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By R E. Myers, G N. Phillips

Many of the worldÆs larger iron ore deposits are hosted by rock sequences of Archaean to early Proterozoic age. Most models for the genesis of these deposits are influenced, either directly or indirectly, by the nature of the atmosphere at the time of their formation, and more specifically by the presence or absence of oxygen in the early atmosphere. Since the early-1950s, the geological literature suggests that the Archaean atmosphere was æreducingÆ, and that it may not have contained significant amounts of free oxygen until ca 2 Ga. There are many different definitions of the term æreducingÆ, but the criterion adopted here is whether crustal iron was limited to Fe2+, or whether Fe3+ was also widespread, ie was there scope for redox changes in the state of iron? Significantly, major Australian banded iron formations span this period of inferred atmosphere transition, eg Mt Goldsworthy, Mt Tom Price, Middleback Ranges. Geological evidence for a reducing Archaean atmosphere is both ambiguous and controversial (see review by Phillips, Law and Myers, 2001). Many earlier ideas (eg no Archaean redbeds; all very large iron ore deposits being post-Archaean) have been disproved by dating, whereas other evidence (eg homogeneous detrital gold grains, inferred palaeosols) has not withstood geological scrutiny. The interpretation of some data sets (eg inferred detrital uraninite and pyrite in some Archaean meta-sedimentary rocks) is still controversial. In fact, some lines of evidence now suggest that oxygen was present in the atmosphere well before 2.5 Ga (eg sulfates in the Pilbara craton, carbon distribution in clastic sedimentary rocks). An oxidising Archaean atmosphere has important implications for the development of iron formations. First, the atmosphere is an obvious potential source of oxygen to stabilise ferric iron minerals. Second, reduced fluids in equilibrium with ferrous iron are commonly inferred to transport iron in solution to the depositional site. The redox state of the atmosphere thus provides critical constraints on the solution chemistry of surface waters, effective transport paths for iron and particularly on viable precipitation mechanisms. Iron formations developed from fluids in equilibrium with the atmosphere also have the potential to provide important constraints on the evolution of EarthÆs early atmosphere. If an oxygenated atmosphere is a necessary condition for the development of iron formations, then the Archaean atmosphere must have been oxidising since at least 3.5 Ga. If the redox state of the atmosphere is not a necessary condition, then the time distribution of iron formations cannot be used to provide constraints on atmospheric evolution. Given these uncertainties, models for the genesis of iron ore deposits of Archaean or early Proterozoic age should not rely on a reducing atmosphere in the absence of independent evidence and the alternative of an oxidising atmosphere should also be considered.

Jan 1, 2002

By Christian Divis

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Jan 1, 2002

By Junji Shibata

Zeolite synthesized from coal fly ash has many intelligent properties such as cation exchange, adsorption, catalyst and so on. The suitable use of the zeolite, however, is not established in an actual commercial scale yet. From the viewpoints of an effective usage of coal fly ash and the zeolite obtained from coal fly ash, we propose the new concept for environmentally friendly usage of zeolite, in which coal fly ash safely returns to the soil with growing plants and purifying wastewater. This method can make great contribution to recycle of coal fly ash, to purification of high nutritious water and to tree planting.

Jan 1, 2002

More and more coal in Australia is extracted by underground mining methods especially by longwall mining. These methods can be particularly sensitive to relatively small-scale structural discontinuities and variations in roof and floor rock character. Traditionally, information on these features has been obtained through drilling. However, this is an expensive process and its relevance is limited to the immediate neighbourhood of the boreholes. The geological uncertainty remains. Seismic surveying, especially by 3D seismic, is an alternative tool for geological structure delineation with growing credibility. In fact, it is one of the most effective geophysical methods available for identification of geological structures such as faults, folds, washouts, seam splits and thickness changes which are normally associated with potential mining hazards. Seismic data even can be used for stratigraphic identification. The information extracted from seismic data then can be integrated into mine planning and design. In this paper, we demonstrate computer aided interpretation techniques for maximising the information from seismic data and illustrate the ability of seismic reflection methods to resolve localised geological features. Both synthetic and real seismic data obtained in recent 2D and 3D seismic surveys from Australian coal mines will be used. Compared with results obtained with drilling programs, the structural definitions from seismic are of unprecedented quality.

