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The first stage in the refining of lead blast furnace bullion is the removal of copper and is normally done as a batch process in open kettles.A number of attempts have been made to establish continuous processes operating in reverberatory type furnaces, but the growth of accretions in the furnace has always presented a serious problem.The Broken Hill Associated Smelters Pty. Ltd. (RH.A.S.) at Port Pirie have overcome this problem by constructing a reverberatory furnace and ancillary cooling system of a novel design.Although a number of mechanical and metallurgical problems still remain to be solved, it is claimed that a workable continuous copper drossing process has been established.INTRODUCTIONLead bullion emerging from the blast furnaces at Port Pirie is at a temperature of about 1100°C and contains, among other impurities, about 1 per cent of copper.The first stage of refining is the removal of this copper by a drossing operation and in the past this was done, batchwise, by allowing the bullion to cool back in 100 ton kettles.At about 700°C, copper dross begins to separate as a crust on the surface of the kettle and this separation was allowed to continue down to about 450°C when the crust was brokenup and skimmed manually using a long handled, balanced, spoon. The dross was then smelted in a reverberatory furnace to produce a saleable copper matte and separate out lead bullion, which was returned to the drossing kettles. The copper content of the drossed bullion was then further reduced by a sulphur treatment process.The drossing operations involved hard manual labour under arduous conditions and the pouring of hot bullion into...

Jan 1, 1963

By Tran T

The kinetics of cementation of silver chloro-complexes from sodium chloride solutions onto copper and zinc was studied using rotating disc electrode system. The activation energies were found to be 10.8 and 30.5 k7/mole, in a 3M NaCl solution on copper and zinc discs, respectively. Higher dissolution factors were obtained on zinc disc, due to hydrogen evolution, whereas, copper dissolved close to the predicted values. Scanning electron microscope studies were conducted both on copper and zinc- cdiscs-to evaluate the deposit morphology and its effect on reaction kinetics. Two stage deposit growth was observed both on copper and zinc discs. Smooth, coherent initial deposit followed by tree-like secondary dendrites formed on copper, whereas, scattered bulbous initial deposit followed by porous dendrites was typical on zinc disc.

Jan 1, 1992

By I P. W Chau

Construction of twin stacked railway tunnels through mixed ground conditions in the heavily populated urban environment of Hong Kong, including tunnelling in poor ground conditions, with low cover and under or adjacent to sensitive structures with minimal impact was the challenge presented by the tunnelling section of the Kowloon Southern Link project. This paper details how twin 1.1 km tunnels of 7.0 m internal diameter were driven by Mixshield tunnel boring machine (TBM) in mixed ground through one of the exclusive shopping and hotel districts in Kowloon. The paper addresses the challenges required to be considered and managed for the success of the project, including ground conditions, TBM selection, Mixshield TBM operation, settlement monitoring and control, ground- borne noise and vibration, proximity to utilities, buildings, roads and operating railways.

Jan 1, 2008

Nickel ores from three different mines, Digger Rocks, Cosmic Boy and Flying Fox, are treated at the Forrestania concentration plant. The ore types vary from oxidised supergene ores to primary pyrrhotite+pentlandite ores. Mineralogical investigations on the ore and process samples have been carried out in different stages of process development. One of the studies was done with the samples collected from the flotation circuit in 19 June 1994 when the Cosmic Boy ore was processed. The process products were screened, and the size fractions were analysed for the main elements by appropriate analytical methods. Mineralogy of the products was studied microscopically and composition of the sulphides was analysed with an electron microprobe. Liberation of the main sulphides in the flotation feed was determined with the point-counting method, and weight percentages of the minerals were calculated using chemical and mineralogical data. The typical sulphide assemblage of the Cosmic Boy ore is violarite, pentlandite, pyrite, pyrrhotite and chalcopyrite. Violarite dominates over pentlandite (ratio being 70 per cent to 30 per cent), and pyrrhotite is strongly replaced with pyrite and magnetite. One of the most common mineralogical features of this ore type is secondary magnetite, which occurs as narrow rims in porous violarite or in association with secondary pyrite. Serpentine, talc and chlorite are the main gangue minerals. In the milled feed (76 per cent -74 ¦m) locked particles between nickel and iron sulphides are common. About 41 per cent of total pentlandite occurs as pure liberated particles, and 33 per cent as locked grains with violarite. Liberation degree of violarite is 55 per cent, and the most common type of locked particles is violarite+magnetite, carrying about 20 per cent of total violarite. To achieve a recovery of 80 per cent for pentlandite, all the particles containing at least 50 vol-% pentlandite should be floated into the nickel concentrate. Correspondingly recovery of 80 per cent can be reached for violarite if all the particles containing at least 65 vol-% violarite are floated.

