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By B. J. Jody

This paper describes a one-step thennal-treatment process, developed at Argonne National Laboratory, to remove all organic contaminants from the glass-fiber waste that is generated during the glass-fonning process. The recovcred glass fibers can then be recycled into new glass fibers or new glass products without adversely impacting the operations of the glass industry or the quality of its products. Our process involves shredding the waste to a manageable size and then processing it at temperatures below its melting point to remove the polymeric-coating layer. The glass industry generates more than 60,000 tons of glass-manufacturing waste annually in the glass-forming process alone. Recycling of this waste stream can keep this non-biodegradable waste out of the landfills. In addition, use of recycled glass lowers energy costs, by an average of about $5 per ton as compared to using virgin raw materials to make virgin glass fibers. This process will also reduce the emission of C02 by 17,400 tons a year and it will also reduce the emission of nitrogen oxides. Economic analysis of our process shows a potential payback of less than 2 years.

Jan 1, 2003

The advantages of quantitative environmental risk assessment techniques over the more commonly used qualitative approach is widely accepted. One important parameter related to the level of risk is the extent and geographic spread of pollutants. Geographic Information Systems (GIS) provide a powerful and highly flexible tool that increases the sophistication of the risk assessment methodology. Through spatial representation, the estimated risk becomes more comprehensive, thus facilitating the decision making process. In addition, valuable qualitative information can be incorporated into the risk assessment procedure with the help of GIS. This paper illustrates a methodology for quantifying risks posed to human health, by exposure to contaminated land, in a manner, which gives a measure of the uncertainty in the assessment and preserves the spatial distribution of the risks. The case study utilised to illustrate the methodology is a large industrial area around a number of decommissioned minerals production and processing sites with known high heavy metal loads at Lavrio, Greece. The spatial distribution of Pb concentration in soils was derived from 425 soil samples collected over a total area of 120 km2. Indicator kriging was used to quantify the spatial distribution of the risk and related uncertainty and the results displayed in map form using GIS.

Jan 1, 2003

By Steve Kral

Borates are minerals that contain boron. Trace amounts exist in rocks, soil, water and people. Boron-containing ores are rare and U.S. Borax, a subsidiary of Rio Tinto Borax, controls one of the world’s two world-class borate deposits. Through its global systems of mines, refineries, ports, sales offices and distribution centers, the company supplies nearly 45 percent of the world’s demand for borates. Borax has been mining borates in California for more than a century. This year the company celebrated 131 years of continuous business in the Golden State and 76 years at its operations in Boron, the site of California’s largest openpit mine. It also has mines and refineries in Argentina, refineries and ship-ping facilities in Europe and technical staff in the United States, North and South America, Europe and Asia Pacific. So, with the 130±years of borate mining and processing experience behind it as well as its global marketing and distribution centers, there is very little that Borax does not know about borates.

Jan 1, 2003

Brand se Baai, on the North-Western Cape Coastline of Southern Africa, is the site of the Namakwa Sands Limited Heavy Mineral Sands Mining Operation. The mine is a 14 000 000 tonnes per annum open-cast strip-style mining operation using truck and excavators to mine the sand. The orebody consists of relatively unconsolidated sands reworked by fluvial, marine and aeolian mechanisms. The total orebody includes three primary ore types, namely the Red Aeolian Sands, the Dorbank (a hardcap layer) and the Orange Feldspathic Sands, which forms the bulk of the resource. Mine planning and scheduling is done using a 50 m + 50 m variable bench height system with three primary bench heights. The Aeolian and Dorbank each have a bench that varies with their thickness of up to a maximum eight metres and the Orange feldspathic sand, a standard bench height of eight metres. For a number of years Namakwa Sands used a complex 2D, Datamine Based, macro system to perform the resource evaluation and mine design. As the mining operations expanded it became clear that a complete system redesign was required to cope with the increasing operational pressures coming to bear on the old system. The biggest challenges facing any replacement system are the sheer scale of the mining operation (16 km long and 7 km wide resulting in a minimum of 30 000 individual 50 m + 50 m mining blocks), the size of the geological data files (up to one gigabyte) and representing the benching system accurately (as the benches follow the topography and are not horizontal). In addition to these large-scale issues, the ability to run multiple mine design scenarios was required, an aspect which the old system was unable to perform adequately. Based upon these primary difficulties, a new business process was developed which required a complete rethink of the mine design methodology as well as the creation of a new system to deplete the resource model, produce monthly reconciliation evaluations and create a ultimate pit limit based on the operations mining cost model. Using a system based on the Earthworks Mine2-4D Mine Design and Scheduling System (with its mine design and scheduling specific tools), as well as a small, customised program, massive time-savings have been made. It is now possible to run several life of mine scenarios in the same timeframe that a single life of mine run took under the old system. This paper will present the methodology and business decisions behind the new Namakwa Sands system, and detail the restructuring and development used to deal with the large data set sizes and long processing times inherent in the old system. Future enhancements to the system that will make it more generically applicable to open-cast mining scenarios will also be dealt with.

