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By R. Baker

A novel electrochemical half-cell and corresponding working electrode were designed to evaluate the electro-catalytic activities of catalysts in an environment close to that of an operating proton exchange or polymer electrolyte fuel cell (PEMFC). Cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) techniques were employed using the novel cell to characterize various methanol electro-oxidation parameters that contribute to the overall reaction on a fuel cell anode. The effect of temperature on methanol oxidation kinetics was examined in the potential range of 0.31 to 0.65V (vs. NHE). The data was collected in the temperature range of 20 to 80°C. Based on the experimental analysis and literature data, an equivalent circuit model (ECM) for methanol oxidation was proposed and was used to fit the EIS experimental data. The experimental data and ECM electrochemical data was used to extract electrochemical kinetic parameters for methanol oxidation such as the exchange current density, Tafel slope, and energy of activation for the reaction. Kinetic data, especially at different temperatures, is very limited in the literature.

Jan 1, 2005

By X. W. Yi, Z. J. Li, G. W. Ma

In this paper, the compressive strength and failure patterns of reinforced cemented paste backfill (CPB) were studied aiming to promote the stability of backfilled stopes. The concept of ductile backfill was proposed and a series of unconfined compression tests were carried out on both non-reinforced and reinforced cemented paste specimens. Portland cement (3% to 5% by weight of tailings) and five different types of ductile materials (0 to 0.5% by weight of solids) were employed in this experiment for the specimen preparation. The test results showed that inclusion of ductile materials enhanced the unconfined compressive strength (UCS), reduced the post peak stress loss and transformed the failure behaviour of specimens from classical brittleness to ductility. The strength of CPB reinforced with different proportions of polypropylene fibres was compared. The stress-strain curves illustrated that both cement and fibres contributed to the increase of UCS, but higher strain values at the peak stress were achieved by fibre reinforcement. CT sliced images acquired from X-ray computed tomography (CT-scan) demonstrated that the reinforced specimen developed irregular crevices at the edge of cross sections and gained the capacity of bearing large displacements owing to the mobilised tensile strength of fibres. It leads to the potential of avoiding unexpected falling blocks of CPB when adjacent mining occurs. This finding highlights a strategy to improve the self-supporting capacity of the fill mass with less cement usage and reduce the ore dilution rates when excavating to adjacent stopes.

Jan 1, 2015

Gold thiosulfate complex is difference with gold cyanide complex, which is easily adsorbed on activated carbon while gold thiosulfate complex cannot be satisfactorily recovered by activated car-bon. However, Gold thiosulfate could be recovered by activated carbon if cyanide is added into the thiosulfate solution. To avoid the cyanide solution, this paper will review several possible processes to recover the gold from thiosuldate solution: such as the cementation with metals, ion exchange resin and solvent extraction. The gold cementation with the powders of zinc, copper, iron and aluminium will be discussed. The advantage and disadvantage of each are compared. The consumption of thiosulfate and copper and feasibility of solution recycling will be discussed. The gold recovery by some ion exchange resins will be suggested. The processing conditions, its applications and the resin elution methods will be presented. The gold recovery by using solvent ex-traction will be reviewed. The processing conditions of solvent extraction process are discussed and compared.

Jan 1, 2014

Optimising flotation designs and innovations is a complex process involving many parameters, one of which is ensuring sufficient testwork is carried out at plant level before these innovations are launched in the marketplace. This paper will describe how modern design tools are utilized, what are testwork phases at various plants and how results and observations have helped to validate and optimise flotation design innovations. Scale-up of equipment has long been the prevalent trend, but how long can it continue? Are there other means for pushing the boundaries of present technology? Some present challenges and future directions are given in the light of theoretical criteria for scale-up and how it has been applied in practice. Very large flotation cells of 300 m3 size have been installed in New Zealand, and relevant results from the metallurgical and mechanical aspects are presented and discussed. Utilization of the cell volume is also important. New innovations in the hydrodynamic domain are presented and discussed. Means to enhance flotation of coarse and fine particles are shown with results from plant testwork. Accurate control of large flotation cells is vital to optimize yields and grades. Froth image analysis and intelligent level control are presented ? again - with relevant plant results.

