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By R. K. Conrad

The Bureau of Mines conducted corrosion research to determine suitable construction materials for geothermal resource recovery plants. Weight loss, pitting and crevice corrosion, U-bend stress corrosion, and electrochemical polarization measurements were made on selected metals in brine and steam process environments produced from high-enthalpy hypersaline brine from geothermal well Magmamax No. 1 at the Salton Sea Known Geothermal Resources Area, Imperial Valley, Calif. Cadmium (and by extension cadmium coatings) and a 6061-T6 aluminum alloy were unsatisfactory because of high general corrosion rates and, in the case of aluminum, severe pitting Molybdenum and niobium (columbium) were resistant to general corrosion, pitting, and crevice corrosion, Copper alloys corroded at rates that may preclude their use in wellhead brine, The presence of iron accelerated the corrosion of the copper alloys Titanium alloys were resistant to general corrosion and stress corrosion cracking in all of the environments. They exhibited crevice corrosion in some of the brine and steam environments and Ti6A14V pitted in the brine environments. They exhibited passive behavior over a broad range of potentials. Exposure tests were conducted on a high-temperature polyphenylene sulfide thermoplastic (Ryton) in the same environments. A 40-pct-graphite fiber-reinforced Ryton composite deteriorated readily in wellhead brine and failed in all of the brine and steam process environments; Ryton coatings on 316L stainless steel were adherent and performed well.

Jan 1, 1983

By Seth C. Schaefer

The Bureau of mines investigated thermodynamic properties of MnSO4 and 2CdO CdSO4 to obtain basic thermodynamic data applicable to the treatment of mineral concentrates during roasting and sintering processes. Standard Gibbs energies of formation were determined with high-temperature galvanic cells using stabilized Zr02 as the electrolyte. Potential measurements were obtained from the cells?

Jan 1, 1983

By D. L. Neylan

The Bureau of Mines evaluated various methods for identifying sources of mercury vapor in excess of the threshold limit value (TLV) of 0.05 mg of mercury per cubic meter of air set by the American Council of Government and Industrial Hygienists (ACGIH) for mines and mineral processing plants. Chemical spot tests and portable devices for mercury determination were evaluated, based on information from published sources and performance in laboratory tests. Among the parameters examined were sensitivity, interferences, cost, ease of use, and other factors pertinent to field application, More than 50 methods were evaluated. The investigators found that many readily available methods are suitable for identifying sources of mercury vapor in mines and mineral processing plants. The best method appears to be one that uses a commercially available mercury test paper sensitive only to mercuric ions. For some of the more promising chemical spot tests, this report includes step-by-step instructions for field application.

Jan 1, 1983

By Barrie T. Wells, Raghu N. Singh, Paul S. Buddery

Rockbolting and dowelling are important methods of ground control. Their effectiveness depends upon the compatibility of the support members and the geotechnical behaviour of the rock mass. Detailed geotechnical investigations are, therefore, necessary for the design of effective rockbolting systems. The study described in the paper was concerned with improving the effectiveness of ground control at Mount Isa Mine. The paper briefly reviews the design methods avail- able when choosing a rockbolting system with a view to identifying the most suitable method. Joint surveys were used for the geotechnical assessment of rock mass stability. These were interpreted with the aid of the stereographic technique of predicting the size and shape of potentially unstable blocks of rock in both the roof and side walls of excavations. The geology and ground conditions at Mount Isa are briefly described together with the current ground control techniques. The requirements for ground control have been investigated at representative sites by analysing typical modes of rock failure and using a geological predictive technique. An application of this technique to the selection of a support system in a shallow Coal Measures tunnel is also described. The paper concludes with a general discussion on the effectiveness of this method of site investigation for the appraisal of rockbolting support in mining and civil engineering excavations.

