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By C. Heckman, M. S. Moats, A. Luyima, W. Cui

"Nucleation and growth of copper on 316L stainless steel from synthetic acidified copper sulfate was studied in the absence and presence of chloride ions and/or organic additives (HydroStar® 4208, DXG®-F7, Cyquest® N-900) using a potentiostatic technique. The current-time data obtained at 0.16V vs. SHE was analyzed using nucleation and growth models. Scanning electron microscope (SEM) images of deposits produced at 300 A m-2 show that the addition of 20 mg/L chloride ions increased the size and reduced the number of copper nuclei. Potentiostatic current-time data from the electrolyte without organic additives indicate progressive nucleation with two-dimensional (2-D) growth under diffusion control. SEM images obtained confirmed progressive nucleation with 2-D growth. 20 mg/L Cl- and 2.5 mg/L organic additives did not change the nucleation and growth mechanism, however the additives increased the number and reduced the size of copper nuclei leading to more uniform coverage of the stainless steel substrate.INTRODUCTION Electrowinning of copper is an important process in the manufacture of high purity copper metal. It is approximated that 20% of the world’s refined copper is produced from acidified copper sulfate solutions by electrowinning (Schlesinger, Sole, and Davenport, 2011). In many plants, copper is electrodeposited on AISI 316L stainless steel substrates for a period of 6-7 days, after which the copper is stripped from the blanks. Even though the deposition time for a commercial copper electrowinning circuit is around one week, it is critically important to control the nucleation, growth, and nature of the initial deposit (Sun and O'Keefe, 1992). Deposit morphology and structure are influenced by the real current density at the electrode surface. The real current density across the cathode surface is made uniform by proper design of the electrowinning cell and electrodes and careful operational practice. Even with good design and control, some current maldistribution occurs. The outcome of severe current maldistribution is poor deposits that affect product quality and/or increase energy consumption. To combat current maldistribution and create a larger operating window in terms of current density, temperature, and copper concentration, small amounts of organic smoothing agents (traditionally guar products) are added to copper electrowinning electrolytes. Moreover, these additives inhibit the growth of copper dendrites, which leads to improved deposit quality by producing bright, smooth, and dense cathodes."

Jan 1, 2015

By McGill Metals Processing Centre, S. Chang, L. Calzado, X. K. Cao, C. H. Hsin, M. Isac

"Due to the increasingly stringent cleanliness requirements for final steel products, there has been a growing interest in the possible use of micro-bubbles for the removal of inclusions with diameters smaller than ~50µm, present within the steel passing through a steelmaking tundish. However, several technological barriers have prevented the adoption of this technique in industry. These are related to a) the generation of micro-bubbles in liquid steel, b) the measurement of bubble size distributions, and c) the optimization of bubble injection conditions to create micro-bubbles. In the present study, a novel Aqueous Particle Sensor (APS) system was developed for the in-situ, on-line, detection of micro-bubbles in water, generated by a newly designed full-scale ladle shroud, located at McGill Metal Processing Centre (MMPC). Measurement results from the sensor were validated against bubble size data collected through a high speed camera and post-processed through the commercial software, Image J.Control variables and orthogonal experiments were designed to assess the dependence of average micro-bubble sizes and bubble size distributions on key experimental parameters. Those chosen were the air inlet flowrate, the distance of the gas injection port from the slide gate, and the number of injection ports used. The investigation demonstrated that the APS system can be successfully adapted to detect micro-bubbles up to ~800 micron diameters. Using this novel sensor, it was shown that multi-port injection using low air inlet flowrates, closer to the slide gate, were useful in forming small micro-bubbles within the flow through the ladle shroud. The results from the APS system were compared and validated against data resulting from an optical technique. INTRODUCTIONModern industry expects increasingly stringent cleanliness requirements for final cast products. Therefore, the numbers and sizes of inclusions need to be strictly controlled in steelmaking operations. Thus, the cleanliness of steel products depends on the amount, morphology and size distributions of nonmetallic inclusions in steel (Zhang L. & Thomas B., 2003). Since large, deep, tundishes provide longer nominal residence times for liquid steel passing through it to the exit SEN’s, this can provide the ideal place to separate inclusions, and bubbles can assist by removing help attach inclusions and float them to the top surface."

