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By Rolando Campos

In August 1993, the operation of Refimet Chile's copper custom smelter commenced at La Negra, near Antofagasta in northern Chile. Design smelter throughput corresponded to 235 000 tonnes of concentrate, calcines and copper cements arising from suppliers in the north of the country to produce 90 000 t/y of blister copper. Refimet had initially gained experienced in building and operating leaching, roasting and a blast furnace facility at Rungue, near Santiago, followed by Roasting at La Negra. The initial smelter project was based on conventional reverb- smelting and Peirce-Smith converting and the majority of equipment was 'purchased second-hand and rehabilitated or modified. After only 3 years in production, the treatment capacity was significantly improved by introduction of technical improvements to the original plant operating scheme. Recently, the plant was further expanded to an annual smelting capacity in excess of 400 000 t/y feed, corresponding to around 160 000 t/y copper production. This expansion, referred to as Phase 2, was achieved by modification of the reverb to oxy-fuel firing, addition of a further (second-hand) acid plant, fire refining and anode casting facilities. Parallel development of concentrate injection into enlarged converters-also took place. Following successful commissioning of Phase 2 expansion, initial engineering studies for a third expansion phase have been completed. This aims to use leading technology based on bath smelting of bone-dry concentrates in a Continuous Reactor. This paper provides an overview of the relatively short plant history, its development and improvements together with operating indices achieved.

Jan 1, 1998

By D Morrison, P Goodman

The cycle time between adjacent stopes is critical to achieving the required production rate from 3500 Orebody; one of the Enterprise Mine orebodies. Current Mt Isa cemented fills require a 90-day cure period which had to be cut to 30 days while maintaining the required strength criteria. The Enterprise Mine Feasibility Study recommended that this be achieved by Cemented Slurry Rock Fill (CSRF), but that on-going research into paste fill be continued. The continuation of the research, in conjunction with overseas visits has recommended that the 3500 Orebody be filled with paste fill, with the potential to fill other orebodies. The paste fill will comprise cyclone and thickener dewatered copper tailings to which Portland Cement (PC) is added before vertical borehole delivery and undergound pipeline reticulation to individual stopes. The benefit is not only re-use of copper tailings but also much reduced binder usage.

Jan 1, 1998

By Shan Mafi

he Broken Aro coal mine is located at the Woodbury Wildlife Preserve 11 km (7 miles) west of Coshocton, OH on State Route 541. Underground min¬ing at the 16-hm2 (40-acre) site took place during the 1910s. During the past five years, surface mining has occurred along the western and northern perimeters of the underground region. The Ohio Department of Natural Resources (ODNR), R&F Coal and American Electric Power (AEP) are involved in a project to remine the abandoned underground complex. The program also includes installing a mine seal made of fixated flue gas desulfurization (FGD) material. Previous mining activity in this area has resulted in an acid mine drainage (AMD) problem on portions of the reserve. In particular, a prominent AMD source is present in the Simmons Run drainage. The project goal is to eliminate or reduce the AMD that is discharging into the watershed. It was initially hoped that the Simmons Run drainage area could be economically mined. Accordingly, this area was included in the mine permit. However, experience with other previously mined areas on this reserve showed that the old mine workings were more extensive than originally thought. Old mine workings present several problems. The most significant are reduced coal recovery, poor coal quality and AMD liability. All of these problems increase mining costs. And the more extensive the old workings, the more significant the increase in cost. Based on R&F's experience with old mine workings in this area, it was decided that economic recovery of the Simmons Run drainage reserve was not possible. As a result, R&F excluded the Simmons Run drainage area from its early mine plans. Some time after it was decided not to affect the Simmons Run drainage area, R&F and ODNR's Division of Mining and Reclamation discussed the possibility of removing this area from the permit and attempting to correct the AMD problem as an Abandoned Mine Lands (AML) project. Specifically, the discussion centered around mining through a portion of the old mine workings to expose the mine openings in the highwall. Once exposed, the mine openings would be sealed using FGD material from the nearby Conesville power plant operated by AEP. In addition, there was interest in reclaiming the old tipple and associated gob pile located adjacent to Coshocton County Road 17 on the opposite side of Simmons Run. R&F attempted to eliminate the AMD problem by sealing the mine openings with FGD material. Once the seals were installed, they were covered with overburden. Monitoring wells were installed to determine the effectiveness of the seal and the inundation progress in the old mine workings as well as monitoring the quality of ground water. The project was jointly funded by revenue from the sale of the coal recovered during the project and AML funds. The FGD seal is expected to cause well water levels to increase above preseal elevations. However, the additional head pressure due to increased water depths in the underground mine may cause seepage through the bottom of the mine or out through the perimeter. The in¬creased water depth in the underground mine is expected to cause lower oxygen concentrations in the underground mine water. Since acidity is produced by oxidation of iron pyrites, less oxygen should result in better quality water. Monitoring wells will be installed before seal installation so that pre- and postseal water levels and well water quality can be determined. Surface sampling locations will be identified. These will be monitored before and after seal placement.

