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By E. Emelyanenko, P. Solozhenkin, J. Yagudina, O. Ibragimova

"To recover tetrahedrite-tennantite series minerals from porphyry copper-pyrite ores by the froth flotation method, further research on thiol collectors is launched to promote the utilization efficiency of copper ores. In the present paper the adsorption mechanism of the collectors on tennantite surface has been investigated by computational modeling and FTIR-spectroscopic analysis, which have revealed that the decrease in prognosis of collector activity evaluation (PCAE) for tennantite is in the following order: BX (-0.34318), AEROPHINE 3418A (- 0.61756), AERO 5100 (-14.18857). The lower PCAE the stronger the ability of the collector to interact with the mineral surface of tennantite and form the stable complex. More kinetic reliable conditions to form suitable adsorption layer and rupture of the liquid interlayer with AERO 5100 have been observed by FTIR spectra due to decrease of the intensity and stretching and bending vibrations of water (less than 20 and 65%, respectively). In order to verify the feasibility of AERO 5100 as a collector the industrial flotation tests have been conducted. Flotation performance has improved significantly with the stadially grinding and preflotation of tennantite in intercycle copper flotation that allows to avoid desliming of the fragile mineral and minimize loss of Cu and As in tailings. The recovery of copper in copper concentrate increases by 3.9% with the grade maintained.INTRODUCTIONCopper is one of the first metals extracted and the main material of choice for different high-technology applications today. Currently 80% of the world's copper comes from copper sulfide ores. However, due to the depletion of high-grade copper ores in the world and constantly growing demand for copper, the need to develop processes and technologies to treat copper resources from additional sources such as mine tailings, low grade deposits, industrial wastes and deposits with high impurity levels such as As and Sb will continue to increase (Miller and Craig, 1983). The beneficiation processes of copper-pyrite ores consisting of tennantite-tetrahedrite series minerals are generally complex. Tetrahedrite-tennantite minerals occur as fine anhedral grains intermixed with grains of galena, sphalerite, chalcopyrite, pyrite and other sulfides (Saharova, 1966). The mineralized zones of Southern Urals, Russia deposits correspond with these ore types but tennantite-tetrahedrite series are more abundant in ores at the Uzelginskoye deposit, some samples of which contain 70% of copper in tennantite form (Seravkin et al., 1994). This deposit differs from other similar copper-pyrite ores by thin mutual ""germinating"" minerals and higher content of arsenic (up to 0.8-1 %) which create additional considerable problems in enrichment (Solozhenkin et al., 2016)."

Jan 1, 2018

By John Hutchings

Drilling and blasting is a clearly delineated work process, which has well defined inputs and outputs. Drilling and blasting is also a process with a number of steps each of which has measurable outcomes. Drilling and blasting is ideally suited to the application of Total Quality Management principles. Most drilling and blasting information is generally poorly managed with disjointed and unrelated Information Technology systems managing parts drilling and blasting data. Data is often moved from on system to another, sometimes manually. In the field, drilling and blasting is still very much a paper based system and which has not generally benefited from some of the recent hardware and software technology advancements now “on the shelf”. Data collected on paper rarely is transcribed back into an electronic system for further analysis. It is often difficult to collate or review historic drilling and blasting data. This paper will present a definition of Total Quality Management and demonstrate how it can be applied to the drilling and blasting work process. Total Quality Management defines the mechanisms for the application of continuous improvement to drilling and blasting. Continuous improvement will provide opportunities to modify drilling and blasting work process outcomes and generate real cost benefits within the overall mining process. A complete drilling and blasting management system frame work, called DBS, is presented in this paper. DBS provides all the components necessary to implement a full drilling and blasting Total Quality Management solution. Also highlighted will be appropriate “off the shelf” technology that can be applied to replace current paper based systems and provide the means to connect with other mine data systems. Various examples will be discussed which will demonstrate potential benefits of applying a structured Total Quality Management approach to a drilling and blasting work process.

