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Silver and gold bearing ore from the Palmarejo mine, located within the Mexican state of Chihuahua, contains a complex mix of electrum, native silver, silver sulfides and silver chlorides. This paper presents a case study that describes the selection, development and engineering of a tailored process plant for the recovery of silver and gold from this ore. Process circuit feasibility study modelling, metallurgical test work and engineering studies are outlined. Options considered to optimise the recovery of the contained silver and gold are compared, based upon cost, operability, recovery and engineering aspects. Concentration by flotation was found to be the preferred primary recovery route. Intensive leaching of the flotation concentrate resulted in solution grades sufficient to allow direct electrowinning to be evaluated against the more traditional Merrill Crowe process. The flotation tailings stream is processed through a separate leaching stage as there is sufficient economic metal extractable from this stream. The processing flow sheet, which is designed to maximise the recovery from both the flotation concentrate and tailings, and to utilise a common metal production facility, is presented.

Jan 1, 2009

By S Pfaff, R Rajic

In the case when the number of independent variables is greater, a careful design for carrying out tests has to be made in order to obtain, with the smallest possible number of tests, as much as possible neutral information about the influence of independent variables on the dependent ones. Only on the basis of such design and its statistical analysis it is possible to come to right conclusions about the function of the whole system. The influence of pressure, temperature, humidity and granulation of the coal upon the resistance to pressure and the water absorption of the briquettes has been tested, with the aim to examine how each of the two dependent variables changes depending on the values assumed by any of the four independent variables and which of the mentioned independent variables significantly influences the dependent ones. The full factorial design with 16 experiments and the central composite design with 27 experiments have been applied. The influence of the independent variables upon the dependent ones has been examined by applying the analysis of variance. The influence values of individual factors and their interaction upon the dependent variables have been stated as well as coefficients of curvilinear equation.

Jan 1, 2003

Future depth and production limitations of an ore hoisting system are fixed by its initial design criteria. There is little scope to extend these limitations once installation is completed. Depth and production rate upgrades from the initial duty to the hoistÆs practical limitations require capital expenditure in stages, each of which can be defined when assessing the initial system design criteria. A means of presenting and assessing the design criteria, the limiting factors in each option and the relative present and future capital costs is necessary to arrive at a solution that delivers the best value to the mine. Application of this technique to recent friction winder installations and upgrades in the Australian mining industry is of particular interest; however, the analysis methods are also applicable to drum hoists. It is usual to specify a minimum hoisting capacity and depth, based on mine ore handling design and production needs. The final hoist depth and production rate are usually a result of the initial hoist design and hence it is useful from the outset to specify a required production versus depth envelope for the mine. Technical solutions can then be modelled within this envelope at their initial and final duties and a comparative analysis made against the cost of installing and progressively upgrading each solution. Understanding the factors that constrain each solution to a maximum production rate at a given depth is important, as the costs of overcoming limiting parameters such as rope tread pressure and motor power can be significant. The task of understanding and evaluating the options open to the hoisting system designer is simplified using this approach. Communicating the results of a multi-dimensional problem such as hoist specification is also made easier using the graphical methods inherent in the analysis.

Jan 1, 2005

By Penney B. K, Baghdadi A. A

An electron probe micro-analyser, controlled by a dedicated mini-computer,has been operating at Imperial College since 1970. The data assessment capability of the computer was limited and, in order to make better use of the information produced by the analyser, extra computing facilities were needed. Following the initiation of a Laboratory Automation Project at Imperial College involving the use of a central computer linked to laboratory type computers and to further more powerful systems,it became possible to carry out much more detailed and extensive mineralogical analyses by connecting the mini -computer to the Laboratory Automation Network. The paper describes the techniques employed including hardware, software, inter- connection, analysis and operating methods.

