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Long-range side-scan sonar and conventional geophysical data for the Peru Trench region (8`S-15¦S latitude) have been analysed. The data show that the Peru Trench is a site of sediment subduction where bending-induced normal fault-ing of the Nazca plate plays a key role. The sediments are continually removed from the trench axis region by their inclusion in normal fault-defined void spaces, such as grabens. In the process of subduction, the sediments are often offscraped, folded arid kneaded temporarily at the base of the shoreward trench slope. The subduction complex comprising such sediments is narrower than 20 km and its volume remains more or less constant due to regular removal of its contents along with the down-going plate. Addi-tionally, morphology of the subducting Nazca plate is responsible for subduction erosion of the South American plate, where the horst blocks cause tectonic erosion by abrasion and the grabens provide a mechanism for removal of the eroded material.

Jan 1, 1990

By R. L. Nyirenda

An investigation of the reducibility of a cassiterite concentrate with charcoal was made in the temperature range of 1123-1373 K. The course of the reaction was monitored by a combination of sample weight loss measurements, product gas analysis, and chemical analysis of the reaction product. It was found that the cassiterite could be best reduced by a combination? of high temperature, reasonably high charcoal proportions, high charge poroslty, and the addition of a small percentage of lime. Analysis of kinetic data obtained from isothermal experiments using theory from the oxidation of carbon by carbon dioxide gave an activation energy value of 255 lci/mole for the consumption of carbon by reaction with cassiterite.

Jan 1, 1990

Mining had a very considerable effect on the country's development. The visual evidence remaining is an integral part of New Zealand history. Early mining for manganese and copper in the 1840s was succeeded by alluvial gold rushes. These gave way to hard rock extraction, hydraulic elevation and dredging. Coal mining dating from the 1850s was fairly widespread. Other minerals were obtained on a small scale. Manufacture of mining' machinery stimulated industrial engineering enterprises. Schools of mines played a significant part in advancing technical skills and several remain as museums. Surviving mine structures and site relics are part of the industrial heritage signifying the technological and economic development of a small isolated nation. Some of these are described. Identification, recording and preservation where practicable is advocated.

Jan 1, 1990

By Johnson RW, Rogerson R

New perceptions of the nature of volcanic hazards on Bougainville Island have resulted from a recent remapping of the geology of the island. Ignimbrites and calderas have been identified at six Quaternary centres (Emperor Range, Tore, Kunua, Billy Mitchell, Loloru, and Laluai), and large-scale explosive activity now must be identified as a significant volcanic hazard on the island. Billy Mitchell and Loloru volcanoes are identified as the most likely sites of future, major, explosive activity. Billy Mitchell was recognised formerly as an extinct volcano, but is now known to have produced major eruptions 370 and 918 years BP. Five ignimbrite units recognised at Loloru range in age from about 12 700 to 3200 years BP. Bagana is an active volcano in central Bougainville, but its explosive activity is relatively minor and does not significantly affect areas beyond the uninhabited area of the volcano itself. Balbi is the largest volcano on Bougainville and has an extensive geothermal area at its summit. It was thought to have been in eruption last in the early nineteenth century. However, 370 and 940 year BP plinian ashfalls from Billy Mitchell cover the central area of Balbi, so the latest significant activity from Balbi may have been at least 1000 years ago.

Jan 1, 1990

By Grouhel P

Blasting performance is directly related to the characteristics and efficiency of the explosives used. The selection of the correct explosive for particular blast conditions and objectives depends on the ability to characterise the performance of individual explosive products. Techniques have been developed by the JKMRC to measure explosive performance and assess the impact of explosive performance on blast results. Studies conducted at a number of mine sites have shown that different types of explosives perform quite differently and that the performance of any particular explosive can vary significantly. The principal causes of these variations have been identified and detailed blast monitoring techniques, including the analysis of muckpile fragmentation and shape, have been used to quantify the effects of explosive performance on blast Results.

Jan 1, 1990

By D. G. Chedgy

Environmental improvement efforts are focusing with increasing intensity on pollutants resulting from combustion. The high cost of removing these pollutants at the power station is well documented. Physical coal cleaning has always been and should remain the most economic method of reducing sulfur oxide emission from coal combustion. It is critical in the selection of preparation plant circuitry to consider capital and operating costs, as well as the level of sulfur reduction. This paper describes the technical criteria which must be used for efficient process selection and summarizes the cleaning systems available or in development.

