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By D. Zhao

High temperature deformation characteristics of austenitic 304L, and martensitic 410 and 416 stainless steels were investigated by conducting compression tests over a wide range of temperatures and strain rates (950-1250 C and 0.001-20 s-1). Flow behaviors of the three alloys were characterized. Optical metallography was performed to determine the as-deformed microstructures. The flow behaviors were related to microstructural phenomena during high temperature deformation. Dynamic recrystallization was responsible for the flow softening. Both dynamic and static recrystallization were operating, and the recrystallized grain size increased with increasing temperature and decreasing strain rate. Strain rate sensitivity was found to increased with increasing temperature and decreasing strain rate. No defects such as cracking and shear bands were observed at those test conditions. Preferred processing conditions can be selected by considering as-deformed microstructure and strain rate sensitivity.

Jan 1, 1994

This United States Bureau of Mines study is based on a review of U.S. mine fire accidents that occurred from 1970 through 1989. Information on these accidents was obtained through investigative reports written by Mine Safety and Health Administration personnel. For this study, 260 mine fire accident reports were examined. A previous Bureau research effort established that fires causing fatalities were more likely to occur in haulage entries than at any other underground location. This study has found that the most prolific source of haulage entry fires was the inadvertent grounding of trolley wires. The largest segment (15 out of 40 trolley wire fires) resulted from not maintaining adequate clearance between the trolley wire and the vehicle. Several novel fire prevention and control ideas have evolved in response to frequently occurring fire-related problems. These included; discriminating power isolation devices, wire cutting devices, more accessible fire extinguishers, vehicle overcurrent protection, and vehicle fire suppression.

Jan 1, 1994

By Brian Lightfoot

Ausmelt technology is a versatile bath smelting technology with application in many waste treatment fields at low capital and operating cost. Heavy metals extracted from wastes may be recycled to mainstream use and the slags produced will be inert and suitable for use as aggregate, shotblasting grit or other applications.

Jan 1, 1994

By L. L. M. Kadnuck

The U. S. Bureau of Mines studied the suitability of using flexible tendon cable supports as secondary roof supports at a western coal mine. The supports were installed in longwall tailgate entries and grouted into the mine roof. This paper quantifies how the use of cable supports can improve ventilation in underground airways. A mine ventilation simulator was used to model the changes in airway resistance and airflow and show potential for further ventilation improvements when cable supports are used. Model results indicated that cable support use translated to savings in air pressure around the longwall panel and increased airflow at the longwall face.

Jan 1, 1994

By M. Springett

Organization of teams for rapid and effective evaluation of international mining properties requires special considerations beyond those needed for domestic activities. Experience, technical ability, a sense of perspective, humor and self-discipline are vital characteristics to look for in the selection of individuals for forming an efficient and productive team.

Jan 1, 1994

By Anil Kumar

In underground mine production units that employ discrete-vehicle face haulage, feeders are used in the belt network so that vehicles can unload rapidly without transmitting to the conveyor network the high material flow rates that result from rapid unloading. They prevent production bottlenecks at the face, while reducing capacity requirements for downstream materials handling equipment. Similarly, surge bins may be installed at intermediate locations in the network to smooth flows from a number of upstream sources, thereby reducing downstream belt capacity requirements. This paper introduces new stochastic process models to temporally describe loading patterns from unit operations and techniques for computing the probability of various fill levels for the feeder or surge bin. These results may be used to analyze the effect of alternative bin or feeder capacities and discharge rates on the performance and costs of the materials handling system.

