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By A K. Bhatnagar, S Saha, P Dixit, A K. Mukherjee, P Patra

TATA Steel’s R&D Division at Jamshedpur has developed a slime beneficiation process to recover iron values from iron ore slime. This process recovers iron ore concentrate containing 2.2 per cent alumina from a feed containing 7–10 per cent alumina. The reject generated from beneficiation of iron ore slime is treated as waste as the iron content in the reject is below 45 per cent. Effective utilisation of this waste is required for making the iron ore slime beneficiation process a zero-waste technology. In this connection several studies were made towards utilisation of slime waste. One of these studies revealed that slime waste can be used as a soil conditioner. Slime waste contains particles of size less than 10 micron and when these particles are mixed with soil in definite proportions, the porosity and the permeability of the mixture goes down. As a result, the water holding capacity (WHC) improves. This concept was evaluated through a series of tests at greenhouse level to optimise the soil to slime ratio. Finally, a pilot scale field trial was carried out over a period of three months using paddy rice as the crop. Three separate plots with compositions of: soil + organic matter comprising Farmyard Manure (FYM), (ii) soil and slime waste (2:1) + organic matter (FYM), and (iii) soil and slime waste (2:1) + organic matter (FYM) + Nitrogen, Phosphorus and Potassium (NPK) fertiliser were used for the pilot trial. The results showed a 20 per cent increase in the productivity of paddy rice for plot (ii) as compared to plot (i). This was due to the beneficial effect of slime waste in the soil. The addition of inorganic fertiliser such as NPK in the ratio of (4:2:1) further enhanced the productivity of paddy rice.

Sep 18, 2023

By A Innis, A Bye, B McCarthy, S Glover

Technology adoption in the mining industry has been steadily increasing over the past decade, driven by the need to improve operational efficiency, safety, sustainability, and profitability. As mining companies wish to implement solutions to improve mining safety and productivity, various technologies are being integrated into mining operations to enhance processes, reduce risks, and optimise resource utilisation. Adoption of new technologies such as autonomous trucks requires a strong focus on foundational operational technology (OT) and a systems-thinking approach. OT support is critical however, OT is traditionally not considered or integrated into standard maintenance activities. Consequently, sourcing and applying service support to OT systems in real-time has posed significant challenges to date. Neglecting the monitoring and upkeep of these operational technologies and equipment can lead to a host of adverse consequences. Operating instability becomes more prevalent, necessitating reactive measures, and the vulnerability to cybersecurity threats increases significantly. To address OT monitoring and maintenance challenges, a systems wide mindset and remote support discipline must be utilised. Remote operations support refers to real-time, 24/7 monitoring, control and support of site OT: network, production systems, maintenance systems, enterprise systems and mobile and fixed plant through a single interface remote from site. The presence of a disciplined team, grounded in a systems-oriented approach, is of the utmost importance to remote monitoring, given the intricate interdependencies of OT systems. The ability to understand the relationships among multiple systems, coupled with the capacity to distinguish between symptoms and root causes, assumes a pivotal role in operations. Through diligent monitoring and the astute understanding of system thresholds, remote operations support can actively identify and alleviate constraints, in turn, serving as the enabler for transformative advancements in technology output.

Sep 1, 2024

Vertical flow systems (SAPS, vertical flow wetlands) are increasingly used for passive treatment of mine drainage that is net acid. Data on 30 systems in eastern US show that well designed systems typically add about 40 g/d/m2 of alkalinity to influent net acid water. If they are designed with a conservative loading rate of 25 g/d/m2 and carefully constructed, they produce net alkaline water. Alkalinity added depends on influent acidity, Fe, pH, and retention time, and ranges widely, from 7 to 484 mg/L, so this is not a useful design criterion. Some waters may benefit from retention times longer than the conventional 12 - 16 hours, but the design must be partly based on cost-benefit considerations. Systems with fine limestone added to the compost layer perform better than average, perhaps to an alkalinity generation rate of 80 g/m2/d. A variety of problems are noted in the 30 systems and others reported in the literature. Systems with high influent Fe (> ~75 mg/L, varying with pH) tend to gradually decrease in flow rate because of precipitation and settling of Fe hydroxides on top of the compost layer. Some high-Fe systems precipitate Fe in the limestone layer, suggesting inadequate compost thickness, or short-circuiting through thin spots. Systems with Al exceeding about 10 mg/L tend to plug because of Al hydroxide precipitation in the limestone layer. Flushing only removes a small part of this precipitate, but can extend life. Some systems are ineffective because of failure of the inflow system. Some systems are uneconomic because they are oversized. A continuing program of inspection and maintenance is necessary for long-term performance.

