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By Larry A. Cramer

"Three primary drivers are setting the trend for base and precious metal processing . they are: continued low real base metal prices, environmental concerns, and continued high prices for PGM.s. Low base metal prices are increasing the search for economies of scale and company consolidation as well as the development of some hydrometallurgical technologies. Environmental concerns are pushing for continued reductions in SO2 emissions and hydrometallurgical technologies. The high prices for PGM.s are driving major expansions and a focus on minerals processing recoveries and, to a lesser extent, reductions in the refining metal lockup.In nickel, HPAL operations on laterites have failed economically but Inco is still pursuing some alternatives. BHP-Billiton and others are developing bioleaching alternatives for nickel laterites and sulphides.Copper continues to be dominated by the hydrometallurgical and pyrometallurgical debate; new hydrometallurgical developments are being tested at several sites whilst the pyrometallurgists continue to make competitive cost and environmental improvements.Gold processing developments are dominated by the use of improved gravity recovery equipment and by the development of thiosulphate as a more environmentally acceptable lixiviant.PGM processing trends are the use of fine grinding technologies, higher power input flotation cells, and new pyrometallurgical technologies. Hydrometallurgical options for some applications are being sought.OVERVIEW The metals industry has remained under price pressure for some time; low and decreasing real prices for most metals have become an expected scenario. Occasional price spikes give some relief but invariably bring expansions and new entrants into an already oversupplied commodity market, thus leading to the continued price pressure. Technical innovation, economies of scale, and improved work systems are continually sought, so as to improve the competitive position of each individual company in such a climate; however, these developments add to the downward price pressure. In such a situation the application of scarce funds to research and development is a difficult task. Excess funding is not available in tight economic times and yet the main route to higher profits is clearly the application of technical developments to lower the cost of producing a metal commodity. Many technical centers have closed as a cost saving exercise and some have coalesced to obtain economies of scale. The Australian based AMIRA research organisation has grown to serve the R&D part of the market well in Australia and in South Africa by acting as the catalyst to form research partnerships between a number of industry players and as an administrator to direct the funding of research projects towards the various applicable research institutions. AMIRA has developed closer ties to Camiro (Canadian Mining Research Organisation) through the appointment of Camiro.s metallurgical processing research director as AMIRA.s North American based director. AMIRA is continuing discussions with MIRO (Minerals Industry Research Organisation) in regard to a merger, with a report outlining the merger proposal expected in March of 2003. Company focused research centers continue to be effective at Anglo American Research Labs, Teck-Cominco Research, Falconbridge Research center, Inco Research and some others."

Jan 1, 2003

By K. W. Stöckelhuber, A. Wenger, H. J. Schulze

"An important elementary step of the flotation process is the forming, drainage and rupture of a thin intervening liquid film between bubble and mineral particle.After the encounter of the bubble with the solid surface a wetting film is formed. The initial thinning of this film is driven by the capillary pressure inside the bubble. When the film has reached a certain thickness rupture can take place. There are two possible mechanisms describing this process:(a) Gas nucleation, caused by nano bubbles inside the film.(b) Growing fluctuation waves (spinodal dewetting) on fluid interfaces under the influence of any kind of attractive forces (electrostatic, van der Waals).Metastable wetting films on negatively charged, hydrophobic glass surfaces (gaseous phase methylated), or on hydrophilic, positively charged glass surfaces (with Al3+ ions), have been analysed by means of the kinetics of film thinning according to the Reynolds law. These experiments demonstrate that both mechanisms can be responsible for the rupture of a thin wetting film."