Jan 1, 2004

By Fidelis T. Suorineni

Rapid drifting enables quicker access to orebodies, higher productivity rates and a resultant reduction in activity costs. Increased advance rates, by examination of the key components (face preparation and drilling, hole loading and blasting, scaling, mucking and support installation) in the development cycle, and optimizing these processes is a high priority for research in the Canadian mining industry. Support installation time alone is typically 36 to 46% of the total development cycle time. A reduction in support installation time or techniques and alternative scaling strategies could result in significant gains in drift development advance rates. Support Staging and hydroscaling within the drift cycle could offer alternative drift development sequences that could reduce the overall cycle time. MIRARCO?s research into the support and hydroscaling processes for rapid drift development also suggests that there are many other factors (e.g. mine ventilation services) that have a significant impact on the rate of advance. These factors should be considered to promote and manage safe and rapid drift development. Constraints to the rapid drift development processes can only be overcome by sound construction management practices. In other words, the goals of rapid drifting can be achieved by the implementation of contractor-type construction management. This paper examines various constraints and processes affecting rapid drift development and draws attention to other factors affecting safe rapid drift development.

Apr 1, 2005

By W. C. Whittaker

Introduction When one thinks of a coal stripping deposit, the picture that usually comes to mind is that of a more or less flat seam from two to twenty feet in thickness overlain by ten to fifty feet of overburden, in suitable ratio for economic operation. This is the usual type of stripping deposit and is quite a common occurrence in various parts of the prairie provinces. Rather unusual types of coal stripping deposits are being presently worked as open-cut mines by Sterling Collieries, Limited, and the Co al Valley Mining Company, Limited, at Miles 47 and 48 on the Alberta Coal Branch, some 150 miles south west of Edmonton. These deposits are of interest chiefly because they represent turned-up and greatly thickened sections of the Mynheer seam, and as such they present their own problems, peculiar to the commercial exploitation of a seam of this type. The area in which these deposits occur was originally owned by the Pacific Pass Collieries, whose operations, however, were confined to under-ground mining at Lovett, some eight miles to the southeast. It was not until l918 that the value of these deposits was realized, when the Company now known as Sterling Collieries, Limited, opened their pit at Mile 47. At the inception of the work, coal was loaded directly into the railway cars by men using wheelbarrows. In 1920, a tipple was built, after which the coal was loaded by steam shovel into mine cars, hauled by steam dinkeys, and loaded over the tipple into railway cars. In 1922, the Coal Valley Mining Company entered the field at Mile 48, with an entirely mechanical equipment, and at the present rime these two are the only stripping properties in Alberta using mechanical equipment both for the removal of overburden and the loading of the coal. These Companies have operated continuously since that time, and have to date mined and shipped 4,000,000 tons of coal, and moved some 5,255,000 cubic yards of stripping. The present annual coal output for the two mines is about 240,000 tons.

Jan 1, 1935

By H. J. Bogert

Shallow, gently dipping quartz veins at the Mineral Hill Mine are mined in room and pillar stopes. Ore zones are severely folded and fractured, thus actual pillar strength and physical properties of the rock mass deviate significantly from conventional laboratory tests and pillar theory. Laboratory specimens large enough to include pre-existing fractures proved to be representative of actual pillar strength. Further adjustment for specific pillars was based on RQD. Deformation and stress were measured in several pillars during pillar recovery. Stress data and finite element modeling were used to estimate absolute pillar stress at failure. The stress/strain relation provided an excellent indicator of pillar behavior. Good agreement between lab data and underground data was found.

Jan 1, 1995

By Gary Brieley

Until well into the 20th century, most construction work was performed under the auspices of a master builder or in a manner that would be described today as design-build. In addition, many civil engineers served as ?interns? under the tutelage of a master builder in order to learn how to design and construct a certain type of structure. This was certainly the case for tunneling projects with various individuals having been identified as tunneling experts as a result of successfully completed projects The master builder approach began to change in the early 1900s to a model that would be referred to today as design-bid-build. A design-bid-build approach to project procurement gives the owner more control over the final product and al-lows the contractor to know exactly what is expected of them before the work is constructed. As a result of this transition in project procurement, civil engineering schools placed a greater emphasis on the training of ?design? professionals. This article will document how the training of tunnel design professionals progressed within the United States. Although it is difficult to generalize about the hundreds of tunnels that were constructed in the first four decades of the 20th century, there is one project that stands out as having resulted in a university program related directly to tunneling and that is the Chicago Subway. During a visit to the United States in 1938, Dr. Karl Terzaghi met a student named Ralph Peck who was then studying at Harvard University in a pro-gram established by Arthur Casagrande. Shortly thereafter, Terzaghi traveled to Chicago for a lecture and was asked to consult on the Chicago subway project that was then under construction. The Chicago subway was being constructed in clay, and the owners were worried about possible settlements to nearby buildings. Terzaghi asked Peck to serve as his field engineer for that project. Thus was established one of the most productive relationships in the history of civil engineering in the United States. Peck, who would become Dr. Peck, moved to Chicago in 1939 to participate in an extensive research project that con-tinued until subway construction was halted in 1941 because of World War II. During that time, the cost of subway construction in Chicago was reduced substantially as a result of Peck?s observations and Terzaghi?s recommendations. In fact, it was reported that subway construction in Chicago cost less than one-half of similar projects in London even though the clay in London is considerably stiffer compared to Chicago. Upon the completion of his work on the Chicago Subway, Peck accepted a professorship with the University of Illinois in Champaign/Urbana.

