Search Documents

By D. B. Williams

The end of the war in Europe and the Pacific failed to curb the upward trend of production in Venezuela,- which easily surpassed that of any previous year. The total production for 1945 amounted- to 323,369, 430 bbl., which was 26 per cent over the total for 1944, the previous peak in the history of the oil industry of the country. This increase was caused mainly by the greater demand for petroleum in the last stages of the war; the fact that the danger from enemy submarines had been overcome, which allowed all oil companies to use increased shipping facilities, and the fact that more materials were available for drilling operations. However, the materials supplied were by no means adequate and considerable credit is reflected on the Venezuelan petroleum industry for the increased production obtained by utilizing all available equipment to its fullest extent.

Jan 1, 1946

By Lucia Vieira

Kelvin probe force microscopy (KPFM) can be used to monitor electrostatic charges on the surfaces of materials. In this paper, we describe the use of KPFM to evaluate the electrostatic effect induced by silver nanoparticles incorporated as clusters in diamond-like carbon (DLC) films, before and after scratching. The results are compared to those obtained for DLC films without silver nanoparticles. Raman spectroscopy was used to identify the DLC signature, and energy dispersive X-ray spectroscopy (EDX) was used to confirm the presence of silver in the film. The morphology of the DLC film containing silver was investigated using scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The findings suggest that the incorporation of silver nanoparticles in amorphous materials could offer new options for electrostatic energy storage on the surfaces of these materials.

Jul 31, 2018

By Jianping Li, Fei Peng, Yunbo Xu, Jiayu Li

In this study, in order to achieve ultra-high strength without reducing plasticity, a novel heat treatment involving a pre-quenching process prior to conventional intercritical annealing (P-IDP) was proposed in a low carbon low alloy DP steel. It revealed that abundant fraction of banded structure was observed after conventional intercritical heat treatment (IDP) due to the inheritance of cold rolling deformation. However, the banded structure in novel heat treatment was eliminated significantly, whilst the refined microstructure was relatively more homogeneous with ultrafine ferrite grains. Moreover, obvious chain-networked martensite grains along the ferrite grain boundaries were obtained. The optimum mechanical properties with ultimate strength of 1238 MPa, total elongation of 17%, product of strength and elongation (PSE) of 21GPa% were obtained by P-IDP treatment, which was much higher than the values reported with similar composition. As to pre-quenching treatment, all of grain refinement, homogeneous distribution of martensite islands and precipitated strengthening of microalloyed carbides were beneficial to improve the final strength and ductility.

Oct 1, 2019

By Bryane Prando Brandão

Aços microligados expostos a ambientes contendo H2S e CO2 (sour gas) sofrem corrosão generalizada que promovem a entrada de hidrogênio atômico no metal, causando fragilização por hidrogênio, podendo gerar falhas graves no material. O objetivo deste trabalho é estudar o grau de fragilização, utilizando ensaio Charpy, de um tubo API 5L X65 após diferentes tempos de imersão em uma solução saturada com H2S. O eletrólito empregado foi solução A (ácido acético contendo cloreto de sódio) da norma NACE TM0284-2011, fazendo-se purga com N2 e injeções de H2S. Os corpos de prova padronizados foram imersos durante 96 e 360 horas, sendo que após doze dias do término da imersão, foram realizados os ensaios Charpy. Foram levantadas as curvas da energia absorvida em função da temperatura, para corpos de prova com e sem imersão. Os resultados mostraram que mesmo após imersão, não houve modificação significativa na temperatura de transição do material, apenas uma pequena diminuição da energia absorvida. Esse comportamento sugere que o teor de hidrogênio em solução sólida aumentou em função do tempo de imersão, levando a tais resultados. O refinamento da microestrutura e o baixo nível de inclusões estão relacionados a baixa quantidade e uniformidade da distribuição dos sítios de ancoramento de hidrogênio irreversível, o que pode explicar o desempenho obtido.

