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By A. G. Waters, N. J. Bristow

A comparative study was made of an untreated and a heated haematite ore and a sinter produced from a feed consisting of 100% ore, to study the influence on reduction behaviour of sinter bonding phases such as SFCA (silico-ferrite of calcium and alumina). Under low-temperature reduction conditions the order of increasing reducibility followed that of increasing porosity and surface area but under similar conditions at 900 degrees C the sinter exhibited higher reducibility than the ores even though the total porosity and chemical reducibility of the individual phases were lower. This behaviour can be explained in terms of the higher total porosity of the natural ore at low temperatures and the higher level of fine pores in the sinter at high temperatures due to the presence of SFCA, which acts to support the fine (c.0.1 micrometre) pores created by the reduction process. This leads to the conclusion that the main role of SFCA in sinter during high-temperature reduction is to maintain a high level of fine porosity. Some implications of this work for granule design and sintering practice are discussed

Apr 1, 1991

By D. D. Lei, H. Sevim

Long-term production planning in open-pit mines requires the determination of cut-off grade, mining and milling production rates, a mining sequence, mine life and ultimate pit limits. Since these variables interact in a circular fashion, a genuine solution to the problem necessitates their simultaneous determination. A methodology with this capability is described. This comprises a group of heuristic algorithms and an unconventional dynamic programming algorithm. The method is demonstrated using data for a gold deposit in the western USA

Jul 1, 1996

By D. J. Allan, W. R. Wilson

For conventional aerospace aluminium alloys of the 2000 (copper) and 7000 (zinc, magnesium) series the recycling of process scrap from both metal suppliers and aircraft manufacturers is a well-established, worldwide industry. The recent introduction of a new family of alloys that incorporates lithium has posed a new challenge to the recycling industry owing to the high cost of lithium, its high reactivity to the atmosphere and to refractories and its absence from the specifications of all other registered alloys. Various process options for recycling have been identified, but vacuum distillation has been selected as the most cost-effective and technically feasible solution. Experimental work established that the separation of Li from AI-Li scrap is feasible and an industrial process has been designed. The economics of Li recovery are very sensitive to the AI-Li content of the feed material. Owing to the design of aerospace vehicle manufacturing plants it is expected that the swarf will be mixed with other alloys. A method of enriching this feed has been developed that is based on the control of swarf morphology by thermal and mechanical treatments as a precursor to eddy-current separation. After eddy-current separation and vacuum distillation small proportions of Li are retained in the AI residue. The effects of this on the properties of conventional AI-Si shape-casting alloys were investigated and safe threshold levels have been established.

Jan 4, 1993

By A. J. Naldrett

"Synorogenic mafic intrusions are a common feature of the northern Appalachians. Two sulphide-bearing intrusions in central Maine that have been investigated revealed a number of important features that illustrate sulphide-silicate interaction that relates to magmatic sulphides. The Moxie Pluton is a large mafic intrusion emplaced during the Devonian Acadian orogeny. The Katahdin gabbro is a small mafic body that is probably genetically and temporally related to the Moxie Pluton. Both intrusions were formed bv the intrusion of variably fractionated magmas into irregular chambers and feeder zones. The southern half of the Moxie Pluton contains three small sulphide accumulations, whereas the Katahdin gabbro hosts a large, predominantly massive, sulphide body. Textural evidence clearly documents the magmatic origin of these sulphides.The three Moxie Pluton sulphide bodies are located at or very close to the intersection between the intrusion and the sulphidebearing Hildreths Formation. Sulphur assimilation, suggested by this relationship, is supported by the isotopically light (634S = —8 to —25) and the selenium-poor (S/Se - 25 000-48 000) character of the Moxie sulphides and correlation with the Hildreths Formation sulphides (S34S = —25, S/Se = 25 000-48 000). Isotopically light sulphur (534S = —20 to —21) and high S/Se ratios indicate that the majority of sulphur in the Katahdin sulphide body was also derived from an unexposed country rock source. The volume of sulphide in this example illustrates the potential efficiency of the sulphur assimilation process—so efficient in this case that marked dilution of the economic chalcophile elements resulted from the addition of so much external sulphur.The three Moxie Pluton sulphide occurrences are all impoverished in Ni and Cu (1.87-0.44% Ni; 0.72—0.32% Cu in massive sulphide), but contain normal Co contents (0.22-0.13%) relative to typical magmatic sulphides. The Katahdin sulphides show a greater Ni and Cu impoverishment (0.2% Ni; 0.1% Cu in massive sulphide) with similar Co (0.17%). The Ni content of the Moxie Pluton olivines document the fractional removal of sulphides during crystallization of the host magma, which resulted in the progressive depletion of the chalcophile metals in this magma. Modelling that involved the fractional crystallization of the magma coupled with the fractional removal of a specified proportion of sulphide has successfully duplicated the Moxie Pluton sulphide compositions. A similar magmatic model has been postulated for the Katahdin sulphides with a greater degree of sulphide fractionation. This latter model is again supported by extremely low Ni/forsterite ratios in olivines, though the compositional range is insufficient to document fractionation. These magmatic models are not unique, but they provide a relatively constrained and consistent explanation for the sulphide compositions.The Ni contents of olivines are the most important indicator of sulphide-silicate interaction in mafic magmas and have exploration potential. They provide a means of assessing the timing and extent of sulphur saturation in an intrusion and are a guide to the Ni content of a sulphide accumulation in equilibrium with olivine. In the Maine examples they provide strong evidence of the magmatic origin of the sulphide accumulations and justification for magmatic modelling."