Jan 1, 1998

By M. Wasel

The Gross Rosebel gold deposits are located in the Guiana Shield of north central Suriname. Initial discovery of surficial gold in 1880 by local artisanal miners preceded small-scale mechanized mining from 1885 to 1939. The first systematic exploration program was carried out by Placer Development from 1974 to 1977. In May 1992 Golden Star Resources optioned the property. Initial shallow reconnaissance diamond drilling of the extensive surface geochemical anomalies intersected sporadic gold mineralization with no apparent continuity between drill sections. Successive deep augering, trenching and systematic grid drilling based on information from surface mapping allowed development of a preliminary geological model. Further drilling of specific structural-lithologic targets and more complete synthesis of geological data from the trenching and deep auger sampling added to the geological model and defined the multiple controls of gold mineralization. Carefully planned infill drilling on a tighter grid spacing resulted in progressive definition of reserves within six discrete gold deposits. In a complex geological setting, the key to success at Gross Rosebel was persistent, systematic exploration, detailed mapping, careful core logging and perceptive geological interpretation. Reserves now stand at 48.6 Mt at 1.6 glt Au, or 2.4 million ounces of gold. The purpose of this paper is to describe the progression of exploration activity that led to the definition of substantial gold reserves and to summarize the geology of the deposits.

Jan 1, 1998

By R. J. Sweigard

Stabilization of slopes on abandoned mine land (AML) invariably involves some channelization to control surface drainage. Typically, these channels are lined with riprap or gabions, depending on gradient and expected flow rate. The conventional treatments pose a problem since they require frequent maintenance and replacement at times. Soil bioengineering presents an alternative to the conventional measures. In soil bioengineering, living woody plant material forms the main structural component in systems designed to prevent shallow mass slope failures, surface erosion, and channel bank erosion. An experimental application of soil bioengineering techniques was designed and implemented at an AML site in eastern Kentucky. The design consisted of live fascines and live stakes using willow branches installed with coir geotextile. Channel gradient, length, and cross-section were considered in the design.

Jan 1, 1998

By D. Neuschiltz, M. Witthaut, R. Cremer

"Metastable (Ti,Al)N coatings with fee structure have been shown to exhibit superior performance as compared to TiN under conditions of wear at elevated temperatures due to their better oxidation resistance and hardness. The oxidation resistance of these coatings increases significantly with increasing Al-content. However, the deposition of (Ti,Al)N films with Ti/ Al ratios below about 30/70 leads to a hexagonal structure which is not suitable for tribological coatings. Only little is known about the location of the cubic to hexagonal phase transition and hence about the optimum composition of (Ti,Al)N hard coatings.To determine the position of this transition, Tii-xAlxN films with different Ti/Al ratios were deposited on high speed steel at substrate temperatures between 100 and 700 °C by means of reactive MSIP. The composition of the films was determined by electron probe microanalysis (EPMA) and X-ray photoelectron spectroscopy (XPS), the crystallographic structure by thin film X-ray diffraction (XRD).It could be shown that in case of deposition temperatures of 300-700 °C a two-phase region exists in the metastable TiN-AlN phase diagram, which expands with increasing temperature, wheras at 100 °C substrate temperature no two-phase region was observed. But in opposition to the phase diagram known from literature, which is based on thermodynamic estimations, the detected two-phase region is narrow for typical PVD temperatures, thus allowing the deposition of cubic single-phase Al-rich (Ti,Al)N hardcoatings for tribological applications. Based on these results, a new Ti1-xAlxN film with x = 0.62 has been developed, which showed an increase of oxidation resistance by a factor of 4."

