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By Enrique Hermana, Raymond F. Dalton, Raymond Price, Barry Hoffman

Introduction Chloride leaching of sulfidic ores has been known about for 100 years. It is recognized as a highly efficient process to produce concentrated leach solutions. Despite this, chloride leaching found little practical application until recently because of the highly corrosive nature of concentrated chloride solutions. This situation changed with the advent of modern construction materials such as GRP, polypropylene, butyl rubber, etc. And in the past 20 years, research has burgeoned in the area of chloride hydrometallurgy. The research impetus stemmed from the belief that chloride leaching can provide an alternative to smelters for treating conventional copper concentrates. In addition, chloride leaching was thought to be suitable for on-site refining of copper at small tonnage operations located in remote areas. And chloride leaching was seen as a logical choice for treating unusual or complex concentrates that smelters could not handle. Underpinning these beliefs is the attraction of chloride-based hydrometallurgical processes for sulfidic ores. Sulfur is liberated in the environmentally acceptable elemental form rather than as sulfur dioxide. Consequently, sulfidic copper ores have received much attention. A review of Edmiston in 1984 describes 12 chloride-based processes. All managed to progress past the "laboratory beaker" stage of evaluation. In nine of these processes, copper is recovered electrolytically. Key features of these processes are summarized in Table 1. Table 1 shows that the processes must include a copper solvent-extraction step. Only these processes produce a clean copper electrolyte capable, with no further refining, of directly producing high quality cathode copper. The ICI/Elkem process is the exception here. The rest of these processes use o-hydroxyaryloxime reagents for the solvent extraction of copper and are constrained by the performance of these reagents. This is governed by hydrogen ion concentration (Equation 1). The practical result is that only relatively dilute copper solutions can be treated (Canmet, Phelps Dodge), or careful pH control or adjustment is necessary (Minimet Recherche, B.H.A.S.). This negates one of the attractive features of chloride leaching - its ability to produce very concentrated copper solutions, up to 40-45 gl-1. [ ] In all four processes using o¬hydroxyaryloxime extractants, solvent extraction transfers the copper from the chloride to the sulfate medium. To minimize cross-contamination of the two anions, the loaded organic solvent has to be scrubbed to remove the chloride ion. This represents an additional complication in the solvent extraction circuit. And it

Jan 1, 1988

By James C. Barker

Recent investigations of a 55-km long trend of intrusive complexes on southern Prince of Wales Island have identified significant resources of Nb, Y, REE. U, Zr, and a host of potential by-product metals. The northwesterly trend comprises multi-phased sodic alkaline and peralkaline diorite, monzonite, syenite, and riebeckite granite. There are at least three significant deposit types recognized, two of which, 1) pegmatite dikes/vein-dikes that zone laterally from the intrusions and 2) concentrically zoned pegmatites, contain most of the lithophile metals. A third, epigenetic replacement-type mineralization, contains much of the U resource. Other deposit types with minor or unknown resource potential include diatremes, carbonatite, and placers. This report summarizes the deposit evaluations, characterizes the mineralization, and estimates the resources. To date a total of 40.7 million tons of mineralized material is estimated as indicated or inferred. Most of the Y203 plus REO is at a grade exceeding 0.5% and half of the Nb20S exceeds 0.125%. Tonnage estimates would likely be substantially lncreased with additional exploration. Mineralogy is generally fine-grained and complex, and consists of more than a dozen principal REE-Y-Nb-U-Th-Zr phases, the sum of which may compose up to half of the rock. Approximately half of the REE-Y content comprises the heavy yttrium subgroup which is uncommon compared to deposits elsewhere. Although the Alaskan deposits are likely subeconomic at today's metal prices and consumption levels. recent technological advances suggest future demand may increase.

Jan 1, 1988

By F. G. Boehm, T. S. Golosinski

This paper identifies the components of belt conveyor shifting force as a vertical force, Pv, a lateral force, Ph, and a longitudinal force, Pl. A method for estimating these forces is proposed that relates each of their values to the properties of the conveyor structure and rails, the shifting operation parameters, and other site-specific conditions. The effect of this force on the shifter behavior is analyzed, and guidelines are developed for selecting a suitable shifter. As well, other equipment requirements for the shifting operation are discussed.

