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By R Zavadil, S Kuyucak, F Fazeli

Proton exchange membrane (PEM) fuel cells generate electricity by reacting hydrogen and oxygen. A thin, bipolar electrode material provides a medium for electron exchange with the electrolyte, alternately serving as anode at the hydrogen-rich side and cathode at the oxygen-rich side. Stainless steels have sufficient corrosion resistance to qualify as bipolar plate materials. However, the protective chromite layer increases the contact resistance, the battery’s internal resistance; and thus, decreases the electrical efficiency of the fuel cell. A heat-treatment is proposed and investigated via simulation by ThermoCalc / Dictra and experimentally, to generate a sufficient quantity of conducting surface carbides that breach the protective layer. Once carbide growth is arrested, a subsequent heat-treatment is also needed at a higher temperature to restore the corrosion resistance by filling-in the Cr-depleted layer (sensitization) around the carbide particles.

Jan 1, 2014

By Ben Hogg

Since the development of the top-submerged lance (TSL) technology for copper and lead smelting by the cooperation of Mount Isa Mines (MIM), now owned by Glencore, and the Commonwealth Scientific Industrial Research Organisation (CSIRO) the core of the ISASMELT™technology has always resided in the lance system. Through continuous innovation and operation of our own smelters, first at MIM, subsequently at Mopani, and also at both the Kazzinc Copper and Kazzinc Lead smelters, Glencore Technology have expanded the core equipment supply to enhance the plant operability. The success of Glencore Technology’s expertise can be directly measured by the success of the Kansanshi Copper Smelter plant, which achieved 100% nameplate capacity within three months of start-up. This paper describes the ISASMELT™ core equipment and how it is applied to smelt sulfide materials. It highlights the strength of the ISASMELT™: continuous innovation to facilitate the versatility and continued increased capacity with every plant implementation.

By Edward J. Harvey

Joplin, one of the most famous zinc mining camps of a bygone era, is today experiencing a healthy growth in manufacturing enterprises. Manufacturing requires water, and knowledge of its availability and quality often is the main factor in location of industry. For this reason in January 1964, on the suggestion of the former State Geologist, Dr. Thomas R. Beveridge, a study of the water resources of the Joplin District was undertaken as a cooperative effort of the Missouri Geological Survey and Water Resources now under the direction of Dr. William C. Hayes and the U. S. Geological Survey. The project area is in southwestern Missouri on the Springfield Plateau and is bordered on the west and north by the Osage Plains of Kansas and Western Missouri, (fig. l). Upland altitudes rise from 900 feet above sea level in the west to 1400 feet in the east. The countryside is rolling to moderately hilly and much is excellent farmland.

Jan 1, 1965

By Deventer Johanna van

Ore bodies around the world are declining in grade, whilst increasing in complexity. The level of impurities relative to the valuable metal is steadily increasing, posing new challenges to existing operations. Ion exchange is widely used in the hydrometallurgical industry for both primary recovery of metals and the removal of impurities. The superior selectivity of ion exchange resins makes them exceptionally suitable for the removal of target impurities to very low levels, thereby saving operating costs, increasing the value of the final product and significantly improving revenue. The ion exchange process in these applications is very simple, using standard ion exchange equipment and acid regeneration. The process can be fully automated, requiring minimal operator interference and supervision Examples of impurities that are successfully removed via ion exchange include iron, antimony and bismuth from copper electrolyte. In the copper electrolysis process, antimony, bismuth and arsenic tend to form slimes which are dispersed in the electrolyte. These slimes contaminate the cathode and/or decrease the quality of the copper deposition. A special chelating resin was developed to remove antimony and bismuth, while at the same time ensuring minimal chloride leakage to the sulphate matrix. The work is described in more detail in this paper. Ion exchange is also used to remove copper, zinc and nickel from cobalt electrolyte. This paper addresses a few of these examples in more detail.