Jan 1, 2002

By Wolfgang G. Brunner

Mai- Liao, in Yun Lin province of Taiwan, which was once a remote area on the coast of the South China Sea, has been developed into an offshore industrial complex. Approximately 100 million m3 of imported sand fill were used to reclaim the site from the sea with an overall area of almost 3.000 hectares. Land reclamation started in March 1994 and was completed at the end of 1998. A total of 41 industrial plants were constructed on the site, including an oil refinery, a naphta cracking plant, a cogeneration plant, a coal- fired power station, a heavy machinery plant, a boiler making plant, water purification plant, several petrochemical plants and a new harbour. From 1998 onwards, new plants were taken into operation in uninterrupted succession. The main purpose of the ground improvement by vibro- displacement, used predominantly to form the foundations of the oil storage tanks , was to reduce the liquefaction potential of the subsoil during earthquakes. The top layer across the site was treated by dynamic compaction before the installation of the stone columns. Heavy structures such as chimney- stacks and buildings were constructed on pre- cast concrete piles driven by diesel hammer. The earthquake design criteria specified an earthquake magnitude M = 7.3 and an acceleration a = 0.21 g. Stone columns were installed by the dry bottom feed process, which was controlled by an automatic monitoring system, to depths ranging from 13 to 20 m to provide flexible tank foundations. Installation of 1.500.000 linear m of stone columns commenced at the beginning of 1997 and was completed in August 2000. 60 % of the stone columns, in particular the deep ones, have been carried out by Bauer vibrators. The Chi- Chi earthquake ( M = 7.3 ) took place on 21 September 1999 and was followed by Cha- I earthquake ( M = 6.8 ) on 22 October 1999. A survey carried out after these earthquakes showed very positive results. The maximum observed settlement was 10 mm and none of the tanks suffered any damage.

Jan 1, 2002

By Tim Ross

J. M. Huber Corporation's Quincey Mine. an underground limestone mine located near Quincy. Illinois, has operated successfully and safely for many years utilizing roof bolts on a very limited basis. Over the years, the mine had experienced several rool falls that did not result in injury to personnel. Nearly all of the roof falls were limited to the first 2 feet of the massive limestone roof. Investigation of the falls indicated the major contributing factor to these roof falls was a randomly occuring thin. horizontal clay layer in the immediate roof. Over time, separation would occur at the clay layer. causing the root to sag. and eventually causing the root to fail. J. M. Huber Corporation contracted with NSA Engineering. Inc. to assist in a study to determine the effectiveness of Ground Penetrating Radar (GPR ) for locating these potential root fall areas so that mitigating action could he taken prior to roof failure. Multiple tests were conducted in areas of known roof conditions. GPR accurately predicted the existence or absence of root separation up to 1.5 meters into the immediate roof for 100 % of the known lest site conditions. As a consequence of this successful studs, J. M. Huber Corporation has used GPR to evaluate roof conditions at both its Quince and Marble Hill Mines.

Jan 1, 2002

By V. I. Kefeli

Public-private partnership efforts are working to create green landscapes from abandoned industrial sites. Fabricated soils, potentially an essential element of such landscapes, are designed to substitute for topsoil on the areas free from ground cover and plant community. The aluminosilicate matrix and humus form the soil micelle - the primary unit of any soil complex. Humus formation is a process based on carbon-nitrogen interaction. Sources of carbon can be materials rich in easily composted products like cellulose and polyphenols (plant leaves) or aged lignin polymers (saw dust from different woody plants). The pathways of carbon-nitrogen complexes are discussed. Properties of the fabricated soil components were examined by bio-tests and plant models.