Jan 1, 1983

By Deborah A. Spotts

Researchers at the Bureau of Mines have developed a technique for re- generating chromic acid-sulfuric acid etching solutions used in metal surface treatment operations. The technique utilizes a diaphragm cell equipped with a cation-selective membrane to oxidize cr3+ to cr6+ at the anode and to remove copper, the major metallic contaminant, at the cathode. Normally, spent etchant is discarded after approximately 3 days of use. Using the electrolytic cell, the etchant can be used for a year without replacement, From data obtained from industrial-scale cells, the installation of a regeneration cell with a 1,000-gal catholyte- holding tank has been estimated to save at least $240 per day, The payback period for the investment is estimated to be about 10 mo or less. Because the magnitude of these cost savings will vary at different locations, several graphs are presented to aid in calculating payback for a specific site. Using these graphs and the capital costs presented in this study, the payback period can be determined for installing a regeneration cell with a 500- or a 1,000-gal catholyte-holding tank in an existing surface treatment plant.

Jan 1, 1983

By P. A. Rey

Water recycle is an important part of the coal preparation process. This study was directed toward: (1) a survey of current practice and an evaluation of both the solid and liquid components of blackwater, (2) an experimental study of blackwater flocculation, and (3) a fundamental analysis of the flocculation process. The solids contained in the blackwater discharge to the fine refuse thickener of a coal preparation plant were found to contain, on average, 56% coal and 44% mineral matter. The mineral matter was largely illitic clay, while the water phase contained relatively large amounts of S04 and Ca++. Detailed studies were made of both natural and synthetic flocculants and the influence of polymer type and pH on the settling rate, turbidity of the supernatent liquid and sludge volume of the settled solids. More tundamental studies were made that clearly indicate the need for controlled mixing of polymer into the suspension to be flocculated, and the need to evaluate, more closely, the structure of the flocs formed during the process. Research recommendations are given.

Jan 1, 1983

By Stephen R. Iverson

Mineral deposits examined in and near the Raywood Flats RARE II area have low potential for development. The Mill Creek Mine (fig. 1), has produced about 14,000 tons (13,000 t) of marble, and another 5.5 million tons (5.0 million t) of marginal marble reserves suitable for lime, chemicals, and cement production are estimated to remain at this deposit. However, nearly all the marble is outside the study area. The deposit is marginal because alternate sources of marble are closer to markets. A tungsten occurrence in the marble is too small and low grade to be considered a resource. Ten tons (9.1 t) of uranium- and thorium-bearing material have been mined from a pegmatite dike at the St. Patrick Mine. However, this occurrence also is too small and low grade to be considered a resource. More than 400 lode and placer claims have been located in or near the study area. There are no current claims or mineral, oil and gas or geothermal leases.

Jan 1, 1983

By Leonard J. Friedman

Modern smelting systems using continuous, flash and/or oxygen smelting processes have a significant effect on the choice of sulfur dioxide control processes and system arrangements. Based on gases from an enriched air or oxygen smelting furnace and copper converters the paper reviews and analyzes alternate processes and system arrangements for recovery of sulfur dioxide. The work indicates the choice system to include a conventional sulfuric acid plant for converter gas and a liquid SO2 plant to handle the high strength smelting fur¬nace gas. The liquid SO2 plant would be used as a fly-wheel to damper the flow and SO2 concentration variations of the con-verter acid plant. Potential energy recovery alternates and product flexibility are also reviewed.

Jan 1, 1983

By J. H. McCarthy, J. M. Botbol, R. B. McCammon, G. H. Gott

Four areas have been identified as favorable drill site locations for determining whether a suspected porphyry copper deposit exists in Rowe Canyon, NV. Favorability is bated on the similarity to a deposit model constructed from geochemical data for the porphyry copper deposit near Ely. Favorability is defined as the coincident number of positive anomalies for zinc, silver, aresenic, antimony, and iron. The favorable areas coincide with an observed magnetic high and areas in proximity to major faults.

Jan 1, 1983

By James J. Brady, James S. Lewis, Robert B. Gordon, Jimmy W. Honeycutt

INTRODUCTION Tunnel construction has always been an extremely high risk form of contracting primarily due to the inaccessability of information concerning the ground conditions to be encountered during excavation. We certainly make every effort to overcome this problem through borings, geological research, site visits, etc.; but at best owners, engineers and contractors alike are only able to interpolate a relatively small amount of factual data from isolated sections of the project into a forecast of ground conditions for the entire project. In essence this becomes an "educated guessing game" with risk to reward ratios (and subsequently the bid price) in direct relationship to the contractor's confidence in the quality of the guess. In many instances it is economically or physically infeasible to obtain information and of course the total picture is never known until the project is complete. This problem effects the contract format as well as price. The contractor's ability to handle unforseen problems on the project become extremely important as to the project's overall success. The following pages contain an actual case history of a project which affords an excellent example of the entire spectrum of situations resulting from tunnel construction in difficult ground conditions.