Jan 1, 2003

By R Blin, R Walde, R Belli, D Inaudi

A fiber optic distributed sensing system allows the monitoring of parameters useful to determine the short- and long-term behaviour of the structure in response to the external actions, including, eg seismic activities as well as long-term phenomena such as seepage, tunneling, sinkholes, and other geo-structural movements. Monitoring of large retaining structures with such a system provides direct strain/deformation and temperature measurements on the broad interior area with an arrangement of several sensing cable lines, enabling early detection, localisation and sizing of subsurface damages. Measurements are provided every meter along the entire sensing cable, this is particularly important in such cases where the location of defects and damages cannot be predicted. Fiber optic distributed sensing cables are generally available for retrofit installation inside the dam structure using trenches on the downstream face or laid during construction below the geomembrane liner within the bedding sand layer. Mapping the cable route enables exact correlation between a linear coordinate on the cable length and a position in the dam. Cable installation is envisaged to be carried out during further raising of the embankment; additional cable sections are plugged to the previously installed cables and measured with the existing measurement system, requiring only an update of the mapping. The measurement system is placed remotely from the sensing area since a section of sensing cable can be used to link to the sensing area at the storage facility several kilometers away. The system is available for on-line, 24/7 real-time operational data management. Such fiber optic distributed sensing systems allow storage facilities to be monitored with long, accurate, continuous and precise data for geotechnical diagnostic purposes. This contribution will introduce the principles, benefits, and limitations of this technology.

Jul 1, 2021

By B G. Lottermoser

The placement of sulfidic waste below the groundwater table ensures limited interaction with the hydrosphere and suppression of sulfide oxidation. However, if sulfidic waste is placed above the groundwater table and remains uncovered, the backfill becomes part of the unsaturated zone and is exposed to atmospheric oxygen and leaching. This study aims to establish the leaching behaviour of sulfidic waste placed above the groundwater table and the impact of such leachate on the local aquifer at the Thalanga base metal mine. Mining of the Thalanga copper-lead-zinc deposit resulted in a large final mining void (600 m + 150 m + 70 m) and extensive underground workings. The underground workings were partly filled with tailings and the open pit was partly backfilled with acid producing sulfidic waste rock. In addition, the pit serves as a sink for acidic run-off from adjacent waste rock piles and mine workings. To date, the backfill of sulfidic waste rock placed into the pit has not been capped with benign materials and for most of the dry season, the surface of the backfill is covered by melanterite-type efflorescences. Results of kinetic column leach experiments conducted on the sulfidic waste indicate that Cd, Cu, Zn and SO4 rich waters migrate from the backfilled sulfidic waste into the local unconfined aquifer. However, the seepage of alkaline (pH 7.3 - 8.0), high conductivity (>10 000 ¦S/cm) tailings waters into the remaining pit void clearly shows that the acid leachate originating from the sulfidic waste rock does not impact beyond the waste repository and its immediate environment. Geochemical modelling implies that minimal or no mixing occurs between the acid waste rock leachate and the alkaline tailings waters.