Jan 1, 1994

By G. L. Palmer

"In 1986, anomalous sampling results for heavy minerals were obtained at various sites in Namaqualand on the west coast of the Cape Province. Drilling in 1987 at Graauwduinen penetrated up to 35 meters of heavy mineral-bearing Tertiary sands which extend several kilometers inland from the coast. The heavy mineral suite includes ilmenite, rutile, leucoxene, zircon and monazite, along with gamet, pyroxene and amphibole. Three deposits are recognized, two of which comprise the resource to be mined by Namakwa Sands Limited, a recently formed Anglo American Corporation subsidiary company.Mineable reserves in excess of 500 million tonnes have been delineated, sufficient to sustain mining for over 35 years at projected production rates. During the feasibility study, on-site investigations included test mining at various sites to assess rnineability and to provide material for metallurgical testing in a pilot plant located at the site. llmenite produced at the mine will be smelted at a new facility to be built at Saldanha Bay. Saleable products comprise titania-rich slag, pig iron, zircon and rutile.During the exploration phase, company environmental guidelines were established and monitored. The feasibility study incorporated a Class 1 Environmental Impact Report, the contents of which were made public following the principles of the Integrated Environmental Management legislation."

Jan 1, 1994

By Liane L. M. Kacinuck

This U.S. Bureau of Mines publication is intended to provide mining industry representatives and regulatory authorities with a reference package dealing with studies on hydrology and underground mine subsidence. An annotated bibliography and a list of additional sources are given and represent references published prior to June 1993. Ninety-two references ware identified and 72 obtained for assessment. Annotating the references included evaluating the study methodology and summarizing the basic results. The references are also compiled based on geographic location to aid the user in identifying articles of particular interest.

Jan 1, 1994

By Jerry D. St. Clair

A multidisciplinary team of scientists and engineers at Wont has been working to understand heavy metal contamination of DuPont process waste streams and technologies for abatement of these metals. As part of this effort, an extensive study was made of a specific waste stream of importance in DuPont's environmental commitment. This 200 gpm stream contains 5-5000 ppm of nickel plus a variety of inorganic and organic constituents. The chemical complexity of the waste rendered conventional. alkaline precipitation ineffective, and only through the simultaneous application of analytical characterization, fundamental chemical understanding, and process engineering did effective technical approaches emerge. In this instance, ion exchange, sulfide precipitation, and caustic digestion ultimately proved successful in reducing the nickel to below the 1 ppm target. The results of this study will be presented, along with key learnings about the process of solving heavy metal contamination problems.

Jan 1, 1994

By J. V. R. Prasada Rao

India is dependent for 60% of its annual requirement of copper and the entire quantity of nickel and cobalt on imports from outside the country. Land-based resources are either too meager or of too low a concentration for economic exploitation. This has prompted the country to look to deep seabed re- sources for meeting its rising demand for these metals. The Ocean Policy of the Government of India announced in 1982 talks about the need to map and assess the availability of minerals in the deep sea and to develop necessary technologies for exploration and exploitation of seabed minerals. To be self-reliant such technologies would have to be largely developed, tested and operated indigenously. The adoption of the Law of the Sea Convention in 1982 gave a fillip to India's desire to get into the field of deep seabed mining. India applied for recognition as a Pioneer Investor in Ocean Mining in 1983 and received allotment of a mine site of 150,000 km2 in the Central Indian Ocean in August 1987. Simultaneously, the Government has taken up a programme of development of technologies for exploration of the mine site for resource assessment, environmental monitoring also to meet the commitments like relinquishment of 50% of the area to the Preparatory Commission. Technologies for exploitation of these seabed resource like the mining system, transportation and extractive metallurgy have also been taken up for development in various research institutes largely in the government sector. While India's objective in the long term is to meet the shortage of copper, nickel, cobalt and manganese by the turn of the century, in the short term, the programme aims at application of the seabed mining technologies to meet the immediate needs of the country such as: a. Exploration for oil and natural gas. b. Exploration and exploitation of placer minerals and other deposits at shallow depth in India's EEZ.