Jan 1, 2016

By R. D. Brown

The first step in achieving a rationalization of Canada's crazy patch-work quilt of mining taxes and policies was achieved with the release last November of a major federal-provincial report on the taxation of the Canadian mining industry. The Report, prepared by a group of federal and provincial civil servants, sets out a concise and informative discussion of the major taxation and incentive issues facing the mining industry, and puts forward major recommendations for more rational and moderate taxation policies. It will be considered by federal and provincial Finance and Resource Ministers for possible action by the respective governments. The Report was prepared in response to a directive from the federal and provincial First Ministers in February 1978 to review the federal and provincial taxation of the resource areas. Although the Report is more successful in identifying problems rather than concrete solutions, and reflects some continuing differences of opinion between the governments involved, it does represent an important first step in a comprehensive review of our resource tax policies. This article summarizes the Report, which is some sixty pages in length. Although a detailed discussion of it is beyond the scope of this article, the report itself is recommended reading for those concerned about the current state of the Canadian mining industry.

Jan 1, 1979

The Bureau of Mines has studied 260 underground coal mine fires which occurred from 1970 through 1989. Every fire had the capacity to be hazardous to life and property, however upon closer examination some were found to be inherently more dangerous than others. Our research involved reviewing and recording specific information contained in published Mine Safety and Health Administration fire accident reports. The objective was to determine if degrees of hazard relative to fire source or location could be construed from information contained in the reports. We specifically looked at the propensity for fires to cause injuries and fatalities as well as the need to seal the area in order to extinguish the fire. Relative to all underground locations, this review found that fires occurring in main haulage-ways were most likely to cause injuries and fatalities as well as require sealing of at least the immediate area to extinguish.

Jan 1, 1993

By Ye Chen, Jianhua Chen, Xianhao Long, Qingxia Liu, Zhenghe Xu

"It is crucial to understand the mechanism of the collector interacting with the mineral surface in the presence of water molecules, which could influence the relaxation and electronic properties of sulphide mineral surface due to the proximity effect for narrow band gap of semiconductors. The adsorptions of three typical collector molecules (xanthate, dithiocarbamate and dithiophosphate) on the sulphide mineral surfaces in the absence and presence of water molecule have been simulated by density-functional theory (DFT). The calculated results show that the adsorptions of collectors on clean mineral surface in vacuum are not in agreement with the observed flotation behaviours. The presence of water molecules has a great influence on the adsorption of collectors. The analysis of density of states of the mineral surface atom suggests that the adsorption of water molecules could influence the electronic properties of mineral surface and consequently influence the adsorption between the surface and the collector molecule.INTRODUCTIONIn the separation of multi-metal sulphide ores, the selectivity of a collector is a key factor for the efficient recovery of the aimed mineral. Xanthate, dithiocarbamate (DTC) and dithiophosphate (DTP) are the most common collectors used in the flotation of sulfide minerals. Generally, xanthate exhibits powerful collecting property but lack of selectivity. While dithiophosphate and dithiocarbamate show the good selectivity in the lead and copper sulphide mineral flotation. The mechanisms of these collectors interacting with the sulphide mineral had been attracted many attentions and several mechanism based on experimental results had been reported (Chander & Fuerstenau, 1974; Fuerstenau, 1990; Raju & Forsling, 1991; Crozier, 1991; Bradshaw, Cruywagen & O’Connor, 1995; Guler, Hicyilmaz, Gokagac & Emekci, 2006). However, the micro-mechanisms of the selectivity of these three thiol collectors on different sulphide mineral surfaces are not fully understood."

Jan 1, 2016

By Donald D. Murphy

My first contact with underground, bolt conveyors came when I was hired as a draftsman by the La-Del Conveyor & Manufacturing Company in 1935. At that tine relatively few nines were using haulage belt conveyors. Wore they were in use, they were usually loaded by chain or shaker type room conveyors which in turn were hand loaded at the working face. Duo to the low room tonnage, a gathering belt might receive who output of from six to eight rooms. For several years belts 26 and 30" in width were the favorites for coal mine use. Belt speeds very seldom exceeded 200 ft. per mm. at that time. Conveyor lengths for the majority of units lay between 1.000 and 2000 ft. For a number of years 25 H.P. drives were adequate for those conveyors. From 1940 until about 1950 loads and speeds went up slightly and 40 H.P. drives became the standard. Since the majority of mines were then using direct current power systems, we were able to use controllers with 3 or more steps of starting resistance. The slow belt speeds coupled with relatively long starting cycles kept the rate of acceleration low and gave us smooth, easy starts.

