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By R. H. Crist

Reactive components of algal cell walls include uronic and alginic acids: In addition, many marine species have half ester sulfate groups which function as fixed anions. Associated metals vary with the media, eg., Ca and Mg in fresh water (FV) and Na, Ca, Mg in seawater. . These metals readily exchange with aqueous phase protons or metal cations. A plot of the total amount of metal cations displaced by protons vs .. pH shows one inflection at pH 4 for FV algae and' in addition a second inflection at pH 2, 3 for marine algae. The first inflection is interpreted as. Indicating the cations associated with carboxyl groups ,and the ,second with half ester ?Sulfate groups. The exchange capacities of various aigal ,species vary widely. When FV algae is placed in a Pb2+ solution,- the amount of Pb2"' deposited on the algae is. Equivalent to the. Total Ca2?, Mg2, and H+ displaced? thereby confirming the ion exchange mechanism. Ion exchange equilibrium constants are reported for the displacement of ca2+ from Vaucheria. With Mg2+, sr2+, Cd2+, Pb2+_ and Na+ as well as the reverse reactions. Cd2+ can .be removed partially from algae by precipitating it as CdS or Cd(OH) 2 Pb2+ and Cu2+ are also partially removed as the hydroxides. Rates of reaction for various alkali hydroxides decrease with increasing .unhydrated cation radius. It is concluded that theory is useful in predicting viable applications for algae in pollution abatement.

Jan 1, 1991

By J. W. Oberholzer

This paper describes research being undertaken by the Chamber of Mines Research Organization (COMRO) which is designed to assist the continuous miner operator and section foreman in the performance of their jobs. The project will initially provide visual assistance to the miner operator, and later will semi-automate the mining (cutting) process. Using a technique known as "RF tagging," the project will also provide real-time or near-real-time information about the performance of the loading and hauling units to the section foreman, allowing him to quickly detect problems and take action where appropriate. The project is based upon the application of currently available technology, and the first phase is scheduled for in-mine testing within the next year.

Jan 1, 1991

By J. C. Cawley

Improvements in today's maintenance practices are mandatory as more complex and productive machines evolve in the mining industry. By keeping machine reliability high, through improved maintenance procedures, overall mining costs can be reduced. The Bureau of Mines is investigating diagnostic maintenance systems for underground mining machinery. A hydraulic expert diagnostic system and an electric motor predictive diagnostic system have been designed and installed on a Joy 16CM continuous miner. An electrical diagnostic system has been designed and installed on a Joy 14CM continuous miner. Each system is functionally described and the relative merits of expert diagnostic systems versus algorithmic diagnostic systems are discussed.

Jan 1, 1991

By Sullivan T. D, Lohe E. M

Geological structure is one of the main controls on ground conditions within mining. It has a significant impact on the mining conditions and productivity of coal mines within the Sydney - Bowen Basin. The three main types of faults common to this region, normal, reverse and strike-slip systems, each present distinct challenges to mining. These systems effect a wide range of geotechnical and mining conditions within the mines. These include coal quality, strata stability, goat and caving behaviour, productivity and maintenance schedules of mining equipment, mine design and mine-site stress fields. A better understanding of the regional, local and mine-scale structural setting, timing relationships of structural events and the mechanisms of fault formation will greatly aid industry's push for greater productivity and competitiveness.

Jan 1, 1991

By K. Meyer, M. E. Goddfellow

"At Teck-Corona Operating Corporation's David Bell Mine, a water quality management strategy is employed to produce both a chemically and biologically clean effluent prior to discharge to the environment.The strategy includes operating methods to minimize contaminants leaving the concentrator and an effluent treatment plant for cyanide, antimony, and heavy metal removal of concentrator, mine and site waste streams.Concentrator practices, the effluent treatment plant, process chemistry and the present day performance of the water quality management strategy are reviewed.INTRODUCTIONThe David Bell Mine is located in the Hernia gold camp 35 km east of Marathon, Ontario. The concentrator has a design throughput of 1,000 tonnes per day. ROM ore (-6"") is ground in a semi-autogenous mill followed by a ball mill, thickener, leaching, and carbon-in-pulp gold recovery unit operations. The concentrator flow sheet is shown in Figure 1."