Jan 1, 2014

By S. A. Pence, A. I. McCallum, V. de Korompay

"Special salt protection rings containing a water-swell• able, polymeric sealant are in successful operation in Canadian potash shafts. Installed above the Prairie Evaporite salt formation at a depth of 3,000 feet, the sealant is preventing formation water migration into the salt and pressure build-up on the concrete lining of both production and service shafts. The salt protection rings are not under the hydrostatic pressure of the formation water.The chemical sealant in use has the unique property of imbibing water and swelling. •Therefore, any water at• tempting to flow by the seal ring actually produces a tighter seal.The purpose of this paper is to discuss the sealant and its properties and uses. Installation of the material and its operation in two Canadian mine shafts is described."

Jan 1, 1971

By M Gao

Six new IsaMills were installed for the George Fisher flowsheet in the Lead/Zinc Concentrator of Mount Isa Mines to produce a product P80 as fine as seven microns. The objective was better liberation of galena and sphalerite. The IsaMill commissioning was completed by the end of 1999. The six new IsaMills were running to the metallurgical specifications almost immediately after start-up. This paper reports the performance of the George Fisher IsaMills in the zinc circuits and some of the latest development in the IsaMill designs and maintenance during George Fisher commissioning.

Jan 1, 2000

By W. Basuki, B. Setyotomo, L. Hakim, R. Hendrajaya

Due to high crack sensitivity of slab product of gas and oil line pipe application, its steel making process and alloy composition were evaluated and then improved to overcome its critical solidification process and reduced surface defects. The study was conducted at Slab Steel Plant Krakatau Steel. The purpose was to improve slab surface quality by reducing surface defects so that the slab surface doesn't need to be totally repaired. The method applied was by performing plant trial process, which the secondary process parameters such as alloying method and the casting parameters such as casting powder selection, metallurgical cooling, mould level control, and superheat were continuously monitored and then adjusted to the surface quality of the product. Based on the calculation of Ferrite potential of the steel, the chemical composition was designed to achieve optimum casting parameters in order to avoid high shrinkage during solidification. The results of the study are decreased surface defect quantity, and smooth casting process. The quantity of crack decreased by almost 90%. The slab surface repairing was significantly reduced from 85. % to less than 10%. These new casting parameters and developed alloy composition are then used and standardized for the mass production of the steel.

Jan 1, 2005

By K. T. Brashear, N. Ripepi

"Over recent years, specifically following the MINER Act of 2006, an increasing number of manufacturers of underground mine seals in the United States have begun using a form of pumpable cement or shotcrete to create barriers separating the working and abandoned sections of underground coal mines. This seal material, while generally considered to be homogenous and solid, contains a network of microcracks, voids, and delaminations. Generally, it has been assumed that methane (CF4) leakage around these seals is a result of movement around the boundary interface between the seal and surrounding strata. Using a perfluorinated tracer compound, perfluoromethyl-cyclohexane (PMCH), the movement of gases can be monitored through seal material to observe how gases move though the material, both intact and with faulting in the material. This paper documents two large experiments where the movement of PMCH was monitored in the field, along with modeling confirmation using 3D visualization software. INTRODUCTION According to a report in 2007, there were over 14,000 active mine seals in underground U.S. coal mines alone (Zipf, Sapko, & Brune, 2007). These seals are used for both ventilation and safety purposes, to direct the flow of air away from the abandoned area of the mine and to help eliminate the propagation of explosions that can occur on the outby side of the mine seal. The atmosphere on the outby side of these seals typical consists of low levels of methane that have the potential of producing leakage along the face of the seal on the inby side. Methane leakage around mine seals has historically been attributed to the permeability between the seal and mine interface (McPherson, 1993). According to the United States Bureau of Labor Statistics (BLS) between 2003 and 2012 an average of 17 deaths occurred annually in underground bituminous coals mines. The only time during the ten-year period where the fatalities were higher than the average was in 2006 and 2010, years which had three major explosions occurring in underground coal mines in West Virginia and Kentucky. Two of the explosions were propagated through the mine by seal failure or methane leakage around newly poured seals (Light, et al., 2007) (Gates, et al., 2006). These recent events, and new regulations regarding seal strength (MINER Act), have created a need to monitor the condition of underground mine seals. BACKGROUND Measuring the permeability of solid materials, such as concrete or seal materials, can be a valuable tool in the field of non-destructible testing (NDT). By using an inert gas, such as nitrogen, injecting the gas into a solid structure, and measuring the resultant flow rate and pressure differential, this can provide valuable information about the structure. Studies have shown permeability can be affected by the stresses applied to the structure, as well as temperature and moisture (Choinska, Khelidj, Chatzigeorgious, & Pijaudier-Cabot, 2007) (Abbas, Carcasses, & Olliver, 1999)."