Jan 1, 1998

By R. L. Lewis

A simple method for estimating the steady-state water quality of a pit lake is presented. The steady-state concentration of a conservative chemical constituent in a pit lake is shown to be a simple function of inflow rate, evaporation rate, and inflow concentration. An analytical method is presented for estimating the equilibrium ground water inflow rate for use in water quality predictions. The time required to reach chemical steady-state is estimated using an iterative mass balance model. Mine operators should find the methodology useful for planning and screening-level regulatory applications where conservative estimates of pit lake water quality are desirable.

Jan 1, 1998

By Takeshi Ohgai, Hisaaki Fukushima, Tetsuya Akiyama, Joon-Seo Ki

"Recently, an intensive attention has been paid to the electrodeposition of Zn-Cr alloy in the field of the production of super-highly corrosion-resistant alloy plated steel sheets for the next generation. In this study the electrodeposition of Zn-Cr alloys from the sulfate baths was conducted to investigate the codeposition mechanism of Cr with Zn. As a result, Cr was codeposited with Zn at higher current densities in both polyethyleneglycol(PEG)-free and PEG- containing baths. However, PEG made it possible to reduce Cr+ to the metallic state and Cr existed in the form of Cr(III) hydroxide in the deposits obtained from PEG-free bath. The measurements of the partial polarization curve of Zn and the pH in the cathode layer revealed that PEG acted as a polarizer to shift the cathode potential to the reduction potential of the composited hydroxides of Zn and Cr formed due to the pH rise in the cathode layer.1. IntroductionRecently, much attention has been paid to the electrodeposition of Zn-Cr alloys because of its application to the production of super-highly corrosion-resistant alloy plated steel sheets for the next generation1Hl_ Some researches have already tried to commercialize this type of steel sheet. High corrosion-resistance of this steel sheet is brought about by codeposited Cr in the alloys. According to Piontelli's classification5l concerned with metal deposition from aqueous solution, Cr belong; to an inert metal and its deposition is associated with a large amount of hydrogen evolution. Therefore the current efficiency for Cr deposition is extremely poor. It has been also reported that Cr is unable to codeposit in the electrodeposited Zn film in the absence of a certain additive in the solution. 0-compounds group colloids7l, ether group organic compounds8), 9>, peptide based compounds10l, etc., have been found to be effective additives to induce the codeposition of Cr with Zn. However, few studies have been made on the codeposition mechanism of Cr with Zn. In this research, the fundamental electrodeposition behavior of Zn-Cr alloys from sulfate baths was investigated to clarify the codeposition mechanism."

Jan 1, 1998

By Garry Biles, Ken Major, Raj Anand

"Prime Resources Group Inc. (Prime) commenced the Eskay Creek Mine operations in 1994 in northern British Columbia. The ore from the underground mine is crushed and shipped to smelters in Japan and Canada. The nominal production rate is 300 tonnes per day.Before commencing the above operations, preliminary evaluations for the high grade gold mine had indicated that an extremely complex metallurgical and chemical process flowsheet would be required to recover the economic metals. Subsequent to the metallurgical testing program, Prime identified markets for the untreated ore and initiated underground mining and ore transportation operations.Prime recently identified lower grade ore zones, which are less economic or uneconomic to mine and ship directly to the smelters. Test programs were initiated to evaluate processes for upgrading the ore to a marketable product. In 1997, Prime will complete the engineering and construction of a 150 tonne per day flotation plant to concentrate the gold and silver values for the NEX and 109 zones. The mine will then, in addition to the direct shipping of the shippable ore, ship concentrate from the millable ore. This paper discusses the development and design of the flotation plant.IntroductionThe Eskay Creek Mine is located in north-western British Columbia approximately 83 km north-west of Stewart, B.C. as shown in the location map Figure 1. Access to the site is provided by a restricted access gravel road from Bob Quinn Lake junction of highway 37, a distance of about 59 km. The work force at the mine is based on a two-week rotation schedule. Employees are flown from as far away as Vancouver to Smithers by commercial airlines and then from Smithers to the Bob Quinn airstrip by local charter. During poor weather conditions, transportation to site is by vans that take about six hours to travel the 450 km road distance."