Jan 1, 1994

[ENGLISH active earth pressure adapter additive adhesion admixture, addition adsorbed water aggregate air air entrainment air hose allowable bearing value allowable pile bearing load]

Jan 1, 1994

By G. Van Weert

Refractory gold ores and auriferous concentrates containing silver tend to form refractory silver jarosites during pressure oxidation. Earlier work with pure Ag2S has shown that the addition of iodine species to the autoclave feed yields cyanide soluble iodargyrite (Agl) instead. Near complete silver extractions from the autoclave product were obtained at a I-/Ag+ ratio of 5 or more. This paper reports on the pressure oxidation and cyanide leaching of two industrial refractory (arseno) pyritic silver-bearing concentrates: 1. from Peru (sulphosalts) and 2. from the USA (pyrite, with acanthite occlusions). While using a I-/Ag+ mol ratio of only 1 in the feed, it has been possible to obtain 98 and 97% Ag extraction from the two autoclave products by cyanide leaching, respectively. This compares to 11 and 54% Ag extraction from the as-received concentrates and 4 and 15% Ag extraction, respectively, after pressure oxidation without KI present. The results of the testwork are discussed in terms of concentrate mineralogy and pressure oxidation conditions.

Jan 1, 1994

The results of studies to ameliorate acid mine drainage by retarding the rate of oxidation of pyrite at source are discussed. In the transpassive region, pyrite oxidizes by reactive dissolution, mass transfer through the product layer and diffusion in the bulk solution. One can decrease the rate of pyrite oxidation by inhibiting either oxidation reactions or cathodic reactions. It is demonstrated in this study that some surface active reagents extend the passive region by affecting both the anodic and cathodic processes. The extension to higher potentials occurs by inhibition of the anodic dissolution process whereas to lower cathodic potentials through decrease in the rate of reduction of molecular oxygen and/or ferric ions. To retard the oxidation of pyrite by ferric ions, which is considered to be the dominant oxidant under conditions of acid mine drainage, it would be necessary to restrict mass transfer or promote complexation of ferric ions at the surface. Imidazoline based reagents were found to be most effective in meeting this goal.

Jan 1, 1994

By L. D. Robbins, M. L. Murphy, A. C. Campbell, L. Murphy

This paper reports on what appears to be the first discovery of prehistoric mica-schist mining in southern 4frica. The mine concerned was found in a location very rich in rock art that is one of the most important archaeological sites in the Kalahari. The authors conclude that the oval pieces of mica schist that were found at the mine site were used by Khoisan peoples to scrape fatty tissue from hides that were to be cured. Radiocarbon datings seem to indicate that such ovals were used for at least 20 000 years.

Jan 1, 1994

By William H. Snyer, Hank Cox

A high explosive device using Linear Shaped Charge (LSC) (to rapidly cut vent and drain openings in a rail tank car) is described. In the event of damage to a tank car loaded with a pressurized flammable fluid, it may sometimes be necessary to perform controlled on-site vent, drain and burn operations. Existing techniques required refinement to achieve the desired safety and procedural reliability for use in emergency situations.

Jan 1, 1994

By E. H. Cho

Pittsburgh #8 coal cleaned by the conventional froth flotation was oxidized in a 2-liter Parr Stirred Top Bench Reactor. The oxidation time was varied up to 5 hours; the temperature, from 150 to 225°C, the oxygen pressure, from 15 to 500 psi; and coal dosage, from 15 to 60 grams in 600 ml of distilled water. The oxidation of coal was evaluated by measuring total acidic group formed on the coal surface as well as by measuring the adsorption of calcium ion from a solution under standard conditions. It was found that the oxidation increased with increasing oxygen pressure without much leveling-off effect. However, the oxidation of coal increased sharply from 150°C to 175°C and then tended to level off above 175°C. The adsorption of calcium was reached more than 3% on the coal oxidized under favorable conditions. The adsorption of calcium on coal increased sharply with increasing equilibrium pH. The BTU loss was sensitive to oxidation temperature. This study concludes that the optimum oxidation of coal should be conducted at high oxygen pressures around (e.g. 500 psi) 170°C for 3 hours. This study also concludes that the oxidation in an autoclave is far superior to that in a fluidized bed in terms of calcium adsorption, BTU loss and reaction time.

