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By Barbara J. Arnold

The Electric Power Research Institute (EPRI) and six EPRI-member utilities are sponsoring research to define relationships between coal properties and coal handling behavior. Deratings and outages caused by plugged chutes or bunkers or frozen coal can cost utilities millions of dollars annually in lost energy production as well as in manpower to restore coal flow. There is also the added expense of maintaining redundant equipment to assure a continuous coal feed to the boiler, a common practice for utilities. Over the past two years, researchers at CQ Inc. and Iowa state university have collected and analyzed coal samples to develop a coal handleability index for utilities to use when specifying coals for their power plants. These coal samples cover ranges in ash content, rank, grindability, size distribution, and moisture content--properties that affect the handling behavior of coals. Other properties, such as the washability and ash composition, are measured as well. Over the remaining two years of the project, all of these analyses will be correlated to handling behavior, measured using a triaxial shear tester that determines the strength of a coal under compression. An index will be developed and validated at host utility power plants.

Jan 1, 1991

Coeur d'Alene Mines is a precious metals producer which is dedi- cated to growth through it's exploration and acquisitions efforts. We foster and support these activities by providing our staff with long-term financial support, the encouragement to proceed with their projects and ideas, and a firm belief that we will be successful. Coeur's corporate headquarters are located in beautiful, historic Coeur d'Alene, Idaho. Our main mining operations are Rochester, locate near Lovelock, Nevada, Coeur Mine,located near Wallace, Idaho, and Thunder Mountain, located in central Idaho. Our Ken- sington Gold project is located about 45 miles north of Juneau in southeast Alaska. We have exploration offices located in Reno, Nevada, and Santiago, Chile. At this time, Coeurd'Alene Mines produces precious metals from mines located in the United States. Our Rochester open-pit opera- tion, which is 100 per cent owned and operated, is located in Nevada. Presently, this operation produces 5.5 to 6 million ounces of silver per year and 60-70,000 ounces of gold. We move 65,000 to 70,000 tons of rock per day of which about 23,000 tons is ore. The ore is crushed, stacked on permanent heaps and leached. The recovery is by Merrill-Crowe. Although the average grade is rela- tively low, 1.4 ounces per ton silver and 0.012 ounces per ton Au, the operation is very low cost. Our cost of production is less than $4.00 per silver equivalent ounce. Rochester is anunusual operation in that the crushed rock stacks without much compaction and the ores are easily leached. The final height on our heaps will be about 220', and overall recovery will be about 55 per cent of the silver and about 85 per cent of the gold. Reserves at Rochester are expanding and are now adequate for at least fifteen years of opera- Tion.

Jan 1, 1991

By G. Heiken

On the Earth's Moon, obvious hazards to humans and machines are created by extreme temperature fluctuations, low gravity, and the virtual absence of any atmosphere. The most important other environmental factor is ionizing radiation. Less obvious environmental hazards that must be considered before establishing a manned presence on the lunar surface are the hazards from micrometeoroid bombardment, the nuisance of electro-statically-charged lunar dust, and an alien visual environment without familiar clues. Before man can establish lunar bases and lunar mining operations, and continue the exploration of that planet, we must develop a means of mitigating these hazards.

Jan 1, 1991

Mining of the Martha Hill epithermal gold deposit via open pit methods will excavate a pit to 15 m below sea level. Regular geotechnical evaluations of pit slopes have taken place. Details of the various components of these evaluations, including geological structure, material strength, and groundwater, are covered. Pitwall geological structures are represented clearly on pit floor grade control maps with the dominant sets being steeply dipping strike fractures. Cross cutting shears are common. Material strength is reflected by the oxidation status of the hydrothermally altered host rocks, with weaker material occurring in partially oxidised ground. Regional groundwater is generally high, particularly on the north-eastern side of the pit, where it has been little affected by de-watering. Geological structures appear to control the flow of groundwater in the proximity of pitwalls and require draining by the introduction of horizontal drains. An overview of pit slope design is given. Slopes are designed for overall slope stability, allowing for the occurrence of minor interbench failures.