Jan 1, 1998

By B. R. Arvidson

Rare-earth elements have some unique properties that are used in many common applications, such as TV screens and lighters. In the 1970's, rare-earths began to be used in a new generation of magnetic materials that have very unique characteristics. Not only were these stronger in the sense of attraction force between a magnet and mild steel (high induction, B), the coercivity (He) is extremely high. This property makes the magnetization of the magnet body composed of a rare-earth element alloy very stable, i.e., it cannot easily be demagnetized.

Jan 1, 1998

Powder River Basin (PRB) mines were originally built to serve power plants designed specifically for their coal. Sulfur was the major concern, with BTU and sodium limiting the market for some. The Clean Air Act has extended the PRB market into plants converting from other coals. These new customers are more sensitive to constituents affecting boiler and precipitator performance. At the same time, the prospect of deregulation is forcing power companies to control cost more stringently than ever. Jacobs Ranch Mine has responded to the changing marketplace with an expanded coal quality and customer service program.

Jan 1, 1998

By Michael J. Nicol

Growing environmental and occupational safety concerns about the use of cyanide in gold processing has increased the interest in more acceptable alternatives. The most likely of these is thiosulfate. However, the thiosulfate process lacks a proven in-pulp method of recovering the dissolved gold, because activated carbon is not effective for the absorption of the gold thiosulfate complex .. Anion exchange resins do offer a possible route for in-pulp recovery. This paper describes work aimed at the evaluation of the effectiveness of commercially available anion exchange resins for the recovery of gold from thiosulfate leach liquors? and pulps. It has been found that strong-base resins are superior to weak-base resins in that they have a larger capacity, which assists in reducing the competition from other anions within a leach solution. Further studies with a selected commercial strong-base resin have shown that competing polythionateanions (particularly tri-and tetrathionate). Lower the maximum possible gold loading but that gold is selectively recovered over other base metal anions in solution. Kinetic experiments found that while? competilig anibns did not affect the initial rate? of gold loading it was important to minimise the contact time of the resin in solution so to prevent displacement of loaded gold by competing anions over longer times. A small-scale resin-in-pulp plant investigation showed gold can be recovered from a leach pulp by a strong-base resin to yield gold loadings of 3000 mg/L, barren pulp containing less than 0.05 mg/L of dissolved gold and. copper loadings of 500 mg/L. Loaded copper was displaced gold and at a loading of 2000 mg/L gold the copper loading was minimal «500 mg/L). The resin was found to recover gold adsorbed on the solids that would, otherwise have. reported to tails if a solid/liquid separation method were used. A patented two-step elution process in which copper and then gold are separately eluted from the resin is also discussed.

Jan 1, 1998

By C. J. Newman

Prior to 1995, the smelting process at the Kennecott Utah Copper Corporation (KUCC) smelter consisted of Noranda reactors and Pierce-Smith converters. In the consideration of expansion opportunities, the existing process did not lend itself to a program geared towards processing the total output of KUCC mining and milling operations. During 1989 and 1990, a number of smelting options were evaluated. The final selection was the Outokumpu flash smelting process, coupled with the new Kennecott-Outokumpu flash converting technology. Facilities were designed and installed to process 1.0 million tonnes per year of copper concentrate, with the ability to expand to 1.2 million tonnes per year. Following the shutdown of the smelter facility utilizing the Noranda technology in May 1995, the flash smelting furnace commenced operation in June with the flash converting furnace startup following a few weeks later. The smelter has achieved design production targets and environmental goals. Current operating rates are at or above design rates for concentrate and matte processing. Emissions are lower than the permit levels and equate to less than 3.5 kg of S02 per tonne of copper. This paper outlines the design, construction, startup and the first two years of operation of the modernized KUCC smelter.

Jan 1, 1998

By T. A. Doyle

Column and batch test methods are used to simulate and model the leaching of various mining by-products. Batch tests are simpler, while column tests more intuitively represent the field conditions to be simulated. Projects that have included different types of leaching tests illustrate the strengths, limitations, and associated uncertainties of each. Column and batch tests have been used to evaluate arsenic solubility in leachate from treated copper smelter flue dust, to simulate the leaching of pit wall rock from a proposed gold mine, and to simulate the release of uranium from aquifer materials.

