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By T. G. Hayes

Economic and environmental regulations in the coal industry have required companies to evaluate their current blasting method of loosening in-situ coal. This paper will review ripping vs. blasting thick in-situ coal seams, handling frozen active coal stockpiles and proper stockpile conditioning and reclaiming. How basic operating technique can improve job efficiency, productivity and cost per ton.

Jan 1, 1995

By R. Burkhard

Recovery of metals from complex mixed wastes is a challenging task of modem material and waste management strategies. Thermal methods are an important tool in this respect. Plasma turned out to be particularly useful for treatment of complex or toxic wastes and residuals. In order to study plasma processes at reasonable costs, a pilot plasma plant has been used and wastes like ~pent Raney-Nickel catalysts, copper and ah.:lminum drosses, and. other metal containing wastes were investigated. The paper summarizes the most significant findings

Jan 1, 1995

The Golden Cross mine is situated in a sensitive environmental setting on the North Island of New Zealand, about 150 kilometres south-east of Auckland and about 8 kilometres NW of Waihi. The mine is situated in dipping topography, with volcanic ashes making up soils, fault zones running through the area, and rainfall of about 3 m per year on average. Water management is the most demanding environmental challenge on site, and a comprehensive programme has been put in place to address tailings deposition, long term tailings storage, and water treatment during and after operations.   The tailings impoundment is built with an underdrainage system that collects groundwaters and waters that seep through the impoundment. The embankment and impoundment are both built to withstand the Maximum Credible Earthquake and the Probable Maximum Flood. Tailings are treated to remove cyanide and to decrease metal solubility to reduce long term risk to water quality after mining. A state-of-the-art water treatment plant is utilised to treat water from the underdrainage system and water decanted from the top of the tailings pond and stormwaters to remove residual cyanide and metals to extremely high standards with a great deal of reliability and at reasonable cost. Closure of the facility addresses long term post mining water quality issues, and rehabilitation of the area with wildlife habitat as a priority.

Jan 1, 1995

By Harvey Alter

National attention in, recycling focuses on municipal solid waste (MSW), even though only about 50'million tons or so of MSW can be recycled, including grass, leaves and other yard wastes. The scope and value of the recycling of industrial "wastes" is much greater. It is possible to account for some 240 million tons of material recycled at the industrial scale annually, which is likely a conservative estimate. Some of this recycling reduces what would otherwise be hazardous waste to 'comrnodities and non-hazardous residue. Global trade in recycled commodities is outlined, as well as the-effect of the Basel Convention on the Trans boundary Movement of Hazardous Wastes A recent Decision under the Convention can, diminish the trade; deny developing countries needed secondary raw materials, and put world markets in chaos. Current U.S. government policies and activities toward ratification of the Convention, and possible new regulation of industrial recycling activities, will be discussed. There are federal proposals that would regulate industrial recycling differently for on-site and off-site facilities and judge legitimate or "sham" recycling according to the concentration of so-called "toxics along for the ride."

Jan 1, 1995

By M. Misra

The volume of low-level contaminated soil at the. Department of Energy's Nuclear Weapon Sites are in the order of several million tons. Most of the contaminants are uranium, plutonium, other heavy metals and organic compounds. Selected Physical separation processes have shown demonstrated potential in COD Centratingthe radio nuclides in a small fraction of the soil. Depending upon the size, nature of bonding and distributions of radio nuclides, more than 90 percent of the radio nuclide activity can be concentrated in a small volume of fraction of the soil. The physico-chemical separation processes such as flotation in a mechanical and microbubble tall column cell have shown, promising applications in cleaning up the high volume contaminated soil.

Jan 1, 1995

By Chien D. Ngo, Andre Bachmann, Rainer Bunge

The remediation of contaminated sites has gained great importance in many industrialized countries. One method for cleaning the polluted soils from such sites is "soil washing," the scope of which is the separation of the contaminants from the soil. Soil washing is an outstanding example for a successful transfer of technology from Mineral Processing to Environmental Engineering. This presentation intends to introduce the Mineral Processing Engineer to soil washing through a short review of the fundamentals, and the discussion of an example for a successful soil cleaning operation in Switzerland.