Jan 1, 1977

Magmatism and mineralization are features of the New England Orogen in late Palaeozoic- Mesozoic time. Voluminous silicic and mafic magmatism, both orogenic and post-orogenic in association, was accompanied by abundant mineralization in the earlier phases. Later activity passed transitionally into less vol- uminous felsic to mafic intraplate basaltic volcanism, with possible migratory hot spot activity through the flanking Oxley and Sydney Basins. Only minor mineralization took place at this stage. A new inerpretation links these magmatic and mineralizing events to a major thermal cycle. A New England hot spot(?) complex evolved in latest Carboniferous/early Permian time. Its activity was partly obscured by orogenic magmatism as Australia moved slowly over magma sources in the deep lithosphere. In Triassic time Australia's movement changed direction and faster drift over the waning hot spot complex produced multiple migratory intraplateòactivity. The volume of magma and hence abundance of ancillary mineralization was related to age of the hot spot, speed of the continental movement over thermal sources and extent of accompanying orogenic activity. The New Eng- land Orogen hot spot(?) possibly existed for 165 Ma, with mineralization changing over this Period.

Jan 1, 1987

By P Rourke

In this climate of increasing demand for commodities, it is becoming necessary to expand and optimise existing bulk material handling facilities in order to increase capacity to satisfy demand. Production capacity in these facilities is often adversely impacted during the expansion process. A successful and proven strategy to reduce this impact is to bring the additional capacity online in stages coinciding with routine maintenance or other short shutdowns. Compatibility of the automation systems with staged upgrades in capacity is the key to achieving a successful outcome. Since 1994, Hatch has been researching a generic, highly configurable product transport control system that can be reconfigured to cater for plant expansions or modifications without incurring significant risk to production capacity. In 2002, BHP Billiton Iron Ore (BHPB IO) recognised the need for such a generic Route Selection and Sequencing (RSS) system and engaged Hatch to build a generic RSS system as part of the $US351 million BHPB IO Products and Capacity Expansion (PACE) project. In 2004, Hatch successfully deployed such a generic configurable control system at BHPB IO Port Hedland Ore Handling Facility. This generic system is known as the Hatch Product Transport (HPT) System.

Jan 1, 2005

The basic principles of mineral valuation were recognised and propounded at the beginning of this century and have remained virtually unchanged since then. Valuation is seen as a two part process commencing with a technical examination of the mineral property followed by a manipulation of the results of the technical examination in order to determine the monetary value of the project. A thorough and competent technical examination was seen then and remains now as the essential but not sufficient foundation for reliable valuation. All authors stressed the need to maintain the integrity of the data base and to ensure adequate coverage of all relevant aspects. The monetary valuation process through most of the first half of this century was mainly based on the Hoskold two rate method, derived from the formulae for valuing annuities but modified to provide explicitly for recovery of capital. Though the basic principles of valuation have not changed significantly, the means of implementing the components of the technical examination, the styles of deposits being evaluated and the mechanisms of monetary valuation have changed dramatically. Despite all the technological improvements, however, mineral valuations are still as apt to vary from realised performance as at any time in the past. As well, mineral property valuations are now being extended to cover all assets of potential value, including valuation of exploration tenements with or without identified resources. Valuation of exploration tenements will continue to be one of the most difficult and contentious of valuation tasks.

Jan 1, 1994

By A He, J Li, J Pan, J Clout

The removal of sulfur from SO2 containing flue gas is improved by adsorbing SO2 into solution with manganese ions as catalyser, however, burnt lime slurry has to be added to modify solution pH and the CaSO3 by-product is of low economic value. In this paper a novel one step process for simultaneous manganese leaching-desulfurisation of flue gas is presented. An investigation of the effect of process parameters included flow rate and SO2 concentration in flue gas, adsorbing time, solution to solid mass ratio, leaching time, and their impact on the oxidation and removal of SO2 from flue gas. The catalysing mechanism of manganese ions on the oxidation and SO2 removal was demonstrated by calculation of the species originating from manganese ions and SO2 in the solution according to solution chemistry. SO2 removal in the adsorbing solution took place at pH 5 - 6, where manganese ions dominantly occurred as Mn2+, and the chain reactions for oxidation of SO2 starting from HSO3- were improved by the presence of Mn2+. SO2 bearing flue gas was effectively desulfurised by leaching rhodochrosite (MnCO3), with desulfurisation of the flue gas and modifying the solution pH being achieved simultaneously, and MnSO4 of high economic value recovered from the leachate. 85 per cent manganese leaching and over 70 per cent desulfurisation of the SO2-bearing flue gas were achieved with only one adsorption stage under optimum conditions.