By N. Myung, G. Hwang, H. Kim, Y. Han, S. Choi

"According to research presently being conducted on selective lithium recovery in seawater, inorganic adsorbents with high selectivity and capacity for capturing lithium ions from liquid lithium resources are called lithium ion-sieves (LISs). Their low toxicity, low cost and high chemical stability make LISs suitable for lithium recovery from seawater. In the present study, the ultrathin LMO nanofibers with controlled diameter were successfully fabricated by an electrospinning technique with a hypothesis that greater aspect ratio (i.e., smaller diameter) would lead to the enhanced recovery of lithium ion from seawater. Design of Experiment (DOE) and dimensionless analysis were performed to systematically optimize the diameter and morphology of nanofibers. Several complementary techniques including FE-SEM and XRD were used to evaluate the physical/physicochemical properties of the nanofibers. Lastly, the lithium ion recovery was tested for the nanofibers with different physical properties using lithium ion solution. INTRODUCTION Demand for lithium resources is increasing in many industries across the world.1-2 However, the conventional resources for lithium is very limited, and it even gets worse to secure the resources due to low grade and/or complexity of feed materials. Much effort has been, therefore, devoted to obtaining lithium from aqueous lithium resources. Several methods such as solar evaporation3-4, co-precipitation5, and solvent extraction6 have been proposed for recovering lithium from an aqueous lithium source, but there are limitations on its use; It takes a very long time or conditions such as temperature, pH and Mg/Li ratio are severe. Lithium ion-sieve (LIS) materials are considered as a good lithium adsorbent because of their unique chemical structure that can selectively separate lithium ion from brine and seawater.7- 10 Furthermore, their low toxicity, low cost, and high chemical stability make LIS suitable for lithium recovery from aqueous lithium resources. Spinel hydrous manganese oxide (HMn2O4) derived from spinel lithium manganese oxide (LiMn2O4) after topotactically extracting lithium from the spinel structure by acid treatment is most widely investigated LIS.10, LIS materials have been actively studied in various forms for easy handling and high efficiency (i.e. membrane11,12, foam13-14, granular15,16). Among them, the 1-D nanostructure LIS with high specific surface area is excellent in efficiency.9 In this study, we present the part of our recently submitted work17. Specifically, we fabricated systemically lithium manganese oxide nanofibers with different diameter as a lithium ion adsorbent using electrospinning technique through design of experiment (DOE). Enhanced lithium ion adsorption properties of the HMn2O4 nanofibers with different diameter were investigated in lithium liquid resources."

Jan 1, 2018

By R. H. Beaton

"About 1905, a plant was constructed at C1ayburn, in the Lower Fraser valley, 4'5 miles east of Vancouver, to process shales from Sumas mountain into heavy clay products. In time, mining operations were found to be more favourable on the opposite side of the mountain, and by 1913 a plant, which soon became the centre of activities, was completed at Kilgard. Destroyed by fire in 1949, the plant was rebuilt on modern lines, and a second plant was established at Abbotsford, six miles to the west. The Company, from its beginning, has grown with development of the Province. In recent years, operations have kept abreast of latest developments, particularly in materials handling. Latest innovation has been the complete conversion of fuel from Bunker C oil to natural gas. In 1957 the Company became associated with Harbison Walker Refractories, Limited, a leader in its field in the United States, and its title was changed from Clayburn Company, Limited, to Clayburn-Harbison, Limited. Currently, the Kilgard plant produces sewer pipe, agricultural tile, and flue liner; the Abbotsford plant, refractories and facebrick. Improvement of products and development of new ones are tasks of a recently-completed testing and research laboratory.Almost all ware produced is marketed in Western Canada or Washing-ton State. The Vancouver area absorbs the bulk of structural clay products."