Jan 1, 2003

By Johan Nell, Paul den Hoed

"Carbochlorination tests were conducted with matched particle-size fractions of rutile, ilmenite and hightitania slag in a small bubbling fluidized-bed reactor. The effects of temperature, the type and proportion of solid reductant in the charge, and the fraction of Cl2 in the fluidizing gas were investigated. Tests confirm the need for solid carbon in the bed if chlorination is to run at high rates. With solid carbon in the bed, CO supplied with the fluidizing gas does not increase significantly the degree of chlorination after 75 minutes.When large proportions (30 wt%) of carbon are added to the charge, then the reactionTiO2 + 2C + 2Cl2 = TiCl4 + 2COis favoured overTiO2 + C + 2Cl2 = TiCl4 + CO2Ilmenite is chlorinated more quickly than titania slag, which in turn is chlorinated more quickly than rutile. Rates of chlorination at 1100°C and 1000°C are much the same and significantly higher than at 900°C. Chlorination is associated with significant increases in particle porosity (even for rutile), which is brought about by the rapid initial chlorination of FeO and MnO (in ilmenite and slag) and (it is argued) by the chlorination of Ti2O3 which forms at high-energy surface sites."

Jan 1, 2003

By Neill Bartie, Jacques Eksteen, Sharif Jahanshahi, Shouyi Sun

The gradual increase in Cr2O3 levels of UG-2 ores has become a matter of concern for platinum producers in South Africa due to the formation of chromite spinels in melters. The effect of bulk FeOx/MgO ratio, Cr2O3, temperature and oxygen partial pressure on phase stability and composition in the system FeOx-MgOSiO2- Cr2O3-Al2O3-CaO has been studied between 1400°C and 1600°C using the drop-quench technique. An increase in temperature was found to result in a decrease in [Fe/Cr]spinel. An increase in bulk FeOx/MgO caused Mg, Al and Cr in spinel to decrease, forming more magnetite relative to other spinels. [Fe]spinel decreased and [Cr]glass increased with a decrease in oxygen partial pressure.

Jan 1, 2003

Jan 1, 2003

By Volker Vogt, Wolfgang Sand, Eberhard Gock

"It was discovered that the selective activity of bacteria during the extraction of raw material concentrates by means of flotation could also be achieved with extracellular polymeric substances (EPS) excreted by bacteria. EPS, which is extracted by means of centrifuging bacterial cultures, can help to significantly reduce the use of cyanides, approximately 200,000 t/a of which are used for ore dressing today.The bacterium used was Acidithiobacillus ferrooxidans. In order to identify the bandwidth of the oxidation activity, 20 bacterial strains of the strain collection of the University of Hamburg were attracted to iron(II) sulfate and pyrite under defined conditions. All strains oxidized iron(II) sulfate ten times faster than pyrite.EPS has so far been derived from four strains. In general, EPS extracts are divided into a hydrophilic and a hydrophobic fraction. The hydrophilic fraction is composed of e.g. fucose, rhamnose and glucose; fatty acids such as dodecanoic acid, hexadecanoic acid, octadecanoic acid and nonadecanoic acid were found in the hydrophobic fraction.Pure mineral phases and mineral mixtures were used for the flotation tests. As opposed to current knowledge, the results were reproducible with technical flotation machines."

Jan 1, 2003

By Chris A. Fleming

"The ability to recover cyanide from gold plant tailings has been known almost as long as the cyanidation process has been practiced, but there has been little incentive to process tailings in this way in the past. With the development of technologies that make it possible to recover and recycle free or complexed cyanide directly from gold plant slurry tailings, which indicates, on paper at least, significant cost savings compared to cyanide destruction, coupled with the introduction of legislation to seriously limit the discharge of cyanide to the environment in most gold-producing regions of the world, many companies are evaluating the cyanide-recovery alternative.There is arguably an even more compelling reason for mining companies to consider cyanide recycling. With the growing storm of negative public opinion that the use of cyanide in the mining industry is attracting - following several highly publicized spills over the last couple of years - the time has come for the gold industry to demonstrate environmental diligence and stewardship in the use of this commodity that is so vital for their industry. There is no doubt that the widespread implementation of cyanide recycling will reduce the impact of the cyanidation process on the environment, both by reducing the risk of spills (with less cyanide being transported from manufacturing plants to gold mines), and by reducing the loading of toxic and nontoxic metals and ions in the tailings.This paper briefly discusses the pros and cons of the different processes that are available for the treatment of gold plant tailings to regenerate and recovery cyanide for recycling, and presents a techno-economic argument for the incorporation of this technology into many gold plant flowsheets today."