Jan 1, 2004

Aspects of the formation, decomposition and acid solubility of zinc ferrite were examined to find potential ways of increasing the recovery of zinc from a calcination process of mineral concentrates. Ferrite can begin to form within 2 hours at 450¦C. while complete reaction can occur after 35 minutes at 700¦C. The nature of the starting materials has a pronounced effect on the rate of formation and below 700¦C. ZnSO4 and Fe2O3 proved to be the least reactive of the materials investigated. It is possible that iron in a mineral admixed h sphalerite can be converted to a relatively inactive form, however, it does not seem possible to prevent zince f formation when iron is in the sphalerite lattice. At the two temperatures examined, 650¦C. and 700¦C, the presence of SO2 in the atmosphere accelerate .e formation of ferrite. Prolonged exposure to such atmospheres, however, caused the ferrite to decompose to ZnSO4 and Fe203. The optimum temperature for decomposition was 650¦C. and it was virtually complete within 2 hours in an atmosphere of 10% SO2 in air. Zinc ferrite was also decomposed by CO at low concentrations, and by heating with limestone at 1000¦C. for at least 2 hours. The solubility of zinc ferrite in acid was influenced by the starting materials used. As both the reaction temperature and the time at temperature increased the acid solubility decreased. The acid solubility was a minimum when the ___i_.. n - I -r~...................c -..... F, fe..i+e --A frn... A01- +^ Z(lo/

Jan 1, 1970

Pulverised coal firing was pioneered in the cement industry prior to the turn of the century. Ash from the coal is absorbed into the mix in the kiln and replaces secondary materials. With high purity limestone coal with high ash content can be used. Fuel cost is a major part of the total manufacturing cost. Cement plants are thus quick to respond to fuel price changes and will use low grade fuels if there is a price advantage. Combustion conditions in a cement kiln differ markedly from a boiler. Flame length is determined by air/fuel mixing but because of fixed secondary air conditions this depends on primary air momentum. Volatile content has some effect on flame length but this can be offset by coal fineness. Much of the heat for cement production is for limestone calcination which is a low grade energy requirement. By allowing long residence time in separate direct fired vessels which then feed the high temperature kiln the energy of materials such as oil shale, tyres and lump lignite can be utilised.

Jan 1, 1987

Since the 1950's drilling has been rapidly mechanised. First from hand held drills with air legs to pneumatic jumbos, then to more effective hydraulic jumbos. Development of underground drilling equipment naturally could not have stopped here. Hydraulic drilling saw an improvement in drilling capacity and efficiency after the introduction of second generation drifters in the early 1980's. Also in the early 1980's a few equipment suppliers started to study how to improve the efficiency in operating the rigs. The first computerised rigs for tunnelling were delivered to work sites in mid 1980's. At the same time a few computerised longhole drills started drilling in mines.

Jan 1, 1988

The mining industry has been slow at adopting the latest management philosophies from other industry sectors, such as manufacturing, and in retrospect, with good cause. With the plethora of three-letter-acronyms such as TQM, JIT, TPM and now, BPR each touted as the panacea for profit improvement, you wonder if you must choose one or attempt to embrace them all! In truth, each new insight into organisational behaviour bears some investigation. This paper looks at the underlying principles and elements of successful change strategies, and how several mining companies, including coal mines, in Australia, Chile and Canada, are applying these principles to their operations. These examples illustrate the need to think radically, and to view mining as an overall process delivering value to the customer rather than a collection of functional silos. They also show that often, a continuous improvement initiative is not enough when a fundamental redesign, a paradigm shift, is needed for a performance breakthrough.