Jan 1, 1984

By G. E. Pearse

Reports, discussions, a written contribution and two written replies are presented from 11 sessions on: Safety and compressed air; Ground movements; Geotechnical; Channel Tunnel (2 sessions); Machines; Case histories; Transport tunnels; Case studies; Site investigation; and Undersea tunnels

Jun 13, 1905

By W. S. Fyfe, G. V. Albino, Ekawat Sitthithaworn

The mineralisation is associated with a composite diorite to quartz monzonite stock of Permian to Triassic age that intrudes Devonian carbonate strata. In the intrusive rocks it is associated with potassic alteration and in the carbonate wall rocks it is hosted by prograde garnet-rich and retrograde epidote-rich skarn. Both porphyry and skarn mineralisation include disseminated and fracture-controlled mineralisation, the latter probably accounting for the major part of the contained minerals. Copper, gold, silver and zinc are strongly positively correlated within the mineralised zones, although there are small differences in metal ratios between the different ore types; molybdenum appears to be negatively correlated with copper and gold. Ore minerals include chalcopyrite, magnetite and pyrite in porphyry-type mineralisation and bornite, chalcopyrite, pyrite, magnetite and lesser haematite in skarn.

Jan 12, 1993

By O. Dojcar

Equations for calculating the parameters of controlled blasting (burden and spacing of boreholes and weight of the bottom charge) are derived and analysed on the basis of empirical values and made more precise through incorporation of the properties of the rock being blasted and explosive applied. For the success of controlled blasting the correct choice of the blasthole diameter/charge diameter ratio is critical. This relation is defined as the coefficient of radial decoupling of the charge; it is recommended that it is chosen to be between 3 and 3.5. Analysis of smooth blasting, cushion blasting and presplitting indicates that cushion blasting is a less destructive alternative to smooth blasting, but it has a slightly higher blasthole consumption and limited possibilities of use. There are definite economic advantages to controlled blasting, especially in rock masses of low and medium strength

Dec 1, 1996

By D. V. Venugopal, W. W. Gardiner

Spessartine-quartz rocks are manganiferous sedimentary rocks rich in spessartine and quartz which occur in north-central New Brunswick. They represent a recrystallised manganiferous siltstone/chert that is contained in or associated with red manganiferous siltstone (RMS) units. The spessartine-quartz rocks and RMS form part of an Ordovician volcanic and sedimentary succession within the Appalachian-Caledonian orogen which hosts numerous massive sulphides and polymetallic vein deposits. The New Brunswick spessartine-quartz rocks are spatially and temporally associated with stratiform base-metal, precious metal and hydrothermal tin-tungsten deposits. This suggests that spessartine-bearing lithologies and zones can be useful in predictive metallogeny and for the understanding of the stratigraphy and palaeographic setting of the early Palaeozoic rocks of the Appalachian-Caledonian orogen.

Jan 12, 1992

By G. J. Lyman

Mayer curves are used for process calculation in coal preparation. They can also be used to smooth washability data by fitting a hyperbola of particular properties to ash and yield, but to introduce the density variable an independent relationship with ash content must be adopted. When this ash-density relationship has a realistic form at low density, the implied form of the mass distribution function is unrealistic, suggesting that Mayer curves represented by a hyperbolic functional form are unsuited to coal washery calculations for low-density separations. Their use at higher densities is also uncertain. A similar conclusion can be anticipated when Mayer curves are used for other mineral systems.