Aug 7, 2018

By Jaiza Bernardo de Oliveira, Iasmim Ariane Silva, Pedro Henrique Medeiros Câmara

The process of manufacturing pig iron in the blast furnace industrial units has the consequence of the generation of slag, a waste that can be produced in high quantity and present damages to the environment, when not reused. In the composition of this tailings, it is sometimes possible to find the presence of metals harmful to nature, such as manganese, which has an important and widespread utility in the metal industries, but still, the slag ends up not being used as a potential source of this element. Knowing this, the slags were subjected to crushing and grading steps to separate the aliquots. These were applied in the tests of technological characterization of the material, from MEV, EDS, Soxhlet and analysis of liberation degree by digital microscope, finding data of several analyzes. Having said that, the objective of this paper is to demonstrate, through the characterization of the slag, that this material has in its composition metallic elements, focusing on manganese, that can be reused in order to avoid the generation of environmental liabilities harmful to the environment. The results show a manganese content with a degree of release greater than 80% in bands from 48 #, which were divided by density and thus allow the gravimetric separation of the material in question.

Oct 3, 2019

In this paper, three types of value-adding in the minerals industry are discussed: downstream processing, improving the efficiency of existing processing and increasing the knowledge base and expertise of the staff. It is shown that, while downstream processing seems to offer a good way of improving Australia's trade position, there are a number of impediments to such development, notably, limited access to the appropriate technology and overseas markets. Transport costs can also be a problem. To reverse the situation will require more positive policies by government. In the meantime, something can be done towards adding value by increasing the efficiency of existing processes. Examples are given, showing how it might be possible to make economies in reagent costs in the gold industry, how innovative technology has led to more complete processing of a tailings dump, how research might lead to an increase in the throughput in the production of synthetic rutile and how it is possible to leach selectively from gold/copper ores.

Jan 1, 1995

By T. A. Henrie, J. D. Marchant, E. S. Shedd

Cerium metal was electrowon in a fluoride bath from cerous oxide and tapped from the cell during prolonged operation . Electrolyte constituents were CeF , BaF₂ , and LiF. Twenty- seven pounds of metal of 99.8 percent purity were produced at a rate of 3 pounds per hour and tapped from the cell . Principal impurities were molybdenum , aluminum , oxygen , and carbon . The operating parameters , such as electrode geometry , bath compositions , and oxide feed rate , were investigated . Anode reactions were found to be important factors in cell operation . Stable cerous oxide reacted more uniformly at the anode surface than ceric oxide . Electrowinning was conducted in crucible hearths consisting of both frozen electrolyte and molybdenum metal . Both materials proved satisfactory and did not react with the molten cerium . Stable cerous oxide was prepared by carbothermic reduction and used as a feed material . Cell design proved to be an important factor in continuous cell operation . Complementary to the investigations of electrowinning of cerium , the metal was purified by electrorefining in a chloride electrolyte .

Jan 1, 1964

By MattelmSki M

Outokumpu Harjavalta Metals Oy has been producing nickel since 1962, based on conventional flash smelting technology followed by electrowinning of nickel. In the 1980s, a research project was initiated to develop a converterless direct smelting process to produce matte for further refining in the then existing refinery. The process was tested on a pilot plant scale at Outokumpu's research centre in Pori and was found to be viable. The process was named the Direct Outokumpu Nickel Smelting Process or the DON Process. At the turn of the 1990s, Outokumpu studied various options to develop its nickel business and the Harjavalta operations. As a result of this work, the DON Process was further developed to produce two mattes: low iron matte in the flash furnace to be leached in the existing leaching circuit and high iron matte in the electric furnace to be leached in the new leaching circuit. In Harjavalta's case, it was essential and important that the process could use the existing flash furnace and electric furnace without converters.