Jan 1, 2003

By M Iglesias-Martínez

The potential for iron ore in the Central African Archean belts has received much less attention by comparison to their equivalents in other cratonic regions of West Africa, South Africa, Australia and Brazil. Historically, iron ore is known to occur in South Cameroon and North Gabon with significant iron ore deposits (eg Mbalam in Cameroon, Avima in the Republic of Congo, Minkébé, Bélinga and Boka-boka in Gabon), having been the subject of geological exploration programs carried out by government institutions and exploration companies. Although the presence of strong aeromagnetic anomalies, undeniably related to the presence of greenstone belt formations, has been recognised, this study is the first attempt to assess the potential of banded iron formations (BIF) in the Northern part of the Gabonese Republic in the region between Minvoul and Minkébé (>10.000 km2). Deep lateritic weathering, inaccessible equatorial rain forest and high operational costs are some of the reasons why only limited exploration has been undertaken in the area. This work aims to improve the geological knowledge and to highlight the potential for iron ore of the eastern margin of the Ntem Complex units dated between 3.3–2.7 Ga. Field work showed a series of mafic rocks (amphibolite, anorthosite and gabbro), schist and BIF (described as itabirites in neighbouring areas). Samples from Minvoul BIF showed an extensive and deep weathering to powdery hematite revealing the presence, in thin sections, of iron oxides including magnetite, hematite and martite, primary and secondary quartz, garnet, hornblende, anthophyllite, cummingtonite and epidote. Mineral assemblages and coarse grain size suggest a metamorphic grade ranging from medium to upper amphibolite facies. The existence of known economic iron ore deposits in neighbouring regions combined with an extensive weathering enrichment process are promising factors for potential iron ore discovery in this remote area.

Sep 18, 2023

By N Trabelsi, D Bakun-Mazor, Y Ben-Ari

As part of a comprehensive project to develop a remote sensing tool for evaluating the mechanical properties of rocks, one must obtain a rapid indication of these properties using conventional field methods. A common method for evaluating the mechanical properties of rocks in the field is to use a Schmidt hammer, a portable device that measures the rebound (R) of a spring-loaded mass impacting against the rock surface. Since the 1960s many studies have been made to find empirical correlations between the R value measured by the Schmidt hammer and mechanical and physical properties such as uniaxial compressive strength (UCS), elastic modulus, density, and porosity. Despite the existing correlations in the literature, this work is required to establish detailed empirical relationships for the carbonate rock units in Israel. To do so, 150 rock samples were collected from 38 different outcrops of carbonate rock units. In each outcrop, 20 impacts were made using a Schmidt hammer at different but adjacent points. The impacts were done horizontally perpendicular to the vertical rock walls. In the laboratory, we measured the density, effective porosity, water absorption, UCS, and elastic modulus. The rock samples we selected contained a wide range of UCS: from 7 to 270 MPa. Our empirical correlations indicate an exponential relationship between R and UCS and the elastic modulus, and linear relationships between R and density, porosity, and water absorbance. The most reliable index is the average of the five maximum impacts out of the 20 made in each rock outcrop. The correlation equations obtained from this work will make it possible to effectively evaluate the mechanical properties of the intact rock in the field, thereby aiding development of advanced tools for rock mass characterisation by means of remote sensing.

Nov 29, 2022

By G J. Showers, P Botman, A G. Hunt

Iron Road Limited (Iron Road) is currently evaluating the feasibility of producing 21.5 Mt/a of high-grade (>66 per cent Fe) magnetite concentrate from a 3.7 Bt resource (JORC) located at Warramboo on the central Eyre Peninsula in South Australia. Bulk concentrate can be produced via a conventional grind and low-intensity magnetic separation flow sheet. Due to the comparatively coarse magnetite liberation size (106 µm), consideration was given to enhancing both the grind economics and coarser product sizing via gravity separation.This paper outlines the test work, flow sheet design and engineering design of a gravity beneficiation circuit (GBC) conducted by Mineral Technologies for Iron Road. The resulting circuit optimisation necessitated mass balance simulation by Iron Road’s SysCAD model to quantify the resulting changes in mill recirculation load. This included the determination of project-critical grinding power and energy requirements with and without the GBC installed into the primary ball mill classification circuit. The outcome of this work was the design of a GBC, including spirals and up-current classification, which led to a substantial reduction (33 per cent) in ball mill recirculating load and power requirements, together with a favourable coarsening of final product size due to the relatively coarser gravity concentrate. This has led to a significant reduction in project design capital and operating costs. A further benefit of this approach is increased recovery of (paramagnetic) hematite and lesser titano-hematite via gravity separation compared to an all-magnetic separation approach.CITATION:Hunt, A G, Showers, G J and Botman, P, 2015. Test work and design of a gravity circuit for Iron Road’s Central Eyre Iron Project, in Proceedings Iron Ore 2015, pp 139–142 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 13, 2015