Jan 1, 1959

By Dimitrios Fillippou

Magnesium hydroxide is used in a number of industrial applications, from the neutralisation of acid effluents to the production of pharmaceuticals. High-quality magnesium hydroxide powders can be produced by hydrating slow-reacting magnesia in dilute magnesium acetate solutions. The process of magnesia hydration shows many similarities with a typical hydrometallurgical leaching operation; however, its kinetics are crucial not only for process design and control, but also for the production of powders with a desirable particle morphology. This article shows the results of an experimental work whereby industrial heavily-burned magnesia powders were hydrated in 0.01 to 0.1 mol/L magnesium acetate solutions at temperatures ranging between 333 and 363 K. Examination of the magnesium hydroxide produced and the analysis of the kinetic data suggest that the hydration of heavily-burned magnesia in magnesium acetate solutions is a dissolution-precipitation process controlled by the dissolution of magnesia particles. The activation energy was estimated to be 60 kJ/mol, while the reaction order with respect to magnesium acetate concentration was found to be about one.

Jan 1, 1999

By Jurij Karlovšek, Marko Žibert, Scott Keniston

"SUMMARY The importance of information management was recognised in surface construction industry decades ago, and has increasingly being recognised through formal process and laws. Around the world, these laws and codes of practice are currently being drafted and enacted, to reflect the development of software tools and corresponding increasing adoption by industry. This paper deals with specifics of implementing information modelling in tunnelling business utilising BIM (Building Information Modelling) technology developed for buildings as well as similar technology developed for mining industry. Although BIM is recognized initially as a 3D digital representation of physical and functional characteristics of a facility, the real benefits come when complex capability through construction sequencing and even detailed programming (4D) and cost capabilities (5D) are included. INFORMATION MODELLING The Architecture, Engineering and Construction (AEC) industry requires the production of design and construction information, which involves the input from several teams. The tasks allocated to each team need to be carried out in a particular order and coordinated in order to benefit all those involved and the project itself; this is known as “collaborative working”. To ensure the quality, and guarantee that information can be used without change or interpretation, working processes and standards needs to be agreed upon or else it will hinder collaboration and have a negative impact on project delivery. Case studies show that the additional capital delivery costs due to uncoordinated, inaccurate and ambiguous information amounts to 20-25%. The solution to overcome these problems and improve collaborative working in a project is the adoption of BIM. It is a modern approach to the design, documentation, delivery, and life cycle management through the use of project information databases coupled with object-based parametric modelling. BIM requires traditional practices shifting from simple drafting to using 3D native models for building design environment. Additionally, it requires that models are equipped with information that has been traditionally decoupled in a text or other kinds of documents. The goal is not in creating a 3D graphic representation of design intent; rather, it is a comprehensive information management tool based on the simulation of design and construction build around a central repository."

Jan 1, 2016

By D. Zhao

High temperature deformation characteristics of austenitic 304L, and martensitic 410 and 416 stainless steels were investigated by conducting compression tests over a wide range of temperatures and strain rates (950-1250 C and 0.001-20 s-1). Flow behaviors of the three alloys were characterized. Optical metallography was performed to determine the as-deformed microstructures. The flow behaviors were related to microstructural phenomena during high temperature deformation. Dynamic recrystallization was responsible for the flow softening. Both dynamic and static recrystallization were operating, and the recrystallized grain size increased with increasing temperature and decreasing strain rate. Strain rate sensitivity was found to increased with increasing temperature and decreasing strain rate. No defects such as cracking and shear bands were observed at those test conditions. Preferred processing conditions can be selected by considering as-deformed microstructure and strain rate sensitivity.

Jan 1, 1994

By H. Kinilakodi

In 2008, the authors developed a methodology for identifying underground coal mines at high risk for major-hazard events. It focused on major hazard-related violations of safety standards associated with high-risk conditions. Later, using a sample of 103 mines with 2008 and 2009 data, injury measures and U.S. Mine Safety and Health Administration (MSHA) citation data were combined into a safe performance index (SPI). The SPI was used to assess the relative safety-related risk of mines, including by mine-size category. In this paper, comparisons are made of SPI-associated, normalized safety performance measures across mine-size categories, with emphasis on small-mine safety performance as compared to large and medium-sized mines. Mining Engineering, 2011, Vol. 63, No. 10, pp. 73-77. Official publication of the Society for Mining, Metallurgy and Exploration, Inc.