Jan 1, 2002

By Zhijing Zhang

The management of hazardous wastes is important in a society which is increasingly concerned with environmental issues. Incinerators such as the slagging rotary kiln are widely used in the treatment of hazardous wastes. However, in order to assure a smooth operation of the rotary kiln, the melt should have both a low melting point and high fluidity. In this study, the fluidity of various hazardous waste rotary kiln slags was measured in terms of length of flow using the crucible test technique. It was found that the slags have melting points ranging from 1372 to 1424°C while their fluidities varied from 61-102 mm. The effect of addition of oxides on the fluidity of a slag containing 47 wt% SiO2 was also investigated. For this slag, additions of SiO2 (up to 56 wt%), FeO and Na20 increased fluidity, whereas the addition of CaO and A1203 resulted in lower fluidity values.

Jan 1, 2002

By Miklós Kovács

A new type of the cast in situ piles is introduced. The installation of the new pile is based on a pushing in/gaining back procedure. A temporarily closed tip element with square shaped cross-section being attached to an upper circular shaft tube is vibrated into the soil. The steel armature is embedded. Concrete is poured into the tube and, the whole structure is gained back while the tip is in opened position. The width of the tip is less than or equal to 40 cm. The maximum length of the pile is about of 14 m. Great bearing capacity is resulted from the double soil compaction effect. No spoil is generated and, the pile construction can be controlled. The paper presents the results of four loading test at three sites with some soil data.

Jan 1, 2002

By Salim Mezazigh

Usually different methods for designing a single pile submitted to a lateral loading are available. They are based on theory of elasticity with the parameters E,v or subgrade reaction method using the p-y curves. The subgrade reaction methods are commonly used. They allow determining the efforts exerted along the piles and their corresponding displacements. Before any design the reaction curves P-y must be well defined for each foundation soil layer. These curves link the pile horizontal displacement y to the subgrade reaction of soil P. Different in situ tests such as the static penetrometer or the pressuremeter give a possibility to get the P-y curves in the case of a single pile installed in sand with an horizontal surface and statically laterally loaded. These ideal conditions are not always respected on the site around the pile if appear slopes, embankments, or buildings... The behaviour of such configurations of piles is more sophisticated due to the proximity ( slope, embankment, earthworks, buildings,..). A research program has been conducted to determine the influence of a slope on the P-y curves by centrifuge modelling. The centrifuge tests constitutes an experimental approach allowing parametric studies in respect with similitude laws in geotechnique. Before all, repeatable tests have demonstrated that the test conditions, the instrumentation equipment and the installation method for piles are well controlled. By this way, the obtained results from centrifuge tests can be transferred to the prototype i.e. the in situ piles. Many tests have been performed on piles in sand to determine the influence of a pile on the p-y curves. The main objective is to give for practice some coefficients to apply to p-y single pile curve to take into account the proximity slope effect. Here the experimental set up is described and in particular the proximity slope effect is discussed. Deduced subgrade reaction reduction factors are proposed for piles in sand under lateral loading.

Jan 1, 2002

The 3.5 million tones per annum Enterprise mine is the newest underground copper mine at Mount Isa in northern Australia. At a depth of up to 2000 metres, it is the hottest and deepest mine in Australia. In situ rock temperatures sometimes exceed 60¦C requiring the installation of substantial amount of refrigeration to provide safe working conditions for mine workers. The latest refrigeration project at the mine, R67, required the design and installation of the worldÆs largest bulk air cooler and AustraliaÆs largest chilled water plant. The plant is mounted on the surface of the mine and provides 25 MW of refrigeration to cool some 580 kg/sec of ambient air to 11.4¦C. This is equivalent to the production of 6300 tonnes of ice per day. The plant was designed for high availability, as any downtime would result in substantial production losses to MIM, and also had the potential to quickly result in unsafe levels of heat stress within the underground workplaces. The bulk air cooler has been designed for a capacity of 34 MW(R), the expected ultimate carrying capacity of the 7 m vertical intake shaft. Being located well inside the tropics, technical issues such as control of thermal pulldown required special consideration. Also, the bulk air cooler had to be designed to handle whatever demand for fresh air was imposed by the mine below, with over 100 per cent variations in airflow expected, and without loss of thermal efficiency. A substantial program of risk assessment and HAZOP studies was used to protect underground miners from leaks of ammonia into the air or water circuits. Fully automatic control systems result in a totally unmanned plant that is supervised remotely. To improve efficiency, the plant is controlled by the outlet air temperature from the bulk air cooler û the first in the world to be controlled in this fashion. Engineering solutions to address environmental considerations were incorporated at the design stage through features such as the use of ammonia (a greenhouse-friendly gas) as the refrigerant, zero atmospheric discharge and a wastewater collection and re-use system.