Jun 1, 2010

By A. A. Compoli

Injecting water under pressure to wet the coalbed in advance of mining reduces mining-generated respirable dust. Owing to economic and geological barriers, water infusion for longwall dust control in the United States is currently limited to the Pocahontas No.3 Coalbed in Virginia. Water is pumped into the coalbed through underground boreholes drilled horizontally from the headgate toward the tailgate side of retreat longwall panels. This paper theorizes that the barriers to widespread utilization of water infusion for longwall dust control could be overcome by long-duration, low-pressure water infusion through vertical gob gas boreholes. Currently, 43% of the 72longwall mines in the United States employ vertical gob gas boreholes. Computer coalbed reservoir simulation suggests that one vertical surface borehole could infuse the same longwall panel area as four horizontal boreholes in the current water infusion system for longwall dust control in the Pocahontas No.3 Coalbed.

Jan 1, 1995

By A. G. Jackson, S. J. P. Laube

"Control of thin films during the growth process is dependent on several parameters that are difficult to monitor, including flux of film material, pressure, substrate temperature, composition, and thickness. One means for easing this difficulty is to take advantage of emission spectra associated with the process and the film. For pulsed laser deposition (PLD), the ion cloud generated by the laser has characteristic emission spectra that can be used to control the flux and, hence, the film. For chemical vapor deposition, the species present can be determined using mass spectroscopy and specific peaks can be used to control the deposition. Raman spectroscopy affords the possibility of real-time control by sensing characteristic peaks associated with film composition and thickness. These spectroscopic methods offer a real-time alternative to process control that is very attractive, because of the ability to accurately control films to achieve the engineered structures and properties sought. Examples are presented to illustrate the capabilities of these methods for thin film preparation.IntroductionThe drive to reduce costs and improve efficiencies of operation sets the tone for much of research, basic or applied. Basic research is limited by the ability of sensors and associated instrumentation to measure parameters accurately and reproducibly. Applied research has the same limitations and also the added constraints of time and costs. Hence, there are strong incentives to explore means for refining existing sensors with respect to performance and cost, as well as finding new sensors and techniques for more accurately and rapidly measuring quantities of interest in experiments and in various processes."

Jan 1, 1997

By Joseph C. Rota

The Carlin Trend is one of the most significant gold mining districts in North America. Located in northeastern Nevada, a total of over 17 million ounces of gold have been produced since 1965 at Newmont Gold Company's open-pit and underground operations. Oxidized portions of the sediment-hosted, disseminated gold deposits at Carlin generally consist of finely disseminated concentrations of sub-micron sized native gold particles hosted in Paleozoic siliciclastic or carbonate rock. Oxide ore is commonly amenable to dump leach or heap leach processing, yielding an average 50 to 70% recovery of total contained gold. Refractory unoxidized ore requires some form of pretreatment oxidation to ensure economic gold recovery. Geologic ore control is typically combined with standard assay and engineering techniques to maintain both grade and metallurgical control ofleach grade ores. Mine geologists provide a vital function through field observation and recording ofmineralogic data during daily, visual blasthole logging. Intricately mixed refractory materials must be separated from oxide ore to ensure highest possible gold recoveries. Geologic information is combined with assay data to create mine polygons in an engineering computer database. Mining selectivity is further enhanced by in-pit ore control geologists who are available to make production decisions based on direct mineralogic observations at active mine faces.