Jan 1, 2015

By P. Rooney

In due course, new smelters will have to be installed in order to meet the increasing worldwide demand for copper. This paper presents the results of a study made for the purpose of identifying the most desirable countries in the world in which to locate a new smelter. Both sociopolitical and economic factors were taken into account. Criteria developed and methods used to assess each possible location are described. The study indicated that the most interesting potential locations are Canada, -Chile, Portugal and the USA for new copper smelting complexes.

Jan 1, 1983

By H. C. M. Gordon

IN every co al mine the hazard of fire in the underground workings is always present. This is a natural condition, because the mineral wrought and the supports normally used are themselves combustible and because underground fires may originate in many ways. The main causes of such fires are: (1) Open lights igniting gas, wood, or the coal itself. (2) Explosives igniting gas or coal. (3) Spontaneous combustion. (4) Electric sparks or short circuits igniting gas, wood, or coal. (5) Frictional heat igniting wood, coal, or oily material. (6) Explosions of gas or coal dust igniting wood or coal. The relative importance of these causes, and others less frequently met with, varies from district to district and depends to a great extent on the equipment and supplies used, on the training and discipline maintained among the workmen, and on the liability of the coal to heat spontaneously. It follows, therefore, that open lights should not be used and that, wherever there is the least possibility of methane being encountered, only locked safety lamps of an approved type should be allowed underground. It follows, also, that only 'permitted' explosives should be used and that the it use should be confined to conditions under which they are ?permitted?. Similarly, electric equipment should be of an approved type and all such stationary equipment should be housed in well-ventilated fireproof rooms. Such rooms, as well as entries to stables and oil houses, should be provided with doors which can be easily and tightly closed and which should be constructed of fireproof material.

Jan 1, 1937

By O N. Savassi

A rigorous methodology for prediction of flotation plant performance is presented, which is based on a standardised batch flotation test called the MFT. The work is part of the FLEET program, developed by MinnovEX with the support of seven large mining firms. The methodology is divided into three key steps: direct measurement of the kinetics of true flotation in the pulp, independent of hydraulic entrainment and other froth effects in the batch cell; benchmarking of the industrial plant over a broad range of ore types and operation conditions; and model calibration to describe froth effects in the plant, with a minimal number of parameters. To date, the methodology has been applied with success at several industrial plants, encompassing copper, gold, nickel, iron, lead, zinc and coal operations. This paper includes a description of the laboratory testwork procedure and scale-up to full industrial circuits. Examples of industrial application are also presented.

Jan 1, 2005

By Ana C. C. Pacheco, Maurício L. Torem

"The aim of this work was the study of the effect of the type (Fe3+, Al3+ and Fe3+ and Al3+ mixture) and of the coprecipitant concentration on As5+ removal by ACF. Removal of As5+ using Sodium Dodecylsulfate (SDS) as a collector was studied by Adsorbing Colloid Flotation (ACF) at laboratory scale. The morphology of the precipitate retained in the foam was analyzed by Scanning Electron Microscopy (SEM/EDS).By comparing the coprecipitant type and concentration studies it could be concluded that As5+ removal in the presence of Fe3+ (160 mg.L-1) alone, or a Fe3+ (80 mg.L-1) and Al3+ (40 mg.L-1) mixture, is equivalently effective (99,9%) and greater than in the presence of Al3+ (80 mg.L-1) alone (97,7%).Through SEM/EDS analyses, it was possible to observe that both morphology and composition of the precipitate produced in the solution and retained in the foam depend on the physico-chemical conditions of the system, that is, on the species present in the solution."