The emerging coal seam gas (CSG) industry has the potential to provide a large-scale energy province for Queensland. Aquifer impacts and management of associated by-product water, both in terms of quantity and quality, are pivotal considerations for the development of a sustainable CSG industry.Legislative changes have been introduced to ensure that the CSG industry manages potential groundwater impacts and beneficial reuse of the by-product water to a level acceptable to both government and the community.The relevant new pieces of legislation covering petroleum and coal seam gas activities include the Petroleum and Gas (Production and Safety) Act 2004 (P&G Act), Petroleum and Other Legislation Amendment Act 2004 (POLA Act), the Petroleum and Gas (Production and Safety) Regulation 2004 and the Petroleum Regulation 2004. Other relevant legislation includes the Petroleum Act 1923 (Petroleum Act) and Part 7AA of the Mineral Resources Act 1989 (Coal Seam Gas Regime). The P&G Act introduces a full regime for managing water rights. This includes provisions for monitoring and reporting on the effects that the taking of underground water under petroleum tenure has on other bores in the area. The P&G Act also imposes a æmake good obligationÆ on petroleum tenure holders, which requires the restoration of bores affected by the taking of water or the payment of compensation. These provisions represent a significant departure from the Petroleum Act, which says very little about water rights and does not specify restrictions on the taking of water under petroleum tenure. This paper attempts to outline the requirements and obligations of the P&G Act for the CSG industry in terms of underground water rights, development impact assessments, aquifer trigger thresholds, monitoring and reporting requirements, as well as the make good obligations.

Jan 1, 2006

The Goonumbla district of central-west New South Wales, Australia, hosts four significant porphyry Cu-Au deposits that contain a combined probable ore reserve of 71.7 million tonnes at 1.2 per cent Cu and 0.5 g/t Au. Mineralisation in the Goonumbla deposits is associated with narrow, pipe-like intrusions of quartz monzonite porphyry, in which several intrusive phases have been recognised. Five textural characteristics have been used to distinguish the various intrusive phases recognised in the Goonumbla porphyry deposits: (1) phenocryst abundance; (2) nature of the groundmass; (3 and 4) proportion and mineralogy of the mafic and non-mafic phenocrysts; and (5) the presence or absence of anhedral quartz grains in the groundmass. In addition, each intrusive phase is classified according to its estimated original quartz, alkali feldspar and plagioclase contents. Features common to all of the intrusions are that they contain two types of plagioclase and two or three types of K-feldspar phenocrysts in variable proportions. Most of the intrusions also contain apatite micro-phenocrysts. The groundmass textures range from aphanitic through granular to euhedral K-feldspar in a quartz matrix. With only one exception, all of the intrusive phases recognised are either quartz monzonite porphyry or mafic (>5 per cent mafic minerals) quartz monzonite porphyry. The exception is a biotite - phyric monzodiorite, which occurs in the basal portions of one of the deposits. Textural variants of intrusive phases at Goonumbla have been investigated to establish whether specific combinations of characteristics indicate mineralised intrusions, while others suggest barren ones. Some correlations between intrusion types and Cu and Au grade have been recognised. The most important textural characteristic that relates to high grade mineralisation appears to be the low proportion of mafic minerals, because the quartz monzonite porphyry intrusions hosting most of the mineralisation in the two deposits studied contain

Jan 1, 1999

By J Davidson

Ion exchange using strong base resins is a well established technology for the recovery and purification of uranium from sulfuric acid leach liquors. Production of uranium at the Beverley Mine in South Australia includes acidic in situ leaching, ion exchange and uranium precipitation. The salinity present in the groundwater results in a relatively high concentration of chloride in the leach liquor reporting to the ion exchange plant. The impact of chloride on the ion exchange process is discussed in this paper. The results presented show that an increased chloride concentration in the lixiviant solution feeding the ion exchange plant leads to increased uptake of chloride by the resin during the loading cycle. At the highest chloride concentration studied (7.5 g/L Cl) chloride took up to 60 per cent of the resin loading sites. The impact of the chloride can be summarised as follows: for a given uranium concentration in the lixiviant feed solution, the uranium loading decreased with increasing chloride concentration; a consequence of decreased uranium loading is an increase in the frequency of elution, with an associated increase in elution reagent costs; and for a given elution efficiency, the uranium concentration in the barrens is expected to increase with increasing chloride concentration.A few options were examined to counteract the impact of chloride: an increase in elution efficiency was targeted to reduce the amount of uranium returning to the loading circuit; increasing the pH improved uranium loading, but this was found to also increase iron extraction; and preliminary screening of alternative resins showed that the higher the theoretical ion exchange capacity of the strong base resin, the higher the uranium loading.Work is continuing on uranium recovery from saline leach liquors, specifically investigating the performance of alternative resins.

