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By R. F. Hammen

Copper is one of the most widely used metals in industrial processes and is also present in most mining operations. Extraction of copper from solutions often proves difficult due to the presence of complexing agents. ChromatoChem, Inc. has developed a Solid Phase Extraction (SPE) support (HiPAC) for removal and recovery of metals from wastewater. The HiPAC SPE support employs chelating agents covalently coupled to a long linker molecule. Several solutions containing copper and complexing agents were tested including 1) copper and carbonate, pH 9.8, 2) mixed metals and anions with copper and cyanide, pH 11, and 3) copper and the chelating agent EDTA, pH 11. The copper was extracted from solutions one and two at high pH, but the EDTA containing solution needed the pH lowered to make the copper available for capture. In each example, the copper concentration was significantly reduced by HiPAC SPE treatment.

Jan 1, 1994

By V. A. Shea-Albin

Sandstone escarpments surrounding western coal-bearing plateaus serve as critical habitat for animal species. Effects of mining subsidence on escarpment stability are not well documented; therefore, regulatory agencies may limit extraction of coal reserves underlying escarpments. Because millions of tons of this coal exist on Federal Lands, associated public revenues from Federal royalties, and valuable coal reserves, risk being lost. The U. S. Bureau of Mines is using numerical modeling techniques to analyze effects of subsidence on escarpment stability. Finite element models that incorporate bedding plane slip, gob formation, and movement along joints simulate escarpment subsidence observed in the field.

Jan 1, 1994

By David K. Ingram

The objective of this U.S. Bureau of Mines (USBM) investigation was to characterize overburden response due to longwall mining. Subsurface strata and surface deformations were monitored at two sites in southeastern Ohio. Site A included two adjacent longwall panels. Site B consisted of one longwall panel. Both sites had similar mine geometries and overburden thicknesses. The major difference between the two sites was the rock strata within the overburden. Multipoint borehole extensometers (MPBX) were employed to measure subsurface displacements. Survey monuments were installed above the centerline and profile of each panel to measure surface deformations. Subsidence of the surface was observed before and after movement was detected in the MPBX units. Initial and final displacement of the MPBX units occurred at the same time at both sites. No deformation was detected outside the panel area. The development of overburden deformation was different over each panel. The final subsurface failure characteristics also varied between panels.

Jan 1, 1994

By Pesic. Batric

A novel chitosan-pyridoxal-epichlorohydrin was synthesized and evaluated in our laboratories. The evaluation was achieved by performing kinetic and equilibrium studies of copper sorption. The parameters examined were pH, temperature, concentration of copper, particle size and selectivity of copper sorption against iron, zinc, cadmium and cobalt. It was found that pH was the most important parameter, and sorption of copper increased with pH increase in the range pH 2.5-6.0. The low activation energy of the sorption reaction, 1 1.13 kJ/mole (2.66 Kcal/mole), showed that temperature was not an important parameter. The synthesized chitosan was selective against iron, zinc, cadmium and cobalt. The selectivity with respect to last three metals was achieved by the kinetic difference of sorption, as sorption of copper was much faster than for other metals. Iron (Fe2+) does not adsorb on chitosan. The mechanism governing the sorption of copper is intraparticle diffusion. This finding was supported by the dependance of copper sorption on the square root of time, the low activation energy, and the fit of experimental data in the diffusion through the product layer equation.

Jan 1, 1994

By H. J. Brown

Pluess-Staufer (California) Inc. Lucerne Valley California operation is one of the largest producers of high brightness high purity fme grind limestone products in western North America. The San Bernardino Mountains area of southern California contains the largest high brightness, high purity limestone mining operations and undeveloped reserves in western North America (Fig. 1, Brown 1987). Combined annual production of high brightness limestone products from several operations is approximately 1.5 million tons, with an estimated gross value of $75 million dollars per year (Fig. 2). An additional 5.0 million tons of cement grade limestone is mined by several large cement producers in the nearby Mojave area (Brown, in press). The purpose of this paper is to summarize the geologic setting, genesis and mining of white, high purity crystalline limestone by Pluess-Staufer (California) Inc.