Jan 1, 1990

Large GDP increases in the Pacific Rim countries have been accompanied by similarly large increases in demand for oil products. In the case of residual fuels, this demand has been tempered by the substitution of other energy products such as coal or gas. In the region's developing and newly industrialised nations, it has not been possible to make the very large investments in infrastructure which allow other energy sources to be used for transportation. As a result, GDP growth has been mirrored in the demand growth for automotive fuels. Other non-substitutable products such as lubricants have also benefitted by the region's GDP growth.   The combination of a number of years of sustained growth, coupled with increasing quality requirements is now stretching the upgrading capacity of the region's refineries. IT, as seems likely, the region continues to enjoy a high GDP growth rate, then this will be accompanied by increasing reliance on finished products coming out of the Middle East.   The owners of the most simple form of refinery in which crude is simply distilled and the naphtha reformed into petrol will face major capital investments. If they decide not to bear this cost, they will face increasing problems in selling their surplus residual fuel oil at an economic price. Quality will become an increasingly important issue. Not only in the well publicised areas such as unleaded petrol, but also for products such as lubricants which play a major role in the efficiency of modem equipment. Quality of service such as hours of opening, ease of access, and service station facilities will also become increasingly important as the oil companies use these to attract customers and gain brand differentiation.

Jan 1, 1990

By J. E. Garlanger

Each year, Florida mines approximately 40 million tons of phosphorite, most of which is ultimately converted to various commercial fertilizers. The phosphorite is mined from within the bottom portion of the 40-to 60-ft. thick surficial aquifer, using open pit mining techniques. The ore zone or "matrix" is generally overlain by relatively permeable fine sand to silty and slightly clayey fine sand. The ore itself is highly variable in nature but, in Central Florida, typically consists of less permeable clayey phosphatic sands and sandy clays with stringers of permeable sand. The ore is much more sandy in the north Florida mining area.

Jan 1, 1990

By N. S. Dalal, Xianglin Shi

"INTRODUCTIONEpidemiologic studies of workers in chromate-ore related industries, 1-3 and stainless steel welding and related occupations4 have shown that they have about 20-40 times higher risk of throat or respiratory track cancer than controls. Although the actual carcinogenic substances were not identified in these statistical studies, Cr(VI) compounds (for example, calcium chromate, zinc chromate, and lead chromate) were implicated as the causative agents, whereas Cr(III) compounds were not suspected as carcinogens. s These suggestions were supporte4 by laboratory studies wherein many Cr(VI) compounds produced sarcomas at the implant or injection sites.1,5 Squamous cell carcinomas and adenocarcinomas closely resembling human lung cancer were induced by intrabronchial implants of calcium chromate in rats, 6·7 whereas Cr(DI) oxide and Cr(lll) sulfate did not induce any tumor formation.6,7While the mechanism of the chromate-induced carcinogenicity is not fully understood, it is generally thought8 that it involves some damage to DNA. Specifically, it has been reported that: a) the chromate ion, henceforth referred to as chromate, can pass through the cell membrane and enter the cell while CR(DI) does not, 9 b) chromate does not interact with either native or denatured DNA 10 while Cr(III) does, 11 and c) the final Cr-DNA complex isolated from cellular reactions of chromate is Cr(III)-DNA, with Cr(III) binding to the phosphate groups.12,13 Thus the important question is: since Cr(DI) cannot pass through the membranes, how does Cr(III)-DNA complex form? For this to happen, Cr(VI) must be reduced to its lower oxidation states, 14 ultimately to Cr(III), by some reductants in the cellular environment. Unless this reduction occurs, the DNA would not be damaged and therefore no chromate carcinogenicity would ensue. Thus the reduction of chromate to its lower oxidation states seems to be a key step in the chromate carcinogenicity .1s One of the major reductants in cellular environments is thought to be glutathione (GSH), both outside and inside the cells.16-lB Some evidence for the role of GSH in the chromate toxicity was provided by recent studies showing that exposure of hamster cells to non-toxic levels of added selemite increases the levels of GSH as well as the Cr(VI)-induced DNA strand breaks,19 and that such DNA strand breaks in hepatocytes also change in direct proportion to the GSH content. 20,21 These observations were interpreted as implying that the reduction of chromate by GSH to some reactive intennediate is an important step in the chromate carcinogenicity. 20.21 In · the present undenaking22 we have used electron spin resonance (ESR) and spin-trap methodology to investigate the reduction of chromate by GSH and find evidence for the involvement of the glutathionyl radical (GS ·) as well as Cr(V)-intermediates."