Jan 1, 1996

By D A. Sketchley

The Merlin Zone, a 2008 high-grade Mo-Re discovery, is a part of the Mount Dore Deposit in the Eastern Succession of the Mount Isa Inlier in Queensland, Australia. Hosted by carbonaceous metapelites and phyllites, the Merlin mineralisation comprises molybdenite veins, breccia infillings, stylolitic fracture fillings, and disseminations. Because rhenium is geochemically similar to molybdenum and commonly associated with it, global production of rhenium has been mostly a by-product of molybdenum refining. The high-grade rhenium in the Merlin Zone is an exciting discovery that is expected to become a direct source of rhenium. At the time of discovery, quality assurance (QA) procedures for rhenium were not in place at the Merlin Zone; therefore, they needed to be developed.The Merlin Zone was discovered using reverse circulation drilling, which led to concerns about molybdenite loss due to poor sample recovery. The twinning of the discovery hole with diamond core demonstrated a two-fold increase in molybdenum grade over several tens of metres. Consequently, the resources of the Merlin Zone were defined using assays from diamond drill core.Early analytical work, which was initially done only for molybdenum, comprised geochemical analysis with an aqua regia digestion, which have poor precision and can be biased low. Although initial testing for rhenium used similar procedures to those for molybdenum, a scarcity of commercial rhenium reference materials led to a validation process using neutron activation analyses and different digestions. This resulted in introduction of four-acid digestion assays, development of matrix-matched reference materials, and improvements to the quality of molybdenum and rhenium assays for reporting resources. Coarse and pulp duplicates were used to check for sampling bias and to ensure that levels of precision were adequate for the style of mineralisation and analytical methods. In addition, the direct and consistent geochemical correlation between molybdenum and rhenium provided another method for checking analyses.

Aug 22, 2011

By K. E. Yassin, A. Yehia, M. Amar

Phosphate fines (size ≤ 45 μm), from the Red Sea Region, Egypt, were subjected to beneficiation process to recover the phosphorite grains from such fines. The sample is characterized by low P2O5 content (18.78%) associated with gangue minerals such as silica (22.77% SiO2) and carbonate (2.01% MgO) indicating its low grade. Phosphate pre-concentrate was prepared by gravity separation, using Falcon, where 63.37% of the phosphate, with 24.94% P2O5, 1.46% MgO, and 10.54% SiO2, was firstly recovered reducing the mass flow to the subsequent beneficiation process. However, the gravity tailing was the feed for the reverse phosphate flotation using bench scale column flotation where oleic acid was used as a carbonate gangue collector and amylase enzyme as a phosphate depressant. Under the appropriate flotation conditions (0.1% amylase, 5·10−4 mol/dm3 oleic acid, and temp. 30 °C), phospho-concentrate assaying 0.61% MgO, 13.14% SiO2, and 27.85% P2O5 with a P2O5 recovery of 55.45%, was finally obtained without the use of expensive depressants, e.g., phosphoric acid or sodium silicate. A tentative flow sheet for the whole process was postulated.

By Amr Sallam, David Thompson, Moataz Hassan

"The Little Lake Harris (LLH) Bridge was constructed in 1951 to replace the eastwest County Road 48 Bridge connecting the towns of Howey-in-the-Hills and Astatula in Lake County, Florida, United States. The 78-span bridge carries two lanes of traffic, is 3,130 feet long, and 36.1 feet wide. The concrete deck is supported by steel I-girders carried by one row of 18-inch square precast concrete driven pile. In the late 1980's, slight settlements were observed in several bents. In 1990, Florida Department of Transportation (FDOT) initiated annual survey of deck elevations during bridge inspections to monitor settlement. Due to the slow nature and magnitude of settlement, substructure instability was not a major concern to the department. However, public concern over the settlement and rough ride of the bridge continued to rise. FDOT contracted Kisinger Campo & Associates Corp. (KCA) to provide the needed design to correct the dips in the riding surface and minimize future settlement. KCA's initial design was based on the concept of ""helper bents"" at the settled bents in order to restore the bridge to original elevation. Estimated construction cost for seven helper bents was about $3.3M. FDOT requested evaluating other alternatives to reduce the cost of the bridge restoration. KCA involved the geotechnical consultant, Terracon Consultants, Inc. (Terracon), to perform a peer review and provide an economical alternative solution. Jacking and shimming the bridge was determined to be both technically viable and economical with a total cost of less than $300K. The design was completed in March 2010 and construction was completed in February 2011. This paper provides an overview of the LLH Bridge history, summarizes the evolution of the design methodology including the findings of the geotechnical study and presents lessons learned during the design and construction of the project.INTRODUCTIONThe Safety and Preservation of the State Highway System is the top priority of the FDOT. Therefore, FDOT initiated a bridge management program that starts with conducting biennial safety inspections performed by Certified Bridge Inspectors (CBI). The inspection reports together with the CBI’s recommendations are reviewed by a registered Professional Engineer (PE) and work orders are issued with priority ranking depending on the severity of the bridge deficiencies. If the scope of work is considered beyond the in-house crews’ capability, the work is then included in a contract for and bid. LLH Bridge was a little different. It was initiated in direct response to number of complaints the FDOT District 5 Structures Maintenance Office (D5SMO) received regarding settlement of the Little Lake Harris Bridge."

