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By A Golsby

Gunite was invented in 1907 by Carl Akeley to repair a crumbling facade of the Field Columbian Museum in Chicago. The method used was to blow dry material out of a hose with compressed air and inject water at the nozzle as it was released. In 1911, he was granted a patent for his invention, the ‘cement gun’; the equipment used; and ‘gunite’, the material that was produced.The advantages of using the dry mix process is that the water content can be adjusted instantaneously, allowing more effective placement in overhead and vertical applications without using accelerators. The dry mix process is useful in repair applications when it is necessary to stop frequently as the dry material is easily discharged from the hose.This paper describes the applications and principles of the gunite pump system in underground coal mining and discusses why it is the preferred spraying system for both cement and plaster products.It also addresses improving productivity and examines dust, respirable crystalline silica (RCS) and health issues around gunite pump systems. The solutions include development of the latest componentry for current gunite pumps to improve their efficiency and allow their operation to be dustless.In particular, this paper addresses:why and where RCS is a problem in underground coal mininghow RCS hazards and its propagation can be managedhow the gunite pump system has become dustlesshow the gunite system has become more productivegunite occupational health and safety issues and how they have been solveda case study of gunite dry spraying.CITATION:Golsby, A, 2015. The development of a dustless dry gunite pump system in underground coal mining – a case study, in Proceedings The Australian Mine Ventilation Conference, pp 41–48 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 31, 2015

By Jr. Schnakenberg

In 1986 the U. S. Bureau of Mines (USBM) embarked on a major research effort to develop technology that can substantially reduce worker exposure to face hazards simply by relocating the equipment operators to an area of relative safety. This reduced exposure mining system (REMS) research effort enhances the USBM ongoing health and safety research efforts to reduce and control dust and noise and to reduce accidents through training and better mining practices. This paper reports progress of the research that is developing and will demonstrate the technologies required for the computer-assisted tele-remote operation of continuous mining machines, haulage systems, and roof bolting machines.

Jan 1, 1996

By Braden Lusk

Vibrations as a result of blasting practices in mining engineering are a complex phenomenon controlled by many variables. Mine blast vibration modeling and prediction is becoming more important as a consequence of interactions by mining activity with an ever closer public. Many communities (all over the world) close to mining activity often complain about airblast and vibrations produced from blasting activity. It is important for the mining industry to have tools and understandable methodologies to model and predict blast vibration. These tools can then be used to predict and control vibration at neighboring structures.

Jan 1, 2013

By D. G. F. Hedley, F. Grant

"In 1958, the Ontario Department of Mines appointed a committee to study the accident situation and mining methods used in the uranium mines in the E1liot Lake district. This committee reviewed the existing knowledge on mine design, pillar support and roof spans and came to the conclusion that scientific knowledge had not yet reached the stage of producing rational design procedures which would reduce the dependence on trial-and-error methods. Since that time, the Mining Research Centre has made numerous stress measurements in two mines to define the pre-mining and pillar stresses. A comprehensive series of tests has been done in the laboratory to measure the compressive strength of the rock; a geological survey of the region has been made to evaluate tectonic stresses; and a survey was done on mining conditions with regard to stable and unstable pillar configurations. This information has been used to evaluate pillar design as effected by pillar width and height, depth below surface, extraction and pre-mining stress fields. The resultant design of pillar widths and corresponding extraction as the depth increased is in line with past and present experience in these mines. The information available on roof stability is still insufficient to design stable stope spans with the same degree of confidence; experience and trial-and-error methods are still required."

Jan 1, 1972

By J. R. Patts, A. B. Cecala

"After industrial sand has been mined and processed, the finished product is typically loaded into small bags of 45 kg (100 lb) or less, large bulk bags of 454 to 1,361 kg (1,000 to 3,000 lb), or vehicles such as trucks or trains for transport to end users. As the sand is being transferred and loaded, dust can be released into the work environment, potentially exposing workers to respirable crystalline silica. A number of control technologies have been developed and utilized in an effort to reduce dust liberation during loading operations. For bulk loading into trucks or trains, the U.S. National Institute for Occupational Safety and Health (NIOSH) evaluated one of these technologies, the Dust Suppression Hopper (DSH), at two industrial sand processing plants. Results from these case studies show that the DSH reduced airborne respirable dust levels by 39 to 88 percent, depending upon the product size being loaded.IntroductionInhalation of respirable crystalline silica dust can lead to the development of silicosis, a disabling and potentially fatal lung disease. Once contracted, there is no cure for silicosis, so the goal is to prevent the development of the disease by limiting exposure to respirable dust containing crystalline silica at or below the exposure limit of 50 µg/ m3 recommended by the U.S. National Institute for Occupational Safety and Health (NIOSH, 2002). At industrial silica sand operations, the product contains high levels of crystalline silica, so effective control technologies are needed to minimize the respirable dust exposure of workers.NIOSH, in partnership with the Industrial Minerals Association–North America, published a dust control handbook (NIOSH, 2012) focused upon control technologies for industrial- mineral mining and processing operations. One chapter in this handbook discussed technologies for controlling dust liberated during bulk loading, including telescoping loading spouts, dust collection systems for loading spouts, enclosures for load-out areas and a newer technology known as Dust Suppression Hopper (DSH)."