Jan 1, 1994

By John J. Mazza

Treatability studies were performed to determine the effectiveness of two commercially available treatment methods (solvent extraction and thermal desorption) for the removal of PCBs and PAHs from contaminated dredged riverbed sediments. The solvent extraction method evaluated was the B.E.S.T. process which extracts the contaminants with triethylamine. The thermal desorption method utilized was the ATP process which desorbs the contaminants at elevated temperature in an anaerobic atmosphere. A description of both methods and. an evaluation of the treatability study results is provided. Each treatment method was used to treat two separate samples (high and low concentration) from the site. Overall, both methods proved to be very effective with solvent extraction achieving 98% removal of both PCBs and PAHs and thermal desorption achieving better than 99% removal of both the PCBs and PAHs from the high concentration sample. Both solvent extraction and thermal desorption achieved greater than 99% removals of PCBs and PAHs from the low concentration sample. Vendor cost estimates for full scale treatment were roughly equivalent. The primary differences between the two methods lies in the realm of permitting, operational requirements, and emission concerns.

Jan 1, 1994

By A. Fawceit, B. C. Dyer

"The basis of the tomographic velocity imaging technique is briefly described and an application of the method to detect and image a cross-section through a chromite pod is presented. Using the chromite application as an example, the relative costs of tomographic data acquisition and processing are compared with those of diamond drilling to obtain similar resolution. A number of different tomographic survey configurations and the potential role of the method in surface and underground exploration are discussed.IntroductionThe technique of seismic tomography has been most widely applied in oil industry exploration, nuclear waste disposal, civil engineering site investigations and in the assessment of the condition of mass concrete structures. Although model studies had indicated that tomography would be a useful tool in mineral exploration, relatively few applications have been reported.Essentially the method relies on the determination of the speed with which sound travels through a region within a cross-section of the earth or large body. The speed of sound is determined by the physical characteristics of the medium through which it is passing. In geophysics the speed of sound is generally referred to as the seismic velocity. Due to variations in the formations of different rocks the seismic velocity will vary and so can be used to map geological boundaries"

Jan 1, 1994

Industry and regulatory agencies have requested guidance on safe blasting near transmission pipelines. The U.S. Bureau of Mines and AMAX Coal Company have studied surface coal mine overburden blasting near four steel and one PVC pipe-line of 15 to 5l-cm diameter, monitoring vibration, strain, and pressure. Unlike tests simulating construction blasting, these were up to 1000 kg per delay in 3l-cm blastholes. Worst case comparisons showed that 12.7 cm/s blasting vibrations produced strains about 1/4 that of pressurization and 10-18 pct of the ultimate tensile strength. No failures occurred from blasting as close as 15 m which produced vibrations over 60 cm/s.

Jan 1, 1994

By J. W. Hawley, G. S. Austin, L. A. Brandvold, J. Renault

Soil next to a smelter abandoned about 100 years ago near Socorro, NM was found, by the US Environmental Protection Agency (EPA), to contain high Pb concentrations. Detailed characterization of the soil by the New Mexico Bureau of Mines and Mineral Resources (Bureau) shows that the highest Pb concentration is in the clay-size fraction, although this fraction accounts for only 1 to 3 wt % of the soil. The depth of contamination, determined in areas relatively undisturbed since the smelter was abandoned, is no more than 76 mm (3 in.). Because of the soil's alkalinity, the Pb mobility is dominated by the movement of Pb-bearing particles, as opposed to chemical transport in solution.

Jan 1, 1994

By J Lyall Workman, Peter N. Calder

Flyrock can be a serious hazard associated with blasting. Many surface blasting accidents involving injury result from excessive flyrock beyond the protected blast zone. Numerous cases of equipment damage at the mine, quarry or construction site have resulted from flyrock. Fragments propelled beyond the property limits of the operation have also caused injury and damage.

Jan 1, 1994

By Morris J. Viljoen, David R. Young

"The zone of economic interest at H.J. Joel Gold Mine is the VS5/Beatrix Composite Reef, a quartz-pebble conglomerate of Archean age. The reef occurs at the base of the Eldorado Formation, Central Rand Group, of the Witwatersrand Supergroup. At least three stratigraphically distinct conglomerates form this economic zone. In order of deposition these are the Footwall, Beatrix, and the VS5/Beatrix reefs. The Footwall and Beatrix reefs are equated with the Aandenk Formation with transport directions toward the northwest, whereas the VS5lBeatrix Reef is of Eldorado age, with transport directions toward the south. The change in the drainage direction was caused by a major basin-wide tectonic event that occurred prior to the deposition of the Eldorado Formation. The Beatrix Reef was formed in a proximal, braided, fluvial environment by a process of aggrading gravel bars between channelways. The VS5/Beatrix Reef was formed by the desegregation of pre-existing Beatrix Reef with the introduction of new material containing much shale detritus and is seen to have been deposited in a more -distal, braided, fluvial environment, similar to the Beatrix Reef.The average gold concentrations are different for each conglomerate; the Beatrix at 32.1 ppm Au, the Footwall at 24.4 ppm Au, and the VS5/Beatrix at only 12.4 ppm Au. A sedimentary gold concentrating process related to higher energy braid channels was primarily responsible for these high gold grades. Not only the basal unconformity surface, but also, internal degredation surfaces, were prime sites for concentration. An understanding of the spatial distribution of these differing conglomerates and their braid channels forming the economic reef zone is necessary in predicting ore grades for future mining."