Jan 1, 1998

By Thomas P. Mucho

Cable bolts are emerging as the newest ?twist? for roof support in U.S. underground coal mines. For decades cable bolts installed in underground metal mines in the United States and Canada used cement-based grouts for anchoring. The cement anchoring process, because of the time and expense for installation, made cable bolts impractical for use in coal mines. Today, the introduction of resin-anchored cable bolts provides a system more consistent with tradi­tional U.S. coal mine roof bolting practices and requirements. Expecta­tions are that the utilization of cable bolts for a number of U.S. mining applications will expand, particularly in coal mining.

Jan 1, 1998

By William E. Torres

The Southern Peru Limited smelter, in Ilo, operates two reverberatory furnaces, seven Peirce-Smith converters, one Teniente Converter, two casting wheels and a single contact acid plant. The Teniente Converter was commissioned in August 1995 and was designed to smelt 744 dry metric tons (820 dry short tons) of concentrate per day. The process off-gas is collected in a water-cooled hood, cooled in a spray chamber, and cleaned in a Joy electrostatic precipitator for further treatment in the Acid Plant. This paper presents the current Teniente Converter operating practices and control philosophy. Relevant improvements and modifications to achieve a 379 day campaign without tuyere replacement and a daily average smelting rate of 862 dry metric tons (940 dry short tons) of concentrate are discussed.

Jan 1, 1998

By D. Duvris

The main objective of this work was to quantitatively investigate exhaust emission levels, as related to maintenance (service) intervals, during the operation of diesel-powered equipment at an underground bauxite mine in Greece. Such emissions depend on a great number of parameters, including the type (technology) and tuning of the engine, the type of work performed as related to the engine workload, suggested maintenance intervals, the altitude, the temperature and the humidity of the atmosphere of the underground mine, the properties of the fuel, the operator's training and experience level. Necessary ventilation quantities were calculated based on exhaust gas concentration measurements, site specific relationships between pollutants and adjusted air quality indices. Diagrams comparing necessary and recommended air flow for several equipment groups featuring two engine types and for different maintenance intervals are presented.

Jan 1, 1998

By J. S. Lee

Alkyl hydroxamates are well known collectors for oxide copper minerals as evidenced by the large amount of published literature. Our studies on a wide variety of copper ores from around the world have shown that alkyl hydroxamates will recover most of the "floatable" oxide copper minerals from an ore. They are available commercially, and they offer many advantages over alternative technologies for oxide copper recovery. In spite of this, the full potential of hydroxamates has not been exploited in the industry. The objective of this paper is to provide relevant practical aspects and guidelines to facilitate successful application of hydroxamates in operating plants. A critical analysis of the available information and data, based on several case studies, notation testing, and microscopic analysis indicates that alkyl hydroxamates can effectively recover well-defined oxide minerals of copper, but not copper occurrences such as Cu-bearing goethite (often misidentified as cuprite) which report as Acid Soluble copper in chemical assays. Prior to any notation testing with hydroxamates, it is necessary to assess the various modes of occurrence of Acid Soluble copper using microscopic and microprobe analysis.

Jan 1, 1998

By Paul Shimizu

BHP Robinson contracted Minnovex Technologies to implement a Comdale Expert System at their greenfields operation in Ely, Nevada. The expert system has resulted in a significant increase in tonnage. Other benefits have also been realised, including a reduction in operation upsets (having a positive effect on downstream processes, i.e. flotation) and reduced production variances between crews. The expert system is written in a unique manner using trend based logic with minimal hard limits. The result is a robust system that requires minimal operator supervision while producing very high results. The development, success and acceptance of the system can be attributed to the strong team that was assembled for this project. The team not only consisted of BHP Metallurgists and Minnovex but most importantly included operations.

Jan 1, 1998

By S. Nygren

Nalco Chemical Company and a North Carolina Phosphate operation have formed a successful supplier/customer team effort that has resulted in major improvements in the operation of the clay thickening circuit at the Aurora, North Carolina concentrator. A Nalco OPTICUS® Automated Process Control System for thickener and flocculant control was installed in 1994. The paper will discuss in detail the development and refinement of the OPTICUS system over the past three years. The paper will survey the development and networking of process control for monitoring, controlling and operating four 325-foot Dorr-Oliver thickeners, three 80-foot high-rate Enviro-Clear thickeners and control links to the facility's clay/gypsum blending operation.

Jan 1, 1998