Jan 1, 2005

Airblast overpressure legislative limits can be extremely difficult to meet throughout Australia, which has by far the most stringent limits of any nation in the world. As the difficulty in meeting the limits is strongly dependent on the scale of mining, it is not surprising that the Australian coal mining industry is experiencing particular difficulties in meeting these limits. Eight full scale overburden blasts have been modelled with respect to overpressure impact for a strip coal mine, involving both dragline (cast) blasting and pre-strip (non-cast) blasting. Overpressure levels in the range 100 to 125 dBL have been measured at distances varying from 2.4 to 5.7 km, and modelling has successfully estimated both the amplitude and shape of overpressure waveforms to within an average of 1.2 dBL. Typical errors of prediction are around 0.6 dBL. This accuracy of prediction has been achieved by considering the impact of only the face holes, and the accuracy of prediction of both shape and amplitude suggests that it is these holes which dominate the environmental overpressure impact at distances in the range two to six kilometres, for cast and pre-strip blasting operations. Modelling has been based upon the Elemental Overpressure Wavelet proposed by Richards and Moore (2002), incorporating actual hole coordinates, actual delay timing, and assumed delay scatter statistics. The incorporation of delay scatter statistics has been particularly significant, and allows the determination of the range over which the peak overpressure levels are expected to vary. To date, modelling has considered only the use of conventional pyrotechnic delays, though simple adjustment to the scatter definition would allow estimation of overpressure levels, and their variability, with electronic delays.

Jan 1, 2004

By K Williams, G M. Evans, S M. Iveson, K P. Galvin, C E. Loo

The Australian Research Council (ARC) has recently established an Industrial Transformation Research Hub in the area of iron ore, focused on iron ore characterisation, beneficiation, materials handling and end-use functionality. The research hubs are part of a new initiative aimed at building stronger relationships between industry and universities, while addressing issues of national significance. The ARC Research Hub for Advanced Technologies for Australian Iron Ore will focus its attention on developing innovative approaches for creating enhanced value across the full value chain through the characterisation of different ore types, beneficiation and materials handling and transport. This hub brings together five industrial organisations and a research team formed from well-established research groups based at the Newcastle Institute for Energy and Resources. These groups have a record of working closely with industry to create opportunities. Examples include new beneficiation technologies such as the Reflux Classifier for achieving gravity separation, the expertise of TUNRA Bulk Solids in materials handling and the Iron Making Centre at Newcastle, which is a capability maintained by BHP Billiton following the closure of its Technology Centre in 2009. The purpose of this paper is to provide an outline of the research hub and its objectives, some background on the research groups that now form the hub and an insight into the strategy adopted for developing and implementing new technologies. The paper also describes a range of novel technologies that have the potential to be developed and applied to iron ore beneficiation.CITATION:Galvin, K P, Roberts, A, Loo, C E, Evans, G M, Williams, K and Iveson, S M, 2015. Australian Research Council research hub for advanced technologies for Australian iron ore – an introduction, in Proceedings Iron Ore 2015, pp 7–12 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 13, 2015