Jan 1, 2003

By David Newman

Coal refuse impoundments and underground mines are frequently sited in close vertical and horizontal proximity in the valleys of the Southern Appalachian coalfield. The steep V-shaped valleys provide the volume necessary for slurry storage against a coarse refuse embankment that is constructed across the valley mouth. The presence of coal outcrops on the valley walls provides economic access to mineable coal seams that may be located under several thousand feet of overburden beneath the adjacent ridges. In some instances where the underground mine precedes the slurry impoundment, the type of mining (partial or complete extraction) and pillar centers were selected without consideration for the potential future use of the valley as an impounding structure. The high standard established for the design and stability analysis of the coarse refuse embankments is clearly illustrated by the absence of an embankment failure in the thirty-one years since Buffalo Creek. However, the recent Martin County slurry spill focused attention on a thorough geotechnical analysis to prevent a connection between the flowable slurry and the mine void. The overburden, roof, pillar, floor, and outcrop barrier stability are examined to quantify the break through potential. The strength and physical properties of the consolidated fine refuse are also important since this material is often the most well-defined and quantifiable barrier separating the slurry and mine void. Because each site is unique, the appropriate analysis ranges from the calculation of roof, pillar, and floor safety factors to detailed numerical modeling of the mine workings and the determination of ground deformation and strains resulting from mine subsidence. The method of refuse disposal may be altered to slurry cells where the accuracy of the mine maps, extent of mining, type of mining (development or retreat) cannot be reliably verified or the break through analysis does not produce an acceptable level of risk. Case histories from the Southern Appalachian coalfield are used to illustrate the application of methodologies to quantify the break through potential of coal refuse impoundments.

Jan 1, 2003

By L. I. Gonzalez de Vallejo

SRC rockmass classification have been applied to 25 tunnels in Spain and Italy, for which it was found that much heavier supports than those estimated by the RMR index were required. SRC and RMR indices and other relevant geomechanical data were obtained during the site investigation and construction stages. Data corresponding to in situ stress measurements, analysis of tectonic structures, and instability problems arising during construction were used to asses the state of stress. The relationship between tunnel section convergence and the SRC and RMR indices was also analysed. Support measurements based on SRC and RMR classification were compared with those actually used during construction. These analyses indicate that for most of the tunnels examined, supports estimated using the SRC were much closer to those actually installed than those predicted by the RMR index. Bei der Verwendung des SRC-Systems zur Klassifizierung des Gesteins als Baugrund für 25 Tunnel in Spanien und Italien wurde festgestellt, dass viel schwerere Abstützungen benötigt wurden, als wenn die Beurteilung anhand des RMR-Systems angefertigt würde. Die Klassifizierung anhand des SRC- und des RMR-Systems, sowohl als auch andere wichtige geomechanische Daten wurden während des Ablaufs der Erkundungen und der Bauausführung gewonnen. Die Resultate der Messungen der Spannungen vor Ort, die Analyse der tektonischen Struktur und die Stabilitätsprobleme während der Bauausführung wurden dazu verwendet, um den im Felsgrund vorherrschenden Spannungszustand zu definieren. Das Verhältnis der Messungen der Tunnelkonvergenz zu dem SRC- und RMR-Index wurde auch analysiert. Die durch das SRC- und RMR-System vorhergesagte Grösse der Abstützung wurde mit der Grösse der Abstützungen verglichen, die am Bau letztlich verwandt wurden. Diese Vergleiche zeigen, dass für die meisten der studierten Tunnel die Vorhersage der Abstützungen, die anhand des SRC-Systems angefertigt wurden, viel näher der wirklich verwendeten waren als die Vorhersage anhand des RMR-Systems. SRC rockmass la classification ont été appliqué à 25 tunnels en Espagne et l'Italie, pour laquelle il a été trouvé que des appuis beaucoup plus lourds que ceux évalués par l'index RMR ont été exigés. SRC et des index RMR et d'autres données geomechanical appropriées ont été obtenu pendant l'enquête de site et les étapes(scènes) de construction. Les données correspondant aux mesures de stress(d'accent) in situ, l'analyse de structures tectoniques et des problèmes d'instabilité surgissant pendant la construction ont été utilisées aux ânes(culs) l'état de stress(d'accent). Le rapport entre la convergence de section de tunnel et le SRC et les index RMR a été aussi analysé. Les mesures d'appui basées sur SRC et la classification RMR ont été comparées avec ceux en réalité utilisés pendant la construction. Ces analyses indiquent que pour la plupart des tunnels examinés, les appuis évalués utilisant le SRC étaient beaucoup plus proches de ceux en réalité installés que ceux prévus par l'index RMR.