Jan 1, 2003

By M. Wright, A. H. Mwale

This paper examines the combination of unit technologies in a minerals beneficiation train, and explores the inter-relationship between energy input and water consumption for a given mineralogy and product recovery, as these are two critical environmental issues which affect the overall viability of many minerals plants. In particular, we review constitutive relationships for each of the sub-processes of comminution, flotation, and tailings dewatering, and suggest how these might be integrated into a unified hybrid model, with particle size distribution as the key design variable. Such a model can then be used to explore the trade-offs between different performance objectives (be these technical, economic or environmental) as part of a multiple-objectives optimisation exercise. In this way, it may become practical to envision situations in which concentrate grade and recovery are sacrificed, marginally, in order to reduce energy demand in comminution, and improve overall water recovery. This becomes more relevant as the industry commits to advancing the sustainable development agenda in the face of the increasing life -cycle costs and impacts of minerals processing operations, coupled to declining ore body grades, and the desire to maximise recovery of minor and trace elements. Some specific observations for copper are offered.

Jan 1, 2003

By Fiona Sofra, Briony C. Ruse, David B. Boger

"The sustainability of the mining industry must be addressed through improving tailings management. The use of thickened tailings and pastes stems from a paradigm shift towards designing tailings disposal sites to suit their surrounding environment, rather than manipulating the environment to accommodate the tailings. Thickened tailings and pastes usually exhibit non-Newtonian behaviour, so a thorough understanding of the rheological characteristics of the material is required in order to determine the disposal plant operating conditions.Full Cost Accounting techniques may be used to provide financial justification for the implementation of alternative tailings disposal techniques through the calculation of a disposal cost per tonne of tailings over the life of the facility. Improved disposal methods such as thickened tailings disposal involve additional initial capital expenditure but reduce environmental impacts. The cost savings associated with environmental impact mitigation are reflected in Full Cost Accounting outcomes.Rheological characterisation is significant as a design basis that may be analysed using Full Cost Accounting to justify the initial capital expenditure of dry disposal systems for improved environmental performance."

Jan 1, 2003

By R. Sharon, P. M. Hawley, X. Ochoa

"Development of Barrick Gold’s Pierina gold mine in north-central Peru requires construction of a waste dump for disposal of nonore grade materials stripped from the open pit to expose the ore. The waste dump site is located near the open pit in a U-shaped valley that is underlain by thin colluvial and morainal soils with locally thick peats and glaciolacustrine deposits. Bedrock underlying the site consists of variably weathered volcanics. The site is subject to moderately high seasonal rainfall and significant seismicity. The geotechnical quality of the waste rock is highly variable, ranging from low-quality, degradable, soil-like materials containing appreciable quantities of silt and clay, to high-quality, hard, durable, blocky waste rock.A hybrid dump design concept was developed that requires in-pit segregation of highand low-quality waste, and selective placement of materials in the dump to maximize stability and enhance internal and subsurface drainage. The design includes a rock drain beneath the dump along the axis of the valley and a series of connected finger drains. Extensive peripheral diversions and stormwater control measures to inhibit infiltration of precipitation are also included.This paper discusses the unique challenges presented by the site and waste materials, the design methodology and stability analyses, and planned monitoring systems."