Jan 1, 1997

By Z. Zhao, B. Li

"Fractures are the key channels for fluid flow and mass transport in fractured rocks of low/negligible matrix permeability. In single rock fractures, surface roughness causes fluid flow in tortuous paths, and reduces the overall fracture conductance. A number of empirical models have been proposed to relate the reduced hydraulic aperture to the mechanical aperture due to surface roughness, which were revisited and compared. Using two of those relationships between hydraulic apertures and mechanical apertures, we studied the influences of local surface roughness of fractures on fluid flow and solute transport processes at the macroscopic scales of fracture networks. The results show that fracture roughness can affect the flow rates and residence time to varying extent, mainly depending on the empirical models between hydraulic apertures and mechanical apertures. However, fracture roughness has negligible influences on the general patterns of fluid flow (channeling) and solute migration (e.g., travel paths and shape of breakthrough curves). This is because the connectivity of a fracture network is mainly determined by other geometrical parameters (fracture positions, orientations, and lengths), rather than roughness or apertures. INTRODUCTIONIn fractured crystalline rocks of low or negligible matrix permeability, fluid flow and contaminant migration mainly occur within the connected fractures. An understanding of fluid flow and contaminant migration in fractured rocks is a crucial issue in many deep underground projects, e.g. underground repositories for radioactive waste, CO2 sequestration, enhanced geothermal systems, oil and gas production, etc. Rock fractures are typically rough-walled, and surface roughness appears to have first order control on the mechanical and hydraulic behavior of single rock fractures (Boutt et al., 2006).It is well known that the mechanical aperture of a rock fracture is usually larger than its hydraulic aperture, due to fracture surface roughness (Tsang and Witherspoon, 1983). However, for naturally fractured rocks including numerous discontinuities, the effects of this reduced hydraulic aperture in local fractures on macroscopic fluid flow and solute transport in complex fracture systems still remain unclear. Many previous studies assumed identical hydraulic and mechanical apertures in discrete fracture network models for simplicity (Min et al., 2004; Zhao et al., 2011). Therefore, the main objective of this study is to evaluate the influences of local surface roughness of fractures on fluid flow and solute transport processes at the macroscopic scales of fracture networks, by employing the empirical models that relate the hydraulic aperture to the mechanical aperture."

Jan 1, 2015

By C. Y. Jia

Adsorption of Thiooxidans ferrooxidans and Mycobacterium Phlei on the surface of pyrite and galena was studied. From the experimental results, it was observed that Mycobacterium Phlei adsorbed preferentially on pyrite than on galena at neutral and alkaline pH values, while Thiooxidans ferrooxidans is not at all pH range, and the scanning electron microscopy photograph also indicated that. FTIR and XPS of two strains of bacteria indicated that there are much functional groups on surface of them, such as O?H, N?H, C-O, C?N, C?O etc, but S-O group occurred on Thioox-idans ferrooxidans cell surface and the P-O group appeared on Mycobacterium Phlei cell surface, and the content of C?O?H and C?O?C groups on Mycobacterium Phlei cell surface is higher than that on Thiooxidans ferrooxidans cell surface, this also been known from UVS investigation. The affinity of these groups to metal ions on sulfide minerals is able to explain the selective adsorption.

Jan 1, 2014

By H. C. Fuller

Depletion of iron ore in the Nation's large deposits has directed attention to other sources. One of these is the titaniferous iron ore of the Iron Mountain, Wyo., area. Tests were made to determine the feasibility of smelting this ore, which contains about 20 percent titanium dioxide (Ti02), in an electric-arc furnace to produce pig iron. Initial tests, which were made in a 30-pound-capacity induction furnace, demonstrated that the iron could be easily reduced to metal and that limestone was a suitable and effective flux. Larger scale tests then were made in a 50-pound-capacity electric-arc furnace to obtain the more detailed information necessary for the planned continuous operation of a still larger arc furnace. The principal facts determined by preliminary batch-smelting studies were that (1) 9 pounds of limestone flux was required for each 100 pounds of ore smelted, (2) expensive coke was not required because coal proved to be a satisfactory reductant (near stoichiometric carbon was optimum), and (3) overreduction, which produced a viscous slag, must be avoided.

Jan 1, 1961

By I. Gaballah

Cadmium is toxic to plant, animals and humans. The council directive of the European Communities No 8315 13lEEC has fixed an upper limit of 200 ppb for the release of cadmium in industrial effluents. The conventional method of neutralization/prccipitation ( NIP ) is inefficient to reach this limit. The objective of this study is to test the efficiency of the trees modified bark to remove cadmium cations from industrial effluents after the conventional treatment by NIP. Laboratory scale tests with synthetic solutions show that the cadmium removal depends upon pH and initial concentration. About 99.9 %, 99 % and 96 % of the metal are removed from synthetic solutions containing 10, 100 and 1000 ppm respectively. Pilot plant trials ( 1 m3 ) with an industrial effluent bearing about 500 ppb of cadmium lead to the almost complete elimination of the cadmium ( final concentration is lower than the analytical detection limits < 20 ppb ).