Jan 1, 1988

By W. K. Chan, R. Lahaie

"The Suncor Oil Sands Mine located north of Fort McMurray, Alberta, produces about 80000 m' per day of tailings waste which must be disposed of economically in an environmentally acceptable manner. To date, this has been accomplished by impounding the high water content tailings wastes behind large dykes, many of which approach 100 m in height .The dykes are constructed using suitable overburden material stripped prior to the mining of the oil sands feed and/ or the coarse sandy fraction of the tailings waste itself. Although the above is common practice at many mining operations, the large volumes handled and the resultant costs require designs to be meticulously fine-tuned toward the optimum. As a result, considerable effort is expended on planning, designing and construction, and performance monitoring. The lack of precedent experience (Suncor pioneered oil sands mining), coupled with the realities of long, harsh winters and a variety of troublesome site conditions and construction materials, has led to some very unique dyke construction.This paper overviews current tailings disposal plans as welt as some of the key issues related to the design, construction and performance of these large dykes."

Jan 1, 1988

Comalco Limited has recently completed construction of a $50 million kaolin plant at the site of its bauxite mining and industrial minerals operations at Weipa. The plant will produce 100,000 tonnes per annum of coating grade kaolin for the paper industry.Comalco produced the first coating kaolin from the deposit in 1979 on a trial basis. Since then a variety of quality coating grades with specific particle ize distributions and brightness values have been prepared.Extensive drilling and bulk sampling of the deposit over eight years has shown that the orebody is large and of a high grade suitable for the production of premium quality coating kaolins.The processing plant technology was developed by Comalco in association with the European kaolin and equipment producer Amberger Kaolinwerke GmbH (AKW).The Weipa kaolin plant is the first of this size to be built in the Pacific Basin region and it will offer the region's paper-coating mills a stable and reliable source of high-quality kaolin, shipped from an established bulk loading port. The paper provides an overview of the development of the kaolin investment, the nature of the production process and details the project management procedure used for the design, construction and commissioning of the plant. Three areas of significant interest, the gas turbine fired pray dryer, the moving bridge shiploader and the use of aerobelt conveyors on the project are detailed.

Jan 1, 1988

The Bureau of Mines conducted a field study to assess the performance of various chain pillar configurations in terms of gate road entry sta-bility. Vibrating wire stressmeters (VWS's) were installed in four consecutive gate road chain pillars. Field data collected during panel retreat were analyzed to gain a better understanding of the mechanics of vertical load redistribution in gate road chain pillars as it relates to ground control problems. Several different pillar configurations were investigated including abutment-yield and yield-abutment-yield designs. VWS data indicate that average pillar loads were lower and appeared abutment-yield pillar arrangement was utilized. port the occurrence of severe roof and pillar to stabilize when an Data analyses also supdeterioration that was visually observed in the tailgate entries during panel extraction.

Jan 1, 1988

By Richard P. Reiff

"The Facility for Accelerated Service Testing (FAST) program has been involved in numerous rail wear tests since its inception in 1976. A number of specialized tools have been developed to aid in assessing specific performance parameters including gauge face wear, head height loss, metal flow, head area loss, hardness, and welded rail end batter. The layout of a test site, including position in curve, number of measurements per rail, and train operation must be properly controlled/monitored to provide valid wear comparisons.This paper will provide an overview of the above-mentioned tools and techniques. In addition, a summary of recent test results from FAST, including information on head hardened rail investigations, will be provided. A set of guidelines for establishing a revenue service field test site will also be provided to aid users in performing evaluations of their own.IntroductionBackground of Rail Wear Testing at FASTThe Facility for Accelerated Service Testing (FAST) located at the Transportation Test Center, (TIC), Pueblo, Colorado has been involved with testing of rail since program initiation in 1976. A huge data base of rail wear information has been gathered from FAST operations under a variety of rail metallurgies, lubrication conditions, and measurement techniques. Attempts at obtaining meaningful rail wear information from early (1976-1978) FAST rail wear data was hampered by two main factors: (I) measurement techniques were insufficiently accurate for the amounts of wear being experienced, and (2) the lubrication was not sufficiently controlled to obtain uniform conditions for a sufficient measurement time period.Subsequent test periods were operated with improved measurement techniques and controls that ensured statistically valid data. The policies and conditions that permit accurate rail wear assessment will be reviewed and outlined in this paper, along with some specific TIC and field examples that will allow the user to improve the accuracy of a field rail test on their own operating property."