Jan 1, 1998

By Junpeng L, Huiguo Q

Field instrumentation was installed to monitor ground and lining behaviour during and after construction of the Mount Shaughnessy Tunnel (Rogers Pass Short Tunnel) in Canada. The instrumentation was placed in a soft ground section of the tunnel at its crossing with the Trans Canada Highway. The tunnel was excavated through a dense bouldery soil. Presentation of the field data and inter- pretation of the tunnel performance from a geological-geotechnical point of view form the basis of this paper. The loss of ground due to the tunnel excavation was found to be exceptionally small. This has been attributed to the unusually high strength and stiffness of the host soil. Evaluation using the Boundary Element Method, together with a simplified analytical technique, were applied to assess the relevant soil parameters and their influence on the tunnel performance.

Jan 1, 1987

By M G. Aylmore

Thiosulphate is an attractive alternative reagent to cyanide for processing gold ores. It is relatively cheap and non-toxic, forms relatively strong gold and silver complexes, and readily leaches gold ores in ammoniacal solutions, catalysed by Cu(II). It is particularly suited to carbonaceous ores where the recovery of gold by cyanide is poor. However research over the past 20 years has identified a number of issues and impediments that must be understood or overcome before an overall process can be demonstrated as practical and economic for typical oxidised gold ores. This paper reviews our current understanding of thiosulphate chemistry and mechanism of gold dissolution, and discusses the stability of thiosulphate and polythionates. It then reviews the results of leaching various gold ores that have been reported in the literature, discusses gold recovery options, and considers environmental and toxicity issues. Some of the issues that require further research include decreasing the oxidation of thiosulphate by Cu(II) or other oxidants, increasing the extraction of gold compared to cyanide, and understanding the variation in gold recovery between ores. More work is also required to minimise the effect of polythionates on gold recovery using resins or alternative absorbents, to improve the elution of copper and gold from resins, and to recycle or minimise the concentration of reagents.

Jan 1, 2002

By Bhaskara Sarma P V R

Solvent extraction of cobalt from an ammoniacal ammonium sulphate medium was carried out using Di(2-Ethyl Hexyl) phosphoric acid in kerosene as diluent. The effect of ammonium chloride and ammonium sulphate on the extraction efficiency was studied. The extracted species in the ammonium chloride and sulphate systems were CoAz2HA.NH4CI and CoA3.HA.2(NH4)2SO4, respectively. Ammonia scrubbing and cobalt stripping studies were carried out from loaded and ammonia free organic Respectively.

Jan 1, 1992

By Salmon P. T, Gilmour R

Commercial production of zinc started at the Pasminco Metals - EZ Plant, Hobart, Tasmania, in 1921. Since that time the capacity of the plant has been steadily increased to its present level of almost 220 000 tpa. Major areas of the plant have been successively upgraded over a number of years, (Roasters, 1969, 1975; Acid Plants, 1981; Casting, 1972; Residue Treatment Plant, 1971), but, until recently, the leach/purification area remained virtually unchanged from the time the plant was built. The major redevelopment of the hydrometallurgical plant began with fully integrated pilot plant testing of the proposed new circuit in 1981. The pilot plant incorporated the Low-contaminant Jarosite Process, and a new two-stage zinc dust purification procedure. In 1985, approval was granted for a major modemisation program which involved the complete replacement of most of the leaching and purification plants, and substantial improvements to the residue treatment plant. Construction of the first of the new plant sections, Strong Acid Leaching, commenced in 1986. This paper describes briefly the modernisation program itself, and the current method of zinc production at the PMEZ plant. The new plant sections comprise a Strong Acid Leach stage to improve lead residue grade; a Preneutralisation stage to reduce metal losses in jarosite; new filtration stages for both jarosite and lead residue; new Neutral Leach and Weak Acid Leach stages to replace old equipment; a new Solution Purification stage to replace the use of organic reagents to remove cobalt; and a new Gypsum Removal stage to cool the solution before electrolysis. At the completion of the modernisation program, only the electrolytic cellhouse remains of the early plant sections.