Jan 1, 2003

By Güven Önal, Gülay Bulut, Mustafa Özer, Yunus Emre Benkli, Olgaç Kangal, Mustafa Tarkan

There are various types of natural zeolite deposits in Turkey. Naturally occurring zeolites are excluded from many important commercial applications where uniformity and purity are essential. In this paper, the beneficiation of natural zeolite, taken from western part of Turkey, was investigated. According to X-Ray Diffraction (XRD) and mineralogical studies carried out on the representative ore sample, the natural zeolite was found to be in the forms of clinoptilolite and heulandite. Clinoptilolite forms as a devitrification product of volcanic glass in tuffs. Quartz, clay minerals, orthoclase, plagioclase, biotite, seruzite-muskovite and epidote were observed as impurities. Several types of mineral processing methods were performed in order to remove impurities from the natural zeolite sample to produce high purity zeolite. Gravity separation methods such as shaking table and superpanner were carried out for separating heavy minerals, while high intensity dry magnetic separation was used for discarding magnetic minerals.

Jan 1, 2003

By T. F. Cho, B .. O. You, K. S. Yoon, K. S. Won

Discontinuity Orientation Measurement (DOM) drilling system capable of retrieving the reference line-marked core log, which can be used for determining the relative positions and orientations of discontinuity planes along the borehole axis, has been developed. Accuracy of the borehole joints data measured from the reference-lined core and, eventually, the significance and applicability of DOM drilling system for site exploration are verified by comparing with the spatial characteristics of joints investigated by implementing borehole image-taking instruments in the same borehole. Enhancement of boring efficiency has been also confirmed by performing twin drilling operations, one with DOM drilling system and the other with a conventional drilling machine equipped with D-3 core barrel, on two neighbouring sites of 5 m apart. Ein DOM(Diskontinuitätsorientierungsmessung)-Bohrsystem, das durch Grundlinien markierte Bohrprobelog extrahieren kann und die relativen Lagen und die Orientierungen der sich im Bohrloch verbreitenden Flächen bestimmen kann, ist entwickelt worden. Die Wichtigkeit des DOM-Bohrsystems und dessen Anwendbarkeit auf die Erforschung auf dem Bohrplatz werden dadurch bewiesen, dass man die Genauigkeit der Daten der Bohrlochsspalte, die durch die die Grundlinie zeichnende Bohrprobe gemessen werden, mit dem räumlichen Eigenschaften der Spalte vergleicht, die durch die Bildaufnahme des gleichen Bohrlochs nachgeforscht werden. Un system de sondage, Discontinuity Orientation Measurement (DOM), capable de récupérer des carottes markés en une ligne de référence a été dévelopé. Il peux être utilisé pour déterminer les positions relatives et les orientations des plans de discontinuité le long de l’axe de trou de sonde. Leur signification et applicabilité pour une caractérisation de site est verifiée par une comparaison de la précision des données a propos des joints mesurés a partir des carottes markés et les carac-téristigues spatiales des joints enquêtés par le camera de sondage

Jan 1, 2003

By M, C Silveira, C Ellice, D Christensen

Peak Gold Mines (PGM), a member of the Rio Tinto Group, is an underground and open cut gold mining operation located near Cobar, NSW. A multi-phase study was initiated in 2001 in support of developing a dry æmoisture store and releaseÆ cover system design for the PGM tailings dam, which contains potentially acid-forming tailings material. The first phase consisted of characterising the tailings and potential cover material (waste rock from an open cut operation) as well as soil-atmosphere cover design modelling. The second phase involved construction of two cover system field trials on the tailings dam and installation of a variety of field instruments to monitor the hydraulic performance of the test covers during all seasons of the year. Field performance monitoring commenced in April 2002 and will continue for a minimum of two wet-dry climate cycles (third phase), prior to using the field data for calibration and subsequent validation of numerical models developed for the cover system trials (fourth phase). This paper describes the work completed for the first two project phases and also discusses the initial performance of the cover system trials.