Jan 1, 1983

By Laurel A. Powers

The Bureau of Mines process for recovering Ni and Co from low-grade domestic laterites uses a reduction roast followed by an ammonia, ammo-nium sulfate leach. This investigation examined the waste streams of the process for their potential environmental impact and focused on the laterite residue produced. The U.S. Environmental Protection Agency's extraction procedure (EP) toxicity tests and column leaching showed that leachable metal concentrations would be low enough so that the residue would not be considered a hazardous waste under present definitions. Under nonacid leaching conditions, about the same amount of metal was extracted from laterites as from their residues, and the leachates were similar to water samples from an undisturbed laterite deposit. Washing tests on the laterite residue showed that ammonia and ammonium sulfate concentrations were reduced according to equilibrium stage calculations, resulting in residues that would be acceptable for revegetation. With water washing only, the residue would not be considered a hazardous waste even though significant amounts of Ni and Co were absorbed from entrained leach solution onto the residue. Washing first with fresh leach solution and then with water prevented this absorption and thus improved the overall metal recovery.

Jan 1, 1983

By Jeffrey H. Welsh

The Bureau of Mines studied the use of computerized, continuous, remote monitoring systems for safety from power system faults in underground coal mines. In this report the need to improve protection against power system faults is documented, and types of faults are identified. The relationship between mine safety regulations and computerized, continuous, remote monitoring is analyzed.

Jan 1, 1983

By Lean P. J

The present The Zinc ODrporation, Limited and New Broken Hill Consolidated Limited (ZC/NBHC) tailing dam (Site C) is expected to reach its terminal capacity late in 1985. Planning and design of new facilities for disposal of tailing after 1985 which includes new tailing dams (Site D) commenced during 1980. This paper briefly describes planning guidelines and specifications, location considerations, environmental aspects, operating strategy, engineering specifications, envirormental aspects and scheduling of works.

Jan 1, 1983

By M. D. Lackey

The "Art" of Big Hole Drilling has been in a continual state of evolution at the Nevada Test Site since the start of underground testing in 1961. Emplacement holes for nuclear devices are still being drilled by the rotary drilling process, but almost all the hardware and systems have undergone many changes during the intervening years. The current design of bits, cutters, and other big hole drilling hardware results from contributions of manufacturers and Test Site personnel. The dual string, air lift, reverse circulation system was developed at the Test Site. Necessity was really the Mother of this invention, but this circulation system is worthy of consideration under almost any condition. Drill rigs for Big Hole drilling are usually adaptations of large Oil Well drill rigs with minor modifications required to handle the big bits and drilling assemblies. Steel remains the favorite shaft lining material, but a lot of thought is being given to concrete linings, especially precast concrete.

Jan 1, 1983

By W. R. Byrnes

This project was initiated on October 1, 1980 and will be completed on December 31, 1983. The project was Initially approved and funded by the Office of Surface Mining and subsequently was moved to the jurisdiction of the Bureau of Mines. It was administered through the Indiana Mining and Mineral Resources Research Institute. The research was done to assess reforestation success and ultimate productivity for areas reclaimed under the Surface Mining Control and Reclamation Act of 1977 (P.L. 95-87). The Permanent Regulatory Program for implementation of P.L. 95-87 Includes provisions for revegetation that require seeding of ground cover plants to control erosion until permanent vegetation such as tree species Is established, and restoration of mined land to its original or better productivity. Much of the land to be surface-mined presently supports forest cover and it is anticipated that reconstructed minesoils will exhibit high productive potential for hardwood tree species. Hence, information was needed on compatibility of ground cover and tree seedlings when established concurrently as well as on revegetation success under postmining versus premining conditions.