Jan 1, 1988

By A. C. Moerman, C. W. Pelley, K. R. Notley

"The software package described in this paper facilitates the handling of diamond drilling information in the creation and maintenance of a geological information database. Once entered, the drilling information is stored in a direct access file for rapid retrieval. The drill data are sorted into vertical cross sections and interpretation is performed using on-screen menus to define areas of common rock type and outline the mineralized zones. Intersections of individual zones can then be examined and outlined in the longitudinal dimension at a graphics terminal.With the aid of surface-fitting routines, the digitized information can be used to generate three-dimensional models of each zone. From these models intermediate cross sections and level plans can be obtained. Several interpretations are possible and plotter drawings can be obtained. An output file for use by ore reserve estimation software can also be created.Future work will tie this software to geostatistics and mine planning programs and will be aimed at converting mainframe software to run on microcomputers. IntroductionComputer applications in underground mine planning and geology are not new. Operations such as Sherritt Gordono and Kidd Creek have been using software developed about a decade ago for handling geological information and designing stoping blocks. However, general use of such systems has been limited mainly due to the cost of hardware which was affordable only to large corporations. Software to perform the work was usually developed on site and was largely unavailable for use by others, being site-specific, or too expensive for other organizations to purchase.The increasing power of microcomputers and mini-computers, and their relatively low cost compared to the mainframe computers which were previously used, has led to the increased use of computers at mining operations of all sizes. Sources of software for use in geological interpretation and mine planning have increased in number with the proliferation of the use of microcomputers."

Jan 1, 1988

By R. J. Fantel

The Bureau of Mines investigated the resources, costs, capacities, market relationships, and short- and long-run supply of phosphate rock and phosphoric acid. The 206 mines and deposits evaluated in 30 market economy countries contain an estimated 35.1 billion mt of recoverable phosphate rock (demonstrated resource level). U.S. resources are sufficient to satisfy the domestic and export markets for phosphate products well beyond the year 2000. Because of resource depletion at current producers, however, new properties (with higher cost levels) need to be developed if U.S. production levels are to be maintained. Existing worldwide capacity can satisfy expected demand through the early 1990's. Expansion at existing mines or low demand growth could mean that no new property development will be needed before the late 1990's. Worldwide, almost $8 billion could be required for development of new phosphate rock properties between now and the year 2000, given 3-pct annual growth in demand. Most properties that could develop in the 1990's would require price increases of 20 to 50 pct to break even. To earn a 15-pct rate of return on investment, prices must rise to nearly double the present level of $24 to $29 per metric ton.

Jan 1, 1988

By J. I. Paige

The effect of fluoride inclusions on the properties of titanium produced from the Bureau of Mines developed induction slag melting process is of concern to members of the titanium industry. The objective of the research was to determine the effect of CaF2 inclusions on the properties of titanium and its survival rate during melting. The data were obtained from single induction-slag-melted ingots prepared with the normal addition of 4 pct and also with 2- and 1-pct additions of CaF2 slag. The results of this effort showed that the mechanical properties of single-induction-slag-melted Ti-6Al-4V alloy exceed the minimum values specified in Aerospace Materials Specification for Titanium Alloy Bars and Forgings AMS4928H, but these materials are much more notch sensitive in fatigue than normal Ti-6A1-4V alloy titanium. First and second vacuum-arc remelts of single-induction-slag-melted ingots fragmented and increased the number of inclusions, while reductions in the amount of flux resulted in an upward trend in the spatial distance between pores in an x-y plane.

Jan 1, 1988

The objective of this study was two-fold: 1. To perform a world literature search pertinent to the analysis, selection and design of hoisting systems and their components and to codify the search into a literature compendium. The search resulted in a technical data file of over 1500 hard copy items. The compendium index was also suitable for establishing a comprehensive computer-loaded data base on the subject. 2. To develop a comprehensive system of guidelines to cover salient aspects of analysis, selection and design of electrical, mechanical and structural components of a hoisting system with a view to establish parameters for maximum safety and efficiency of operation, installation and revision of the system. 3. (a) The system design of hydrostatic drives for mine hoists, usually of special nature, is considered along with oil hydraulic component selection suitable for the application; (b) The criteria for head frames of steel and/or concrete are developed with full consideration of all operating and environmental conditions.