Jan 1, 1991

By S. A. Rholl

This paper describes the Bureau of Mines experimental test program which evaluated the effectiveness of using high explosives to enhance orebody permeability. To determine the effect of stress on the fracture network generated by blasting, fifteen single-hole laboratory tests in granite blocks up to .067 m3 (2.4 ft3) in size were blasted using .12 to .20m (4.8 to 8.0 in) of 1.6xl0-3-, 3.2xl0-3-, or 6.5xl0-3-kg (25-, 50-, or 100-grain) detonating cord. In situ stresses were simulated using polyaxial load cells to apply uniform stresses of 1.72xl06 to 1.76xl07 Pa (250 to 2550 psi). All of the blocks were sawed to expose the blast-induced fracture patterns for analysis.

Jan 1, 1991

By J. L. Fuller

Mine ventilation surveys were conducted by Technical Support engineers during June 1987 and September 1989 at the Dutch Creek Hine. The mine is located near Redstone, Colorado and is operated by Mid-Continent Resources, Inc. Following completion of the initial survey, several recommended improvements were incorporated into the ventilation system by mine personnel. The second survey permitted documentation of the effects of those changes on the ventilation system performance. This paper describes the processes involved in the implementation of the recommended changes. The substantial improvements in system efficiency and reduced operating costs are also described.

Jan 1, 1991

By J. M. Keane

The Solution Mining review arrived too late to appear in the May issue. Solution mining, in its broadest definition, includes all forms of leaching where a lixiviant solution is brought into contact with a metalliferous or non-metallic ore and the resulting pregnant solution is processed for recovery of the valuable soluble material. Technologies such as dump leaching, heap leaching, stope washing and in situ lixiviant solution injection and recovery fit into this definition of solution mining. A publication entitled the US Gold Industry (Dobra and Thomas) reflects the major impact that solution mining techniques have had on precious metal recovery. In 1989 (the last year for which statistics are available), the United States passed Australia to become the third largest gold producing country in the world after South Africa and the Soviet Union. It is estimated that when the final figures are in for 1990, the US will probably pass the Soviet Union in gold output. If the state of Nevada is ranked as a separate country, it will rank fourth in the world in gold production for 1990. A good proportion of this increase in gold production over the past few years can be attributed to the application of solution mining technology to low-grade, precious-metal-bearing material. Solution mining techniques have also made inroads in copper production. Many operations located at former underground mine sites employ in situ leaching as an adjunct to conventional dump and heap leaching practices.

Jan 1, 1991

By Richard D. Hagni

The mineralogy of dusts from the lead sinter and lead blast furnace at the Doe Run Smelter at Herculaneum, Missouri is being studied by reflected light microscopy and scanning electron microscope-energy dispersive spectroscopic analysis (SEM-EDS). Oust from the sinter plant consi5ts of abundant slag and galena particles, and lesser amounts of coke, sinter, and chalcopyrite particles. In contrast, dust from the blast furnace consist of abundant coke and sinter particles, and lesser amounts of slag, galena, chalcopyrite, metallic lead and lead-copper particles. The particles in dusts from remote sampling sites !-l mile from the sinter plant and blast furnace are fine-grained and composed principally of calcium-aluminum silicates that are locally derived, but some of the larger particles consist of sinter, slag, galena, and other minerals. Additional dust samples from the plant and remote sites are currently being studied.

Jan 1, 1991

By G. Bloomsburg, R. E. Williams, S. D. Vincent

A modeling scheme is developed to simulate the hydrogeologic effects of mine design and development in unsaturated rock. Simulations are conducted using the UNSAT2 finite element computer program and hydrogeologic data from the site of a proposed mined-out waste repository at Yucca Mountain, NV. Results of the simulations are analyzed for: •variations in the direction of ground water flow and in the distribution of pressure head caused by the design of the mined out openings; and •mine design variables that affect the predicted rates of mine water inflow. Evaluating the hydrogeologic impacts of mine design and mine development in unsaturated rock is significant in several respects. Characterization of the preemplacement of wastes along the fastest path ground water flow system at the Yucca Mountain site has been a primary research effort. Ultimately, however, the degree to which waste isolation is achieved will depend largely on the post-mining hydrogeologic environment as altered by the mine design and on the radionuclide inventory and resulting heat effects of the repository. Therefore, an ongoing characterization of the proposed mined-out nuclear waste repository at Yucca Mountain, NV, is recommended. Modeling results indicate that: •mined out openings will affect the movement of ground water, both in rate and direction; •hydraulic effects of mine development depend on the hydrogeologic environment and on mine design geometry; •mine water inflow is possible in the unsaturated zone, even for mines developed in hydrogeologically homogeneous rocks; and •mine water inflow can occur at values of down ward flux that are appreciably less than the saturated hydraulic conductivity of the overlying rocks.