Jan 8, 1992

A study of the thermodynamic properties of magnesium chloride ammines was carried out with the ultimate objective that the thermal decomposition of the hexammine MgCl2.6NH3 may prove successful on a commercial scale for the manufacture of anhydrous magnesium chloride, which is required for the efficient electrolytic production of magnesium. The experimental data are presented in the form of an equilibrium diagram that aids the understanding of the conditions associated with the thermal decomposition of ammines

Jun 13, 1905

By B. H. Smith

"Most of the discoveries of nickel sulphide deposits in Western Australia have followed the search for gossans. The chances of further discoveries depend on improving our understanding of the cover of strongly leached and transported materials that obscure approximately 85% of the area of the Yilgarn Block that has nickel sulphide mineralization potential. The lateritic profiles that are observed on the Yilgarn Block today were formed over a period of more than 100 m.y. of warm and humid climates. This lateritized land surface has been preserved by induration during subsequent arid climates as well as by the structural stability of the Yilgarn Block.In geochemical surveys of lateritied terrain samples have to be taken from at least the saprolite zone usually by drilling so that confident predictions can be made of the significance of analytical data. Account must be taken of the mineralogy of samples, as well as the nature of the horizon of a laterite profile that is being sampled, owing to the concentrating effects on trace elements of Fe and Mn oxides.Multivariate techniques have been applied successfully to analytical data in gossan recognition when textural evidence is ambiguous. Pathfinder geochemistry has also been used in gossan recognition and the most significant recent advance has come from studies of platinum group metals in nickel sulphides and their dispersion during weathering."

Jan 1, 1984

By Ruddle R. W.

Magnetite occurs in the reverberatory furnaces, blast furnace and converter (a) as the result of its presence in the materials charged, and (b) as the result of oxidation of the FeS in the charge in the absence of sufficient SiO2 to slag the FeO as it is produced and thus prevent its subsequent further oxidation. Magnetite is reduced by FeS according to FeS+3Fe3O4=10FeO+SO2 and similar reactions. This reaction is markedly affected by temperature and does not proceed to any important extent below about 1200°C. To ensure comparative freedom from magnetite it is therefore necessary to raise the temperature of the furnace to the highest practicable figure and to use plenty of siliceous flux. Since the maximum operating temperature is likely to be limited by the resistance of the refractories to attack by the slag, investigation of the factors affecting this attack should be helpful. It is reasonable to suppose that the formation of magnetite might be minimized by ensuring intimate admixture of matte and slag during conversion so that silica is readily available for combination with ferrous oxide as the latter is formed. The literature gives no clue to the importance of this factor and some experimental work on this aspect might be fruitful

Jan 1, 1953

The paper, presented at the North of England Institute of Mining and Mechanical Engineers' general meeting held in Newcastle-upon-Tyne, 8th April 1916, presents experimental work undertaken to observe the quenching effect of different substances, to find the most efficient of these substances, and to arrive at a possible explanation of their preventive action. The coal-dusts experimented with were such as passed through a 100-mesh sieve (10,000 holes to the square inch), and were obtained by grinding the coals. The quenching substances, used in as fine a state of division as possible, included gypsum, dried Chance mud, quicklime, magnesia, magnesia alba (levis), anhydrous sodium carbonate, sodium bicarbonate, soda-crystals, Glauber salts, ground shale and boiler-ashes

Dec 1, 1916

By C. E. Dunn

Paper presented at the 28th International Geological Congress held in Washington DC, July 1989 (International geochemical mapping sessions). Evidence is accumulating that reconnaissance-level biogeochemical sampling can provide valuable insight into the chemistry of the substrate. Problems such as seasonal variations in plant chemistry and the lack of a universal biogeochemical sample medium may be circumvented by adopting normalising procedures. The planet can be divided into a few climatic zones, each of which is characterised by one or two common plant genera. If it can be demonstrated that the chemical differences between certain species of a single genus are small - as is suggested by studies of boreal forests - it would seem feasible to apply biogeochemistry as a low-density geochemical mapping tool. The technique could prove particularly useful for assessing the substrate chemistry of areas of dense forest, rugged terrain and difficult access by employing airborne sampling of trees from helicopters

Jul 1, 1991

By T. Sharma, T. C. Rao

Laboratory studies have been carried out on acid leaching as a possible route for the extraction of potassium from glauconitic sandstone. Leaching efficiencies with sulphuric, hydrochloric and nitric acids were investigated. The effects on potassium dissolution of temperature, concentration and type of acid, stirring speed and leaching time were also studied. The results show that it is possible to recover 87.5, 93 and 85% potassium with 5 M H2SO4, HCl and HNO3, respectively. During the initial stages of the sulphuric acid leaching process the chemical reaction at the mineral surface is the rate determining step, whereas during the later stages diffusion through the product layer is rate-controlling. Overall, the process follows a mixed-control model that includes both chemical reaction and diffusion. The activation energy for the dissolution of K was found to be in the range 25.79-106 kJ/mol.