Jan 1, 1990

By R. A. Jankowski

The U.S. Bureau of Mines has conducted a study to identify the sources of respirable dust and appropriate dust controls applicable to today's high tonnage longwall faces. The primary source of respirable dust identified is the cutting action of the shearer; however, the pct contribution of dust from coal transport through the stageloader/crusher was significant. This was primarily due to the high rate of mining, requiring rapid and constant coal transport. Techniques implemented for the control of shearer-generated dust included high drum water flow rates, deep cutting, shearer-clearer-type external water spray systems, and radio-remote control. The high water flow rates, and an enclosed stageloader with scrubber, were used to control dust during coal transport. No novel or effective control technology exists to control dust during support advance. Administrative controls for dust avoidance, and manual and batch-activated electro-hydraulic control systems were used to keep support movers out of the dust generated during support advance.

Jan 1, 1990

By J. Roger Loebenstein

Small amounts of arsenic trioxide were shipped in 1988 from remaining stocks at ASARCO Incorporated's closed plant at Tacoma, WA. Imports of arsenic trioxide were at about the same level in 1988 as in the previous year. Legislation and Government Programs The Occupational Safety and Health Administration (OSHA) levied a $1.6 million fine against Asarco for exposing its workers at its East Helena lead smelter in Helena, MT, to unacceptably high levels of lead and arsenic. The bulk of the fine was for violations of a respiratory protection program. The same smelter and its environs has been listed as a Superfund toxic-waste site by the Environmental Protection Agency (EPA). Tests had shown high levels of lead, cadmium, and arsenic in the soil near the smelter. EPA planned to extend the cleanup to areas within the town of East Helena because high levels of arsenic had been found in shallow test wells outside the smelter site. Federal and State health officials have warned residents living in the vicinity of East Helena to avoid eating certain home-grown vegetables because of high concentrations of heavy metals.2

Jan 1, 1990

By Cheryl L. Mardock, Michael D. Strickler

The Bureau of Mines is examining mineral deposits bearing strategic elements such as cobalt, for which the United States heavily relies on imports. The Turner-Albright volcanogenic sulfide deposit in southwestern Oregon is marginally economic based on its gold content and associated silver, copper, zinc, and cobalt values. Bureau research on the Turner-Albright deposit was performed (1) to evaluate domestic cobalt recovery as a byproduct of gold production from massive sulfide ores; (2) to develop an analogue of modern sea-floor polymetallic deposits to determine the economic potential of the deep-sea resources; and (3) to compile information on the geochemistry and genesis of the deposit that can aid in future onshore exploration. Cold was introduced as near micrometer-sized disseminations by exhalative hydrothermal fluids near sea-floor vent sites and by late influxes of mineralizing fluids into lower zones of brecciated sulfides and basaltic fragments. Cobalt is a substitutional element in pyrite that occurs in outlying halos around original vent sites. Mineralogic studies conducted with a scanning-electron microscope and an electron microprobe determined that none of the ore minerals are amenable to traditional beneficiation methods such as gravity and flotation. An experimental oxygen pressure-leaching procedure developed by the Bureau has proven successful in treating such complex ores.

Jan 1, 1990

By R. M. G. S. Berezowsky

Treatment of Hudson Bay Mining and Smelting Co. Ltd. (HBM&S) zinc concentrate in the Sherritt zinc pressure leach process produces a residue containing elemental sulphur, residual sulphides, precipitated iron species, si1ver and gold. Flotation of the residue recovers most of the elemental sulphur and residual sulphides to the concentrate, leaving iron oxides and bask sulphates in the tailings. The tailings also contain most of the sflver and some gold. Direct cyantde leaching of the oxide tailings (220 g/t Ag, 1.4 g/t Au) was capable of leaching most of the gold, but only a minor portion of the silver. This paper reports testwork, conducted by Sherritt on behalf of HBM&S, to define a process for a high recovery of the precious metals from the oxide tailings. A si1ver enhancement treatment, consisting basically of digestion of the residue with lime at 90°C to render the silver amenable to enhanced recovery by subsequent cyanidation, was selected as the most promising approach. Batch silver enhancement and cyanidation tests showed that treatment of the oxide residue with 80 kg/t CaO at 90°C for 1 to 2 h increased the silver extractability in subsequent cyanidation from <20% to 96%. A 96 h continuous miniplant test (1 kg/h solids feed rate), of a circuit including a silver enhancement treatment step followed by conventional cyanidation and carbon in pulp silver and gold recovery, confirmed metal recoveries to the carbon of 90% Au and 96% Ag. Reagent consumption rates were 1ess than 100 ?kg/t CaO and 5 kg/t NaCN.