Jan 1, 1996

Fluid bed sulphation roasting of bismuth concentrates began at Warrego in 1980 in con- junction with the recommissioning of the Tennant Creek Smelter. This process, develop- ed by Peko Mines, is used to separate copper and bismuth by converting copper minerals to a water or weak acid soluble form and then leaching. Pilot scale testwork conducted at the Australian Mineral Development Laboratories (AMDEL) and by Dorr Oliver Pty Ltd in the USA indicated that close control of bed teaper- atures and exhaust gas composition was required to ensure high levels of soluble copper. After overcoming some initial problems, the plant now achieves typically 89 percent copper extraction. Plant capacity is 2.7 tonnes/h by design but in practice this is limited by feed analysis, air requirements, cyclone operation and calcine particle size Consideration.

Jan 1, 1984

The carbonatite-hosted apatite deposit at the Cajati open pit mine in the Jacupiranga igneous-carbonatite complex is located in south-eastern Brazil. The major styles of apatite mineralisation include veins or veinlets, small pods or patches, disseminated apatite and locally massive aggregates. The metallurgical concentration of the apatite is accomplished by grinding the carbonatite, removal of magnetite with a magnetic drum, size classification with cyclones and flotation to suppress carbonates and collect apatite. To examine the character of the apatite grains and to apply those observations to apatite beneficiation, specimens of carbonatite were collected from recent exposures in the mine and from selected drill holes. This study utilised a variety of microscopy methods, including transmitted and reflected light, cathodoluminescence (CL) and scanning electron microscopy with wavelength-dispersive spectrometers for mineral compositions. It was found that LREE, Na and Sr are the main elements replacing Ca in the apatite, with relatively low oxide contents (<0.5 per cent, but up to about one per cent for Sr). LREE and Sr contents consistently increase in the latest intrusions (C4, C5 and SP24). Chemical and morphological modifications of apatite were recognised to be related to detrimental effects on flotation recovery. Three examples illustrate this relationship: 1.  Apatite with reddish CL is fractured. Locally that apatite exhibits no CL due to CL quenching caused by iron entering the apatite structure.2.  Apatite from the xenolith-rich area exhibits abundant fine, platy silicates that appear to interfere with flotation and lower apatite recovery.3.  So called æhardÆ apatite, which is more difficult to grind, occurs in an area in the mine that was affected by hydrothermal activity. That activity is evidenced by the development of a bright, white CL rim in the apatite, and by the presence of late veins of carbonates and sulfides that fill fractures and appear to contribute to higher cohesiveness of those apatite grains.

Jan 1, 2008

By T Davis

The 500 orebody in the upper levels of Mt Isa Mines in north-west Queensland was mined by sublevel caving and block caving from 1962 to 1969. The hot and reactive rock mass of this orebody provided significant mining challenges including ground temperatures above those resulting from the geothermal gradient. Recently Xstrata Copper has been studying the potential to mine this orebody by modern caving techniques. Part of the study process has included re-accessing the ore zones for diamond drilling and trial development. A cross-cut trial drive, the first primary development into the orebody in more than 30 years, encountered a temperature increase in development holes from low sixties to almost 80¦C in less than 10 m advance. The issues associated with managing this risk include sourcing suitable quantities of reactive ground explosives for a single small heading and the temperature limitations of the explosives and detonators. Risk management outcomes included controls to mitigate the safety and reliability risks relating to misfires. The control that dealt directly with the challenge of continuing development in elevated temperature ground was to cool the holes before and during charging. The most effective and practical cooling medium proved to be water. Rapid rock temperature recharge time meant cooling had to continue as close to firing as possible. Reticulation systems were constructed to allow cooling to take place up until withdrawal for firing. No misfires occurred with the cooling system and additional controls in place. This proved that developing safely and effectively in the elevated ground temperatures of the 500 orebody is practicable.