Jan 1, 2002

By D Kay, M Lovitt

Mass Blasts are generally required at the completion of longhole stoping cycles to maximise the recovery of ore from a specific orebody. During the course of mining, the practice is to leave pillars of ore to support the opening left by extracted ore and to mitigate stresses from working areas of the stope. These pillars usually contain ore that has been included in the resource evaluation and is highly valuable to the mining operation. Due to their stressed nature, the removal of pillars by conventional blasting techniques, through small blasts, can result in pillars being reduced beyond their critical size and ultimately failing, rendering the ore unrecoverable. The AurionGold Kanowna Belle Gold Mine operates a Mine to Mill philosophy. This philosopy requires the fine tuning of blasting to provide the best possibe ore feed at the highest grade for mill productivity. This means that ore to the mill must be well fragmented from blasting that provides high extraction rates from draw points, with minimal dilution from overbreak or fall off, and sized to maximise SAG mill throughput. The AT04 Mass Blast contained significant ore reserves which were required to meet gold production targets. KBGB needed the AT04 Mass Blast to perform as well as if not better than conventional stope blasts to maintain mill production. This paper describes the circumstances, planning philosophy, techniques, including the use of Electronic Initiation Systems and Bulk Emulsion Explosives, and results that provided a highly successful outcome.

Jan 1, 2002

By A Sinuhaji, R Poedjono, G Flumerfelt

PT Freeport Indonesia is currently building the DOZ mine. It is a 25 000 tonne/day block caving operation which is scheduled to reach designed production levels by the fourth quarter of 2002. This paper describes some of the issues and challenges faced by the operation when introducing a new undercut method part way through the project. Advantages and disadvantages are discussed as well as the expected benefits of the new method.

Jan 1, 2002

By Timothy F. McConachy

Between April 2000 and April 2002, the Commonwealth Scientific and Industrial Research Organization (CSIRO) Division of Exploration and Mining has led 6 research expeditions totalling 160 days ship time in waters of Papua New Guinea, Vanuatu, Solomon Islands, Indonesia and Australia. Five expeditions were undertaken aboard the Australian research vessel Franklin following successful competitive research proposals, and the sixth used the Indonesian vessel Baruna Jaya VIII (see Table 1). In addition, two CSIRO participants joined JOIDES Resolution for the Ocean Drilling Program Leg 193 in the Manus Basin of PNG. The major scientific objective underpinning these expeditions was to locate and study present-day seafloor and sub-seafloor hydrothermal ore-forming activity in order to develop improved methods of exploring for ancient mineral deposits on land that originally formed by similar processes. The research has been supported financially by a number of Australian-based mineral companies, by Australian international aid agencies, and by appropriation funds from CSIRO, and was conducted in collaboration with researchers from Australia, Indonesia, Portugal, New Zealand, United States of America, South Korea, and the host nations. Building upon earlier successes in the 1986-1997 PACLARK-PACMANUS programs in the Woodlark and Manus Basins of PNG, we have sought to examine a wider range of geological settings in which ancient orebodies are inferred to have formed, including both volcanic and sediment-hosted environments. We have now visited volcanic arcs, fore-arc and triple-junction related submarine volcanoes, and back arc basins associated with convergent plate margins in the SW Pacific and SE Asia, as well as conceptual Mississippi-Valley-type targets associated with warm seeps at passive margins in the Great Australian Bight (see Figure 1). Surveys ranged from northern Sulawesi via far western Bismarck volcanic arc near PNG-Indonesia border, through the eastern Manus Basin and the Tabar-Lihir-Tanga-Feni chain in PNG, the western Solomon Islands festoon, the San Cristobal arc, parts of the Vitiaz arc, to the northern and southern New Hebrides arc in the Solomons and Vanuatu.