Jan 1, 1990

By J. Stachurski

Flotation tests were carried out on 6 coal samples of different rank as well as their oxidized samples. A mixture of diesel oil and alcohols was used in these tests. Surface oxidation caused a distinct decrease of the flotation recovery with some improvement in the grade The reduction in the recovery increased with increasing the concentration of the oxidizing agent. The floatability of low rank coals was affected by oxidation to a higher degree than medium and high rank coals. The recovery size curves of oxidized samples mere similar in shape to that of non-oxidized coals.

Jan 1, 1990

By L. C. St. Arnaud

"Open pit mines can produce large disturbances within regional hydrogeologic systems. The degree of disturbance and the consequences on the local environment depend on the size of the pit and on the physical setting of the mine. Comparisons and contrasts are presented for three Noranda base metal open pit mine sites.The Brunswick Mining and Smelting No 6 open pit has a surface area of 11 ha and a depth of 185 m. It is located within complexly deformed schists and meta-volcanic rocks. The massive sulphide and iron formations visible along the north and southwest walls of the pit generate acid drainage. Mining ceased in 1983, and the pit is presently being filled with waste rock and neutralized drainage water. Water balance calculations estimated a total fill up time of sixteen years. As the water level rises, leakage to groundwater could take place across a fault zone intersecting the pit.The Mattabi Mines F-Group pit has a surface area of approximately 3 ha and a depth of 50 m and is also set in meta-volcanic rocks and acid generating iron formations. Production at this site ceased in 1982, and the low pH pit water is neutralized and pumped into a nearby lake at least every five years. Major water inflows are from precipitation and groundwater. Groundwater mounds within adjacent high land surrounding the pit provide a natural hydraulic barrier to groundwater flow, except for the southeast side. As a consequence, the pit water elevation is being kept below the elevation of the nearby creek in which some of the pit water could drain.The Bell Copper open pit covers an area of 40 ha and is 270 m deep. With present ore reserves, the mine might be in operation until 1992. The geology around the pit consists of andesitic tufts, siltstones and shales, and the acid generation potential of the rock is relatively low. A recent hydrogeological study estimated fill up time by precipitation and groundwater to be in the order of 260 years.With increasingly more stringent requirements for mine closure, it is anticipated that more detailed hydrological and hydrogeological studies of open pits will be required to determine post-closure environmental impacts and the suitability of open pits for mine waste disposal."

Jan 1, 1990

By J. T. Sitarski, R. C. Emmett, L. W. Luinstra, R. P. Klepper

A mining operation in Zimbabwe produces a pyritic gold concentrate that requires oxidative pretreatment prior to cyanidation in order to liberate 80 percent of the gold values. Bio- oxidation offered the potential of increased gold recovery and was considered to be an economically advantageous alternative to the existing practice of roasting the concentrate. Based on bench- scale test work, a small bio-oxidation plant, capable of processing approximately 50 percent of the concentrator production, was installed at the mine to evaluate this approach. The plant included two 57 m3 bioreactors in series and the ancillary equipment needed to prepare the feed concentrate, to wash the leached residue prior to cyanidation, and to neutralize the waste liquor. The plant was operated for a year-and-a-half, and the conditions needed to achieve a 90 percent liberation of gold values were determined. A number of critical technical problems were encountered, and many were resolved on-site. Others have been addressed since the pilot plant was moth-balled in June 1988. Valuable insight was gained from the operation of the pilot plant, which has provided useful guidance for continued process and equipment improvement.