Jan 1, 1994

By Dean H. Herrick

The production of crushed stone in the United States has exceeded 1.0 Gtpy since 1987. Eighty percent of the crushed stone produced is used in the aggregate industry, accounting for over half of the quantity of natural aggregate consumed in the United States. Approximately 718 of the crushed stone produced in 1989 was limestone and dolomite followed by granite, traprock, sandstone and quartzite, miscellaneous stone, marble, shell, calcareous marl, volcanic cinder and scoria, and slate in order of descending volume (Table 1). Of the remaining 20% crushed stone produced in the United States and not used as aggregate, 12% is used in the manufacture of cement which is an important construction material. Only 8% of crushed stone is used in specialty products not associated with the construction industry. Therefore, this chapter will concentrate on crushed stone as used in aggregates, with occasional reference to other uses or to chapters which discuss specific nonconstruction uses of crushed stone. Construction aggregates are hard, essentially inert materials suitable for being formed into a stable mass by the addition of cementing or binding materials that produce a concrete by compaction, or by natural weight to produce a road or foundation fill. Aggregates are usually from 80 to 100% of the material volume of the construction masses in which they are used. Conditions necessary for a rock deposit to be developed for construction crushed stone include: Quality-should pass rigid specifications for strength and durability; Quantity-adequate volume of rock is needed to have a production life of at least 10 years, preferably 20 or more years; Market-must have adequate market to support a new crushed stone operation; Transportation-transportation cost must be competitive for the intended market; Environmental-the impacts of mining, processing and transportation of crushed stone on the environment at or surrounding the mine site must be within acceptable limits; Permitability-mining, processing and transportation of crushed stone must usually be permitted by governing agency. The following discussion will touch upon all facets of crushed stone operations from the mineral deposit and its geology to technology, uses, economic factors and end with governmental regulations of mining crushed stone. The sections are not designed to answer all questions, but rather to be an introduction to the crushed stone industry. Where more information is required, The Aggregate Handbook by Barksdale (1991) is recommended as the best general source.

Jan 1, 1994

By D. J. Bowen

"Abstract -The Great Dyke extends for 540 km along strike, to unknown depth, and varies in width from 3 km to 11 km. Rb/Sr age determinations gives values of approximately 2470 Ma.The Dyke consists of a variety of mafic and ultramafic rocks, many altered to serpentinites. These include, from top to bottom, successions of gabbro/norites, pyroxenites, peridotites/harzburgites, and dunites/picrites.The layers dip in from either margin, steepest at the edges (20°) and flattening toward the central sections. Four separate complexes are present. From north to south these are termed the Musengezi, Hartley, Selukwe and Wedza Complexes, and are described as 'boat-shaped' or 'pig-troughed'. All are similar in petrological sequences. Physiographically, the Dyke is spectacular in the north, where as a mountain range it meets the Zambezi Escarpment. Elsewhere in the central parts there is little surface expression and wide open treeless vleis. Dyke rocks cut through granite and schist belt terrain and are termed 'The Magnesia Belt'.Vast mineral resources exist. These include chrome, asbestos, platinoids, nickel, copper and gold. Up to eleven chrome seams numbered from top to bottom occur in the lower ultramafic sequences. Seams are narrow at 10 cm to 30 cm but of high grade. The platinum occurs 10 m to 40 m below the norite/pyroxenite contact.A 60 m wide zone of Light Sulfide Mineralization (LSM) of Jess than 1% sulfides extends from the lower gabbronorites into the upper pyroxenites. In this LSM, four enriched zones carry up to 5% sulfides. The most widespread is termed the Main Sulfide Zone (MSZ), below which is No. 2, No. 3 and No. 4 Sulfide Zones. The MSZ carrying pyrite, pyrrhotite and chalcopyrite is a multi­ element ore with components of PGE (Pt-Pd-Rh), nickel, copper and cobalt, and gold and silver.Extensive exploration programs have been carried out and the intention is to begin large-scale mining. However, with Russia supplying metals to the western markets, South Africa's cutback on production, and an end to the Cold War, delays have arisen."