Jan 1, 2002

By C E. J de Ronde, I C. Wright

Oceanic subduction-related volcanic frontal arcs extend over 20 000 km within the western Pacific basin and over 21 500 km worldwide, yet they remain largely unexplored with respect to active seafloor mineralization. Systematic exploration of 26 major submarine volcanoes along ~840 km of the Kermadec arc northeast of New Zealand has documented ten (39 per cent) as being hydrothermally active. This frequency of venting is comparable to that on slow-to-moderate rate spreading mid-ocean ridges, which comprise ~80 per cent of the 60 000 km-long global system of spreading centers. The chemistry of fluids discharged from the Kermadec arc volcanoes is moderated by magmatic components in both the gaseous (CO2 + SO2-H2S) and liquid (Fe) phases at very high concentration.The high frequency of venting coupled with chemically rich discharge discovered during this first systematic survey of any arc system forecasts submarine arcs as being important sources of chemicals to the oceans and as potentially lucrative exploration sites for seafloor mineralization. The exploration protocols developed during these surveys include bathymetric mapping of mostly unknown volcanic edifices, followed by detailed water column profiling and sampling to detect and characterize volcanic fluid emission signatures. These procedures are being refined as the survey progresses, both for efficiency and as direct seafloor observations become available for predictive application of water column plume information to guide seafloor mineral exploration.

Jan 1, 2002

By B Morey, J Gordon, P Mackenzie

Mount Tom Price Mine is peerless amongst Rio Tinto iron ore resources around the world. It has provided Hamersley Iron with premium quality, high lump yield haematite ore over the last four decades. The Brockman type bedded ore, containing bands of haematite and shale of varying thicknesses has been traditionally bulk mined to either high-grade or low-grade based on alumina cut-off grades. As open pit mining has progressed deeper into the orebody approaching the keels of the megastructure, increased structural complexity, chemical and physical variations in the ore, unfavourable ore presentation and reduced blending options have become an issue for grade control and may have serious impacts on product stockpiles. The grade blocks and boundaries must be accurately defined according to geological contacts and where identified, selective mining may be applied. Therefore in-pit geological mapping is the definite and ultimate guide to achieve target grades and grade predictions. Under this scenario, it is absolutely vital that the mine geology team ensures this geological knowledge is passed onto the related departments including mining crews as well as to the short- and long-term planners.

Jan 1, 2002

Acid mine drainage (AMD) forms when sulfide minerals are exposed to oxidizing conditions in coal and metal mining, highway construction, and other large-scale excavations. Iron sulfides common in coal regions are predominately pyrite and marcasite (FeS2), but other metals may be complexed with sulfides forming chalcopyrite (CuFeS2), covellite (CuS), galena (PbS), and sphalerite (ZnS). Pyrite commonly occurs with these other metal sulfides thereby causing AMD where Cu, Pb, and Zn are mined. Upon exposure to water and oxygen, sulfide minerals oxidize to form acidic, sulfate-rich drainage. Metal concentrations in AMD depend on the type and quantity of sulfide minerals present. The drainage quality emanating from underground mines or backfills of surface mines is dependent on the acid-producing (sulfide) and alkaline (carbonate) minerals contained in the disturbed rock. In general, sulfide-rich and carbonate-poor materials produce acidic drainage. In contrast, alkaline-rich materials, even with significant sulfide concentrations, often produce alkaline conditions in water. Approximately 20,000 km of streams and rivers in the United States are degraded by AMD. About 90% of the AMD reaching streams originates in abandoned surface and deep mines. Since no company or individual claims responsibility for reclaiming abandoned mine lands (AML), no treatment of the AMD occurs and continual contamination of surface and groundwater resources results. The oxidation of iron disulfides and the generation of acidity occur through several reactions (Stumm and Morgan, 1970). The chemical equations can be found in Caruccio and Geidel (2000). If any of the processes represented by the equations were slowed or altogether stopped, the generation of AMD would also slow or cease. The equations show that 1000 Mg of rock containing 1% sulfur, all as pyrite, would yield upon complete reaction 31.25 Mg of acidity. Therefore, 31.25 Mg of 100% CaCO3 would be required to neutralize the acidity. The alkaline content of overburden determines whether there is enough neutralization potential (NP) to counteract the acid produced from pyrite oxidation. Of the many types of alkaline compounds present in rocks, only carbonates and clays occur in sufficient quantity to effectively neutalize AMD. A balance between the acid-producing potential and neutralizing capacity of an overburden sample will indicate the ultimate acidity or alkalinity that might be expected in the material upon complete weathering. Accurate prediction and control of AMD before surface mining require an understanding of three important factors: 1) overburden geochemistry, 2) method and precision of overburden handling and placement in the backfill during reclamation, and 3) the postmining hydrology of the site.