Jan 1, 2015

By Robert Bissonette, Samir Sbai

A critical component of implementing autonomous systems is the ability to use information from a robust sensory and information system to make sound, predictable, and repeatable decisions to assure safety. This means that any such system would need to evaluate what objects (people, equipment, boulders, etc.) of interest exist in that environment (with relevant data about identity, trajectory, characteristics, etc.), project a future continuum of those objects (including considerations for variabilities), and make control intervention choices to minimize risk due to exposures in the present operational area. The components of an overall system would include: a) sensor and data fusion, b) probability projection of future states, c) generation and evaluation of alternate futures, and d) implementation of best course of action to reduce risk. The National Institute for Occupational Safety and Health (NIOSH) Spokane Mining Research Division (SMRD) is studying this framework for applications for autonomous mining equipment. This paper focuses on using information from the sensor fusion engine to generate a continuous projection of future and alternate states (b and c above) incorporating the factors of confidence, accuracy, tolerance, and other variabilities. We refer to this as Machine Situational Awareness (MSA).

Jun 25, 2023

By Arash Nikvar-Hassani, Lianyang Zhang

To address the drawbacks of the conventional portland cement/fly ash (PC/FA)–based cementitious material currently used in practice to construct pumpable roof supports (PRSs), a novel cementitious material has been developed based on geopolymerization technology. The novel cementitious material is comprised of two pumpable grout streams: Stream 1 is a slurry composed of pozzolanic material and high-calcium additive and stream 2 is an alkaline solution comprised of a gelling agent. Biopolymer has been added to the second stream to provide ductility to the geopolymer cementitious material. In the laboratory scale, systematic experiments have been carried out to investigate the viscosity, setting time, and uniaxial compressive strength (UCS) of the new cementitious material and develop the right recipe for field applications. By collaborating with industry and the National Institute for Occupational Safety and Health (NIOSH), full-scale PRSs have been constructed and tested. The results show that (1) the novel cementitious material based PRSs has much higher peak UCS and similar or higher residual strength than the conventional PC/FA-based PRSs; and (2) unlike the PC/FAbased cementitious material, the novel cementitious material shows good long-term durability with nocracking/disintegration when exposed to air.

Jul 1, 2023

By Fabio Santillan, Lyndon Bedford

"This paper presents the main features of the Wolf Creek Dam Foundation Remediation Project, highlighting the innovative construction approach and stressing on how the collaboration between the contractor and the owner became a key element for the success of this project.The main rehabilitation contract, $341 M, was awarded in 2008 for the construction of a 980,000 sqft concrete barrier. Most of this 2ft-wide concrete barrier wall is being built to depths reaching 277 ft using innovative construction techniques proposed by the contractor and under quality control measures that exceed by far the industry standards.The construction of the barrier wall entails the use of nine different foundation techniques which run concurrently following very stringent requirements in terms of verticality, distance between open elements, strength, permeability and dimensions that control the installation sequence of each barrier wall element.The innovative construction approach by the contractor and the collaborative efforts by the contractor and the USACE (“US Army Corps of Engineers”) have brought this unique and very difficult project to a successful completion, setting new standards in the dam foundation industry and nine months ahead of scheduleINTRODUCTIONWolf Creek Dam is on the Cumberland River in south central Kentucky. It provides hydropower, flood control, water supply, and water quality benefits for the Cumberland River system and surrounding region. The lake is a source of recreation that has attracted more visitors (4.89 million) than Yellowstone National Park (2.87 million).The dam and its adjacent reservoir reside upon a heavily Karst bedrock foundation. In late January 2007, the USACE placed the dam under a 'high risk' for failure designation. As a temporary measure, the pool elevation was lowered to 680 ft Above Main Sea Level (“AMSL”), 80 ft below its maximum capacity, with huge impacts to the local economy while the major, and ambitious, $ 594 million remediation program to bring the dam back to its full operating condition was carried out.The main rehabilitation contract of $341 million was awarded in 2008 for the construction of a 980,000 sqft concrete cut-off barrier. Most of this 2ft-wide concrete barrier wall has been built to depths reaching 277 ft using innovative construction techniques under quality control measures that far exceed the industry standards."