Jan 1, 2003

By Yves Boissonnas, Marco Bettelini

"INTRODUCTION AND OBJECTIVES The operational safety of long and very long rail tunnels represents a key issue in all development stages, including design, construction, commissioning and operation. The spectrum of potential threats is very broad and challenging. These issues can only be mastered by means of a proper combination of a number of safety measures at various levels. This paper focuses on the specific safety issues and the extremely challenging conditions characterizing very long and deep tunnels. They include a significantly increased risk during operation that the incident train cannot exit the tunnel by its own means, long self-rescue and rescue distances, the presence of a number of trains, possibly mixed traffic as well as significant thermal issues. Amberg Engineering is strongly involved in the design and construction of most long and very long rail tunnels in Europe, including in particular the Gotthard Base Tunnel (GBT), Lyon-Turin Base Tunnel (LTF) and the Brenner Base Tunnel (BBT). The combined experience arising from these tunnels forms an invaluable body of expertise, which is summarized in this paper. The focus is on shared issues with practical relevant examples and project-specific solutions. Special attention will be devoted to the 57 km long Gotthard Base Tunnel, which will be operational by mid-2016 and will be the longest infrastructure tunnel worldwide. VERY LONG TUNNELS IN EUROPE Overview From the point of view of safety, tunnels in excess of about 20 km exhibit a significantly increased risk that incident trains could stop within the tunnel. This is related to the European Technical Specifications for Interoperability (TSI) on rolling stock, to be discussed in the chapter on rescue stations. This paper will specifically focus on the following longest tunnels in construction or operation, listed in Table 1."

Jan 1, 2016

By N. Gurulaxmi Srikakulapu

The demand for high-grade iron ore has increased the importance of beneficiation of low-grade iron ores. The captive mines of Tata Steel Limited, India has reserves of Banded Haematite Jasper (BHJ) ore assayed 40% Fe, 40% SiO2 and <1% Al2O3. QEMSCAN study has revealed haematite and quartz as a major iron bearing and gangue mineral phases respectively. Liberation characteristics have showed 80% liberation can be obtained at particle size below 10µm. In the present study, reverse cationic froth flotation of BHJ using ether diamines is explored in Denver-D12 flotation cell. Polynomial response surface regression equation coupled with six-factor Box-Behnken design of experiments is used to generate the correlation between process separation efficiency and flotation parameters. Flotation studies of BHJ indicated that concentrate of 62% Fe can be achieved with 62% Fe recovery from Jig concentrate at optimum conditions. The obtained product can blend with pellet fines to feed in blast furnace. Keywords: banded haematite jasper, flotation, box-behnken design, response surface methodology

Sep 1, 2012

By Greg Watson, Dennis Ofiara

"TBMs have been used in mining in decades past, but their use has been limited and sporadic, due to both perceived and actual application difficulties. With new technology and mounting success stories, this is changing. For both coal and metals mining, deep ore bodies require long access tunnels, and an efficient and economical method of reaching those deposits. Today, mining engineers are considering TBMs as part of the overall mine development plan. Planned TBM mine drifts are not only longer, but have more complicated trajectories. Mine development TBMs will have to cope with varying geology, potential for high water inflows, steep gradients, and high temperatures. TBM systems are being planned to cope with such difficulties. TBM systems will be considered and increasingly deployed for mine development, even if commodity prices remain low. TBMs can satisfy the need for increased productivity, better life of mine infrastructure, and safety. Effective conveyor systems are essential to support TBM operation in many mining applications. Many mine development tunnels are slopes, driven down at the steepest practical gradient to reach the deep ore body. Conveyors are often the only safe and effective way to haul the TBM muck form such tunnels. This paper will review the historical use of TBMs in mining, and will discuss the 2015 status of TBMs and conveyor systems in mining, and the special requirements and adaptable features needed in order to make efficient TBMs a reality in mines worldwide.HISTORICAL USE OF TBMS IN MINING APPLICATIONS The first successful hard rock TBM was invented in 1954. Over the next decades, TBMs have been used in many mining applications: Mine access drifts in several Spanish mines •,White Pine Copper Mine, USA •,Selby Coal mine drift, UK •,Coal slopes in Appalachia, USA •,German coal mines accdess drifts, several mines •,Magma Copper San Manuel, USA •,Cape Bretton Undersea Coal Slopes, Canada •,Stillwater Mines, USA"