Jan 1, 2008

By Subrahmanyam T. V, Rao V. D

GOLD, the most important and highly coveted valuable metal, is being sought and exploited in almost all the geological environ- ments by the developed, developing and underdeveloped coun- tries of the world. Brazil, one of the five largest countries of the world, has similar geological and lithological environments as of Africa, Australia and Canada and also produces this noble metal. With the recent gold rush in Serra Pelada Hill in Para State of Brazil and the consequent migration of a large number of enter- prises to the Amazon region in search of geological conditions similar to that of Serra Pelada, the status of Brazil in gold produc- tion has been considerably elevated to be among the first five of the world. The principal geological environments or the lithologies where gold can be explored are the greenstone belts, banded iron for- mations, quartz lodes and placers; and the tectonic controls like shear zones in these horizons, or the tectonic relics or the annular- structures that limit the quartz vein systems in felsic as well as volcanogenic systems and epithermal models. The greenstone, BIF associations are present in all the Archean-Proterozoic ter- rains in Central and Northern Brazil. The quartz boudins in Al rich schistose rocks and the weathered and chemically enriched

Jan 1, 1988

By Lynch AJ, Musgrove NH

The behaviour of chalcopyrite and pyrite in the rougher-scavenger and regrind-retreatment circuits in the Warrego concentrator is discussed. The effects of change in xanthate addition on the separation of chalcopyrite and pyrite is described. The effect of the regrind mill on the (flotation rate of particles containing chalcopyrite and pyrite is discussed with particular reference to the importance of removing sub-mesh particles from the feed to the regrind mill.

Jan 1, 1975

By D R. Swinbourne, Y H. Yang

Calcium ferrite slag has gained prominence in the copper smelting industry over the last decade due to the emergence of continuous converting as an established technology. As smelters move towards processing which is higher in intensity, more efficient and more environmentally acceptable, its use is likely to increase because it has technical advantages over conventional iron silicate slag, which include a higher magnetite-holding capacity, lower copper losses to slag and a lower viscosity. Calcium ferrite is currently the converting slag of choice in the Mitsubishi process at operations in Japan, South Korea, Indonesia, Canada and Australia, and in the Kennecott/Outokumpu flash converting process in USA. However, users of this slag have experienced problems in containment due to its highly corrosive nature and low viscosity. As use of this slag becomes more widespread the containment problem will assume greater importance. Consequently, work has recently been carried out to establish the mechanism of refractory attack and devise means to retard it. This work will be critically reviewed in this paper.

Jan 1, 2000

By S Z. Petho

The South Deep surface shaft system is being sunk to a final depth of 2750 m below surface and on completion will be the deepest single drop shaft in the world. The shafts will intersect the target reef horizon at 2650 m below surface. In order to negate the requirement for a shaft pillar, which would be extremely large at this depth, the reef horizon in the vicinity of the intersection is currently being mined. A high quality crushed waste/classified tailings backfill is being placed in the longwall stoping panels around the shaft intersection area. This will limit closure and ride which following shaft reef intersection could have a detrimental effect on the long term shaft stability. This paper discusses underground instrumentation results and numerical modelling exercises carried out to confirm that the shaft system will be stable throughout the life of the mine. Instrumentation projects include closure and ride measured between backfill paddocks and haulage leveling exercises carried out to determine the far field rockmass response to mining with stiff backfill. Results from the numerical modelling exercises show good correlation with measured data. This indicates that a high degree of confidence can be placed in the model input parameters and consequently in the design of the shafts to ensure their long-term stability.

Jan 1, 1998

By Lewis J. W

The mineral sand orebodies of the east coast of Australia occupy approximately three per cent of the dune-heath-wetland coastal environment. They are associated with coastal plant communities ranging from Holocene high dunes carrying mature Eucalypt forests to low- lying heaths on Pleistocene deposits. Commonly, 0.25 to 1.5 per cent of the sand volume mined is removed from the site. Therefore, the volume change is insignificant. The equipment and techniques in use are flexible and the land can be returned in a manner suited to its subsequent use for grazing, subdivision or recreation. Landforms similar to the pre-existing are created in two case studies given. Sophisticated revegetation techniques are practised and are discussed in two case studies. Pre-mining vegetation surveys and post-mining monitoring are used to guide the management of the ecosystem.