Jan 1, 2003

By John C. Gathje, Rick Moritz, Wilhelm de Beer

"Froth flotation has a long history of success for the recovery and concentration of a wide variety of minerals of commercial interest. Both the art and science of flotation have progressed greatly, and as our knowledge has increased so has our ability to improve mineral separations and recoveries.One area of interest in recent years has been the flotation of refractory gold ores to recover the gold-bearing sulfides. In many instances, the use of conventional air flotation to concentrate these values has achieved only limited success. However, as a result of intensive research, Newmont Mining has expanded the boundaries of flotation, and it can now be used to successfully treat many gold-bearing sulfide ores as well as platinum and palladium ores. This has been achieved through the use of the N2TEC technology, which utilizes nitrogen as an inert gas in the flotation process.Laboratory and pilot plant investigations and a commercial plant have proven its worth. Compared to air, the patented N2TEC process has increased the gold recoveries of many ores by 5 to 15 percentage points, and improvements of an even greater magnitude have been observed. This paper describes the process development for the flotation plant now being operated at Newmont’s Lone Tree Mine located in Nevada, as well as development work that was done on ores from their Twin Creeks Mine also located in Nevada."

Jan 1, 2003

By Takashi Furuyama, Sukeyuki Mori, Ltd. Kyushu Metal Industry Co., Abel Bissombolo, Yoshitsugu Koga, Masamichi Hata

"Actually, the recovery of valuable metals such as iron, aluminium and copper is a nowadays practice in factories dealing with the processing of scrapped automobiles (Harder (WERG); Koga et al., 1997). This process has reach a recycling rate of about 75%, and generates a huge volume of waste (including cottons, sponge, plastics, rubber, etc…), locally known as “shredder dust”, which is commonly dumped on landfills; its recycling is either unsatisfactorily or not yet performed (Keller and Schebdat, 2000).The saturation and depletion of valuable disposal sites in the not-so-distant future, as well as the social and environmental problems related to the accumulation of these residues disposals are a major challenge for the automobile shredding industry.To promote an alternative way for the management of these disposals, the authors have initiated and developed a system for their processing, on the basis that more than 90% of these residues are combustible materials that could be used as refuses derived fuel. The developed processing system points out the mechanical/physical separation of a calibrated (–80+5mm) shredded automobiles residues into two streams by means of an ascending airflow passing through a vertical zigzag separator and, the compaction of the light-weight materials (that is about 60% of auto shredder residue recovered as float products and mainly composed of cotton, sponges and light plastics) to form a refuse derived fuel (RDF), the density, calorific value and ignition loss of which are 1.19 g/cm3, 4470 kcal/kg and 60.7%, respectively. A sedimentation tank is used to recover the light-weight materials deported in the heavy fraction stream."

Jan 1, 2003

By Pat Turner, Abrie Schutte, Tim Olson, Roman van Ommen

The key to good cyclone circuit design and operation in primary grinding circuits will be discussed. Cyclone circuit design issues include individual cyclone design features such as cone angle or materials of construction, as well as orientation and manifold configuration. Cyclone performance issues as well as maintenance considerations will be detailed in an effort to achieve consistent cyclone operation with minimal coarse solids in the overflow. The new gMAXTM. cyclones will be introduced and evaluated using operating circuit data in closed circuit grinding applications

Jan 1, 2003

By Andrew T. McBride, Malcolm S. Powell, Indresan Govender

"Current empirical Semi Autogneous Grinding (SAG) mill models contain assumptions concerning the amount of energy available for particle breakage, how this energy is distributed in the mill media and the rate at which the energy is transferred. Despite these assumptions the JK SAG model is highly functional with a proven track record. DEM provides a numerical framework to greatly improve on these assumptions that were necessary due to a lack of available input data.This paper identifies key outputs of the Discrete Element Method (DEM), such as energy spectra and impact probability distribution. It describes how they can be incorporated into current mill models utilising practical rock breakage data. The rate at which energy is transferred is shown to be dependent on particle position and mill rotational speed and not once per cycle as previously assumed. Based upon this an improved energy transfer methodology is presented. The fundamental outputs of the DEM are validated against experimental three-dimensional particle tracking data, so as to establish whether the DEM produces correct energy transfer predictions on the inter-particle level, which is crucial to this work."