Jan 1, 1991

By Michael W. Neill, O&apos

Drilling slurry has become an effective aid to the construction of drilled shafts in caving and/or waterbearing soils. Historically, drilling slurry made of bentonitic clay and water was first used in the US in water well drilling as early as 1889. In coastal Texas drilled shaft contractors began using slurry, often made of on-site clay mixed with potable water, in the years following World War II, on a relatively routine basis. This type of slurry was used to "process" boreholes, in which the borehole was drilled "in the dry" until water or unstable soil was encountered, after which water and on-site clay were introduced into the borehole and mixed in place with the auger or other drilling tool. Drilling then continued under a slurry consisting of the uncontrolled mixture of clay and water until the excavation had reached a relatively impermeable and cohesive material. At this point, a steel casing was dropped into the hole and sealed into the lower stratum of impermeable geomaterial (soil or rock). The slurry inside the casing was bailed or pumped out, drilling continued to plan depth in the dry, a reinforcing cage was set in the partially cased borehole, concrete was placed and the casing was withdrawn. Some soil-slurry was undoubtedly trapped between the casing and the borehole wall, but the quality of that slurry was usually of no concern, because engineers of the period usually viewed drilled shafts as nothing more than deeply buried footings. Any unejected slurry would only serve to lower side shearing resistance, not yet considered in design, but would have no effect on end bearing. In the 1960 's the effectiveness of soil-slurry came into question because it was often ineffective in maintaining borehole stability at marginal drilling sites and because the economy of using shaft resistance, in addition to end

Jan 1, 1991

By David S. Holmes

An overview of existing biological technologies for the recovery of copper and uranium is presented. Engineering and biological challenges and opportunities in these areas. are discussed. New opportunities for the biooxidation of refractory gold ore are described. Techniques for the development of new strains of microorganisms. for commercial metal recovery applications are discussed with special reference to the genetic manipulation for bacterial strain improvement.

Jan 1, 1991

By D. E. Larson

In cooperation with the National Institute of Environmental Health Science and the National Institute for Occupational Safety and Health the U.S. Bureau of Mines conducted grinding research on non-asbestiform tremolite. The goal of this effort was to prepare ground tremolite samples containing a considerable percentage of acicular grains with aspect ratios (approximately = 8um long with widths = 1 um) similar to those of asbestos particles suspected of causing cancer, Optical-and electron-microscopic examinations were used to monitor the size and shape of the grains in the ground products. Although customized milling techniques do have noticeable effects in producing acicular grains, the prismatic nature of fracturing in the non-asbestiform tremolites limited the number of acicular grains that could be purposely produced, and indicates that the likelihood of high concentrations of acicular particles occurring under normal mining and milling conditions is small.

Jan 1, 1991

By Robert C. Dyni

This report details the investigation of multiple-seam longwall subsidence conducted by the U.S. Bureau of Mines from 1978 to 1989. A field investigation monitored ground surface movements over four upper-seam longwall panels and six lower-seam panels. The characteristics of the subsidence occurring as a result of mining these panels are examined; in particular, the angle of draw, subsidence development, total magnitude and areal extent, and critical width are evaluated and discussed. Comparisons are also made between the characteristics of multiple-seam longwall subsidence and single-seam longwall subsidence that occurred at the same site.

Jan 1, 1991

By H. G. Stephenson

Canada and the United states are both developed countries with economies which are extremely dependant on oil. Canada exports 37% of its production (to the United states) and imports 35% of its consumption (mainly into Eastern Canada), making the country self-sufficient in oil. Canada is attempting to increase its oil production so as to simultaneously reduce its dependence on foreign oil while producing more oil for export. The United states -imports no less than 50% of its total consumption of 17 million barrels/day. Canada's exports to the United states form only 7% of the United States total imports. The United States would clearly prefer to achieve self-sufficiency in oil. Consequently both countries are dependent on foreign oil. The united States is however in the sensitive situation of depending, for its imports, on countries which are susceptible to destabilizing political events. It is the author's hypothesis that recent developments in underground oil recovery from the Athabasca oil Sands of Alberta may well, for both countries, form part of the solution to these problems.