By B A. Wake, G G. Lowder, M J. White

The Tooloom gold field is located within the New England Fold Belt in the far northeast of New South Wales, approximately 130 km south southwest of Brisbane. Gold was first discovered at Tooloom in 1857. Within a few years up to 10 000 people were mining placer gold deposits in the Tooloom valley and a few tried their hand at mining hard rock occurrences as well. Mining of alluvial gold continued in a small way at Tooloom until very recently, but only in the last few years, since Malachite Resources acquired its interest at Tooloom (now 100 per cent), has the full potential of this large, reduced intrusion-related gold field been appreciated. By the mid 1870s, once the alluvials were largely worked out, most of the early miners had made the 270 km trek north to the newly discovered Gympie gold field and Tooloom slipped into obscurity. Such was this obscurity that the Tooloom gold field was not recorded on published Government geological maps until 2001, four years after Malachite became involved. The many hard rock prospects that Malachite has identified in recent years were largely or completely unknown. Tooloom is a good example of blinkered thinking when it comes to modern mineral exploration. The New England province in NSW has long been the æpoor relationÆ to the much better known and more highly favoured Lachlan Fold Belt in NSW. It has also suffered serious neglect compared with the Queensland part of the New England Fold Belt that hosts such major gold deposits as Mt Morgan (>7 Moz), Gympie (>3 Moz) and Cracow (>1 Moz). Tooloom is proof that prospective geology does not stop at state borders.

Jan 1, 2004

In addressing the need for non-degree tertiary training, let us examine some recent reviews of engineering and geoscience education. The Finniston Report (1) criticised the formation of engineers in the UK and stated that this was largely due to the narrow British conception of engineering as a branch of applied science which militates against an effective marriage between theory and application. It also criticised the system for not giving students sufficient grounding in the synthesis of technical, human and financial considerations within their undergraduate courses. As we all know, this report has led to the restructuring of engineering education in the UK. More recently, a Review of the Discipline of Engineering was carried out in Australia by a committee chaired by Professor Sir Bruce Williams (2). The report stated that: Australia has a fairly good system of engineering education that should be made better. more should be done to develop the communication skills of both staff and students. more attention should be paid to changes in engineering practice and the human element in technology. there is a serious shortage of state of the art equipment in most engineering schools. female enrolments in engineering courses should be increased from the current level of about 7% to 20% by 1997. employers should develop a better understanding of the need for continuing education. staff in engineering schools should develop closer relations with employers of engineers. higher education institutions with engineering schools should give financial and other inducements to staff to increase the proportion of study leave or professional development leave spent working as engineers in the business sector. there is considerable room for improvements in the teaching process and in the development of evaluation schemes for assessing the teaching contributions of staff. In its recent report to the Council of the Institution of Engineers, Australia, the Task Force on Engineering Education(3) makes the following points: managerial, entrepreneurial, professional and interpersonal skills should be introduced and integrated into the undergraduate courses but studied in depth as part of continuing education. the continuing education policy of the Institution should be promoted and strengthened with all engineers required to pursue continuing education. the Institution should develop a comprehensive guide to continuing education available from universities, colleges and other public and private sector organisations.

Jan 1, 1989

By C M. Rebagliati, J G. Payne, K Roberts

The Pebble deposit, located in south-west Alaska, is one of the largest Copper- Gold-Molybdenum (Cu-Au-Mo) porphyry systems in the world, with a current resource of >8 billion tonnes which contain 73.7 billion pounds of copper, 87.1 million ounces of gold and 4.16 billion pounds of molybdenum. The Pebble deposit formed at ~90 Ma, during emplacement of subduction-related hornblende granodiorite porphyry intrusions emplaced into Jurassic-Cretaceous sedimentary, volcanic and subvolcanic intrusive rocks of the Kahiltna Terrane. The Pebble West and Pebble East Zones represent two thermal and fluid centres in a single large magmatic-hydrothermal system. The West Zone extends from surface to about 500 m depth, has thin zones of oxide and supergene mineralisation overlying hypogene chalcopyrite mineralisation, and is amenable to open pit extraction. The East Zone extends to at least 1700 m depth, is higher grade, occurs beneath an eastward-thickening cover of younger sedimentary and volcanic rocks, lacks oxide and supergene mineralisation, and is being evaluated for underground block-cave mining. Most Cu-Au-Mo was introduced with early K-silicate alteration and related quartz-sulfide veins. In the East Zone, a structurally-controlled overprint by advanced argillic alteration significantly increased Au and, to a lesser extent, Cu grades. Exploration potential at Pebble and its surrounding district remains high. Several other porphyry, skarn and epithermal deposits have been discovered in the district, but only limited exploration has been conducted. The eastern, higher grade part of the Pebble deposit remains open in several directions, with significant potential for resource expansion by ongoing, aggressive drill exploration. An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation.