Jan 1, 1994

By Jyri Talja, Shaolong Chen, Hannu Mansikkaviita

"Drying (water removal) prior to smelting is always economically feasible. Unnecessary heating of vapour can thus be eliminated resulting in savings of5-15 MUSD every year.Thermodynamically removal of one ton of water out of copper concentrate at 100 °C (with 10 % moisture) requires approximately 3150 MJ/tH2o, consisting of heating of the water (377 MJ), heating of the concentrate (509 MJ) and water evaporation (2260 MJ). This is quite independent of the selected drying technology. In reality some more heat is needed as higher temperature is practiced to enhance the drying performance and to reduce the equipment size.Major nominator in drying energy efficiency is amount of gases, which depends greatly on the drying technology. Dryers based on direct heating with fossil fuels have high gas flow rates, and thus they require additional energy of about 1400-1600 MJ/tH2o, compared to indirect modemsteam drying at 250-400 MJ/tH2o.Significant benefits in energy consumption (900-1300 MJ/tH2o) with additional potential for a bonus profit of 2-4 MUSD/y year, together with full elimination of some 40 000 tpy CO2 per mid-size dryer is available by selecting sustainable, energy efficient steam drying.IntroductionRemoval of water from the concentrate is very energy intensive thus having a significant environmental impact. However, drying prior to smelting is always economically feasible and very often viable also from the perspective of process operations. This environmental impact of drying can, however, be decreased or even fully eliminated with proper selection of the drying technology.Energy incorporated in drying consists always of a number of phases like liquid (water), solids (concentrate) and gases (water vapour, purging I dilution air, combustion gases). Each phase is heated to a specific temperature during the drying process.Heating of water, heating of the concentrate and water evaporation consumes more or less the same amount of energy despite of the drying technology (3150 MJ per ton of water). In conventional drying this amount of energy is achieved by combustion of fossil fuels wirg subsequent CO2 emission. Alternatively, chemical energy derived from sulphide smelting can be utilized in a form of steam thus generating zero emission ofCO2, in modem steam drying."

Jan 1, 2012

By E. Larsen

Marine tailings disposal may in some cases be the best solution to one of mining’s major environmental problems. The public standing of this solution is poor, partly because of past bad practices. Among the tailings problems spreading of super-fines and toxic substances stand out. The two are often interrelated as heavy metals, insoluble to sea water, tend to adsorb on fines and spread piggyback on them. Only one paper seen, has addressed the mineralogy of fine particles in suspension. The topic was a secondary tailings deposit. Studies on the sedimentation of fines in large river estuaries show that different minerals sediment sequentially as the salinity of the river increase. Mineralogy in the particle size range where particle separation takes place, has so far, naturally been in focus for the mineral processors. Next to nothing is known about the fines which may cause environmental problems. Tailings disposal has, due to its complexity, to a large extent been taken over by specialists in other fields, biologists, engineering geologists, chemists. The basics of the subject ought also to be given more input by the mineral processing community. A drawn out battle about tailings discharge into some fjords has taken place in Norway. The detractors focus at fine particles (could be dangerous nanoparticles) spreading and emphasize the effects. Calculation is simple: 5 million tonnes tailings annually discharged, containing 1 wt. % < 1µm determined by laser diffraction, results in 50 000 tonnes of nanoparticles let loose in the environment. The industry`s difficulty to answer, is lack of basic research on this topic. Test work to develop a methodology to address the problem is described. One thing the mineral processors know is that final tailings may be comprised of tailings from separate separation processes, with different properties, some of which may require special treatment. One tailings stream from a Norwegian mine is investigated in such a context.