Jan 1, 2003

By David Dreisinger

"The leaching of base and precious metal ores and concentrates continues to progress in both laboratory study and industrial application. These developments are being driven by the need to respond to difficult ores and concentrates that are not amenable to conventional treatment. In many cases alternatives are being developed to conventional treatment (e.g. Pyrometallurgy) for technical and economic reasons.In this paper, a brief general review of some new developments in leaching will be followed by a more detailed explanation of three process developments that have either been industrially applied or are expected to be applied in a short time frame. The three processes to be reviewed in detail are the Mt. Gordon Copper Process, the Anglo American Corporation/University of British Columbia Copper Process and the PLATSOL Process. These leaching processes operate at low (90°C), medium (150°C) and high (220°C) temperature and are successful in quickly and completely extracting metal values from ores and concentrates."

Jan 1, 2003

By Rodney J. Hundermark, Sharif Jahanshahi, Shouyi Sun

"The major platinum producers in South Africa make use of electric furnaces for the melting of platinum group metal (PGM) bearing nickel – copper concentrates. To gain better understanding of the furnace operation, research was conducted at CSIRO Minerals in Melbourne, Australia. One aspect of the research project was the investigation of the factors affecting the electrical conductivity of melter type slags.Electrical conduction in slags can occur through two mechanisms: ionic and electronic. There is good understanding of the ionic mechanism. In slags containing high levels of iron, the dominant mechanism is electronic as a result of charge hopping (electrons or holes) between ferric and ferrous ions. There is limited understanding of the electronic mechanism and one of the aims of the research was to investigate this mechanism further.Experimental work was carried out at 1450 °C on Al2O3–CaO–FeOx–MgO–SiO2 slags similar in composition to the melter slags (typical composition range (wt%): Al2O3: 5, CaO: 5-15, FeOx: 10-30, MgO: 15-25, SiO2: 40-60). The approach was to vary the oxidation state of three different basicity slags and measure the conductivity response. The slags had molar (CaO+MgO)/(Al2O3+SiO2) ratios of 0.43, 0.64 and 0.94 and FeOx contents of up to 40wt%. A twoelectrode technique was employed with a shallow layer of slag contained in a magnesia crucible. The small amount of slag facilitated relatively quick equilibration (up to one hour) with the gas atmosphere. Experiments were typically started in air and sequentially reduced using different ratios of CO and CO2 gases.Conductivity increased with increasing basicity and increased significantly with iron oxide content. Above 20wt% FeOx, electronic conduction was significant and the conductivity varied with the oxidation state of the slag. The typical response of the conductivity to the change in oxidation state was the following: starting in air, as the slags became more reduced, the electrical conductivity increased to a maximum at around pO2 = 10-7 to 10-4 atm and then decreased with further reduction. The value of the pO2 at which the maximum occurred was dependent on the total iron oxide content and basicity of the slag. The magnitude of the conductivity of the slags increased with increasing FeOx content in a range of 20 to 170 S/m for 20 to 40wt% FeOx. For a given FeOx content in the slags, the oxidation state dependence of the conductivity varied with slag basicity. The trend observed was that the maximum in the conductivity occurred at higher oxygen partial pressures for the lower basicity slags."

Jan 1, 2003

By Lawrence Devon Smith

"The concept of risk is well established in the mining industry. It is acknowledged when estimates of reserves are expressed as proven or probable, when mining and metallurgical recoveries are applied to the ore, and when contingencies are added to costs. However, it is difficult to provide a quantitative assessment of risk. The significant sources of risk in a mineral project and how these are addressed in project evaluations are discussed. The discount rate is examined as a fundamental means of reflecting risk in discounted cash flow evaluations. Current industry practice is discussed, and a methodology for the analysis of risk levels is proposed that assesses the constituent components of the discount rate: real interest, mineral project risks, and country risk.IntroductionThis paper examines the components of the discounted cash flow discount rate and proposes a method of estimating project-specific discount rates. The motivation for this work comes from experience of project evaluations in which owners and purchasers had agreed on virtually every aspect of the evaluation except how much the project was worth. Agreement was reached on reserves, grad~, recovery, capital costs, operating costs, taxes, and, by combining these components, even on the fmal cash flow values. The only difference in opinion concerned the discount rate to be used in the calculation of the net present value. Depending on the life of the project, such differences of opinion can cause a variation of more than 50% in the value placed on a project! This is illustrated in Figure 1."