Jan 1, 1988

The objective of this study was two-fold: 1. To perform a world literature search pertinent to the analysis, selection and design of hoisting systems and their components and to codify the search into a literature compendium. The search resulted in a technical data file of over 1500 hard copy items. The compendium index was also suitable for establishing a comprehensive computer-loaded data base on the subject. 2. To develop a comprehensive system of guidelines to cover salient aspects of analysis, selection and design of electrical, mechanical and structural components of a hoisting system with a view to establish parameters for maximum safety and efficiency of operation, installation and revision of the system. 3. (a) In-shaft equipment design and specification criteria are considered as they influence guideline preparation. (b) A comprehensive review of hoist electric drives and controls as applied to mine hoists is set forth with special reference to duty cycle calculations and their effect on electrical component selection.

Jan 1, 1988

By Victor V. Verbinski

This report presents the development of a raw coal concentration sensor for hydro-transport of coal and refuse (rock) from underground mines, and the results of an international test series carried out at the Colorado School of Mines Research Institute in Golden, Colorado, the U.S. Bureau of Mines, Hydraulic Transport Research Facility in Pittsburgh, Pennsylvania, Saskatchewan Research Facility in Saskatoon, Saskatchewan, Canada, and the Steinkohlenbergbauverein Test Facility in Essen, West Germany. Test results are presented for a three-component sensor and also for the more rugged two-component (all nuclear) sensor.

Jan 1, 1988

By Terry R. Neumann

In 1987 and 1988, the U.S. Bureau of Mines conducted a mineral resource investigation of the 31,400-acre Muddy Creek Wilderness Study Area (UT-060-007). The investigation was requested by the Bureau of Land Management and authorized by the Federal Land Policy and Management Act of 1976 (Public Law 94-579). The study area is located in Emery County, Utah, about 50 air-miles southwest of Green River, Utah. The wilderness study area is in the San Rafael Swell region of the Colorado Plateau Physiographic Province. Rocks in the area consist of gently dipping sedimentary strata of Permian, Triassic, and Jurassic age.

Jan 1, 1988

The wealth of a nation may be measured in many ways, but one of the most important is its natural resources, particularly its minerals. Minerals create the wealth upon which economic prosperity and defense preparedness rest. Managing mineral resources for the benefit of all Americans continues to be an important national goal. In its 78-year history the U.S. Bureau of Mines has established itself as the world's premier mineral information and research agency. Its authoritative, comprehensive data and pioneering research have contributed significantly to a strong U. S. mineral position in the world.

Jan 1, 1988

By G. L. Bartlett

"INTRODUCTION The major objective of our research is to help reduce the incidence and severity of coal worker's pneumoconiosis (CWP). To that end, this project is designed to improve our understanding of the processes that lead to pulmonary dysfunction following mine dust exposure, and how those processes might be interrupted or attenuated. The response of the lung ' to inhaled particles is complex, and the course of development of disabling CWP is slow and unpredictable. From among the numerous cellular and molecular interactions involved in the pulmonary response to inhaled particles, this project is focussed on the role that the pulmonary alveolar macrophage (PAM) may play in regulating the activity of fibroblasts.The PAM is the lung cell that has the most immediate and the most obvious interaction with inhaled particles. Within a short period after particles are arrested in the alveolus of the lung, they are phagocytized (engulfed) by these specialized cells. The PAM then has a diverse potential repertoire of subsequent activities. Which reaction actually ensues is determined, in large part, by the nature of the phagocytized _particles. Activated PAMs produce a variety of products that may affect adjacent lung tissue, including superoxide free radical, elastase, collagenase, prostaglandins, platelet activating factor, etc. Those may well be important in the pathogenesis of CWP, but they are beyond the scope of this project. Background information that is cogent to this project has come primarily from investigations using animal models of silicosis and asbestosis. PAMs that have ingested silica particles synthesize and release molecules that control the behavior of surrounding cells. One such mediator is interleukin-1 (IL-1), a molecule that plays a central role in many aspects of the response to injury. It can stimulate fibroblasts (the cells that help to hold tissues together) to release the enzyme collagenase, resulting in breakdown of the structural collagen fibers that support the lung tissue. IL-1 also stimulates fibroblasts to undergo mitosis and to proliferate, which is an initial stage of fibrosis. Certain stimulants cause PAMs to release fibroblast growth factors (FGFs) that are distinct- from IL-1. Under other circumstances activated PAMs synthesize and release molecules that stimulate fibroblasts to accelerate synthesis of collagen fibers, thus contributing to fibrosis. Although these observations provide a valuable precedent for analysis of the mechanisms involved in CWP, their relevance to CWP cannot be assumed since most of those studies involved macrophages or fibroblasts obtained from tissues other than the lung, and because almost none of them have used CMD as the stimulating particles. Therefore, the goal of this project is to learn how exposure to CMD affects the behavior of PAMs, and in turn how products of dust-exposed PAMs affect fibroblasts and the process of fibrosis in the lung."