Jan 1, 1963

By Gilbert Sauriol

The mining complex, which the Mines Gaspé division of Noranda Mines Limited has operated in Murdochville since 1954, includes open pit and underground mines, two mills, one leaching plant and a smelter. The under- ground mining uses predominantly a large scale room and pillar method, rooms 15 m wide, 30 m high and 300 m long being common. Ore production is effected by 4.5 m3 front-end loaders and 32-tonne trucks powered respectively by 225 and 325 kW diesels. Daily dust and gas readings show that air quality can be maintained at an acceptable level with much less ventilation than that normally specified. This paper emphasizes the point that air requirements should be based on Air Quality Standards, thus allowing an operation to benefit from favourable conditions or from improvements such as exhaust treatment, fuel alteration, etc.

Jan 1, 1983

By Charles R. Barnhart

The Nitrogen Dioxide Cloud: After one year of testing it can be stated that we do know and understand a great deal about why the nitrogen dioxide formation is exacerbated in cast blasting. Picture 1 is an example of how concentrated the NOx can be from a cast blast. It has long been felt that 300 or more milliseconds of timing needs to be put between each row of detonations to allow the rock a maximum time of flight so the cast percentage is high. Our experiments have found that higher cast percentages can make with timing between 150 to 200 milliseconds between rows. Picture 2 show a definite improvement in nitrogen dioxide concentration and most of that was the result of shooting a previously shot end of the cast pattern that had not been dug, thus no confinement of the powder columns.

Jan 1, 2004

By Harry R. Nicholls

Preliminary tests on presplitting rock in the presence of an in situ static stress field were undertaken to study the influence of a horizontal static stress field on the creation of a vertical presplit fracture plane. These tests indicated that it is easier to fracture the rock parallel to the in situ maximum compressive stress than in other directions. Instrumented shots indicate that the interaction of stress waves generated by the detonating charges is probably responsible for starting tensile fractures between shotholes and that expanding gases may propagate these initial cracks by a wedging action. The hole spacing for presplitting appears to be equal to the half wavelength of the stress wave. However, wider hole spacing appears feasible if the initial fracture is started by closer hole spacing.

Jan 1, 1966

By C. Geier

Previous mine incidents show weaknesses in mine rescue preparedness from poor training in decision making, leadership and incident command center (ICC) protocols. Computer simulations offer a larger range of training opportunities for mine rescue teams focusing on exploration and communications. The mine rescue simulator developed by the Colorado School of Mines and Rite Solutions Inc. utilizes four computers for the instructor and team, with the instructor monitoring the team?s progress. As the team explores, it relays information back to the Fresh Air Base, which then reports to the ICC. This forces a three-step communication procedure, enhancing the team?s overall communication skills and developing ICC protocols. The simulator is decision-based, demanding team decisions be made quickly. Upon completion, teams commented positively. Generally, participants said that the simulator is useful for learning how to communicate and make decisions during mine rescue emergencies. This mine rescue simulator improves team training, providing effective communications practice with an easy setup and no production interruption.

Feb 1, 2014

By John G. Kuhm

INTRODUCTION The goal of any development drilling program is the drilling of the exact number of holes necessary to adequately determine grade and dimensions of an orebody, no more and no less. This cost of development drilling represents a large part of the total development budget. Any technique which eliminates unnecessary drilling costs produces beneficial results, both to the company and to the person who can claim the savings. This high development cost factor has produced a quantity of research to develop techniques, for efficient control of drilling programs. Recent mining literature is full of articles describing methods for measuring and increasing the effectiveness of these expensive projects. The method described in this paper was developed during the latter part of a major development drilling project at the Christmas Mine of Inspiration Consolidated Copper Company in Gila County, Arizona. It was used to test the need for drilling individual holes but could be expanded to control an entire project. This technique was used at Christmas as a practical means for evaluating adequacy of drilling on an individual hole basis, and it was possible to eliminate several previously approved holes. Application of this method involves an evaluation of geological conditions present and a good bit of common sense. Projects involving large disseminated, rather homogeneous orebodies of the porphyry-copper type would be the most likely candidate for application of the technique. Discontinuous orebodies would not be amenable to this technique. The method is based on the measurement of the linear correlation between the spatial distribution of two sets of data. The Pearson product-moment correlation coefficient is used. This is a standard statistic commonly used to measure linear correlation between two sets of data. The statistical significance of the correlation coefficient at a 95% confidence level is the main criterion for controlling the project. For purposes of reference we will call our technique the "correlation method" in this paper.