Jan 12, 1992

The first part describes a model (the C model) based on the motion of the grinding charge. The charge is treated as a continuum, which allows analytical solutions to the equations that are developed. The C model is equally applicable to ball-, semi-autogenous and autogenous mills and contains a description of the power draw of both the cylindrical section and the cone-ends. Differences between the power draw of grate- and overflow-discharge mills are described from consideration of the different shapes and compositions of their charges. A large database of industrial mill data is used to demonstrate the accuracy of the model. Part 2 describes a simpler, empirical model (the E model) whose performance is based on that of the C model. The same database was used to assess the predictive capabilities of the E model. The model was shown to be only slightly less accurate than the C model despite its much simpler structure

Jun 18, 1905

By G. Merrington, B. J. Alloway

Tailings from three historical mining areas in the UK were leached in columns under a simulated weathering programme which was chosen to represent periods of 1 and 2 years at 3 different ambient temperatures. The total concentrations of Cd, Cu, Pb and Zn in the primary ore minerals present in the tailings showed only a limited correlation with metal concentrations in the leachate. The leachate from columns of tailings that were maintained at a temperature of 25 (+/-3) degrees C contained, on average, 50% more Pb and 75% more Cu than leachate from tailings that were maintained at a temperature of 10 (+/-3) degrees C. The pH values of leachates from all three types of tailings at 25 (+/-3) degrees C were 0.2 units lower than those from columns maintained at 10 (+/-3) degrees C. The concentration of Cd and Zn in the tailings leachates showed no marked difference at the different temperatures. The composition of the leachate was found to be dependent on the type of gangue mineral, the presence of other sulphide minerals and the formation of secondary iron minerals. A comparison of the concentrations of heavy metals in the leachates produced in the laboratory with those in leachates that were collected in the field over a similar period of time from two of the mine sites showed that concentrations were of a similar order.

Jan 8, 1993

By R. G. Siddall, W. Gale

In the UK the development of the science of strata control has been strengthened by a resurgence of interest in the specialism of roofbolting and its associated techniques. The evolution of the theories and practices of strata bolting in roadway stabilisation is discussed. Practical experiences are considered, principally the use of Australian techniques, the relationship between bond strength and annulus and the effects of stress in the ground. Areas of new technology such as cable bolting, injection anchors and on-board bolters are also discussed. The recent advances in computer technology and rock testing equipment and methods have provided the opportunity to simulate ground behaviour under various conditions. Computer modelling developments and the use of techniques to predict ground behaviour are described.

Jan 4, 1992

By Ruddle R. W.

Solid mattes are generally held to be either (a) eutectiferous mixtures of the component sulphides Cu2S and FeS or (b) mixtures of complex sulphides. This chapter shows that liquid mattes consist essentially of a homogeneous phase in which iron, copper and sulphur are present. The amount of sulphur is generally less than that required to account for all the metals as stoichiometric sulphides; mattes cannot therefore be regarded as mixtures of FeS and Cu2S. Some iron oxide may be dissolved in the sulphide phase and magnetite is often present as a second phase. If the sulphur content of the matte is reduced the composition enters the miscibility gap in the ternary system and either an iron- or copper-rich solution (depending upon the composition of the matte) separates as a new phase. On solidification any one of four phases (iron, copper, Cu2S and FeS solid solutions) may crystallize as primaries. The remainder of the matte solidifies as a ternary eutectic. It is possible that iron oxides enter into this eutectic. Knowledge of the ternary Cu-Fe-S system is far from complete and nothing is known of the quaternary system Cu-Fe-S-O

Jan 1, 1953

By K. El-Barawi, Hussein M. Kamal

Chlorination was performed of iron-rich chromite ore from Barramyia, United Arab Republic (UAR), together with its concentrate. The effects of change of grain size, chlorine gas flow rate, time and temperature were studied. The extent and mechanism of chlorination were followed through chemical and structural analyses of the feeds and complete chemical analysis of the chlorination products. By conducting the chlorination process for short periods at 600°C or lower temperatures, products having high Cr-Fe ratios suitable for ferrochrome production can be obtained.

Dec 1, 1971