Jan 9, 2018

By A. Desbiens, A. Pomerleau

During the summer of 1994, a new PID-based control strategy was installed on line B of the grinding circuit at the Kidd Creek Division of Falconbridge Ltd. Part I of this paper described the methodology used to select the appropriate control strategy using a phenomenological dynamic simulator. Part II presents the implementation of the control strategy. Prior to the controller installation, it was necessary to solve various problems related to the process, such as a cyclic behaviour of the rod mill feed tonnage, a problem related to the mill water source and the calibration of the flowmeters. Once these problems were solved, the control strategy was accomplished in two steps. Step 1 corresponds to the installation of control loops to regulate the pump box level and the cyclone overflow density. Step 2 describes the implementation of a loop to control the cyclone feed density. According to Part I, a loop to control the circulating load is also part of the original design. However, reasons are given to explain the rejection of this loop. For both steps, technical procedures such as filtering, process identification and controller tuning are detailed. Finally, the operator’s interface is briefly described.

Jan 1, 1997

By Takefumi Takuma, Ali Fayad, Shigeru Kambe

"This paper discusses the unique design and construction circumstances of the cantilevered dual sheet pile walls and the Accordion Sheet Pile Wall for the repair and upgrade of the East Garden Grove-Wintersburg Channel in Huntington Beach, California that was concluded in 2014. It also describes the 2008 Emergency Sheet Pile Project for the same channel. Both projects utilized the Press-in Piling Method for its low noise and almost no vibration advantages.BackgroundThe East Garden Grove-Wintersburg Channel is part of the Orange County Flood Control District (OCFCD) and is operated and maintained by OC (Orange County) Public Works (see Figure 1 for its location). The channel, referred to as OCFCD facility # C05 (C05), had suffered significant toe undercutting and slope erosion of its levee due to a series of storms. These began after the facility was constructed in the 1960’s and culminated in 2005. Consequently, the levee was deemed significantly deficient and was eventually declared as a local emergency in 2007. C05 was an incised channel and its levee was constructed primarily from native materials. Operation and Maintenance (O&M) personnel notified the design staff at OC Public Works to be aware of major consequences associated with the dilapidation problem in the most downstream reach of the channel in the vicinity of the Bolsa Chica Wetlands Restoration Project. In 2007, the Orange County Board of Supervisors declared a local emergency to fix the levees with sheet piles to be driven by the Press-in Piling Method, hydraulic pushing piles into ground by holding onto previously installed piles. The project that ensued represented the first in-tandem use on the West Coast of the United States of the Press-in pile driver with its GRB System (Press-in pile driver, a support crane and pile transporter travel on top of already-driven sheet piles). This is further discussed in this paper in the sections titled “Press-in Piling Method” and “GRB System”, respectively. The project repaired approximately 3,800 feet of erosion on the north levee of C05 with 45-foot long cantilevered sheet piles. The sheet piles design constraints are discussed in this paper in the section titled “C05 2008 Emergency Sheet Pile Project (Phase 1)”. Between 2012 and 2014, another mile’s worth of levee reach was improved with the Soil-Mix-Sandwich (SMS) Method. This concept consisted of deep soil cement mix (DSCM) columns sandwiched within the dual rows of sheet piles. Additional details on the SMS, its DSCM construction, and its hybrid geo-structure design concepts are well beyond the scope of this discussion, which is primarily focused on sheet piles. Instead, the interested reader is referred to two papers on the SMS and its DSCM metrics (Fayad, 2015; and Arora, et al., 2015). These were presented and published in the Proceedings of the Deep Foundations Institute (DFI) 2015 Conference on Deep Mixing. Hence, in the section of this paper titled “C05 SMS Dual Sheet Piles Project (Phase 2)” only the sheet pile design constraints of the SMS are covered. Finally, in the area where the project traversed the Alquist-Priolo zone of the Newport-Inglewood tectonic fault, an expandable and deflectable sheet pile wall was used to isolate the flood channel from the Bolsa Chica wetlands. Its details are addressed in the section titled “C05 Accordion Sheet Pile Wall (Phase 2)” of this paper."