Jan 1, 1971

By E E. Hall, S, E D. Thimons, R J. Timko

The heart of mine ventilation science and technology is the protection of the life and health of the miner. Lung diseases that result from overexposure to various mine aerosols can largely be prevented by maintaining concentrations below prescribed limits. Maintaining safe aerosol concentrations depends, in part, on our ability to know what mine aerosol concentrations are in a timely and accurate way. The Centers for Disease Control and Prevention (CDC), National Institute for Occupational Safety and Health (NIOSH) has been developing several new tools to help miners monitor respirable coal dust, silica and diesel particulate matter. This paper will discuss three main topics. First, the latest results of the person wearable dust monitor (PDM), developed by Rupprecht and Patashnick under CDC contract. The PDM was tested side-by-side with conventional samplers at a number of US coal mines and results indicated that the PDM was comparable to conventional samplers. Second, improvements to the dust dosimeter monitoring technique that includes a new pump with built-in pressure transducer and algorithm to convert differential pressure to dust concentration have shown good precision. Third, advances in the use of the detector tube technique to monitor tailpipe diesel emissions and ambient diesel particulate matter show that strong correlations exist between differential pressure measurement and elemental carbon in the samples.

Jan 1, 2005

By M. J. Sapko

The U.S. Bureau of Mines has developed a portable meter for measuring the component concentrations in binary dust mixtures whose constituents have different optical reflectivities. The meter has been successfully tested with coal dust-rock dust mixtures taken from coal mines in Europe and the United States and fluorinated-carbon mixtures that change from carbon black to pure white during fluorination. Additional study has also substantiated the theoretical expressions used in the design of the meter.

Jan 1, 2010

By Krishna Parameswaran

This paper discusses sustainability considerations in primary copper smelting using selected examples of practices at ASARCO LLC, an integrated U.S. primary copper producer. Using the classic Brundtland Commission definition of sustainable development, i.e., “development that meets the needs of the present without compromising the ability of future generations to meet their own needs,” the paper discusses how copper mining and smelting practices can be made sustainable. The examples used to illustrate sustainability considerations include: (1) adoption of flash smelting; (2) emission reduction and process improvement associated with anode refining of blister copper and the converter retrofit project, and (3) preliminary research findings on alkali treatment of copper smelting slags and copper mine tailings.

By P. Condori

Palabora Mining Copper has a unique ore body composition which unlike other copper ore bodies has three main components in significant proportions; these are copper bearing ore, magnetite and dolerite. The high content of dolerite, a hard barren material, creates a high proportion of pebbles which normally are recycled back to the mill. This action increases the mill bearing pressure and power progressively until corrective actions are taken. A logical action to solve the pebbles generation would be to incorporate a pebble crusher. This in fact was done however two fundamental issues were encountered; the high content of magnetite and existence of a cyclone classification section. Due to the high content of magnetite, metal detectors have not been able to work efficiently to separate tramp metal which causes damage to the pebble crushers. The existence of cyclones in the circuit had a detrimental effect on the final product when the pebbles crusher was online producing coarse sandy material. Due to the difficulties in treating pebbles via conventional procedures and the unique Palabora ore composition and characteristics, sorting technology was investigated at laboratory and pilot scale. It was found that a combination of optical and electromagnetic sorting could efficiently separate dolerite from the copper bearing and magnetite ores. This paper reports the findings of the laboratory and pilot scale work performed and discusses the additional benefits to the circuit.

Jan 1, 2012

By B K. Da, S A. Balaji, G P. Roy, T K. Dutta

The raw material handling complex at the Durgapur steel plant provides iron ore, crushed coke and flux to two sinter plants. Either some facilities were not envisaged or not properly designed before the project stage which caused problems during operation of the plant. The absence of an in situ roll turning facility, used to increase maintenance activities for disassembly, transportation of rolls to central machine shop and assembly of rolls, led to decreased crusher availability and increased activities for the maintenance crew. The provision of a smaller vibro feeder/screen in place of a suitable sized screen caused jamming of the screen deck, adversely affecting screening efficiency and the crushing index of crushed coke. Some design modifications and developmental work was undertaken, such as the development and installation of an in situ roll turning facility in the existing limited space, achieving low feed (0.1 - 0.2 mm/rev), lower cutting speed of 30 - 40 m/minute for 350 BHN hard roll, which was also a difficult engineering challenge to bring within the tolerable limit of vibration. This was successfully achieved. Modifications to the screen deck, introduction of differential speed crushing and modification to the vibro screen and vibro feeder for uniform distribution of feed have been incorporated. These innovative design modifications to the in situ roll turning have led to a drastic decrease in maintenance activities and an improvement in the crushing index. Modifications to the screen have resulted in the elimination of jamming and improved screening. Modifications to the vibro screen before the primary crushers and to the vibro feeder before the secondary crushers have prevented excessive wear in the central portion of rolls, ultimately leading to increased roll life. Incorporation of differential speed crushing has resulted in an increased crushing index and decreased generation of micro fines. All the above modifications have led to distinct improvements in equipment availability, increased roll life and a decrease in maintenance activities and improvement in crushed coke granulametry, ultimately resulting in improved productivity and quality of iron ore agglomeration at the sinter plant. The innovative design modifications mentioned above are discussed in detail in this paper.