Jan 1, 2011

By H. Polat, Q. Hu, M. Polat, S. Chander

"The electrostatic charge on spray droplets of ionic surfactant solutions and coal particles was measured and the results were correlated with the dust collection efficiency. When various surfactant were added, the magnitude of the droplet charge increased significantly and it was observed to be a function of surfactant type and concentration. The concentration of maximum droplet charge coincided with surfactant concentration where maximum collection efficiency was observed for these surfactants. Particles of coal also carried substantial amount of charge magnitude of which seemed to be a function of coal rank.Based on the results presented in this paper, it was concluded that ionic surfactant primarily act as a strong electrostatic charge inducer for droplets. Due to interactions between these highly charged droplets and naturally charged particles, the efficiency of droplet-particle collisions play a primary role when compared to the wetting and engulfment phenomenon which could only follow a successful collision. INTRODUCTIONWater spray are widely used to suppress airborne dust in mine atmospheres (Walton and Woolcock, 1960; Kobrick, 1970; Hamilton, 1974; Jayaraman et al., 1986). Several investigators have considered the use of surfactants to enhance the effectiveness of water sprays especially for difficult to wet particles such as those of coal (Glanville and Wightman, 1979). The capture of dust particles by water droplets involves droplet-particle collisions, adhesion of particles to droplets, and engulfment of particles into droplets. Surfactants affect these sub processes through their influence on droplet charge, surface tension, and wetting. The last two mechanism have been thoroughly studied in recent years (Walker et al., 1952; Cohen and Rosen, 1981; Glenville and Haley, 1982; Chander et al., 1988; 1991). However, little attention has been paid to the role of electrical charge on particles and droplets on the collision and adhesion of spray droplets and dust particles."

Nov 1, 1995

By V Mutton, L Potts, D Joyce

This paper describes the method of extracting sill pillars within the underground operation from under unconsolidated mullock fill at the Cracow Gold Mine. This pillar recovery method was initially successfully used to recover sill pillars at Crusader Mine, Western Australia in 2001. Globally significant resources have been sterilised due to the placement of loose rock fill above crown pillars and within adjacent stopes. The method described here offers significant opportunities to increase recovery of sill pillar recoveries.The royal orebody sill pillars at Cracow Gold Mine form a significant resource. Extraction of these pillars needed to be undertaken with minimal ore dilution and maximum ore recovery. The application that was selected to consolidate the loose mullock fill above each pillar used an injection grouting process (Minova FB200).Cracow Gold Mine mining method is bottom up bench mining. The pillars were left within the orebody to allow for stoping to commence whilst the decline was being developed. Due to the remainder of the orebody being extracted the only access to consolidate the backfill was from the sill pillar extraction level. Numerous problems were encountered and overcome from product selection and trial, system of injection to extraction.This pillar recovery process achieved a 95 per cent recovery of the sill pillar compared with an estimated 60 per cent typical for other mining options.CITATION:Potts, L, Mutton, V and Joyce, D, 2012. Pillar recovery at Cracow gold mine using grouted consolidated mullock, in Proceedings Narrow Vein Mining 2012 , pp 179-184 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Mar 26, 2012