Jan 1, 1991

By James C. Barker

Alaska's expansive continental shelf represents future opportunities for marine mineral development. Although today's metal prices and subsidized foreign mineral production continue to discourage industry investment in marine exploration worldwide, the longer term outlook is one of increasing costs on-shore with a dwindling land-base available on which to search for and extract minerals. Likely, the generations of the 21st century will increasingly recover their minerals from the sea-floor. Though largely unexplored, Alaska potentially represents a major port ion of the U.S. marine resources. Several factors demonstrate this. First, the Alaskan OCS is huge; 74% of the entire United States' continental shelf lies off of Alaska, and 54% of the U.S. coastline is Alaskan. Combined with the jurisdiction waters of the Soviet Far East, the Bering-Chukchi shelf is one of the world's largest tracts of shallow water. Second, Alaska is situated at the northwestern terminus of the mineral-rich American cordillera. From Chile to Alaska, major on-shore deposits of precious and base metals, ferroalloys, and industrial minerals are found in the tectonically disturbed belts of the cordillera. In 1988, the western U.S. cordilleran states produced 70% of this country's mineral output (excluding construction materials). Throughout the cordillera's entire 10,000 mile length, the rock units strike largely parallel to the coastline, but in Alaska they extend directly offshore and onto the continental shelf. Consequently, the mineral-rich terranes off of Alaska have a much more complex interaction with coastal and lit-

Jan 1, 1991

A knowledge of airway friction factor (K-factor) is necessary to designing mine ventilation systems for least cost and optimum effectiveness. The friction factor used must be accurate and reliable to estimate correctly roadway resistances and pressure sources for required flows. Though the resistance to flow offered by mine airways has been an object of study over the last half century, no accurate relation has yet been established from which the prediction of the resistance of a projected airway can be made. In Kentucky, only limited and incomplete data on local K-factors are available. Therefore, there is a need for field investigations to determine these values in-situ for existing mining conditions. The author describes a study concerning K-factor that was carried out in ten coal mines, located in eastern and western Kentucky. The results of these investigations are presented in both tabular and graphical form.

Jan 1, 1991

By P. D. Rao

The combination of high moisture and low heating value has restricted most low-rank coal (LRC) usage worldwide to mine-mouth power generation. Coals from Usibelli Coal Mine and the Beluga coal field have a heating value of approximately 8,000 Btu/lb and 28% moisture. Hydrothermal treatment (at 275 to 352'C) of lump coal from Usibelli Coal Mine and Beluga coal field enhanced the heating value of the coal, on an equilibrium moisture basis, from 8,000 Btu/lb to nearly 12,000 Btu/lb. The product coal with high heating value and 0.2 % S is an environmentally acceptable premium fuel. The Hardgrove grindability index of the coal is greatly improved, further enhancing its value. Increase in hydrothermal drying temperature promotes vesiculation of resinite. Vitrinite reflectance increased to 0.72 and vitrinite was subjected to widespread visiculation resulting in a coke like structure indicative that the material went through the fluid stage.

Jan 1, 1991

By J. P. Bunch

As the number of environmental laws continues to steadily increase and the economic penalties for contamination problems become more severe, environmental management represents an important management function within today's U. S. mining industry. The economic impact to a mining company for contamination is not only realized in legal fees and fines but also in the cost of doing normal business. For example, a mining company with contaminated property applying for a loan may be refused because of a lending institution's reluctance to finance due to liability concerns. Or, an insurance company may decide to greatly increase its annual premiums because of existing or potential contamination problems. One of the main duties of the environmental manager is to seek ways to reduce these types of problems by eliminating contamination or by knowing what problems exist and designing corrective measures to prevent the situation from worsening.