Jan 1, 1976

Gold mineralisation at the Enterprise Mine, 230 km south of Darwin, occurs within folded and metamorphosed sediments of the Lower Proterozoic Burrell Creek Formation adjacent to the Cullen Granite. The mineralised zone, which occupies an area of approximately 800 m x 300 m is local- ised by a moderately tight, upright symmetrical anticline which plunges shallowly southwards. The anticline has been disrupted by numerous faults on which the maximum movement is 40 m. Gold is associated with quartz and sul- phide veins which are present as saddle reefs, inter-reef veins and fault controlled reefs. it occurs within the veins or their alteration haloes, either as free gold (2 - 50 per cent of total gold content) or intimately associated with sulphides, principally arsenopyrite and Pyrrhotite.

Jan 1, 1984

The nickel ores mined in New Caledonia for one century are mainly silicate ores. These ores are nickel enriched saprolites, formed by partial weathering of peridotites (predominantly harzburgites and some dunites), serpentinised to varying degrees. Saprolites constitute the lower horizon of lateritic soils, sometimes up to 100 metres thick, developed on peneplains now greatly modified by erosion. Saprolites are generally overlain by laterites, a more weathered horizon, where the main components are iron oxy-hydroxides with a low nickel grade. The structure of saprolites depends essentially on the serpentine content of peridotites and, on the other hand, serpentine minerals may have a high nickel content and, so, represent important nickel bearing minerals in silicate ores. Two types of serpentines can be found in nickel ores from New Caledonia: ò primary serpentines, formed by hydration of olivine at temperatures below 400¦C, during overthrusting of peridotites in late-Eocene (Paris, Andreieff and Coudray, 1979), are generally very abundant; ò secondary nickeliferous serpentines, associated with other sheet silicates in garnierites, are now relatively scarce but garnierites were selectively mined one century ago, because of their high nickel grade.

Jan 1, 1996

This paper reviews the role of fill in mining including consolidated fill both histor- ically and currently as determined by a recent survey of the Fill Subcommittee of the Canadian Advisory Committee on Rock Mechanics (CACRM). It covers the application of fill in modern min- ing methods including mechanized cut and fill, undercut and fill, post pillar cut and fill and longhole pillar recovery between stabilized fill. An automated fill preparation plant and recent developments in rotary drilling of hydraulic fill conducting holes are described briefly. The paper also summarizes the findings of some of the important laboratory and field work carried out on the behaviour of fill in Canada, the United States and Australia and again draws on current information obtained from the Fill Subcommittee of the CACRM. Space limitations and unavailability of suitable material prohi- bit the summary of similar information from other countries.

Jan 1, 1973

By Stille H

The choice between drill and blast and mechanical boring methods is often not obvious. There are several factors which may have a de- cisive influence on this choice, such as the geometry and length of the tunnel, site con- ditions and borability of the rock. Both the un- confined compression strength and the joint dis- tance have a considerable influence on the net penetration rate. Site conditions, rock quality and water conditions influence the utilization of the tunnel boring machine. The drill and blast method is normally less sensitive to devi- ations from assumed ground conditions.

Jan 1, 1987

By Flann R. C

A small modification to current industrial practice should lead to better nickel powders for use in alloying, electroplating, and powder metallurgy. Nickel powder compacts sold for alloying are not always suitable for electroplating applications, since some presently used commercial powders will expand on sintering. Further, such nickel powders are unsuitable for use in the production of powder metal parts, because of expansion during heating of the near-net-shape preforms. Research in these laboratories has enabled the elimination of expansion, and led to techniques for the production of compacts suitable, in particular, for commercial use in both alloying and electroplating. The techniques include: powder pretreatment, cold pressing and sintering, hot pressing, and hot pressing and sintering. In this way compacts are readily prepared with densities of at least 93 per cent of solid nickel, and these, when used as anodes in Watts general purpose and bright baths, give both cathode current and plating efficiencies of 90-98 per cent.