Jan 1, 1995

By Tatsuo Itou

Both sales volume of Aluminum Can and its recycling rate are remarkably increasing here in Japan. In 1993, recycled can volume was 11.78 billion cans ( 116,258 metric tons ) and its recycling rate 57.8 percent. We, MITSUBISHI MATERIALS CORPORATION. the leading manufacturer of aluminum can in Japan and our affiliated companies are very deeply involved in recycling used beverage cans ( U.B.C ) and recycling them back to can stock. In this paper. I would like to present the following; 1. Recent trend of beverage can consumption in Japan. 2. Trend of aluminum can and its recycling rate in Japan. 3. Future of aluminum can business in Japan.

Jan 1, 1995

By Richard Jr. Ray, Richard Druesedow

The Virginia Operations of Consolidation Coal Co. include a diversity of mine fan configurations which have been tested to quantify pressure losses through the inlet ductwork. Airflow and pressure measurements were taken at four shaft sites to calculate losses for the 90-degree bend at the top of the shaft and the self-closing dampers or closing doors located between the shaft and fan. Velocity contours were then developed from the test data to determine flow patterns in each fan system component. In addition, yaw and pitch angles of airflow through the fan annulus were measured to evaluate turbulence levels created by various inlet ductwork designs. The test results indicate that proper design of the shaft collar and ductwork arrangement for main mine fans can substantially reduce system pressure losses and air turbulence. BY minimizing the pressure drop experienced on the surface, these design improvements enable the bulk of the total pressure developed by the fan(s) to be utilized in the mine.

Jan 1, 1995

By Luis W. Pommier

Large quantities of sea sludge containing halogenated organic compounds, such as PCB, oils and metals like arsenic and lead have accumulated throughout the years at the bottom of sea channels and harbors and are obstructing navigation and creating environmental problems which need to be resolved. A sludge from a California port would be dredged by suction pumps, it would be processed in a plant which would be built either on firm soil or on floating platforms. The sludge shows contents of up to 1 ppm of PCB, 15 % oil and 10 ppm of arsenic, which generates a very fetid odor. Bench scale work indicates that most of the contamination concentrates on the solid phase, in fact, only minor amounts of oil report to the sea water and can be readily removed by physical means. After separation of the sea water from the solids of the sludge by decantation, it is possible to solubilize the PCB, the oil and the metals into an organic solvent leaving a non-hazardous soil for disposal near the harbor. The PCB is dehalogenated during the solubilization process leaving a liquor solution containing the oil and metals. The oil is extracted leaving an aqueous solution containing the arsenic. Further process extracts the arsenic from this solution rendering the liquid non-hazardous. Transportation and disposal of the sludge is impractical. There are hundreds of thousands of tons of hazardous soils accumulated in each harbor, which would fill the hazardous waste disposal sites available and it would be, prohibitively expensive to do so. It is not possible to compare the costs of decontamination with a competitive method. If it were, the proposed process would be less expensive than transportation and disposal and it has the advantage of removing the liabilities from the Responsible party. After a full scale continuous pilot project is run to decontaminate a small, 500 cubic yards accumulation of this type of sludge in a California harbor, a full scale environmental project would be initiated. The decontamination of one million tons of sludge would be completed in five years.

Jan 1, 1995

By E. Suoninen, K. Laajalehto, L. Kartio

Efficient separation of pyrite from other sulfides is of great importance for the metallurgical performance of flotation processes. In this work Fourier Transform Infrared Spectroscopy (FTIR) and X-ray Photoelectron Spectroscopy (XPS) were used to study the surface chemistry of pyrite in depression, activation and xanthate adsorption under conditions of controlled potential. Modifications of pyrite surfaces after treatment with depressants (lime, sulfur dioxide, sodium cyanide) and after activation with metal ions (Cu, Pb) were studied. The principal adsorption product identified on pyrite was dixanthogen whose formation started at about +0.15 V and +0.25 V (vs, SHE) in ethyl and amyl xanthate solutions, respectively. Copper xanthate was formed on copper(II) activated pyrite. Activation mechanism of pyrite by copper(II) salts is likely to be electrochemical where copper occurs as copper(I) on the surface of pyrite. Effective depression is achieved by sulfur dioxide and sodium cyanide. Depression at high pH is due to formation of iron(III) hydroxides. Calcium ions do not affect the electrochemistry but adsorb on pyrite and reduce the surface sites for dixanthogen adsorption.