By Jong-Jip Kim, J. G. Byrne, W. Kim, In-Ok Shim, John E. Flinn

"Two rapid solidification processes for 304 stainless steel were studied: centrifugal atomization (CA) in a helium atmosphere and atomization by exposing argon-containing melt to vacuum (VGA). Positron annihilation and x-ray line broadening measurements of explosively consolidated monoliths were used to clarify microhardness measurements as a function of annealing temperature. Interesting differences in positron response between CA and VGA materials are ascribed to more carbide formation in the CA material than in the VGA material in the 600 0C range. In addition, hot isostatic pressing of the CA material was examined as to the relations between mechanical behavior, pore shape, and relative density. A variable stress concentration factor is introduced into the theory to allow for changing pore shape as relative density increases.IntroductionThere are many potential advantages of rapid solidification processing (RSP), such as a high degree of matrix supersaturation, finely dispersed microstructures, improved chemical homogeneity, and retention of metastable phases, which have been studied extensively. To consolidate rapidly solidified material which is in powder form into useful shapes often requires subjecting the material to elevated temperature for extended periods of time under mechanical forces, as in hot isostatic pressing or hot extrusion. In such cases, some of the characteristics of the rapid-cooling step can be strongly affected. An alternative is dynamic consolidation (1), for example by explosive forming, where the time frame at least is extremely short.In the present work, effects of the consolidation processes of hot isostatic pressing (HIP) and explosive forming in a die are examined. The particular material is 304 stainless steel. The characteristics of both RS and VGA 304 stainless-steel powders were described by Wright, Flinn, and Korth (2) earlier."

Jan 1, 1988

By Takashi Fujii

In the OG (Osaka Gas) process which includes a fusion process of sewage disposal sludge in coke bed knowledge of molten and fluid properties of the sludge are most important to controll the process in good condition. Thus, the softening and melting temperatures and viscosity were measured by the sessile drop technique and a rotating viscometer. Obtained results are summarized as follows: Melting character of sludge slag is varied according to their composition, but closely related to CaO/SiO2 ratio in ordinary sludge and to CaO/(Cr2O3,+Al2O3+P2O5) ratio in Cr2O3 containing sludge. Fluid property of sludge slag has a correlation with optical basicity or Riboud parameter, However, the correlation is poorer than that of metallurgical slags. Especially, chromium oxide containing sludge shows high viscosity and behaves somewhat different manner from ordinary sludge.

Jan 1, 1992

By E. Divers

This Bureau of Mines report presents results of an underground evaluation to determine the respirable dust and gas control effectiveness of a combined (push-pull) face ventilation system for coal mines. The system utilizes both blowing and exhaust curtain, continuous miners equipped with radio remote control, and flight conveyors. Bureau of Mines tests showed a 97% reduction in respirable dust concentrations from the usual cab position on the continuous miner to the remote control operator's position. This allowed the remote control operator to be well within, and the usual cab position to exceed, Federal respirable dust standards. Tests utilizing a safe tracer gas, sulfur hexafluoride (SF6), to determine the face ventilation effectiveness of the combined blowing and exhaust system showed that the system also has excellent methane dispersion capability. Where wide entries permit, this combined face ventilation system and use of remote control can be a very effective method for dust and gas control.

Jan 1, 1982

By Paolo Prevedini, Antonello de Risi

"The city of Naples has one of the most ancient traditions of tunneling in the world, since Roman age until today. This was due to the softness of volcanic rock covering most of the city surface, this determined in centuries the excavation of many connected cavities, today still accessible. The building of metro lines promoted industrial tunneling construction: TBM, Raise Boring Machine, Vertical Shaft Machine and freezing technologies played a decisive role facing water pressure near the sea. MNspa is an advanced constructor with two lines built in parallel, mainly underwater. The planning of this infrastructure has been upgraded with the projects of international architects from all Europe, with installation of art masterpieces in station spaces while archeological excavations revealed artifacts since Paleolithic. The city expects to give a new image of the urban landscapes within the completion of all stations and consequent rehabilitation of interiors and external city spaces. A case study of Municipio square station, is chosen to explain the relevance of archaeological research in improving and developing the projects of Line 1 stations. In these pages, it will be explained how the engineering process required to deal with Art, Architecture and Archaeology to finally realize an extended urban renovation of Naples. 1 CITYSCAPE 1.1 Introducing the geological history of Naples In the evolution of the city, capital of the Magna Graecia and of consequent kingdoms, a new layer of buildings was added over the foundations of demolished walls of the precedent domination period: from the top of the Bourbons layer (the most common scenery of the city since 1734) to the Aragonese layer found just underneath it; then below stands the Angiovin city, which in turn is built above the Swabian traces; underneath the ancient traces of the Byzantine age are found just above the extended Latin age layer. The most ancient settlement, known as Parthenope, dates back to 1500 b.C. It sits below the Greeks remains of the city of Palepolis, which had been rebuilt under the name of Neapolis by Romans."