Jan 1, 1990

By N. S. Dalal, B. Jafari, F. H. Y. Green, V. Vallyathan

"INTRODUCTIONThe mechanistic details of the biological events leading to coal workers pneumoconiosis (CWP) are not yet fully understood, despite several decades of extensive epidemiologic1.2 and laboratory studies.2-6 Epidemiologic studies1.2 have shown, for example, that the incidence and severity of CWP differ markedly in the different regions and mines at comparable exposures, but laboratory investigations2-6 have demonstrated only partial correlation of the epidemiologic data with the differences in the mineral composition and the rank of coal mined. In particular, while epidemiologic data indicate1.2 direct correlation of the· prevalence and severity of CWP with the rank (i.e., % carbon content) of coal, this correlation has not been established by laboratory4'6 and animal exposure3 studies. In order to explain these results, in 1980 Artemov and Reznik' suggested that perhaps they arise from the fundamental differences in the surface properties of the coal. dusts inhaled by the coal miners and those used in the laboratory studies: while the miners inhale freshly fractured coal particles, henceforth called the 'fresh' coal dust, the laboratory studies generally utilize 'aged' coal dusts (i.e., dusts that have been stored for many days or even longer). Reznik and Artemov' used electron spin resonance (ESR) spectroscopy to show that the mechanical crushing of some Soviet Union coals generated organic free radicals and that the concentration and the decay times (hence the reactivity) of these radicals were higher for the coals of higher ranks. Since some of the radicals decayed within a few minutes in air, the authors surmised that while these radical species could lead to certain specific pathogenic reactions at the sites of mining operations, this might not be the case in the laboratory studies, due to the conventional use of 'stored' dusts which would be expected to contain significantly smaller free radical concentrations. This is consistent with the recent findings that, standardized, aged coal dusts exhibit minimal cytotoxicity. 8While the above mentioned work of Artemov and Reznik7 did suggest a possible new clue to the pathogenesis of CWP (i.e., the role of the coal based free radical species), no direct biological/cytotoxicity data were provided to show that 'fresh' coal dusts were, indeed, more pathogenic than the 'stale' ones. Because of the rather significant implications of the Artcmov-Reznik hypothesis to the understanding of 1hc biochemical mechanism and, hence, the strategies for the eventual containment of CWP, we have initiated a comparative study of the free radical formation and cytotoxicity properties of freshly crushed coal ·particles. As done by Artemov and Reznik, 7 we have used the ESR technique as the direct method of measuring the concentration and decay kinetics of the coal based free radicals. Our preliminary ESR studies on two Pennsylvania coals, a bituminous (carbon content 72 % ) and an anthracite (95 % carbon) coal, have confirmed the Artemov-Reznik finding that the crushing-induced free radical sites are higher on the coals with higher carbon content (i.e., higher rank).9-11 In the present work we describe our more recent results of a parallel study of the time dependence of the decrease in the free radical content of a freshly made anthracite dust (as measured via ESR) and that of the dust's cytotoxicity potential as measured by the extent of hemolysis of (sheep) erythrocytes. We have also investigated the effects of free radical scavengers on the cytotoxicity potential of the dust and deduce that indeed the free radicals could play a significant role in the initial events in the mechanism of the cytotoxic effects due to the inhalation of coal dust inhalation."

Jan 1, 1990

By Daniel B. Conn, John L. Floyd

PhotoSeis™ is a blast analysis method that combines the advanced technologies of high speed motion picture photography and digital seismology. When fracturing rock with the use of explosive energy, the human eye cannot detect the details of the process due to its short duration. An extended time base is required to accurately quantify the response of the rock mass to the detonation process. This time base is provided by the use of high speed motion picture cameras. The control of ground vibrations and airblast is an important consideration when developing efficient blast designs. High vibration and airblast levels can be an indication of improper design, inaccurate detonators, or adverse geology. Since many factors can elevate airblast and ground vibration, a greater understanding of the site specific response to the blast design is needed that is beyond the scope of simple seismographic recordings. By synchronizing the photographic record provided by the high speed motion picture cameras with the airblast and vibration information from digital seismological monitoring, the Photoseis™ technique can be of great assistance in controlling airblast and vibration and optimizing the use of explosive energy for rock fragmentation.

Jan 1, 1990

By L. J. Blatnica

Throughout the 1980's the tem Mine-Wide Monitoring System has had various meanings for manufacturers of these systems and underground mine operators alike. System suppliers had visions of grandeur in the early 80's as they envisioned each mine, that has more than a single section, installing a computer based monitoring system to provide surveillance, control and documentation of the entire mining operation, including everything from a single heat detector to the weekly payroll. In a few cases this may have become reality but the truth is these systems have quietly become a steady but unspectacular workbase for the modern mining industry of the 1990's. As it exists today the total market for underground monitoring systems may not exceed $10 million annually. Suppliers have lowered their expectations of the dollar value of this particular market. Some were entering a new market because of experience with computer based data acquisition systems. Others had been active in the mining industry for years with more traditional equipment (communication systems, methane monitors, safety equipment, etc.) and decided to become involved with Mine-Wide Monitoring Systems.