Jan 1, 2008

By McIlveen GR

The water pollution hazard posed by the derelict Conrad mine site, to the water and associated stream sediment of Borah and Maids Creeks and the nearby Copeton Dam storage, has been assessed. Mine water, tailings and tailings dump leachate have polluted water and stream sediments in Borah Creek downstream of the mine site. Acidity, arsenic, copper, lead, iron, silver and zinc are the principal pollutants. Under dry and low flow conditions, mine water was found to be the dominant polluting source, however, leachate and run-off from tailings dumps were also significant under and following wet conditions. Soluble arsenic, lead, iron and silver species in mine water and leachate were found to be rapidly incorporated into sediments, but acidity, copper, and zinc persisted in the creek water. Under low flow conditions, the water of Maids Creek is polluted with copper and zinc (up to 4.4 and 34 mg/l for copper and zinc respectively) and the pH is decreased (from pH 5 - 7 to pH 3 - 6) by entry of Borah Creek water. Values found in Maids Creek were variable and related to flow regime and distance downstream from Borah Creek confluence. Water in Copeton Dam storage, having a much larger volume of water with a higher bicarbonate buffering capacity (50mg/l versus 15mg/1), is not affected by entry of Maids Creek water. Polluted sediment from Borah Creek has contaminated Maids Creek for 2km downstream to Copeton Dam storage. Stream sediment downstream of the Borah Creek confluence, contains up to 1.0% As and 1.4% Pb in the less than 200 micron size fraction. Under high flow conditions, arsenic was found to be moved out from the mine site as insoluble species, associated with suspended sediment in Run-off.

Jan 1, 1988

By K G. van den Boogaart, U Mueller

"An accurate prediction of benefit for some types of ore may require not just the ore grade, but a whole compositional characterisation of the estimates; that is, its full mineral composition including waste composition and nuisance elements. An example is Nickel laterite ores, where Ni/Co content must be complemented by estimates of many other elements, as these might have a notable impact on ore processing.Estimates are often obtained with (co-)kriging or co-simulation; however, geostatistics applied to compositional data may yield spurious and inconsistent results because of the constant sum constraint. The log-ratio approach avoids such problems. It proposes a three-step procedure: data are mapped to a set of log ratios of components; for example, the additive log-ratio transformation (alr) transformed scores are modelled with an appropriate fully multivariate geostatistical toolbox; for example, direct/cross-semivariograms and co-kriging or co-simulation results are back-transformed to the original units.Some practical aspects may make the application of this technique difficult: the assumption of Gaussianity and the high dimensionality of the compositions combined with the need for using multivariate methods. This contribution compares several ways of treating compositional data (combining normal score transformation, log-ratio transformations, and minimum/maximum autocorrelation factor (MAF) decomposition) with respect to their ability to generate sensible simulations. The various approaches considered are illustrated with a Nickel laterite data set for which ten variables are available. Both theoretical considerations and illustration results suggest that the best combination is (log)ratio-normal score transform-MAF, in this order. The factors so obtained are closer to Gaussian, approximately spatially decorrelated and can be simulated independently. Simulations can later be recombined to alr-simulations, which in turn may be converted back to point compositions. The resulting simulated compositions are compared with a full Gaussian co-simulation of the raw data. The log-ratio methods show reasonable to good reproduction of mean values, and distribution of the data set and by construction satisfy the total sum constraint, in contrast to the simulations based on raw data for which the total sums fluctuate strongly.CITATION:Mueller, U, Tolosana-Delgado, R and van den Boogaart, K G, 2014. Approaches to the simulation of compositional data – a nickel-laterite comparative case study, in Proceedings Orebody Modelling and Strategic Mine Planning Symposium 2014, pp 61–72 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Nov 24, 2014