Jan 1, 2016

By Qiang Yu

This paper reports on a research project supported by NSF, which aims at developing a multi-scale methodology for systematic microstructure prediction in thermo-mechanical processing of metals. This methodology is based on combining mesoscopic microstructure models with macroscopic process formulations and involves the following three main steps: (I) based on the given global processing conditions, the gross deformation patternof the entire workpiece is modeled using a continuum-based algorithm, (2) the resulting parameters are then extracted from the continuum-based simulation, post-processed and passed on to the mesoscopic numerical module, and (3) the microstructural changes are finally modeled at the mesoscopic scale. This approach is expected to overcome the disadvantages of current microstructure prediction practice employing empirical relationships between microstructural features and processing parameters. Keywords: Thermo-mechanical processing, Microstructure, Grain growth; Recrystallization; Mesoscopic models; Finite Element Method

Jan 1, 2003

By John A. C. Fortescue

Details of the interactions between the environment and the growth of terrestrial plants may be complex and difficult to study. This paper focusses attention on some of these complexities by means of six examples, each of which provides information on an aspect of the interaction between the growth rate of plants and the chemistry of the environment. The relationships which exist between the information obtained from these examples and the concepts of "holism" and "transfer rate problems" are pointed out and the importance of long-term biog•eochemical studies in Canadian environments is stressed.

Jan 1, 1971

By S. Deonarain, L. S. Schultz

"This paper details the process and methodology followed to rehabilitate a rectangular ventilation shaft, situated in the Free State region of the Witwatersrand Gold Fields in South Africa. The shaft consists of seven compartments where self-mining of the sidewalls had taken place and damage to the decayed steel work in the shaft had taken place, thus limiting access down the shaft. The paper will provide some insight into the successes and challenges encountered during the project and may provide some learnings for future projects of a similar nature. INTRODUCTION The ventilation shaft forms part of the Phakisa Mine, situated in the Welkom area of the Free State province of South Africa, and is located in the Southern part of the Witwatersrand Basin, one of the world’s largest known and richest gold deposits (Figure 1).As is typical in South African gold mines situated in the Witwatersrand basin, the shaft is 1 770 metres deep (below collar). The shaft was sunk during the early 1940’s and comprised a rectangular shape with 7 compartments, used for both rock hoisting and men and material winding, respectively, with a single lift “Mary-Anne” compartment. Early in 2003, the mine decided to change the shaft from a downcast hoisting shaft to an up-cast ventilation shaft. The conveyances, ropes, winders and headgear (head frame) were removed and replaced with a high volume fan delivering 323m³/s of air at a pressure of 4.2Pa on surface. The up-cast velocity in the shaft was 6.5m/s, however this reduced significantly with the scaling of the shaft and the restrictions at shaft bottom. Although Harmony had converted the shaft from a downcast service shaft to an up-cast ventilation shaft some years back, the shaft steel work in the barrel of the shaft was left intact. Over the years, the steelwork in the shaft had decayed (rust and grime) and portions of this steelwork fell down the shaft. Concurrent with the decaying steel work, portions of the shaft lining had collapsed and it was getting progressively worse."

Jan 1, 2019

By Yi Luo

Subsurface strata movements and deformations caused by longwall mining operations in underground coal mines could affect many important coal mining activities, such as gob well degasification, ground water protection and multiple seam mining. The stratifications in the overburden have significant influence on the subsurface and surface movements and deformations in the ground subsidence process. An enhanced subsurface subsidence prediction model considering overburden stratifications has been introduced in this paper. In this method, the entire overburden strata are equally divided into a finite number of layers and the percent of the hard rocks in each layer is an additional input. The proven influence function method is applied to predict the subsidence on each of the predefined layers progressively upward using the predicted subsidence on the previous layer as the subsidence cause for the current layer. A computer program is developed to facilitate the calculations. A case demonstration is used to show the applicability of the proposed subsurface subsidence prediction model.

Jan 1, 2012

By Mark A. Koestel

Cobalt-sulfide mineralization can he found in potentially economic quantities where permeable, basal Cambrian formations "pinchout" against Precambrian pal eotopographi c highs. These environments are common around the Saint Francois Mountains of southeastern Missouri and they share many similarities with the geologic environments of Zambia and Zaire in South Africa. Exploration for this type of deposit involves test drilling targets identified by trend analysis from past drilling, geophysics, geochemistry and a comprehensisve study of regional geology and isopach maps. Innovative ideas, new exploration concepts and insoluble residue geochemical methods may provide the necessary "edge" needed to complement basic geologic understanding leading to ore discovery.

Jan 1, 1987