Jan 1, 2015

By WenJun Dong

This paper presents the stability assessment of the steel pipe piles that are used to support a deadman beam to anchor an adjacent bulkhead wall. Finite element analyses are performed to assess the stability of the bulkhead wall and determine the required tie-back force to the pile. The piles are relatively close to the bulkhead wall such that their soil resistance wedge zones are not fully developed but truncated by the bulkhead wall. The reduced lateral resistance capacity of the anchor piles is determined by applying the Coulomb wedge method on the truncated soil passive zones between the pile and wall. Both the conventional soldier pile stability (in terms of force and moment equilibrium) and Winkler soil spring (for soil-pile-interaction) analyses are used to assess the stability of the anchor piles.

Sep 8, 2021

By Oladayo O. Komolafe and Majid Ghayoomi

p-y curves have been used over the years to determine the lateral resistance of piles. This method is popular among practicing engineers due to its simplicity and its ability to determine the slope, displacement, shear force, and bending moment for various depths along the pile. The ultimate lateral load resistance is a key component of p-y curve formulation. The p-y curve formulation by Reese et al. (1974) does not consider the effects of soil’s degree of saturation on theoretical ultimate lateral resistance of the failure wedge. This limits an accurate assessment of the lateral soil resistance near the ground surface and the consequent p-y curves. This paper extends the existing approach for determining the failure wedge in unsaturated cohesionless soils with suction dependency, especially for the depths that are above the water table within the wedge. The modification to the failure wedge analysis was made by considering the variation of the degree of saturation which affects effective stress and lateral earth pressure. Through a set of parametric analyses, the impact of incorporating principles of unsaturated soil mechanics in the estimation of theoretical ultimate lateral resistance is examined, and its implications on lateral pile response are discussed.

Sep 8, 2021

By F. K. Crundwell

The rate of dissolution of sulphide minerals is frequently interpreted in terms of the passivating behaviour of a layer of material on the surface. This interpretation has driven research to identify and possibly remove this layer from the surface, and thus yield higher rates of dissolution. The identification of such layers has proved difficult, with different researchers claiming different compositions for possible layers. An alternative framework has been pursued by the author and co-workers, who have argued that the rate of dissolution is governed by the electronic structure of the minerals which give rise to their semiconducting properties. Researchers sceptical of this approach have argued that semiconducting properties are only important in highly pure substances. In this paper, we review the electronic and semiconducting properties and discuss how they impact dissolution behaviour. These properties affect their colour and dissolution properties even though the minerals are not high purity substances. Keywords: Dissolution, leaching, passivation, semiconductor, chalcopyrite

Jan 1, 2020

By Mario E. Rossi

Often geometallurgical models are prepared at various project stages from very few data and are assumed to be representative of very large tonnages. These may include recovery models; crushing and grinding parameters and models; models of concentrate grades; models of acid consumption; etc. These models commonly do not carry a measure of uncertainty or variability, and are taken at face value at the time of design and planning. This paper proposes a proactive approach to modelling variability, providing uncertainty estimates and thus allowing for risk analysis and mitigation of geometallurgical models. The variability model is built up by understanding the limitations of the pillars of a geometallurgical model: data uncertainty; geologic model uncertainty; domain definition uncertainty; and parameter estimation uncertainty. Of these factors, typically domain definition is the most significant contributor to geometallurgical model variability. First, the fundamental supports for these models are briefly discussed, with domain definition emphasized. Second, two methods for uncertainty modelling are proposed. The first, more applicable to conceptual or early-stage projects, is a simpler and more expedient alternative that provides initial assessments of variability. This is intended to aid management in decision-making related to budgeting, including further sampling and testing. The second, a block-by-block approach that allows a detailed assessment of risk for specific designs and mine plans, thus providing further opportunities for mitigation. In the example provided, emphasis is placed in communicating this variability to both management and technical personnel in the form of “measured-indicated-inferred” indicators and also block-by-block confidence intervals.