Jan 1, 1979

By P Pieterse

Kumba Iron Ore Ltd is currently commissioning the Sishen Expansion Project (SEP) û a brownfields project on the Sishen Iron Ore Mine located in the Northern Cape Province, South Africa. SEP is designed to produce 13 Mtpa of product from 21.7 Mtpa of ROM feed. The beneficiation section of SEP employs jigs to process narrow size fractions in the 25 x 0.8 mm size range. The -0.8 mm fraction is screened out ahead of the jig plant and rejected as waste without any prior beneficiation. The processing of this fraction was not included in the early stages of SEP development because no suitable beneficiation or dewatering technologies could be identified within the time-frame required to implement SEP. This paper presents the SEP 1B project, ie the metallurgical and process engineering study that was done to evaluate the techno-economic viability of processing the -0.8 mm material of SEP. To support this evaluation, metallurgical bench scale testwork was done on selected samples characterising the material types used in the SEP for gravity concentration beneficiation. Subsequently, pilot testwork on a 300-ton bulk sample demonstrated that an integrated teeter-bed/spiral circuit could be used to successfully beneficiate the -0.8 mm fraction. The study has established the viability of the proposed process and has concluded that approximately 390 000 tpa could be produced and added to the SEP fine ore product without violating the applicable product specifications. The proposed process has been designed to be implemented in modular units in order to facilitate implementation and ensure future expandability. Based on the recommendations of the study, approval has been granted for the detail design feasibility study. Production is scheduled to commence in the first quarter of 2010.

Jan 1, 2008

The aquifer at Phosphate Hill, north-west Queensland, presents special management challenges. The site contains a phosphate rock mine, fertilizer plant and camp. All of the site water is provided by the Duchess Embayment Aquifer, located within the Burke River Outlier of the Georgina Basin. The Duchess Embayment is a triangular shaped, Cambrian marine sedimentary basin consisting of siliceous and calcareous phosphorites, shales, siltstones and sandstones. It is fault-bounded on all sides and has a regional dip of 5¦E. The aquifer is largely confined to the siliceous facies of the Beetle Creek Formation. It has a very flat potentiometric surface and an average thickness of 45 m with confining beds above and below. The siliceous facies derives from weathering of the calcareous phase and is highly transmissive while the calcareous zone itself contains less water and is dependent upon interconnecting fractures for its permeability. Recharge appears to occur where the siliceous facies crops out around the edges of, and within, the Embayment. Aquifer management issues revolve around two points: successful dewatering of the orebody for mining; and efficient management to maintain water quality and ensure supply over the predicted 30-year life of the project. Current operations are extracting water at levels much below that originally estimated. This is having a detrimental effect on mine dewatering with the SWL lowering at a rate slower than anticipated. As a result, ore parcels are now beginning to intersect the water table, providing a major constraint to the mining plan. The aquifer drawdown cone is extensive and very flat so to keep the water table at an appropriate level for mining the management plan will include more aggressive dewatering to lower the level of the entire aquifer. The additional water will either be disposed of downstream or stored in a holding dam or via the use of artificial storage and recharge. Water resource management will also need to maintain the current quality. About 37 per cent of the water currently extracted forms the low chloride supply required by the ammonia plant and the power station. This ratio is expected to remain applicable under any future operating conditions but the low chloride resource is restricted so will require prudent management to enable the supply to continue. At current usage rates aquifer recharge versus use will need careful monitoring to ensure that the resource remains viable in the long-term.

Jan 1, 2003

By Waller M. D, Whittaker B. N, Singh R. N

This paper overviews the recent research progress in predicting cutting performance using fracture mechanics principles. It is emphasised that rock fragmentation due to cutting is mainly a process of chip formation resulting from crack initiation and propagation or crack interaction for multi-tool cutting. This process can be simulated by using the well developed fracture mechanics criteria coupled to numerical methods. Fracture toughness is shown to be an important and useful parameter in quantifying cutting performance and in designing cutting tools. The paper concludes with discussions on the dynamic effects involved in rock cutting processes which should be taken into account for optimum cutting efficiency and tool design.

Jan 1, 1992