Jan 1, 2016

By L. Shang

In conventional continuous hot rolling processes, metals are usually reheated to a temperature such that the workpiece will maintain appropriate hot working characteristics as it proceeds through the rolling mill, assuming that the temperature is continually decreasing. Metallurgically, reheating will reduce micro-segregation in the as-cast material, may increase the as-cast grain size and will affect any second phase particles present in the as-cast structure. All these changes can affect the hot working characteristics, and the final as-hot rolled microstructure. In order to study the effect of reheating on AZ31 magnesium alloy, a plate sample was cast in a water cooled copper mould and a series of compression tests was performed at a temperature of 350 °C, strain rate 0.01 5-1, and strains from 0.2 to 1.0, after different reheating schedules. It was found that there is no significant difference in flow behavior between the as-cast sample and all but one of the reheated ones. The reheat treatment of the 'anomalous' sample was a two stage heat treatment; it was first reheated to 450 °C, cooled to room temperature, then reheated to 350 °C. The effect on the flow curve was to increase the flow stress. This result may be related to changes in second phase particle characteristics.

Jan 1, 2006

By D. Gill, R. Burgess, B. Kyslinger

"There is always a demand in the mining industry to improve the safety and efficiency of roof bolting. Since 2008, Anglo American and Fletcher® have been working together to develop a new roof bolter concept that is safer and more ergonomic while maintaining current production rates. The recognized types of machines currently used in South Africa are always under constant review for improvement; however, there are limitations to the current design. The majority of the machines in South Africa are the “Man in Position” roof bolters. There are currently over 200 of these roof bolters in South Africa, with the bulk of the machines being twin-boom units. When operated correctly, these machines are safe, versatile, reliable and productive. However, with the operators located close to the drilling and bolting operations, they can be exposed to operational hazards. In addition, the major amount of material handling can be quite difficult on an operator. Anglo American, with a desire to improve safety, approached Fletcher to develop a remote style machine with simplified controls that maintained the productivity of the twin-boom machines. After several prototypes, the current model was developed. The chassis was designed for better operator comfort. A dual mast drill module was implemented to reduce the total time to bolt a cut. A remote operator’s station was incorporated to remove the operator from the front of the machine. The design was all about producing a safe and ergonomic machine from front to rear. This paper will explain the evolution and technological advancements from earlier prototypes to the current production machine. INTRODUCTION With mining, especially coal extraction, comes the necessity of supporting the roof. Since the 1950’s, the primary method for roof support has been the use of roof bolts. Roof bolting is considered one of the most hazardous jobs in underground coal mining. In 2004, there were 3,405 injuries reported to MSHA (Mine Safety and Health Administration). Of those injuries, 17 percent were associated with bolting machines (593 injuries). The majority of the injuries resulted from rock falling from supported roof. However, injuries involving a part of the body being struck by, or caught between, during bolting and drilling occurred with relatively high frequency (Burgess and Steiner). Roof drilling and bolt installation is labor intensive and repetitive. These labor intensive and repetitive requirements can lead to cumulative trauma. Operators are expected to perform a considerable amount of lifting, carrying, bending, reaching and stretching. Back and shoulders become sore from bending and twisting to install bolts or lift and position drill steels, wrenches and bolts. Confined operator spaces also contribute to difficult and awkward working positions for the operators (Cornelius and Turin)."