Jan 1, 1990

By B Mohanty

Full-face blasting rounds have been used to excavate a 4.6-mdiameter shaft at Atomic Energy of Canada Limited's Underground Research Laboratory near Pinawa, Manitoba. Both standard pyrotechnic delay detonators and the newly developed electronic delay detonators (EDD) were used on the project. The full-face blasting technique, employing 89-mm-diameter relief holes and 38-mm diameter blast holes, NG-based explosives, and the regular long period delay detonators, has been standard practice at the site, giving excellent wall control and fragmentation results. The comparison blasts using pyrotechnic detonators and EDDs were carried out to test the operational logistics, timing accuracy and blast results obtained with the latter. The long period pyrotechnic delays ranged from O to 18, with the nominal delay varying between 350 ms and 800 ms. The EDD blasts used the same number of periods, with the respective delay interval between successive periods set precisely at 190 ms and 210 ms for the two blasts. Based on a broad range of critically assessed parameters, the EDD blast results proved to be signficantly superior to those obtained with regular pyrotechnic detonators. The results have been analyzed in detail and the relative merits of the two delay systems have been determined. Alternative designs to derive maximum benefits from EDDs in shaft and tunnel blasts have also been suggested.

Jan 1, 1990

Scientific drilling and blasting techniques are currently being presented to the mining industry as an aid in the overall optimisation process. The degree of success in the development of these techniques over the last ten years has prompted statements that generally relate to blasting becoming a science rather than an art. Many of the techniques are currently operated or at least analysed by scientists. As such, their use has been restricted to project type activities while the more routine activities associated with day to day mining has continued to be carried out by engineering rather than scientific staff. Some of the scientific techniques will remain legitimately as a project or an occasional use facility. Generally speaking a cost/benefit analysis at a particular mine will decide the level of use. This should logically highlight a number of techniques with potential of regular mine site use. Regular mine site use implies mine site analysis and hence the gulf between the scientist and mine operator/engineer must be addressed. There are all sorts of solutions and they are not mutually exclusive. One alternative could be to increase specialisation at the mines. With "career paths" becoming more formalised the trend would seem to be away from mine site specialists unless, for instance, this specialisation was provided by term secondment from research establishments. Another alternative could be the scientists themselves applying their developmental skills to "humanise" and "package" the projects in such a manner that they can be routinely used at mines.

Jan 1, 1990

By Alexander May

The U.S. Bureau of Mines conducted studies to determine if phosphate slag stockpiles at Tennessee Valley Authority&apos;s National Fertilizer Development Center were hazardous materials. The stockpiles were not hazardous materials as determined by Environmental Protection Agency (EPA) extraction procedure (EP) toxicity test. Radium-226 concentration was 28.7 pCi/g in slag and 2.1 pCi/g in background material. Radium-226 was not leached from the slag. Fluoride concentration was 3.87 pct in slag, 0.18 pct in subsurface material under slag, and 0.08 pct in the background. Slag material permeability was 1.65 x 10-3 cm/s, and subsurface material permeability was 3.24 x 10-6 cm/s. Rain water, trapped in a depression on top of the east slag stockpile, became seepage water at the base of the stockpile. Concentrations of EPA toxic elements in seepage water were much less than concentrations from an EPA EP toxicity test on the slag. Twelve elements-Na, Mg, Ca, Sr, Ba, Cr, Mn, Co, Cu, Cd, AI, and P-had higher concentrations in seepage water than in rain water on top of the slag stockpiles, or in creek water adjacent to stockpile bases, indicating that they were leached from slag stockpiles.

Jan 1, 1990

By J. E. Rourke, O&apos

This paper describes the use of index testing to obtain rock properties that are useful in the design and construction planning of an underground development for civil engineering or mining projects. The index properties discussed include: point load; Schmidt hammer hardness; abrasion hardness; and total hardness. The first two index properties correlate to uniaxial compressive strength (UCS) and Young&apos;s modulus. Discussions are given on empirical, normalized relationships of UCS to rock mass properties and the integrated use with semi-empirical, geotechnical design methods. The hardness property indices correlate to construction performance parameters and some relevant experience is cited. Examples of data are presented from an index testing program carried out primarily on siltstone, sandstone and limestone rock core samples retrieved from depths up to 1005 m (3300 ft) in a borehole drilled in the Paradox Basin of eastern Utah. The borehole coring was done for a nuclear waste repository site investigation.

Jan 1, 1990