Jan 1, 1994

By Luis W. Pommier

The developed processes, the subject of this paper, extract the hydrocarbons, halogenated organic compounds and metal contaminants from hazardous soils, rendering them non-hazardous and ready to be placed back on the ground. The processes first segregate a non-contaminated fraction from the contaminated soil. This initial task is performed using available minerals processing technology: sizing, gravity separation, magnetic separation, froth flotation, etc. The remaining contaminated fraction, is submitted to two leaching operations for the removal of organic and metal contaminants, whenever both are present or to a single leaching operation if only one type of contaminant is present. The decontaminated soil fraction is mixed with the non-contaminated fraction and is placed back on the ground. The leaching liquors, used at neutral pH, are non- hazardous. After decontamination the liquids are processed to extract the contaminants, now valuable materials, for commercialization. Organic contaminants are removed by distillation of the solvents. The metal contaminants are precipitated in their oxide form. In both cases the regenerated solvents are recycled. The decontamination processes are economically competitive with transportation and disposal of the soils to permitted facilities for hazardous materials, and most importantly the developed processes remove the liabilities from the Responsible Parties. The law establishes that these liabilities do not disappear with either fixation nor with transportation and disposal since the environmental liabilities are of the ? cradle to grave? type.

Jan 1, 1994

By J. Z. Keating

There are close to two million tons of Industrial Minerals processed and sold in North America wherein the processor/marketer has no affiliation with the source mine. The largest quantity, about 800,000 tons, is barium sulfate, which is sourced in lump ore form mainly from China and India. The Alumina Trihydrate Industry sources several hundred thousand tons from various alumina refineries. Substantial quantities of bauxite, zircon, magnesite, and fluorspar arrive in North American ports each month. There are also rapidly growing quantities of offshore talcs and calcium carbonate ores being processed in U.S. plants. These feedstocks are usually quite pure, have unique properties, and enjoy bulk rail or waterborne freight economies that allow successful competition with locally sourced raw materials. With increasing restrictions on mining activities, and the increasing need for sophisticated functional minerals, the importation of minerals will continue to grow.

Jan 1, 1994

By J. E. Brownhill

This paper does not deal with the typical start-up issues of equipment, production capacity or work force. This is a description of the challenges faced and the changes made by the project team to bring to fruition the reconstruction of Port Inland. Many honored traditions and norms had to be overturned to find the winning combination that provided the productivity, flexibility and cost necessary to survive in today's competitive minerals environment. This paper covers the innovation in terms of machinery, operations, and management philosophy that permitted the renovation and reopening of Port Inland as a commercial limestone producer in the spring of 1992. Port Inland, constructed by Inland Steel in 1930, operated as a captive source of metallurgical grade limestone for the steel industry until its closure in 1989. Located in the Upper Peninsula of Michigan on the north edge of Lake Michigan, the operations consist of a deep water port facility with crushing, screening and stockpile storage for 500,000 tons of finished product at the port. Ninety-nine percent of the stone is shipped via lake boat to ports within the Great Lakes. The operation is unique in that both metallurgical Dolomite and Limestone are produced on site. In 1930, Port Inland was at the fore front of technological advancement. It was the first major mining operation to use roller bearings and other equipment innovations. Over the 60 years of operation, Inland Steel placed emphasis on steel making technology and iron ore mining at the detriment of the limestone operation. By the early 80's, Port Inland was no longer a leading competitor. Inland Steel, unable or unwilling to spend the capital to modernize, closed the facility in the fall of 1989.

Jan 1, 1994

By M. Karmis

The determination of the surface area which may be impacted by underground mining is an important consideration in subsidence engineering. A number of parameters have been utilized to identify this influence area, most notably the angles of draw and break. This paper discusses the implications of selecting an appropriate "damage angle" for defining a potential damage area due to mining, within which surface structures may be impacted Furthermore, the influence of both mining and geological factors, such as mining width and depth and overburden lithology, on this angle is examined, using the Surface Deformation Prediction System (S.D.P.S) software. Finally, recommendations are given for applying these concepts in subsidence control.

Jan 1, 1994