Jan 1, 2017

By M. Schreiner, J. Brune, D. Theisen, C. S. -J. Tsai

This study reports that routine mining activities could produce a high number of nanometer sized particles which have not been well characterized and may represent an unacknowledged exposure present in the mining environment. A preliminary survey of the particle emission from the feed-leg drilling activity was conducted in the excavations of an experimental mine. The level of particulate exposure was monitored by real time direct reading instruments include a NanoScan scanning mobility particle sizer (measurement range 10-420 nm) and an optical particle sizer (measurement range 0.3-10 μm). Particulate morphological and structural examination was conducted through transmission and scanning electron microscopy and x-ray dispersive analysis of samples collected by a thermophoretic sampler, and a novel nanoparticle sampler. The real time instrument data revealed high concentrations (> 3.5 x 106 particles/cm3) of ultrafine/nanoparticles generated from the drilling activity. Analysis of particle sampler specimens with energy-dispersive x-ray spectroscopy showed a large amount of submicron silica, spherical primary particles and agglomerated soot particles rich in carbon. Exposure to particles in the nanometer size from various sources within the mining environment may be associated with the poorly understood rise in respiratory and systemic disease among miners. INTRODUCTION Exposures to mine dust have been measured and evaluated for decades. Exposures to aerosolized dust such as coal or silica particles can cause lung and other diseases (1-7). One way that The Mine Safety and Health Administration (MSHA) characterizes inhalation exposures within the mining environment is through measuring the respirable dust mass concentration within the breathing zone of workers (8). Respirable particulate matter (RPM) is of great concern due to its ability to deposit in the alveolar region of the lungs (9-10) where it can affect respiratory function. Interventions championed by MSHA have greatly reduced the prevalence of coal workers pneumoconiosis (CWP) and progressive massive fibrosis (PMF). Although great progress has been made, the prevalence of CWP and PMF appears to be trending upwards and the measured increase in prevalence is not elucidated in RPM measurements (11-12). Though the presence and risk associated with ultrafine particles such as emission from diesel engine within the mining environment has been previously established (13-14). There is suspicion within the mining industry that this resurgence of lung disease may be due to very fine particulate matter from various source that is not properly characterized by current sampling methods. Nanometer sized particles, in the range of ultrafine particles, fall within the RPM size range and have been found to deposit in all regions of the respiratory tract (15). Nanoparticles are commonly accepted as particles that are greater than 1 nm in two or three dimensions but smaller than 100 nm (16). Once in the lungs, nanoparticles can enter the blood stream (17) and selectively affect other target organs such as the heart, liver, bone marrow, lymph nodes, spleen, and brain (15,18-19). The size of nanoparticles has been shown to correlate with their translocation behavior on secondary target organs (20-21). There is strong evidence that the clearance mechanisms used to rid the lungs of particulate matter are not as effective on nanometer sized particles, leading to a greater fraction of never-cleared particles which may enhance disease development (20). Research has demonstrated that nanometer sized particles have unique properties (22) whose adverse health impact is greater than what has been found with micrometer sized particles of the same type (23-26). The large ratio of surface area to mass compared to larger particles is believed to make nanoparticles a greater hazard. Utilizing mass to measure these types of exposure will be very difficult to accurately characterize the quantity of

Jan 1, 2019

Since early-2001, Kalgoorlie Consolidated Gold Mines (KCGM) has successfully operated an ultra fine grinding (UFG) circuit to supplement its roaster capacity for the treatment of the refractory gold flotation concentrate. A second UFG mill was installed in 2002 taking the total UFG capacity to over 20 tph while grinding to 11 to 12 microns and achieving over 90 per cent gold recovery. A development program in 2002/3 involving plant trials, pilot plants and laboratory testwork resulted in process improvements and a better understanding of the milling and gold leach processes that assisted in narrowing the gap between UFG and roasting. This paper details the operation of the ultra fine grinding process at KCGM as a non oxidative treatment for the extraction of gold from a refractory ores.

