lesser gold mineralisation. Pre-existing dilatant structures have acted as a host to the ore fluids, resulting in the formation of the semi-continuous Tolukuma-Gulbadi veins over a 1100 in strike. A fluid flow model suggests that mineralizing fluids were sourced from a diatreme margin and migrated laterally along dilatant structures. Bonanza gold grades are interpreted to be derived through fluid quenching in the flexure between a hanging wall split, which hosts much of the Tolukuma Hill resource, and the feeder graben structure. Thus, the relationship between the pre-mineral structural geometry and fluid upflow at the margins of a diatreme breccia, controls the ore setting.

Jan 1, 1995

By T Gibbons, M Korte, C Brent, K Runge

The Barrick Osborne concentrator has gone through a number of upgrades since commissioning and steadily increased production from the original 119 t/h design capacity to 265 t/h milling throughput in 2008. This was achieved incrementally over several years, by maximising operating efficiencies, in order to minimise capital expenditure, and take advantages of economies of scale; but more importantly it was reached with no measurable loss of recovery. Osborne currently processes a blend of under- ground with open pit material from the nearby Trekelano deposit. Following primary/secondary crushing, the material is processed through a rod/ball mill grinding circuit ahead of rougher/scavenger flotation that produces a copper concentrate.Osborne was seeking a further increase in plant throughput of the order of 15 per cent, but at more sustainable levels of secondary crusher plant utilisation. In early 2008, Osborne contracted Metso Minerals Process Technology Asia-Pacific and South America (MMPT) to review the entire process from run-of-mine feed to final copper concentrate. This review would be done concurrently, with surveys of both the crushing/ grinding and flotation circuits being performed at the same time. The outcome would be a steady-state model of the complete flow sheet allowing the crushing/grinding model to interact with the flotation circuit model such that overall process optimisation was possible. Two key outcomes for the operation are exploration of the operating limits of the currently installed plant, and projection of the logical next stage of potential capital plant expansions. This paper covers Part B or the flotation component of the project. A separate paper discussing Part A or crushing and grinding is also being presented at this conference. Surveys of the Osborne flotation circuit were performed along with a comprehensive review of the cell characteristics including measurements of the gas and froth phases of individual flotation cells. These data resulted in a size-by-size floatability component model of the complete circuit. This circuit model was then used to perform steady-state simulat- ions to evaluate options to improve both overall circuit and individual cell performance. The grinding circuit model discussed in a separate paper or Part A of this project was then used interactively with the flotation circuit model to recommend the best operating regime to maximise overall efficiency. For example, the balance between increased crushing and grinding costs versus higher copper recovery and final concentrate grade. Due to changes in market conditions in the fourth quarter of 2008, the focus was shifted to prioritising operational changes rather than capital expansion modifications, in order to improve circuit performance.

Jan 1, 2009

By Phillips D. N, Herbert H. K, Fletcher A. C, Lewis R. K

Quartzite is a common feedstock used for the production of silicon by reduction at high temperatures in a submerged electric arc furnace. Silica fume, formed as a by-product in this process, contains crystalline silica in the respirable fraction. The crystalline silica in the fume represents entrained quartz derived from unreacted quartzite raw material within the furnace. A knowledge of the fragmentation of quartzite feedstock, in response to thermal disaggregation in the furnace, is important in feedstock selection to help minimise (a) the amount of crystalline silica in fume, critical from an occupational health and safety perspective, and (b) impurity levels necessary to achieve the highest possible purity of product silicon. In this study, a series of quartzites has been assessed in terms of the above requirements and correlations drawn between mineralogical and chemical characteristics. Alkaline solubility correlates with grain-size and level of stored strain in the quartz matrix. Grain-size affects the surface area available for attack while stored strain enhances the chemical reactivity of the strained matrix as well as profoundly influencing the disaggregation and microfracturing characteristics of strained grains and, hence, available surface area for chemical reaction.

Jan 1, 1995

According to our experimental results, the following oxygen probe recommended, that is, the magnesia stabilized zirconia was employed as a solid electrolyte and Fe.FexO solid elect- rode was used as a reference electrode. Using such an oxygen probe, we tried to measure the oxygen potentials in molten metals, mattes and gases in the following fields of non-ferrous metal industry, molten copper in the side launder before casting, molten crude lead in the forehearth of ISP blast furnace, molten copper mattes in the forehearth of blast furnace and in the settler of flash smelting furnace, gas in the settler of copper flash smelting furnace and flue gas in the electric furnace for ferro-silicon. In the past ten years or so, many experi- mental results in the field of fundamental studies have confirmed that the equilibrium oxygen potential could be measured conveniently and accurately by an electrochemical method using a zirconia solid electrolyte. Recently, such an electrochemical technique has been also applied to a device for physicochemical invest- igation or process control in the non-ferrous metal industry. Such a device consists of an oxygen con- centration cell with stabilized zirconia, and it is commonly called an "oxygen probe" or "oxygen sensor".

Jan 1, 1980