Jan 1, 1994

By Y. Héroux, A. Chagnon, M. M. Savard

"Résumé- Le gîte de Pb-Zn de Gays River s'accompagne d'anomalies des propriétés de la matière organique (MO) et des assemblages de minéraux d'argile (AMA). L'association entre la minéralisation, la distribution de la réflectance de la MO et des AMA suggère que ces traceurs peuvent servir à l'exploration des sulfures de métaux de base dans cette région.A l'emplacement du gîte, la réflectance varie considérablement (0,80% à 1,88%), pouvant même afficher une baisse avec l'enfouissement, ce qui est interprété comme une altération chimique de la MO. Les valeurs les plus élevées s'accompagnent localement de quelques textures en mosaïque et délimitent une anomalie thermique au centre sud de la région. Parmi les minéraux des argiles identifiés, l'illite et la chlorite sont terrigènes alors que la smectite, la kaolinite et la corrensite sont authigènes et, à l'instar de l'altération de la MO, résultent des nouveaux équilibres chimiques créés suite à la précipitation des sulfures.Abstract- The Gays River Pb-Zn ore deposit is associated with anomalies defined from the characters of the organic matter (OM) and from the clay minerals assemblages. The relationships be­ tween these anomalies and the mineralization at the mine suggest that these parameters can be used as new guides for the exploration for base-metal sulfides in this area.The vitrinite reflectance (RJ shows a wide range of values (0.8% to 1.88%) and exhibits an anomalous suppressive effect with depth of burial at the mine site, suggesting a chemical alteration of the OM. The highest R, values are associated with mosaic textures and outline a thermal anomaly at the south-center of the studied area. Among the identified clay minerals, illite and chlorite are terrigenous, whereas smectite, kaolinite and corrensite are authigenous and, like the alteration of the OM, are due to the new chemical equilibria resulting from the precipitation of the sulfides."

Jan 1, 1994

By Rahul Bhaduri

Mercury levels in Twin Creeks Vista pit ore (previously Chimney Creek, North pit ore) increased substantially since plant start-up in November 1987. Consequently, modifications were necessary to minimize industrial hygiene hazards and potential operational problems. The original plant design included mercury control measures. With progressive increases in mercury levels, the issue had to be re-addressed. Modifications to operational practice, industrial hygiene and management philosophy will be discussed. Additionally, a detailed examination of the mercury vapor suppression system currently employed at Twin Creeks will be presented.

Jan 1, 1994

By Alastair Torrance, George Boucher

The authors were involved in the Trial Blast work at Chek Lap Kok, the site of the new Hong Kong Airport. As part of that work a series of computer programs including 3x30, QFRAG, DESIGNER and 3DMUCK was employed to predict various aspects of the trial blast programme. These aspects included fragmentation and muckpiie shape. This provided an excellent opportunity for these programs to be calibrated, verified and compared under controlled conditions. The results indicated that computer simulation has reached a high level of sophistication and good correlation between prediction and measured results was found.

Jan 1, 1994

By Richard R. Klimpel, Simon Isherwood

"The industrial processing of ores containing gold and/or platinum minerals is generally mining site specific, e.g. McQuiston and Shoemaker (1985). The variety of various mineral processing techniques employed is extensive and includes size classification, gravity concentration, amalgamation, roasting, cyanidation, chemical leaching, ion ex-change/solvent extraction and froth flotation. Because of the relatively small quantities of Au and Pt that exist in the earth’ s crust, the economical recovery of Pt and Au often requires that the Au and Pt be associated with other industrially important minerals. This association of Au and Pt with other minerals can occur in very complicated mineralogical forms. It is probably safe to say that Au and Pt mineral concentration from natural ores represents some of the most complex metallurgical challenges facing the mining industry.Froth flotation is a technique that is receiving increasing industrial attention for the treatment of finely disseminated and/or associated Au and Pt minerals. The high throughput at relatively low capital cost, the potentially high selectivity, and the existence of a well-established technology for treating more abundant associated minerals such as base metal sulfides makes froth flotation an attractive processing alternative. Broadly speaking, the industrial oriented froth flotation experience with Au and Pt minerals exists in two major categories: 1) the flotation of Au and Pt associated with pyrite (or pyrrhotite) and 2) the flotation of Au and Pt associated with primarily Cu, Zn, or Cu/Pb/Zn containing sulfide ores.In the case of the precious metal association with pyrite (or pyrrhotite), much of the published froth flotation experience comes from South Africa. Typically, such processes are done using an acid side flotation with a collector such as mercaptobenzothiazole. The approach obviously is to float pyrite and hence recover associated gold. Generally the higher the total sulfur recovery the higher the gold recovery. Similar experiences of Pt associated with pyrite are a lot less common mineralogically and hence less well documented industrially. For example, in Canada, Pt is often associated with pyrrhotite but is not really processed as a straight pyrrhotite recovery.For the situation of Au and/or Pt associated with other base metal sulfide minerals, the industrial experience base is quite varied and is well documented from both North and South American operations. The nature of most of these flotation processes is to design, operate, and optimize the installed concentrator to get the Cu, Pb, Zn, Ni, etc. that is the bulk of the valuable sulfide ore and then take whatever precious metal recovery comes. Typically, such flotations are on the basic side using standard thiol collectors such as xanthates, dithiophosphates, thionocarbamates, etc. It is very common with such ores to use mixtures of collectors in order to get ""everything"". Often in such plants, there is an inherent balancing act occuring so as to operate in such a manner to reject pyrite (and pyrrhotite) in order to maintain high base metal mineral concentrate grades and yet recover sufficient precious metals such as Au and Pt minerals which often are associated with the iron sulfides being rejected. Obviously in such an environment, the smelter operation often ends up telling the concentrator what the precious metal recovery actually was in a given production period."