Jan 1, 2003

By D. F. Zhang, X. Q. Jiang, N. Tahreen, D. L. Chen, F. S. Pan, D. Y. Li

Alloying with rare-earth elements has been proven to be an important tool for magnesium to achieve superior properties via texture randomization. The role of yttrium in texture weakening and the link between texture and formability are fairly well known. Since annealing is a vital part of metal processing which could significantly contribute to ductility, it is important to ascertain the impact of annealing in terms of texture change. Also, an understanding about texture development during pre- and post-deformation annealing is essential to improve the industrial deformation processing as texture is closely related to formability. While there is independent information in the literature regarding the effect of rare-earth addition and heat treatment on the texture formation, no systematic studies have been reported on the collective impact of yttrium addition, annealing and deformation on texture evolution. The present study was, therefore, aimed to identify the inter-relationship among texture evolution, yttrium content, heat treatment and deformation behavior in an extruded Mg-Zn-Mn-Y alloy. Annealing at 450°C for 1 hour and uniaxial compression tests at a certain amount of deformation were performed. The deformed and annealed samples were then subjected to annealing and compression test, respectively, followed by texture measurements. It was observed that yttrium addition effectively weakened the crystallographic texture in all conditions, which was evident from the changes in the microstructures and textures.

Jan 1, 2015

By D M. Brady

Underground coal mines in Australia have embraced the use of various inertisation techniques both proactively and reactively. The use of such techniques can have a significant influence on ratios and trends used to monitor the status of the underground environment. Whilst control strategies should never be ignored in favour of preserving the integrity of ratios, the influence and significance of the changes likely to be seen should be anticipated and understood for reliable interpretation of the situation. This paper looks at the influence inertisation techniques can have on results and subsequent interpretation.CITATION:Brady, D M, 2013. The influence of inertisation techniques on gas interpretation, in Proceedings The Australian Mine Ventilation Conference , pp 259-264 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 1, 2013

By Hairong Zeng, Shahram Tafazoli, Edmond Chow

Blast fragmentation is one of the main parameters for optimizing mineral processing, but reliable data is difficult to acquire, resulting in unpredictable performance and efficiency. Crusher and grinder circuits are designed to process specific rock size ranges. Oversized rocks require extra energy to reduce before feeding into the process, and undersized rocks indicate that the process is not used to its full extent. Blast design is the key to controlling the blast fragmentation, so the ability to accurately monitor the particle sizes is imperative.

Jan 1, 2011

By Vanessa M. Torres

Cia. Vale do Rio Doce is currently developing Niquel do Vermelho Project. The laterite deposit is located at Carajas Mineral Province at less than 15 km from Sossego Copper Project, scheduled for start-up in 2004. The available infrastructure, includes paved roads, large capacity railroad and port complex owned by CVRD, power supply and good quality water. The project was evaluated in the past for ferronickel production. In the late 1990s, CVRD switched its attention to investigating the usage of pressure acid leaching. The combination of good metallurgical behaviour for pressure acid leach (PAL) process route with reasonable mineable grades, and existing infrastructure justified the start of engineering studies in 2002. The project approach at the engineering phase is based on the dual objective of minimizing risks while maximizing project profitability and value. CVRD is currently completing the Niquel do Vermelho prefeasibility study. This paper outlines the main outcomes of the study and future perspectives for the project.

Jan 1, 2004

By J. J. Brummer

"A reconnaissance geochemical survey, using the stream sediment technique, is described. The survey covered an area of about 400 square miles, in the Seal Lake area of central Labrador, underlain by basaltic flows, diabase and metadiabase sills, and sedimentary rocks. Previous work had indicated numerous small copper occurrences within the Seal Lake group of rocks. Stream sediments were tested for the readily extractable copper content and total heavy metal content. The results of the copper survey did not yield any new data on the distribution of copper mineralization. Results of the total heavy metal survey attracted attention to a remote portion of the area (Ten Mile Lake), which had hitherto been regarded as having no economic interest. The anomalous values found, suggested that zinc mineralization should occur in this region. Geological mapping indicated that the rocks exposed belonged to the Letitia Lake Group, which is older than the Seal Lake Group exposed to the east, which contains the copper mineralization of the district.Investigation of the area lead to the discovery of: (1) uneconomic lead-zinc mineralization; (2) radioactivity extending over a considerable area. Evaluation of the radioactive rocks led to the discovery of columbium-thorium mineralization in amphibolite and in diopside-actinolite schists along a contact with intrusive alkali syenite.Thus a geochemical survey, which was planned to evaluate a copper province, resulted in the discovery of lead-zinc-columbium-thorium mineralization."