Jan 1, 2002

By Robert H. Hsu

Palladium finely dispersed in a substrate of kieselguhr, Pd/k for short, has been successfully used for hydrogen storage, separation and pumping for a number of years at the Savannah River Site (SRS). Recently SRS has developed a new pd/k flow through bed (FTB) prototype for separating hydrogen from other gases and simultaneously storing the hydrogen on palladium. The FTB uses single-pass liquid nitrogen cooling during hydrogen absorption/separation/storage and electrical heating for desorption/unloading of hydrogen. Fourteen absorption-desorption or loading/unloading cycles using hydrogen have been conducted with the new FTB prototype. Test results show that all design performance objectives have been successfully achieved: recover 295% of hydrogen gas from feed gas, produce 99.9% hydrogen product gas and < 5% hydrogen in discharge gas. This paper will discuss characteristics of the palladium-coated kieselguhr or diatomaceous earth, design and operation of the FTB, and results of performance tests such as separation efficiency, hydrogen storage capacity and system heat transfer characteristics.

Jan 1, 2002

By Mark R. Svinkin

Construction vibrations may adversely affect surrounding buildings and their effects range from human discomfort and disturbance of sensitive devices to visible structural damage. There is no unique conclusion regarding the effect of construction vibrations at every site. Measurement is usually made to monitor vibrations and control them with the vibration thresholds for disturbance of sensitive objects as well as damage to structures. To prevent potential litigation and mitigate the vibration effects on sensitive devices, people and structures, it is necessary to manage and minimize vibration problems before the beginning of construction activities or installation of vibrating machine foundations, and during construction. Pre-construction damage survey and engineering vibration investigations, including the prediction of anticipating vibrations, have to be made at most construction sites in advance of construction activities. Vibration monitoring and control have to be provided during construction. The instrumentation feedback of vibration prediction, monitoring and control provide the basis for choice of measures to prevent or mitigate vibration problems and settlement damage hazards.

Jan 1, 2002

By K Osman, P Bennett

The mining of an underground orebody requires development both in waste and ore before stoping commences. Regardless of what metal is being extracted, the waste development is minimised to reduce the cost per unit of metal mined. At the Western Metals Zinc Kapok mine site, reducing the cost per tonne of lead and zinc mined is paramount. Decline waste development costs can be minimised by methods such as increased gradient or reduced drive size. Ore development will also involve some mining of waste. The degree to which waste mining can be minimised will depend on the thickness and dip of the orebody. The drive geometry will also determine the percentage of waste within the face. It is by mining methods such as resue mining that selective mining may be used to maximise the amount of metal mined and reduce waste dilution. Resue mining can be used around a set of selection criteria established by the mine site. These selection criteria will determine how resue mining can be applied to the mine site. Selection criteria include firing times, number of headings available, acceptance criteria for percentage lost metal, dilution and most importantly operator acceptance. The single pass or two pass resue mining method should be chosen depending on the site acceptance criteria and selection criteria. The Western Metals Zinc Kapok mine site has established a set of parameters which accept the two pass resue mining method for the mining of the ore drives. The blasting results from a single pass resue method were reviewed during more recent trials in a single heading. Through a comparison of results, the parameters allowed the decision to determine the applicability of resue mining and its current form to Kapok. This paper outlines the parameters set by the Kapok mine site, reviews these in relation to the two forms of resue mining and examines the criteria which make this mining method applicable for Western Metals Zinc.

Jan 1, 2002