Jan 1, 1990

By N. S. Dalal, X. Shi

"This study reports a new property of the important NAD(P)H-dependent flavoenzymes, glutathione reductase, lipoyl dehydrogenase and ferredoxin- NADP oxidoreductase, that can catalyze a one electron reduction of metal ions such as chromium(VI) and vanadium(V). During the enzymatic reduction process, molecular oxygen is reduced to H2O 2 , which reacts with the reduced metal complexes to generate hydroxyl radicals. Since the hydroxyl radicals have been suggested to play an important role in Cr(VI) toxicity, this study provides a basis for a recent observation that Cr(VI) mutagenesis is strongly oxygen dependent. These results also point to an enzymatic pathway for the metabolism of some metal ions and concomitant generation of hydroxyl radicals. l. INTRODUCTIONThe purpose of this communication is to report that some important NAD(P)H-dependent flavoenzymes (glutathione reductase, lipoyl dehydrogenase and ferredoxin-NADP+ oxidoreductase) can catalyze one electron reduction of metal ions such as chromium(VI) and vanadium(V) and simultaneously reduce molecular oxygen to generate Hi02 and, eventually, the ""OH radical. This finding is significant because (i) the known substrates for the flavoenzymes are organic species and not metal ions, and (ii) the report on the enzymatic formation of the ""OH radical provides a new pathway for understanding the mechanism of genotoxicity of some non-ferrous metal ions. For example, it has been suggested that OH radical is likely to be the major species responsible for Cr(VI) genotoxicity [1-5). The 'OH radical is generated through the reaction of Cr(V) complexes with cellular Hi02 [4,5]. Cr(V) itself is known to be generated from Cr(VI) in various biological systems, in particular, microsomes [ 6), mitochondria [7] and mitochondrial electron transfer chain complexes [8]. However, no specific enzyme responsible for the Cr(V) generation has been identified except possibly glutathione reductase [4]. In this study we have used ESR and spin trapping techniques to show that the flavoenzymes can generate Cr(V) and provide a catalytic redox cycle for 'OH formation in such reactions. Herein we present our results on Cr(VI) and summarize those on other systems. Correspondence address: N.S."

Jan 1, 1990

By D. S. Choi

This paper describes an improved source location technique for microseismic events related to coal mining. A system of non- linear distance equations is solved with the use of the Newton-Raphson method. This computational method is- advantageous when the number of geophones is limited. In addition, this paper includes the results of the analysis of data from several instruments which characterize both mine seismicity and environmental noise such as vehicle traffic. Analysis of the mine seismicity has contributed to a better understanding of caving above a longwall gob and of what constitutes stable ground conditions.

Jan 1, 1990

By F. M. Jenkins

Longwall mining systems are used to mine approximately 50 pet of the world's total underground coal production. Single entries are the predominant method of longwall development in Europe and Asia, where mining conditions are more severe than those encountered in the United States. During the 1970's and early 1980's, the U.S. Bureau of Mines and the U.S. mining industry invested nearly $20 million in single-entry and related research. This report reviews the accomplishments of single-entry research in the United States and describes two U.S. single-entry field projects: the Sunnyside single-entry project in central Utah and the tunnel-boring project in northern West Virginia. Also discussed are a single-entry study conducted by North American Mining Consultants (NAMCO) and a single-entry design study conducted by Ketron, Inc. This Bureau report compares the resulting technology with European counterparts to further assess the utility and efficiency of U.S. systems.

Jan 1, 1990

By M. Misra

The dielectric properties and flotability of different ranks of Argonne Premium Coal samples are presented. The flotability of different ranks of coal are correlated with the dielectric properties and intrinsic moisture (or bound water) content. Measured dielectric properties of as-received coals and other constituents are incorporated into a mixture equation to calculate the dielectric properties of bound water present in the different ranks of coal. The nature of bound water present in low-rank hydrophilic coals is significantly different from that present in high-rank hydrophobic coals. The water molecules present in low-rank lignite have an oriented dipole-dipole interaction and are tightly bound to the surface. For high-rank coals, the water molecules are not bound to the surface and have a randomly distributed clathrate ice-like structure. Controlled thermal treatment can modify the structural nature of bound water present in low-rank hydrophilic coals and increase their flotability.

Jan 1, 1990

By Drummond Earley III

The U.S. Bureau of Mines is currently conducting laboratory experiments to study the reactions occurring during in situ leaching of oxide copper ores hosted by biotite-poor granite and biotite-rich granite porphyry. Detailed pre-leach and post-leach petrographic examinations of the rock samples are combined with the leach solution chemistry resulting from core leaching experiments to enable an evaluation of the various reactions which are responsible for the observed fluid chemistry. The information resulting from these laboratory studies is being utilized to support the design of the Bureau's ongoing field research project at the Santa Cruz deposit near Casa Grande, AZ. Atacamite and chrysocolla are the primary copper minerals present in this deposit, and both are readily soluble in the dilute 5% sulfuric acid solutions used in these experiments. In addition to the dissolution of copper minerals, biotite dissolution also occurs during the experiments, contributing K, Mg, Fe, and Al to the leach solution. The biotite dissolution appears to be non-stoichiometric, as it is progressively altered to vermiculite and finally, amorphous silica. While K, Mg, and Fe concentrations in solution steadily increase with time, Al quickly reaches a maximum, and then remains relatively constant for the remainder of the experiment. This suggests that Al saturation is achieved, and this Is supported by the presence of precipitated Al sulfate and aluminosillcate clay mineralization in the post-leach rock samples.