Jan 1, 1993

By Just GD, Phillips R

The application of high pressure water jet technology to the drilling of longholes in coal has resulted in the development of a system currently capable of drilling to lengths greater than 200m. Field tests at the German Creek Mine have demonstrated directional control of the holes within a 0.5m section of the seam. Initial application of the technique at the German Creek operations is for drilling methane drainage holes. These developments, in three stages, result from support by the National Energy Research Development and Demonstration Council

Jan 1, 1991

By Thompson D, Burgess G. C

Subsequent to large scale trials in 1987, the installation of a submerged lance Sirosmelt furnace system was approved in late-1988 for the cupellation of retort bullion to dore silver. Commissioning work commenced in June 1990. During the process air is lanced into a molten slag bath contained in a cylindrical vessel to rapidly oxidise the granulated feed bullion from 15 - 25 per cent silver to rough dore grade. The process is now an integral part of the Precious Metals operation replacing the first stage reverberatory cupellation furnaces to achieve productivity improvements, lower silver inventory and increased silver Recovery.

Jan 1, 1992

By C B. Valentin

It is acknowledged that the analysis of iron ores using X-ray fluorescence (XRF) for major and minor elements is best carried out on fusion discs. This method of sample preparation eliminates mineral and particle size effects which can lead to biased results when using pressed powder pellets. However, the fusion disc method is costly as it requires a high capital investment in platinumware, requires experienced operators and uses expensive fluxes. Also, the dilution effect complicates the analysis of trace elements. For many applications, such as exploration and mining control, the method of XRF analysis of iron ores by pressed powder pellet probably provides data of adequate quality. Kumba Iron Ore, an iron ore producer in South Africa, recognises this and carries out most analyses of iron ore by pressed powder pellet and uses the automated fusion method mainly for certification of in-house calibration standards and quality control (QC) samples that are used for validation of pressed powder pellet method purposes. Automated fusion is also used for analysing the composite export shipping samples. All the other exploration, production, despatching and plant operation samples are done by the pressed powder pellet method. Automation of sample preparation procedures should improve the quality of data for pressed powder pellets. To compare the precision of the three methods of sample preparation and XRF analysis, 20 aliquots of a QC standard were prepared and analysed by each procedure/preparation method. The results and statistical data on the most important elements, Fe, K2O and P, are as shown later in Table 2.Clearly the precision is best for the auto prepared fusion discs, as expected, and worst for the manually prepared pressed powder pellets. However, the data generated from the auto prepared pressed powder pellets compare remarkably well against those from the auto prepared fusion discs.

Jan 1, 2007

By Anylmore M, Walker A, Fletcher A

Roasting of sulphide and sulph-arsenide gold ores produces unwanted emission of sulphur and arsenic oxides, and a less than complete recovery of gold. Pyrite loses sulphur and arsenopyrite loses arsenic at a useful rate at temperatures of 600¦C and above in an inert atmosphere. Sulphur and arsenic driven off can be condensed before entering the atmosphere. During the process, solid-solution gold redistributes itself on internal surfaces of the resulting iron sulphide. Two subsequent processing options may be used; direct cyanidation of the porous sulphide resulting from the anoxic pyrolysis, or a second-stage roast to oxidise the remaining iron sulphide. The first option may be viable under certain conditions of pyrolysis. The two-stage option has an environmental advantage over the traditional roast because it reduces oxide vapour emissions by 50 per cent. The second stage may provide nearly enough energy to sustain the entire process.

Jan 1, 1992