Jan 1, 1995

By Federico Chavez

The process for recovering lead from battery residues used in several Mexican Plants include lead blast furnace and rotary furnaces. The formers are basically fed with recycled batteries together with the necessary additives to produce metallic lead. One of the by-products generated in the blast furnace is a dust mainly formed by lead sulfide. The rotary furnace is used to recover lead .from lead batteries, dross from the refining-alloying process and the leady fines produced in the blast furnace. This paper describes thennodynamic analysis made to the rotary furnace process to understand the effect that each component of the system has upon the lead recovery. In order to enhance the process, the influence of iron chips composition and excess coke on slag viscosity is discussed. A computer optimization program . has been developed to design the furnace charge based on material and energy balances, .together with the thennodynamic equilibrium calculation.

Jan 1, 1995

By Gregg PEH, Stewart RB

Reclamation field trials commenced in 1985, two years before the granting of the Mining Licence. The level of pasture production on varying soil depths (0 cm, 5 cm, 15 cm and 25 cm) overlying both tailings and oxidised waste overburden was assessed. After seven years, the rate of increase of N, C, P and S, losses of S and P and pH changes were investigated on the plots where grass seed was sown into bare tailings. It was determined that on these plots it would take approximately 24 years to reach the original carbon and nitrogen levels at the mine site.

Jan 1, 1995

By Shelley M. Burg, Dennis K. Poulton, Robert B. Gordon

This project includes the excavation and concrete lining of approximately 18 900 m (62 000 ft) of 5.5 m (18 ft) finished diameter subway tunnel for the Los Angeles MTA. The project required that four soft ground headings be excavated from a single shaft located near the mid point of the tunnels. The tunnels were classified "gassy" during the excavation phase. Because of the contract schedule requirements and the limited urban work site available, many logistical problems had to be overcome during the project while excavation was accomplished at a record setting pace. Some unique project features include the muck handling system and an access shaft using a high strength tieback support system. In order to accomplish the work, an extensive effort to plan and construct the main work site was required.

Jan 1, 1995

By A. C. Hitchins, C. N. Orssich

The Eagle zone is a gold-bearing, sheeted, quartz vein porphyry deposit hosted by the Cretaceous Dublin Gulch biotite granodiorite stock, located in central Yukon, 50 km north of Mayo. The deposit occurs at the western end of the stock and has been drill tested over a 1000 m by 500 m area, to a depth of 150m. Mineralization consists of 1 cm to 2 Cm wide, parallel, grey and white quartz veins with accessory gold, arsenopyrite, pyrite, pyrrhotite, chalcopyrite, native bismuth, bismuthinite, and scheelite. Vein densities range from two to fifteen veins per metre and average approximately five per metre. The majority of the veins have potassic and or phyllic alteration envelopes. Alteration of the granodiorite becomes pervasive as vein densities increase. Mineralization outside of the Eagle zone, but spatially related to the Dublin Gulch stock, includes: (i) scheelite bearing sheeted quartz vein zones within the east-central portion of the stock; (ii) a swarm of gold-bearing quartz-sulphide veins up to a metre wide in a zone along the northern contact of the stock and extending 7 km further west; (iii) the Mar scheelite skarn located on the south side of the stock; and (iv) cassiterite-bearing breccias located 2 km north of the stock. A geological potential resource of 64.5 Mt tonnes at a grade of 1.03 g/t Au has been estimated for the Eagle zone from widely spaced core and reverse circulation drill holes. Mineralization is open at depth, on strike to the west and beneath the hornfels to the north.