Jan 1, 1991

By James E. Fisher, Roger Cotton

"The legal background f or environmental issues, and the growing emphasis both from government and private concerns of corporate and management liability for environmental problems provides one of the driving forces behind the growing concern with environmental law for the future. One prime objective must be the identification and minimization of potential liability, both for the corporation and its officers, directors and employees.This paper will identify the basis for liability of individuals and corporations for environmental matters, focussing on current legal requirements, and the appropriate legal response to events of such potential liability. It will also consider the reduction of liability through the implementation of management systems and environmental policies in order to ensure due diligence both with respect to corporate responsibility and the responsibility of the individuals within the corporation.IntroductionConsolidated Professor Mines Ltd . and its predecessor have been exploring in northwestern Ontario for about sixty years . During the last twenty years, the company has been interested in developing a gold mine, the Duport Project, on Stevens Island in Shoal Lake . The lake straddles the border between Ontario and Manitoba and is a drinking water supply for Winnipeg and environs.The Duport Project involves the mining of 450 t/day grading an average of 0.35 oz Ault of ore . At the minesite, located on Steven s Island in Shoal Lake, only preliminary processing of the ore will take place, to produce gravity and flotation concentrates for final gold recover y at a mainland plant well removed from the Shoal Lake watershed. No hazardous chemicals will be used at the island site."

Jan 1, 1991

By Aureo D. V. Machado

An experimental study to obtain zirconia powders (ZrOz) from carboxylate zirconium solutions followed by hydrogen peroxide stripping and precipitation, has been carried out. Zirconium carboxylate was prepared by solvent extraction from a chloride aqueous phase using magnesium carboxylate as organic phase. The variables examined in the precipitation reaction were: Temperature: 25 - 90 ?C ? H202= concentration: 0.3 - 5% wt/wt - pH: 1 ? 9 Organic/Aqueous ratio (1/1) and reaction time (30 minutes) were maintained at constant levels. The optimum results (98% precipitation) were achieved at 25 °C, 5 % wt/wt H202=, and pH = 5. The precipitates were composed of large amorphous aggregates (<I00 micrometers). After calcination for 1 hour at 1000 OC, monoclinic ZrO2 with a large variation in particle size (1 -100 micrometers) was obtained.

Jan 1, 1991

By R. C. Bryan, D. B. Jamison

This paper describes a procedure for minimizing the operational costs associated with blending sodium in coal at a surface mine in the Powder River Basin. Mine site blending is performed by adjusting daily production rates for high- and low-sodium pits. These adjustments are designed to produce a consistent sodium value called the blending target. The mine&apos;s contractual limit for sodium is sufficiently close to the field average value that any decrease in the sodium blending target may result in an opportunity cost, if the number of potentially minable tons is reduced. Conversely, any increase in the blending target may result in a higher sampling cost if more information is required to keep the blend within contractual limits. Blending parameters were defined using a geostatistical block model of sodium content that was based on analyses of hundreds of in-pit sample holes. Variograms for these data were used to compute the marginal costs of opportunity and sampling for a series of hypothetical in-pit drilling patterns. These marginal costs provided a basis for selecting optimum values for key parameters such as the blending target, production variance and in-pit sampling density. The benefit of implementing these optimized parameter values is that operational costs of sodium blending will be minimized over the long-term. At the mine where this procedure was developed, each dollar spent to increase the sampling density to the optimum value was shown to generate a $10 savings in opportunity cost.

Jan 1, 1991

Cordeaux Colliery is more logically sited than the historic escarpment Corrimal Colliery, on the same reserve. At Cordeaux the modernisation of mine plans and equipment and the introduction of high production longwalls have created a record achieving producer of both steelmaking and export coals.Further changes achieved have been in employee related attitudes and performance, enhanced by business strategies and total quality control and particularly benefiting from innovative employee input With this present example of co-operative effort Cordeaux Colliery will continue to improve through management of total quality. resources, development rates and customer satisfaction.

Jan 1, 1991

By J. G. Groppo, B. K. Parekh

A series of performance studies were conducted using countercurrent column flotation to recover a marketable clean coal product from existing preparation plant fine waste streams. The test work was conducted at several preparation plant sites in Kentucky and Virginia using a 150-mm (6-in.) inside diameter column that was 5.8 m (19 ft) high. Both thickener feed and classifying cyclone overflow with a typical size distribution of 150 µm (100 mesh) X 0 were tested. The percent solids of the column flotation feed varied from 1.5% to 15% while the ash content ranged from about 30% to 60%. The concentrates produced contained 2% to 10% ash with Btu recoveries of nearly 90% using 0.12 to 1.25 kg/t (0.25 to 2.5 lbs per st) fuel oil and 0.12 kg/t (0.25 lbs per st) MIBC. These results were consistent with or better than results obtained in preliminary laboratory scale column flotation evaluation. Test results from seven different seams are discussed as well as scale-up relationships used to design a full-scale installation presently in operation.

Jan 1, 1991