Jan 1, 1983

By Richard W. Patton

With the advent of the Clean Air Act and the installation of flue gas desulfurization (FGD) equipment (scrubbers) on coal fired power plants, the management of solid wastes has taken on added importance. Aside from the large amounts of fly ash and bottom ash usually generated, large quantities of liquids in the form of scrubber sludge are also produced. These wastes must be disposed of within the constraints of land and water quality regulations. This paper describes the practices adopted by the electric utility industry in denting with this problem, including methods of generation and treatment, quantities and characteristics of the materials, and transportation and disposal practices. The paper also briefly describes final product characteristics and several applications for commercial utilization and land reclamation.

Jan 1, 1983

By G. Adel, J. Richard Lucas, C. Haycocks

This paper describes over sixteen computer programs developed at Virginia Polytechnic Institute and State University during the past twenty years to assist in the design of coal operations. Overall development concepts in the construction of the programs are outlined, commencing with those used in the exploration phase of mining and extending through economic analysis and into the design of specific engineering systems such as belt, rail and power networks, scheduling, rock mechanics problems and simulation of face systems. Summarized information is given for the use of the major programs including user restrictions, input data, typical output and industrial applications and case studies. Analysis has been made of the programs' applications by industry throughout the world. Such analysis is facilitating development of new programs as well as a refinement of existing ones. To date programs have been constructed in four categories: exploration, ground control, economic and simulation. Face production simulations are stochastic in nature and require the use of time study data obtained at sites underground. Future programming efforts currently under development are aimed at interactive programs for use with minicomputers and, where advantageous, with graphical displays.

Jan 1, 1983

The purpose, basic data requirements and various analysis/modelling tools employed for geomechanical evaluation of mine-site conditions are overviewed. The impact and application of computer technology are dis- cussed. Broad guidelines and criteria are presented for establishment of a practical geomechanics data-base system to yield infor- mation suitable for mine design purposes. Future needs of the Australian mining in- dustry are examined.

Jan 1, 1983

By Catherine C. Kilgore

The Bureau of Mines investigated the availability of lead and zinc from 104 domestic mines and deposits. Fourteen primary lead and fifty-three primary zinc operations with in situ demonstrated resources containing 27.3 million metric tons (t) of lead and 53 million t of zinc were subsequently evaluated. Potentially 17.5 million t of lead and 2.4 million t of byproduct zinc could be recovered from 14 primary lead operations. Economic evaluations performed in constant January 1982 dollars determined a long-run total cost per pound of recoverable commodity. Including a 15-pct discounted-cash-flow rate of return (DCFROR), 59 pct of primary lead was potentially available at or below $0.32 per pound of lead. Potentially 40 million t of zinc and 5.6 million t of byproduct lead could be recovered from 53 primary zinc operations. Ninety percent of the recoverable zinc is potentially available from currently nonproducing mines and deposits, and a weighted average of their long-run total costs was determined at $0.98 per pound of zinc. At a breakeven (0-pct) DCFROR, these non producing operations had a weighted average long-run total cost of $0.58 per pound of zinc. Sensitivity analyses illustrated that operations that recover byproducts were most sensitive to fluctuating metal prices, producing operations were more sensitive to increased smelter treatment charges, and nonproducing operations were impacted most by the DCFROR.

Jan 1, 1983

By Scott G. Britton

This chapter is concerned with the construction of the dynamic component of belt haulage systems. The dynamic system includes the belt line and tailpiece extension and retraction movements in a production system where mine management is continually placing the belt in the most effective operating position. Correct installation of the belt and tailpiece during an extension is very important for many performance reasons. Two of the most important reasons are to eliminate spillage and safely operate the belt line. This chapter is divided into three major discussions. The first discussion looks at analyzing the parameters of effective belt line construction. This includes a review of the parameters and management tools needed for proper scheduling of a move-up. The second major discussion topic centers on efficient procedures for a belt line extension. Topics such as site preparation, tailpiece breakdown and setup, stringing the belt line and structure, plus operating and maintenance tasks needed after the belt line is installed and running, are covered. The third discussion presents a list of conveyor and conveyor component manufacturers who provide services and products to the coal mining industry. Again, any discussion on underground haulage systems must generalize much of the site specific design approaches to be practical. This text will mention, where applicable, some of the alternatives available to construction engineers in designing belt line systems.

Jan 1, 1983