Jan 1, 1990

By Urabe T

In June 1989 a diving cruise of the French submersible Nautile has been carried out on the North Fiji basin spreading ridge. The objective of the cruise was the geological and geochemical study of the active spreading axis and associated hydrothermalism processes. This operation was the third cruise of the French-Japanese STARMER project following two cruises of the R/V Kaiyo in 1987 and 1988.INTRODUCTIONAfter the Seapso III cruise (Auzende et al., 1986, 1988a and b) of the R/V Jean Charcot in 1985, the objective of the Kaiyo 87 and 88 cruises was the complementary Seabeam mapping of the North Fiji Basin spreading axis between WS and 22'S and a systematic sampling (water and rocks) and deep towing (TV and photos) at about every ten milles along the axis.

Jan 1, 1990

Flotation of dolomite from apatite was investigated, using dodecylamine hydrochloride or sodium oleate as the collector, in the absence and presence of inorganic modifiers such as sodium chloride. Separation of dolomite from apatite was anticipated from the single mineral experiments under various pH and collector concentration conditions. Flotation selectivity in the mixtures, however, was found to be limited. Attempts to control the flotation response of these minerals by addition of salts such as NaCI and KCI indicated that selectivity is possible. The presence of sodium chloride was determined to depress apatite flotation using sodium oleate leaving dolomite flotation unaffected (Moudgil and Ince, 1989). In this paper, conditions for optimum separation and the effect of major parameters on the desired selectivity are discussed.

Jan 1, 1990

In order to reduce waste and improve resource conservation, mine planning, and development, the U.S. Bureau of Mines is investigating the effects of multiple seam interactions associated with longwall coal mining. Field investigations were conducted at a mine located in Boone County, WV, where a longwall panel was operating subjacent to room-and-pillar workings in an overlying seam. To assess the effects of overlying workings on longwall headgate stability, the Bureau gathered various geotechnical information at this minesite. Headgate pillars and entries were instrumented and monitored to study their behavior during side-abutment loading as the longwall panel approached and passed beneath the overlying room-and-pillar developments. The two operations are separated by 800 ft of interburden, and although interactions between operations separated by this distance are uncommon, geomechanical measurements indicate the occurrence of an interaction. These measurements show that convergence on the headgate entries was most adverse subjacent to barrier pillars in the overlying mine. Pillar measurements indicate that side-abutment pressure increases were slightly greater than predicted values. Several factors related to both geology and mine design, believed responsible for this large interactive distance, are discussed.

Jan 1, 1990

By Phillip Allender, Wolf Karo, Knox Van Dyke, Lixin Wu, Ali Ardekani, Jorge Garcia, Jaime Gutierrez

"We report that two different micropolystyrene round beads linked to either luminol or lucigenin have been developed. The 1-µ.m-diameter beads arc useful reagents that allow one to perform chemiluminescent (light producing) phagoeytic reactions without opsonization. It is known that luminol reacts with peroxidases (e.g., myeloperoxidase) while lucigenin reacts mainly with superoxide anion. Luminol and lucigenin beads produce cellular chemiluminescence (CL) with neutrophils, macrophages, monocytes, and differentiated human promyelocytic leukemic cells (HL60). When myeloperoxidase (MPO) is present luminol beads evoke higher CL from neutrophils, but when little or no MPO is present, lucigenin beads produce higher amounts of light. Lucigenin beads appear to be active inside these cells where unbound lucigenin does not enter freely.INTRODUCTIONA variety of cells, e.g., neutrophils (Ns) and macrophages (Ms), can engulf foreign particles (1). This engulfing or phagocytic activity is used by the body to kill bacteria and to eliminate foreign particles such as respirable dusts, e.g., coal, silica, or cotton. The neutrophil engulfs or phagocytizes bacteria which are coated with plasma antibodies and/or complement proteins (Fig. 1). The coating or opsonization allows the neutrophil to recognize foreign substances. Usually the absence of opsonization prevents the cell's recognition of a foreign particle and the particle is not phagocytized. Macrophages, particularly the alveolar Oung) cells, do not require opsonization for phagocytosis. Ms should not be selective toward individual dusts because they serve a major role in eliminating a variety of these.Particle size can also be a factor. Usually a particle with a diameter of 0.5-5 µ.m is considered in the respirable range. Larger particles are trapped before they reach the alveoli Oung spaces where oxygen exchange with blood occurs), ·and smaller particles do not generally settle, and are not engulfed by macrophages (2). Tabato and Ikada (3) found that maximal phagocytosis of microspheres takes place when their diameter is in the range of 1.0 to 2.0 µ.m. In addition, they found that beads with hydrophobic surfaces were more readily phagocytized than hydrophilic surfaces."

Jan 1, 1990