Jan 1, 1988

By Robert G. Bottge

The Bureau of Mines has engaged m a program to determine the availability of land for mineral exploration and development in Alaska. Land availability, based on ownership and Federal and State laws and policies, is compared with mineral terranes and mineral deposits. This is the fifth of six regional studies, which cover the State with a comprehensive set of maps and data compilations. This study covers an area of 112.3 million acres in western Alaska. In July 1986, 41.0 million acres, 37% of the study area, were available for mineral exploration and development; 14.6 million acres, 13%, were available with restrictions; and 56.7 million acres, 50%, were unavailable. Nearly 65% of the unavailable land is classified as national parks, preserves, wildlife refuges, and wild and scenic rivers. Of the 34.0 million acres of mineral terranes that underlie the study area, 12.9 million acres, 38%, are available for exploration and development; 3.6 million acres, 11%, are available with restrictions; and 17.5 million acres, 51%, are unavailable.

Jan 1, 1988

This report is a proceedings of a briefing recently sponsored by the Bureau of Mines at which Bureau personnel presented findings from their research efforts to improve steelmaking techology currently used in the United States. The papers contained in this report address many areas of concern to the iron and steelmaking industry. Among these are improving arc stability in electric arc furnaces, preheating ferrous scrap to reduce energy consumption, fluorspar substitutes in steel-making, basic steelmaking refractories, corrosion of iron-based materials, improvements in stainless steel acid pickling processes, recycling of stainless steel dusts and other wastes, and use of wastes as a source of zinc for electro/galvanizing.

Jan 1, 1988

By Henry P. Cole

A series of studies are described that identify critical health and safety skills needed by underground coal miners for coping with mine emergencies. First aid and self-rescue and escape were selected as two broad performance domains that include many subordinate skills needed for preventing, recognizing, and coping with mine emergencies. The performance domains and their objectives were used to direct the development of simulation exercises that permit miners to experience mine emergencies in the safety of a training room. The exercises are based upon research with similar simulations for the training of flight crews and medical personnel in information gathering, judgment, and decision making skills. Exercise content is drawn from actual mine accident and disaster case studies. The exercises incorporate recent principles of cognitive psychology and instructional design. Initial studies in annual refresher training classes suggest the exercises are stimulating for miners and their instructors, easy to use and read, sufficiently complex and authentic to challenge experienced miners, and useful devices for both teaching and testing critical problem solving skills required for preventing and minimizing emergencies.

Jan 1, 1988

By Kenneth M. Maas

The Bureau of Mines inventoried the land in southwestern Alaska to classify ownership and availability and compared this land with known mineral terranes and mineral deposits. This report discusses and quantifies the potential for favorable location of mining claims for metalliferous (locatable) mineral deposits. Of the nearly 24 million acres that constitute the study area, approximately 3.6 million acres or 17% are available for mineral location, 3.4 million acres or 14% are available with restrictions, and 17 million acres or 71% are unavailable. Mineral terranes are known to underlie about 7.8 million acres or 33% of the study area; 3 million acres or 38% occur on land available for mineral location, 1.3 million acres or 17% occur on land available with restrictions, and 3.5 million acres or 45% occur on unavailable land. The State of Alaska has opened over 91 % of its land in the study area to mineral location; in comparison, the Federal Government allows mineral location on 0.07% of the land under its jurisdiction. There are 117 known mineral deposits or occurrences within the study area, including 77 lode deposits and 40 placer deposits. Of the 41 lode deposits occurring within a mineral terrane, 2 occur on available land.

Jan 1, 1988