Jan 1, 1995

By Viacheslav Lyakhov, Cornelis H. Iestra, Victor I. Beloborodov, Vitaliy Bogdanovich

The results of a study and effective use of flotation for processing of ores with complex mineral composition containing fine-disseminated minerals with high specific density are presented in the paper. The object of research was complex baddeleyite-containing ore from Kovdor deposit (The Kola peninsula, Russia). Baddeleyite is a valuable, rare mineral, natural Zirconium dioxide with 5.8 - 6.0g / cm density, grade content 0.15 - 0.17 and dissemination less than 0.2 mm. The authors carried out a thorough investigation of baddeleyite- containing products selected in different sites of gravity flowsheet. It was determined that due to similar specific weight some sulphide minerals (pyrite, pyrrhotite) come into concentrate together with baddeleyite and, also, minerals of pyrochlores group (hatchettolite). The results obtained revealed the possibility of use the flotation for retreating rough baddeleyite concentrate. he given gravity concentrate has a number of specific features, e. g. high density of its minerals which, in its turn, provides for high speed of sedimentation of solid phase in pulp, and for the presence of large amount of sulphide minerals (up to 10%) having good flotability. With these features being taken into account a technology for flotation of baddeleyite-containing products after their preliminary gravity concentration has been developed (up to 5 - 10% Zirconium dioxide). The technology has three flotation stages. At the first one the reverse flotation of baddeleyite is carried out during which "light" minerals (forsterite. apatite and carbonites) come into froth product and at the second one flotation of sulphide minerals and at the third one direct flotation of baddeleyite is performed from the underflow product. The following reagents were used for flotation: of phosphate type (sodium tripolyphosphate, mono and diethers of alkylphosphpric acid) and sodium xanthate as collector for sulphides. The given set reagents provides for high effectiveness of flotation due to selective of collectors and presence of froth layer with high carrying ability. New flotation technology of recovering of baddeleyite from complex ore was developed and applied at the Kovdor Mining Plant, using AKER flotation machines.

Jan 1, 1995

By G. R. Cope, C. D. Spence

"The Mac porphyry molybdenum prospect is located 100 km east of Smithers in central British Columbia. The identification of anomalous levels of molybdenum, copper, and silver in three adjacent lakes, sampled during a regional lake sediment survey, lead to the discovery of molybdenite mineralization in float. Subsequent magnetic and soil geochemistry surveys, together with prospecting and mapping, located the source of the float. Mineralization is hosted by a leucocratic granite stock of the Upper Jurassic to Lower Cretaceous Francois Lake Intrusions which has intruded Carboniferous and Permian Cache Creek Group volcanic and sedimentary rocks. The stock measures 500 m by 300m at surface and is mineralized throughout. Sulphide mineralogy is simple and consists of molybdenite with minor pyrite and local chalcopyrite. Molybdenite occurs within fractures and as selvages along quartz stockwork veins and is best developed near the margins of the stock.Known mineralization is coincident with distinct soil geochemistry and magnetic anomalies. Two additional areas of the property display similar features and these remain to be tested.IntroductionThe Mac property is situated in the Babine Lake area of central British Columbia on NTS map sheet 93K/13E, approximately 100 km east of the town of Smithers (Fig. 1). The property lies on the western margin of the Hogem Range at the northern tip of the Nechako Plateau. The centre of the claim block lies at 54°51 ' 30""N and 125 °34 '30""W.Topographically, the claims are characterized by gently rolling hills ranging in elevation from 900 m to 1500 m. Slopes are forested with tall conifers and underbrush is minimal. Flat-lying areas are swampy with tall grasses and scrub brush.Presently, the property is only accessible by helicopter from bases located in Smithers and Fort St. James. Recent road construction by the British Columbia Forest Service has brought road access from Burns Lake to within 5 km due south of the property. It is expected that in the near future, roads will be advanced into the claim area to facilitate logging of mature timber."

Jan 1, 1995

By W. G. Pariseau

Recent advances in rock mass mechanics and computational technology now allow for stability analysis of excavations in "wet" mines where mining-induced changes in rock mass deformation and fluid flow are coupled and time-dependent. All the usual dry mine parameters including the premining stress state and rock mass properties are taken into account, in addition to water pressure and flow in jointed, possibly porous, rock masses. Finite element analyses of shafts and tunnels as circular, elliptical, rectangular and arched-rectangular hole shapes excavated in an initially stressed and pressurized rock mass indicate that the usual guidelines for optimum shape and orientation of single openings apply. Here, optimum means maximizing the minimum wall safety factor, or equivalently, minimizing the peak stress concentration. The results also show that failure originates in elements at the wall and that the minimum safety factor at the wall in the wet case is always less than the dry case regardless of drainage time allowed.