Jan 1, 2016

By I Ritchie, A Johnston, D Yataco

Marcobre SAC (Marcobre) is developing the Mina Justa copper mine project, located in the Ica region of Peru. The Mina Justa IOCG orebody comprises of a sulfide mass overlain by an oxide cap with a sharp transitional zone between the sulfide and oxide masses. The primary target metal is copper, but there are minor amounts of gold and silver. The oxide will be treated by HPGR, crushing and vat leaching, whereas the sulfide will be treated by HPGR, milling and froth flotation. The processing selections are due to some unusual ore characteristics which have required relatively unconventional solutions.Vat leaching was chosen over heap leaching and other processes after detailed trade-off studies found it to be the most attractive, primarily due to the high acid consumption of the ore. The sulfide flotation produces a wide range of concentrate grades due to the complex nature of the mineralogy. The selection of HPGR circuits for both the oxide and sulfide ore is due to the extremely hard and competent nature of the deposit. These factors and others have contributed to a unique process selection for this resource.The selection process for the oxide and sulfide ores, and an overview of the technology, equipment selection and geometallurgy, will be discussed.CITATION:Johnston, A, Ritchie, I and Yataco, D, 2017. Process development for the Mina Justa project, in Proceedings MetPlant 2017, pp 207–217 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 11, 2017

By J. E. Dutrizac, J. B. O'Reilly

"Zinc is a relatively abundant element which occurs as both high-grade sulphide ores {sphalerite ZnS) and oxide ores which the ancients collectively termed ""calamine"" (smithsonite ZnC03 and/ or hemimorphite Zn4Si201(0H)2 - H20 and/ or hydrozincite Zn5(C03) 2(0H)6). Although oxidic zinc is readily reduced by carbon, the process becomes thermodynamically viable only at - 1000°C, and at this temperature the zinc is released as a vapour (B.P. 907°C). Casual cooling of the vapour results in its re-oxidation by excess combustion air or even the carbon monoxide product of the reduction reaction. ZnO + C = C09,, + Zn vapom Only fairly rapid quenching of the zinc vapour and the isolation of the reduction products from the combustion gases will yield metallic zinc; these conditions were not produced deliberately until the advent of distillation technology. Until quite recently, the principal use of zinc was in brass manufacture; galvanized iron was not discovered until the 19th century and zinc casting alloys are a relatively recent invention. As will be seen, brass could be produced without recourse to a pure zinc intermediary, and the discovery of brass preceded that of zinc by many centuries. The purpose of this paper is to outline the discovery and early development of both zinc and brass with special reference to the European scene."

Jan 1, 1999

By T. M. Yegulalp

A new explanation of the scale dependency of the strength properties of rock is presented based on the theory of extremes. A review of past work on specimen size strength relationship is followed by an introduction to the fundamentals of the underlying theory of extremes and its relationship to the scale effect on the statistical properties of the strength distribution. It is shown that the weakest link theory is directly related to extremal statistics and properties of strength distributions of rock can be derived as a function of the specimen size. Three sets of Brazilian test data are used to demonstrate the use of this approach.

Jan 1, 1992

By Valentine Chanturiya1

We have developed a classification of geochemical barriers according to their origin, i.e. natural and artificial, and according to methods and areas of application. There has been an examination of the interaction between different classes of geochemical barriers with sulfate solutions containing nickel, copper and iron. As natural barriers, carbonates (calcite and dolomites) were used. For artificial barriers, a mixture of serpentine and carbonatite, thermo-activated copper-nickel dressing tailings, and a magnesium-containing sorbent based on brucite was used. Keywords: geochemical barriers, physical-chemical geotechnologies, treatment of natural and waste water, recovery of nonferrous metals

Sep 1, 2012

By Ho-Sung Yoon, Jyothi Rajesh Kumar, Chul-Joo Kim, Sung-Don Kim

A recovery process for rare earths (REs) such as dysprosium and neodymium from the leach liquor of permanent magnet scrap (PMS) was developed. The two hydrometallurgical routes namely liquid-liquid extraction (solvent extraction) and selective stripping were implemented. The present study deals with the separation and recovery process development by using organo-phosphorous based extractant di-(2-ethylhexyl phosphoric acid (D2EHPA) as reagent for REs processing. Initial studies considered the influence of time on the extraction process, as well as pH and extractant concentration effects. This suggested the aqueous mechanism and separation factors played a role in process during development. McCabe-Thiele diagrams for extraction isotherms were developed. Counter current extraction (CCE) using various phase ratios influenced metals separation. Maximum loading capacity of the D2EHPA was determined. The loaded organic generated by the CCE process was water washed followed by a scrubbing process to remove the other metal ion from targeted metal. Finally, a stripping process was tested using various mineral acids.

Jan 1, 2015