Jan 1, 2005

By G. W. Norval, V. G. Papangelakis, G. A. Moldoveanu

Smelting has been the primary method of treatment for refractory copper sulfide concentrates such as enargite (Cu3AsS4), but the pyrometallurgical processing generates elevated levels of volatile arsenic. The present research investigates a novel hydrometallurgical process of oxidative dissolution of enargite at ambient conditions in the presence of chlorine dioxide (ClO2), a very powerful oxidant generated in solution by the reaction between a strong acid (HCl or H2SO4) and sodium chlorite (NaClO2). The effects of initial oxidant concentration, particle size, agitation speed and temperature on dissolution kinetics and copper extraction were investigated. It was found that a stoichiometric ratio of ClO2:Cu3AsS4 = 9:1 were needed to completely and congruently dissolve the mineral with fast kinetics (<15 minutes) under ambient temperature. The dissolution extent (metal extraction) increases with increasing ClO2 concentration and decreasing particle size of solids, but is not influenced by temperature or agitation speed.

Jan 1, 2014

By A. G. Eccles

Western Mines&apos; milling circuit produces three concentrates (copper, lead and zinc), with the tailings being disposed of at the bottom of Buttle Lake. In view of the mine&apos;s location and the method of tailing disposal, a comprehensive pollution control program has been in effect since start-up. Changes -in the ore over the past few years have required the use of increasing quantities of sodium cyanide in order to effect a good copper-lead separation. This led to the use of alkaline chlorination for destruction of ?residual cyanide and precipitation of dissolved copper contained in the tailing effluent. The development of Western Mines&apos; alkaline chlorination plant is discussed in detail, including initial test work and the evolution of procedures leading to the present operation. The current monitoring program is also reviewed.

Jan 1, 1977

By Lassaad Hazzar

The ultimate lateral resistance of piles in cohesive soil is studied using the well-known finite difference code, FLAC2D. The Modified Cam Clay (MCC) constitutive relation is adopted in the analyses to model the cohesive soil behavior, whereas the structural pile model with three degree of freedoms, available in FLAC2D library, is adopted to model the piles. The reliability of Broms&apos;s method, still used in the current design practice of piles under lateral loads, is verified. Comparisons between the ultimate lateral resistances of piles and those deduced from the graphs proposed by Broms (1964) are presented in graphs. Different factors thought to affect the lateral resistance of piles in cohesive soil, not adequately considered in Broms&apos;s method, such as clay stiffness, pile length, pile diameter and axial load are parametrically studied. A special concern is devoted to elucidate the effects of over-consolidation ratio (OCR) on the ultimate lateral resistance of piles in cohesive soil.

Aug 1, 2013

By L Bergin, D J. Williams, S Islam, T A. Vangsness

The flooding of open strip coal mines in the Bowen Basin and Hunter Valley Coalfields of Eastern Australia has the potential to soften the spoil and floor materials to produce “mud”. This mud can act as a slip plane or weak zone when spoil is dumped into it, resulting in geotechnical instabilities. Once mud has formed, typical handling techniques include its costly removal by mechanical means, or its isolation and capping.There are little data available on the moisture state and shear strength of the capped mud. To investigate the effectiveness of isolation and capping, research has been conducted using a large slurry consolidometer (150 mm in diameter by up to 410 mm in height) to simulate capping in situ. Once consolidated, the mud was subjected to shear strength testing in a direct shear box measuring 60 mm by 60 mm by about 20 mm high. The shear strength of the consolidated mud was compared to that of competent, fresh spoil, a mixture of spoil and mud, and to completely degraded spoil (mud alone).These results have been used as inputs in stability calculations using the commercial computer program Slide 7.0, which demonstrates the strong influence of consolidation of the mud on overall low wall slope stability. The results provide insight into the design and construction of capping to isolate in-pit mud.CITATION:Vangsness, T A, Williams, D J, Islam, S, Smith, A and Bergin, L, 2018. Consolidation and shear strength testing and stability analysis of coal mine spoil degraded to mud, in Proceedings Mine Waste and Tailings Stewardship Conference 2018, pp 97–109 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 23, 2018