Jan 1, 2017

By Ronaldo Luna, Donald Deardorff

"The use of load and resistance factor design (LRFD) is well documented since the 1960s for structural applications when it was first adopted into the American Concrete Institute Building Code in 1963 and was established for geotechnical applications by the Danish Geotechnical Institute about the same time under the name of Limit State Design (LSD).The Federal Highway Administration required all federally funded projects to use the LRFD method by 2007. Due to this funding requirement, recent LRFD research for geotechnical applications has focused on common bridge foundations (i.e., driven or drilled shafts), resulting in good documentation for design using these methods. Unfortunately, the practicing geotechnical engineer does not intuitively know how to create resistance factors for deep foundations systems that have design methodologies and installation techniques significantly different from driven or drilled shaft foundation systems.Helical anchors typically use semiempirical methods for preliminary capacity design and a torque correlation methodology during installation to verify required capacity. Here we provide basic information on the LRFD methodology for helical anchor design. Additionally, the First- Order Second Moment (FOSM) method is applied to a previous helical anchor study (Hoyt and Clemence 1989) to determine resistance factors for an ultimate tension capacity strength limit state.MethodologyThe concept of the LRFD method is to establish factors for both the load and resistance that account for uncertainties using probability theory. The factors increase the nominal load and/or decrease the nominal resistance such that the probability of failure is an acceptable value. LRFD also accounts for the effects of load combinations (dead, live, seismic, wind, etc.) by determining the probability of the combined occurrence. The general form of the LRFD equation used by American Association of State Highway and Transportation Officials (AASHTO) is:"

Jan 1, 2009

By Hylton McWhinney, Doanh Tran, Jewel Andrew Gomes, George Irwin, Sameer Pallavkar, Md Islam, David Cocke, Mohammad Rafiqul Islam

"High-performance nickel-based nanocrystalline zinc oxide adsorbents have been prepared adjusting Ni/Zn mol ratio of 1 :5 by thermal decomposition, coprecipitation and sol-gel method for selective adsorption of thiophene in liquid hydrocarbon fuels at ambient temperature and pressure. To understand the nature of reactive adsorption of thiophene (C4H4S) on Ni/ZnO, the effect of preparation techniques, morphological and textural structure on the desulfurization activity was investigated. A model fuel (20 mL) consisting of pentane (C5H12) and thiophene was prepared and adsorption experiments were performed by a batch method under ambient conditions. The physicochemical behaviors of the fresh adsorbents were obtained using X-ray diffraction (XRD) with EDAX, scanning electron microscopy (SEM). The sulfur concentration in the mixture was monitored by UV-vis spectrophotometry. The adsorption reaction confirmed that ZnO played a crucial role in taking up S element to convert it into ZnS. The deposition of nickel on ZnO is an innovative approach which takes advantage of the selectivity of Ni towards S-species and the high adsorptive capacity of ZnO support.IntroductionLow temperature deep desulfurization of fuels via selective adsorption of sulfur compounds keeping coexisting aromatic hydrocarbons and olefins intact is receiving increasing attention in the research community worldwide in order to satisfy the upcoming environmental regulations and fuel specifications. The sulfur compounds in the transportation fuels is a matter of concern when global crude oil slate is becoming heavier and sourer and environmental restrictions on both the refining process and the refined products are becoming more stringent. According to the current refinery technologies, the sulfur content in refinery fuel is typically around 300-500 ppm by weight (ppmw) [1-3]. Starting in 2006, sulfur limits in highway diesel and gasoline were set to 15 ppm and 30 ppm, respectively. During combustion sulfur in the fuel are converted to toxic sulfur oxide (SOx) and contributes to air pollution and acid rains [ 4]."

Jan 1, 2011