The relative contents of Au in a series of groundwaters from water bores and exploration drillholes, located near Au mineralisation at Stawell, Ararat, Clunes and Ballarat in central Victoria, were found to be clear indicators of relative proximity to mineralisation in each region. In the same series, waters with anomalous concentrations of As distinguished Au mineralisation in bedrock from secondary palaeochannel or deep lead Au. In some groundwaters, acid pH values, high sulphate relative to other anions and detectable concentrations of reduced Fe reflected sulphide minerals associated with bedrock Au deposits. Close to some ore zones, locally anomalous groundwater concentrations of Mn reflected the Fe carbonates that accompany Au in these zones. In addition, elevated concentrations of other elements provided geochemical signatures for the aquifer lithologies associated with Au mineralisation. Of the lithological indicators Co and Ni, U and F, Rb and Cs, Mo and Li respectively reflected the mafic, felsic, potassic rich and quartz zones, principally in the Stawell mine area and to a lesser extent those at Clunes and Ballarat. Mineral stability diagrams, based on groundwater activities of K', Mgt and H`, demonstrated that a series of ore-zone groundwaters follow a trend that conforms with a biotite to sericite to kaolinite alteration sequence in aquifer mineralogy. This is a good illustration of how present day groundwaters under surface conditions can reflect the underlying mineral sequences that accompany these Au deposits. These observations around mine areas suggested that groundwater chemistry could provide a rapid and cost effective method of assessing prospectivity for An of extensive areas in central Victoria. To test this, regional sampling and analysis of 355 bore waters was carried out in a region where potential An bearing rocks are covered by Mesozoic and Cainozoic sediments and volcanics. Contoured elemental abundances and distribution from this program indicated five zones in which groundwaters had elevated Au and despite the cover, appeared to reflect variations in the underlying Palaeozoic rocks. Three of the Au zones could be in terrain affected by extensions or intersections of faults, a feature in common with the established Au deposits in central Victoria. Reflections of concealed Palaeozoic rocks included a possible zone of concealed Cambrian greenstones that coincides with three of the Au zones. It was concluded that each of the An zones represents a groundwater Au focus that warrants follow-up exploration.

Jan 1, 1997

By Butt C. R M

Resurgence in Au exploration during the past decade has been characterised by a considerable emphasis and dependence on geochemical procedures. This has been made possible, firstly, by marked improvements in analytical sensitivity over those previously available and secondly, of particular importance to exploration in Australia, by a better understanding of the distribution of Au in the regolith, which has led to the optimisation of sample media. These developments have given exploration companies the ability to seek and detect subtle and widespread geochemical signatures of concealed Au mineralisation and provided an enhanced capability to interpret the data. As a consequence, several new discoveries have been made, even in areas that have been intensively explored in the past. In the deeply weathered Yilgarn Craton (WA), and in equivalent areas elsewhere in Australia and overseas, Au has accumulated in the upper lateritic gravels and duricrusts of the regolith, probably during humid climatic periods in the Tertiary. The laterites may not only be Au ores in themselves, but research by CSIRO and CRC LEME has shown them to be very important sample media, (eg Anand and Smith, 1992). In many areas, however, the laterite has been eroded and hence is unavailable as a sample medium and chemical modification under more and conditions since the Tertiary has leached Au from the upper saprolite. This has greatly increased the difficulties of exploration, particularly where reliance was placed on sampling between 2 and 15 m of the surface. Further research, however, has demonstrated that, despite this leaching, recent remobilisation of An has caused it to concentrate in a specific soil component, pedogenic carbonate, usually in the top I - 2 m, thereby giving surface expression even to mineralisation that is concealed by over 20 in of leached overburden. Secondary carbonates, commonly referred to as calcrete, may precipitate as calcite and/or dolomite in regoliths where the average annual rainfall is less than about 600 mm. Pedogenic carbonates are those that form in unsaturated (vadose) soil horizons. They are widely distributed in the Gawler and Yilgarn Cratons. In the Yilgarn Craton south of about 30¦S ('the Menzies Line'), they are seemingly more abundant over more basic rocks and towards the south east (Figure 1). In contrast, groundwater calcretes form in saturated (phreatic) environments, typically in the axes of major drainages north of the Menzies Line. These are known to accumulate economically-significant grades of U but not, apparently, An.

Jan 1, 1997