Jan 1, 1960

By W. J. Li, L. Kong, G. L. Li, X. M. Xi, J. Qiu

"A novel hydrothermal method was applied to prepare the precursor of LiMn2O4 using pre-treated electrolytic manganese dioxide (EMD) and lithium hydroxide as the main raw materials. The precursor was subjected to heat treatment between 400 and 900ºC to obtain spinel Li1.05Mn1.95O4 and Li1.035Co0.035Mn1.930O4 positive materials for lithium ion batteries. The structure and morphology of the obtained powder materials were studied in detail by means of X-ray diffraction (XRD) and scanning electron microscope (SEM). It is found that the precursor has an amorphous structure and a high reactivity, which is easily transferred to spinel structure during heat treatment, obtaining a positive material with an uniform structure and good performances. The XRD patterns reveal that single phase spinel Li1.05Mn1.95O4 can be obtained from the precursor after heat treatment at 600°C in air. The final Li-rich Li1.05Mn1.95O4 product obtained showed a well-defined stable spinel structure and distinctive crystal faces with particle size between 200 and 300 nm. The as-prepared Co-doped spinel sample exhibited a excellent electrochemical performance with an initial discharge capacity of 113.0 mAh/g and 93.8% of its original value was retained after 100 charge-discharge cycling at 0.5 C.INTRODUCTIONThe increasing demand for portable electronic devices and hybrid or full electric vehicles is driving the development of cheap, efficient, compact lightweight and environmental friendly rechargeable batteries systems (Chung et al., 2002; Scrosati, 1995). Lithium ion secondary batteries have satisfied this demand to a greater degree than other battery systems. The cathode material plays a critical role in the performance of Li-ion batteries. The high cost and toxicity of cobalt compounds for the cathode material of LiCoO2 has prompted a search for alternative materials. LiMn2O4-based spinels offer a potentially attractive alternative to LiCoO2, due to its abundance, low price, ease of preparation, environmentally friendly characteristics, better thermal stability, and its effortless recycling (Tarascon et al., 1991; Yabuuchi and Ohzuku, 2003; Amatucci et al., 1999; Tsai et al., 2003). Some achievements have been created to meet the requirements (Guo et al., 2010; Kang et al., 2005; Park et al., 2008; Takahashi et al., 2006; Lee et al., 2001; Yoshio et al., 2001; Arumugam et al., 2008). However, the largest obstacle encountered in the practical applications of LiMn2O4 is its fast capacity fading during long term cycling, which is due to Jahn-Teller distortion of the [MnO6] framework, the electrolyte decomposition at high potentials and manganese dissolution into the electrolyte (Fey et al., 2003). The electrochemical performance of LiMn2O4 is also strongly dependent on its morphological properties, such as crystallinity, phase purity, surface area, grain shape and particle size distribution, etc. All these morphological properties are closely related to the material synthetic routines and heat treatment processes (Huang et al., 2000; Myung et al., 2000; Takada et al., 1998)."

Jan 1, 2012

RME has a vision for a new mill operational paradigm made possible by RMEÆs fast, safe Mill Relining System. This vision can be moved forward into reality at any time with or without guidance from recent development in measurement and predictive modelling tools.Some new liner designs can degrade SAG mill performance because of mill volume loss, ball strike (rotational speed limitations) and other issues often brought about by optimising liners for life and without a backward glance at metallurgical consequences. Freshly relined mills can initially produce as little as 80 per cent of their maximum throughput, that maximum occurring toward the end of the linersÆ wear life. RMEÆs proposition is to design new liners for maximum commercial performance. This may mean more frequent changes of liners but with liners designed to yield optimum grinding, metallurgical and profitability performance. In other words, mill liner profiles and mill relining speed become key operational controls and not simply æmust doÆ maintenance functions. Taken to the extreme, liner profiles may prove capable of ætuningÆ a grinding plant for maximum profitability in any metal price environment. This paper provides an update regarding RMEÆs fast, safe Mill Relining System technologies and outlines RMEÆs vision of a æliner profile versus profitabilityÆ model as a function of metal price, developed intuitively or by using a combination of new measurement and modelling technologies. These new measurement and modelling tools provide the opportunity to predict the optimum commercial outcome, off-line in the virtual world, before committing to an expensive liner experiment.