Jan 1, 1995

By R. Lasmanis

"Washington State's diverse geological setting is reflected by its several types of porphyry Cu-Mo deposits. All are associated with calc-alkaline intrusions, and they range in age from Jurassic to Miocene.The largest is the Mount Tolman Mo-Cu deposit located in the Omineca Belt. It contains 2.18 billion tonnes of material averaging 0.093% MoS2 and 0.09% Cu. There are intermediate-size Mesozoic deposits in the Intermontane Belt. The Cascade volcanic arc hosts small- to medium-Tertiary deposits. Among these, of particular interest is the Sunrise breccia pipe, which has been explored over a vertical distance of 1000 m. It contains reserves of 64.6 million tonnes averaging 0.319% Cu and 0.071% MoS2 with significant tungsten values. The Glacier Peak deposits have potential resources of 1.7 billion tonnes averaging 0.334% Cu and more than 0.015% MoS2 and also contain tungsten. The Margaret deposit can be classified as a porphyry Cu-Au type; it has reserves of 200 million tonnes averaging 0.434% Cu, 0.0175% MoS2> 0.27 g!t Au and 1.92 g!t Ag. Drill intercepts of the North Fork deposit also show significant gold values.Mineralization and hydrothermal alteration of these deposits are typical of porphyry deposits, although some differences can be noted. The Mount Tolman molybdenum deposit contains topaz alteration zones and is transitional between a plutonic type and a Climax-type molybdenum system. Other deposits, such as the Kelsey, Mazama, North Fork, and Margaret, are low-sulphide systems that contain significant amounts of magnetite."

Jan 1, 1995

By Kenichi Moriyama

The Sumitomo Toyo Copper Smelter started operation in 1971, as an epoch-making smelter at which 9996 of the charged sulfur could be captured. In the past ten years, the amount of treated copper concentrate has-been increased from 1,300 l/ day to 1;900 t/ day by the extremely effective application of the oxygen enrichment for a flash smelting furnace and converter furnace. The sulfuric acid production capacity at the acid plant has also been increased up to 1,900 t/ day corresponding to the increase of copper concentrate smelting rate without installing an additional acid plant. Furthermore the sulfur fixed ratio is kept at a high level, more than 99.996. despite the SO. strength fluctuation of the wide range of 596 to 1396 which is attributed to the combination of flash smelting furnace and, P.S. converter. These -operational results at the? acid plant were achieved by several modifications. and two examples are briefly described as follows; (1) Converter modifications in order to cope with the high SO, strength -gas (2) Introduction of the anodically protection shell and tube type acid coolers In addition. the quality of sulfuric acid has been positively increased. For example, the concentration of iron and arsenic, which were the main Impurities in ?sulfuric acid, was successfully .reduced.

Jan 1, 1995

By David J. Herzog

There are two steps in evaluating potential mine waste impacts on ground and surface waters. Characterize the mine waste (characterization methodologies) and assess potential impacts (assessment strategies). One or both may be required for mine permitting, operation and closure. The first step is to characterize the waste. Determine if it has the potential to release chemical constituents or acid rock drainage to the environment. If no potential exists for release to the environment, the evaluation process is complete. A monitoring plan is then established. If the potential exists for release of chemical constituents or acid rock drainage to the environment, a strategy to evaluate potential impacts must be implemented. Strategies discussed here to evaluate potential impacts were developed during investigations at precious metal and base metal mines in Nevada. Water resources in Nevada consist mostly of ground water. So the strategies discussed focus on potential impacts to ground water. However, several of these strategies also apply to assessing potential impacts to surface water. Implementing these strategies has helped determine the potential for impact and has been successful in permitting mine expansion as well as allowing continued operation and obtaining mine closure at several mine sites in Nevada. These strategies were carried out in accordance with Nevada Division of Environmental Protection (NDEP) regulations and through the National Environmental Policy Act (NEPA)

Jan 1, 1995