Jan 1, 2003

By Tatyana A. Ivanova, Tamara N. Matveyeva, Anatoliy A. Fedorov, Tatyana V. Nedosekina, Valentin A. Chanturiya

An ingenious methodology purposively developed by the authors for comprehensive assessment of flotation properties, electrophysical characteristics and. crystal chemistry features of natural gold-bearing sulfide minerals of different origin has been used in this study. Examination of the elemental composition of the minerals, ion-molecular components of the liquid phase in suspensions, surface properties of sulfides and different flotation reagents sorption forms was performed using the methods of X-ray phase and spectral analysis, potentiometry, UV and IR spectrometry, computer image analysis, and computer simulation techniques. The role of isomorphous impurities in the formation of hydrophobic sulfhydric collector layers on mineral surfaces in complex ore processing has been elucidated. The parameters characterizing the variability of the Fe:S ratio in pyrite of different origin have been determined based on non-stoichiometry characteristics of natural gold-bearing sulfide crystals. An ingenious method of formatting and linear approximation of experimental data was used to find out the quantitative relationships between the impurity content, electrophysical characteristics, non-stoichiometry and floatability of pyrite from a number of different deposits. The effect of the impurity species present in sulfides on the characteristic pH value marking the floatability peaks as such and their trend of shift towards higher alkalinity has been revealed. A theoretical substantiation has been given to prognostic assessment criteria for processing characteristics of gold-bearing sulfide minerals with varying composition. New flotation reagents and advanced reagent systems which help to increase the contrast of processing characteristics for different gold-bearing sulfides, resulting in improved selectivity, have been developed. The mechanism of selective flotation of precious metal-bearing Fe and As sulfides achieved by using short-chain dithiocarbamates and a mixture of cyclic trithiocarbonate with oxyalkylsulfides has been analyzed.

Jan 1, 2003

By Stefaan J. R. Simons, Michael T. Spyridopoulos

In this paper the effect of humic substances (natural surfactants), electrolytes and solid particles on bubble coalescence, and as a consequence on froth stability, has been investigated. We formed two bubbles of equal size and forced them to collide using a novel experimental apparatus. The interactions were recorded by a high-speed camera, the images of which helped to determine the coalescence frequency and the coalescence time, as well as the mechanisms of the interactions. Two types of humic substances were used, along with three different electrolytes. Humic substances appeared to have a considerable effect on bubble coalescence, while the effect of electrolytes was minimal. Moderate and high hydrophobic glass spheres were used between two bubbles. Very hydrophobic spheres promoted fast bubble coalescence, while moderate hydrophobic spheres had no effect. We present data of coalescence frequency and time, as well as images of the coalescence events.

Jan 1, 2003

By Francesco Vegliò, Luigi Toro, Francesca Beolchini, Francesca Pagnanelli, Stefano Ubaldini

"Biosorption is an innovative technology used to remove heavy metals from aqueous solutions from mining waters and other industrial wastes. A wider application of this alternative process is strictly dependent on the understanding of the chemico-physical aspects involved, in order to optimize the operating conditions. Mechanistic models are the most useful tools used for understanding purposes, even if the empirical models are still widely applied for their simplicity.In this paper especially propagated biomasses of Sphaerotilus natans, calcium alginate and some waste materials were tested as adsorbents for single and binary solutions containing heavy metals at different pH. The equilibrium experimental results were fitted according to empirical and physical models with growing complexity outlining the inadequacy of the predictive models; in fact, the non-ideal interactions among metals require the insertion of additional correction parameters."

Jan 1, 2003