Jun 25, 2023

By S. T. L. Harrison, M. Smart, C. J. Edward

Biooxidation, a biohydrometallurgical process, utilizes a mixed microbial consortium to mediate the dissolution of refractory gold-bearing ores to enhance gold recovery during cyanidation. Recognition of water as a critical resource has prompted improved water management strategies within mining and minerals processing. Bioremediated wastewater from the cyanidation tailings provides a potential water source to supplement the water required for the biooxidation circuit, reducing freshwater extraction. Gold biomining operations have typically been reluctant to recycle this wastewater due to the potential inhibitory effects of cyanide and thiocyanate (SCN-) on the microbial population. Historical process upsets suggest that the microorganisms are sensitive to SCN- concentrations as low as 1 mg/L. However, effective bioremediation processes resulting in effluents with low or negligible SCN- concentrations may allow gold biomining plants the opportunity to recycle available water. Microbial activity as well as alteration in community structure were monitored as a function of increasing SCN- concentration over the range of 0 mg/L to 5 mg/L to investigate the response of the biooxidation community to potential SCN- spikes resulting from upsets in the remediation process. Appropriate microbial growth and ferrous iron oxidation activity with a nominal shift in community structure were observed at SCN- concentrations up to 1 mg/L. Thiocyanate concentrations above 1 mg/L resulted in the complete inhibition of ferrous iron oxidation activity. This was attributed to Leptospirillum ferriphilum’s sensitivity to SCN-. Exposure to a SCN- concentration of 5 mg/L resulted in a lower cell concentration and a significant increase in growth lag time, and the absence of L. ferriphilum from the microbial population. At. caldus and Ap. cupricumulans were still present at 5 mg/L SCN-, although Ap. cupricumulans was unable to oxidise ferrous iron at this SCN- concentration. It was concluded that recycling bioremediated cyanidation tailings wastewater within the biooxidation circuit is feasible; however, to retain process performance, SCN- concentrations should not exceed 1 mg/L. Keywords: Biooxidation, thiocyanate, water recycling, community structure

Jan 1, 2020

By Katherine Hynard, Colin Eustace

Development quarterly mine plans is generally time-consuming and requires consideration for many operational constraints and competing objectives. With lengthy turnaround times, there is often limited opportunity to adjust the quarterly plan details to account for differences between actual state of the mine operation at the time of execution and expected state at the time that the plan was developed. Actual mining task completion times can vary significantly from the expected task completion times, due to many factors. In the absence of revision to account for differences between the planned and actual state, resource allocations and mining sequences, embodied in the quarterly mine plan may no longer be the best approach at the time of execution to achieve an efficient mining operation. Simulation and optimisation tools can be used to support rapid refinements for development and execution of weekly mine plans. When initialized with an operations data feed to establish the actual state of the mine operation, optimisation models can be used to facilitate both automation and revision of the quarterly plan to produce a weekly or daily plan for execution. This approach can remove much of the manual burden of revision if the existing quarterly plan no longer represents the best approach to meeting production objectives. Following initialisation with mining actuals, simulation models can provide a representation of the range of likely mine operations outcomes. The models can be used to accelerate the planning process by providing visibility of future performance and identifying likely operational issues. They can also be used to test the robustness of the plan with respect to performance variability and response to disturbances. Following identification of issues, simulation models can also be used for evaluating mitigation measures, through automated testing of alternative plans. Integration of mine data feeds with simulation and optimisation tools enables automated optimal responses to variations between the quarterly mine plan and actuals to be tested prior to release of and execution plan and implementation. The use of simulation and optimisation in weekly mine planning will be discussed in this paper with reference to surface mining examples.

Jun 25, 2023