Jan 1, 2006

Longwall mining operations have been in place in Australia since the early 1960s. This mining method is currently used to extract the bulk of coal obtained from underground mines in Australia (CSIRO, 2010). Despite the high tonnages extracted the expected utilisation of much equipment remains relatively low. To some extent this level of utilisation is influenced by the variability in conditions inherent in the mining process. This variability in production rates presents challenges to those attempting to design a coal clearance system. The difficulty is to design a system that has sufficient capacity to support production, without over capitalising or incurring high operating costs. The need to allow for a series of largely unplanned events in the design of a coal clearance system makes simulation modelling an ideal technology to employ. Simulation modelling is a methodology that allows a system with interacting components to be modelled over time, while explicitly taking into account unplanned events that may disrupt operations.This paper discusses how dynamic simulation models have been used to assist in the design of coal clearance systems. Typically this type of modelling has been used to look at the likely profile of production rates from the Longwall shearer and to determine how well various proposed combinations of belts, bins and stockpiles would support production.

Sep 26, 2011

By Torma A. E.

Biotechnological processes are considered to be cost effective especially for situations where the recovery of metals from 'Very large volumes containing trace metal concentrations (less than 10 ppm) is concerned. Microorganisms, alive or dead, or their products can be highly efficient and selective biosorbents for metal concentration. It is important that the metal bound to the biosorbent can be stripped by suitable agent(s) and regenerated for repeated use. The stripped solution should be concentrated enough to be introduced into the common metal recovery circuit. The industrial acceptance of biosorption processes is dictated by increased competitive advantage over other processes. This paper reviews the pertinent literature?, regroups the information, and points out future possibilities for the mineral and metal processing industries.

Jan 1, 1992

By T. Boyd, K. McTaggart, J. Qiu

"Hudbay Minerals’ Flin Flon process plant produces a copper concentrate and zinc concentrate from the three ores it processes: 777, Reed and Lalor. Unlike many Cu-Zn ores, the average Zn: Cu ratio in feed is around 2:1, whereas, in many Cu-Zn separation plants the Zn: Cu feed grade is substantially higher than 2:1. The lower Zn: Cu in plant feed is a challenge for limiting Zn recovery to the Cu concentrate. While total recoveries of Cu and Zn at Flin Flon are very good; selectivity is the key challenge and small changes in ore or plant, can result in quite variable Zn recovery to Cu concentrate, and accordingly, Zn recovery to Zn concentrate. Magnetic conditioning has been shown to be selective between the two paramagnetic minerals chalcopyrite and sphalerite. Statistical testing of magnetic conditioning was undertaken at Flin Flon with the objective of increasing Cu recovery to Cu concentrate without increasing the Zn recovery to Cu concentrate - in effect increasing Cu-Zn selectivity. This has been achieved elsewhere with magnetic conditioning with the probable mechanism being an increase in fine chalcopyrite recovery, and a reduction in entrained, ultrafine, non-activated sphalerite to Cu concentrate. The results did indeed show an increase in Cu recovery to Cu concentrate of 0.8% to high confidence, but the decrease in Zn recovery to Cu concentrate was not to high confidence. This is effectively an increase in Cu: Zn selectivity in the Cu circuit – higher Cu recovery with no change in Zn recovery. However, while there was an increase of 1% in Zn recovery to Zn concentrate with magnetic conditioning, the variability in this parameter meant that this increase, though larger in magnitude than the Cu result, was not to high confidence."

Jan 1, 2019

By S. Kelebek, E. Yalcin

"Diethylenetriamine (DETA) and/or triethylenetetramine (TETA) are reagents that can generally be categorized under ""flotation modifiers"". These polyamines are known to be effective for the deactivation/depression of pyrrhotite that is present in Canadian nickel-copper sulphide ores in large quantities. Recent bench scale testing on some of these complex ores indicated that chalcopyrite flotation can also be adversely affected under certain conditions involving polyamines, which may be taken to be an evidence of their specific affinity towards chalcopyrite. In general, DETA shows no significant depressant action on chalcopyrite while TETA's promotion of hydrophilicity for this mineral has been observed even in the presence of xanthate. This prompted an investigation on thermodynamic equilibria involving these polyamines and copper ions. Results serve a useful purpose to identify conditions for deactivation phenomena. CuDETA2+ and CuTETA2+ chelates as products of sequestration have large predominance areas covering a wide range of redox and pH conditions, where copper xanthate species are not stable, especially in the presence of TETA."

Jan 1, 2009