Jan 1, 1994

By Derek Ellis

Volume II of this two-part series on Submarine Tailings Disposal (STD) as a tailings management option for coastal and island mines contains descriptions of lesser known case histories. The Misima gold mine (Papua New Guinea) and the Black Angel lead-zinc mine (Greenland) are described in some detail as the best documented cases. Atlas copper mine (The Philippines) is less fully described due to relative lack of documentation. The Misima and Atlas STD systems are working to their design criteria. At Black Angel the system adopted did not prevent contamination for a number of reasons, which are now understood. Two cases are described where STD is being developed. They are the Cayeli Bakir copper mine Turkey), and the Toquepala and Cuajone mines (Peru). There is excellent documentation available for both cases. Three case histories are described where tailings have reached the sea either through beach or river discharge. In one case the STD option has been explored (Marcopper Mine, The Philippines). In the others we explore in hindsight whether STD might have been a viable alternative using the Screening Criteria that this Volume develops - see below. The mines are Bougainville Copper Mine in Papua New Guinea, and Jordan River Mine (Canada). There is potential for STD at all three sites. Finally, the Volume presents Screening Criteria for appraising STD, based on the experience in design, operation and environmental impact reviewed in the case histories.

Jan 1, 1994

By Erik Sherer

Indonesia is poised to become a major player in the Pacific Rim thermal coal markets. Although the colonial Dutch developed numerous coal mines in the late 1800's for steamship bunkers and domestic fuel, Indonesia's coal industry has only recently begun to actively participate in the growing global marketplace. This export coal is primarily the result of the commercial development of coal mines in eastern Kalimantan by foreign contractors. From virtually no coal exports in the late 1980?s, Indonesia's coal industry has increased its exports to approximately 15 million metric tons (Mmt) in 1992. In 1992, Indonesia was the world?s sixth largest exporter of steam coal, By the year 2000, Indonesia projects that it will supply approximately 25 percent of the seaborne thermal coal requirements of the Pacific Rim countries. Although limited quantities of this coal may enter the European and U.S. markets, high qualities, low production casts, and favorable transportation rates will make Indonesian coals very competitive in the rapidly growing Pacific Rim markets. This study examines the Indonesian coal mining industry and compares it to the U.S. coal mining industry. This report is the sixth in a series of coal exporting country studies requested by the House Appropriations Committee. Previous studies examined the Colombian, Canadian, Australian, South African, Polish, and Venezuelan coal industries.

Jan 1, 1994

By Edward Kline

A review and synthesis of literature pertaining to biological consequences of submarine mine-tailings disposal (STD) was conducted. STD can result in massive sea floor sediment deposition. STD may also increase suspended sediment, trace metals, and residual milling reagents in receiving waters. These perturbations, which are highly site dependent, invariably smother benthic organisms, and could potentially affect or alter fish, plankton, and benthos through acute and chronic toxicity, bioaccumulation, behavioral changes, smothering, derived secondary effects, and habitat alteration. Much of the available information concerning STD is unpublished and limited to a restricted number of sites. From this information and related research, it appears that benthic smothering is the only major consequence of a properly designed STD system. There have been cases of metal bioaccumulation due to inadequate preliminary evaluation, Also, shallow water habitat alteration has resulted from STD. Reductions in biological production are likely due to benthic smothering. The rate of ecological recovery after termination of an STD operation varies and is difficult to assess, The consequences of STD are site specific. Additional research is needed concerning possible consequences of milling reagents and the broad implications of benthic smothering. Also, methodologies are needed to allow better prediction of benthic recolonization and ecological implications of metal bioaccumulation.

Jan 1, 1994