Jan 1, 2003

By Katsutoshi Inoue

Pectic acid gel crosslinked with epichlorohydrin was found to have very high selectivity to lead(II) and iron(III) ions over zinc(II) ion compared with commercial weakly cation exchange resins containing the same carboxylic functional groups, suitable for removing small amount of impurity metal ions from waste zinc plating solutions. In order to lower the cost, new adsorption gel was prepared from orange juice residue containing pectic acid by crosslinking with epichlorohydrin, which was also found to be suitable for removing these impurities. Further, very cheap adsorption gels was prepared not only from orange but also from apple juice residues by a simple method through just saponificating pectin substances contained in these residues into pectic acid by calcium hydroxide followed by water washing and drying. These adsorption gels exhibited excellent adsorption behaviors for removing the impurity metal ions away from zinc.

Jan 1, 2003

By Ramana G. Reddy

Thermodynamic modeling and experimental study on impurity capacities and their distribution between mattes or metal and slags in smelting, converting and refining of non-ferrous metals was discussed. A brief review on the recent developments in copper smelting and converting is presented. The analysis showed that, copper smelting capacity increased by a factor of 10 since 60's, smelting rate increased by a factor of more than 5 and process fuel equivalent decreased by a factor of 2. A thermodynamic model for prediction of impurities capacities in slags and their distribution in mattes and slags was developed. The impurities capacities (i.e. sulfur and arsenic) of slags were calculated a priori with no adjustable parameters using the Reddy-Blander model. The capacities predictions were made in a wide range of matte and slag compositions, Pso, and temperatures in conditions pertaining to copper and lead industrial slags. The calculated results for sulfide and arsenate capacities are in good agreement with the available experimental and industrial copper and lead industrial slags data. The sulfide and arsenate capacities in copper slags (fayalite, ferrite and olivine) and lead slags are reviewed. The application of RB model predicted ratios of 02 and S2 partial pressures in industrial copper smelting processes are discussed. Application of this model for the prediction of Sb, Bi and other impurity capacities and their distribution ratios in mattes or metal and slags, in industrial smelting and refining processes is discussed.

Jan 1, 2003

By Buks Kruger

"After the milling and flotation of the platinum bearing ore, the flotation concentrate is electrically smelted in 6-in-line electric arc furnaces and the resulting furnace matte treated in Peirce Smith converters to remove the iron sulphide. The iron free (less than 1% Fe) converter matte is then granulated and sent to the Base Metals- and Precious Metals Refineries for further processing.During the smelting and converting processes two distinct gas streams are produced.The Peirce Smith converter off gas contains 4% - 9% SO2 which is treated in a conventional Sulphuric Acid Plant to produce sulphuric acid (H2SO4).The electric furnace off gas contains 0.9% SO2 and was (until September 2002) vented through a 91 meter high stack to atmosphere.Off gasses which contain less than 3% SO2 is difficult to handle and quite a few processes had been developed over the years to cope with this gas. A broad spectrum of process suppliers and technology approaches is available and the different technologies can be divided into a few main approaches i.e.Scrubbing of the off gas with an alkaline solution to produce an environmentally friendly and stable waste product which can be discharged onto a tailings dam or permanent landfill site.Physical absorption of the SO2 into a chemical solution to produce high quality chemically pure process chemicals.Catalytic reaction of SO2 with O2 to produce SO3 which is absorbed in water to produce sulphuric acid of less than 90% strength.In October 2002 Impala Platinum commissioned a Sulfacid Plant at its Smelter in Rustenburg which recovers the SO2 from the electric furnace off gasses into a weak sulphuric acid solution.The Sulfacid Plant technology is widely used in the paint pigment industry. This is, however, the first application of the technology on electric furnace off gas.The furnace off gasses contains flue dust which is removed in electrostatic precipitators. The gas exiting the precipitators normally still contains between 40 mg/Nm3 and 60 mg/Nm3 dust and passes through a quench-scrubber before entering the reactors. The quench-scrubber cools the electric furnace offgas down from ± 200 °C to 60 °C and act as a final dust removal stage."

Jan 1, 2003

By R. Singh, A. K. Dhawan, M. Dixit, H. Dev

ABSTRACT: The modulus of deformation of rock mass is an important engineering parameter required for the design of foundation of hydraulic structure and to study the interaction of rock mass and the structure at the foundation support. Different equipment and techniques are used to arrive at the design modulus value. Since any error in the estimation of modulus values results in multiplication of its effects in the analysis, it is necessary to know about the reliability of testing equipment and procedures. In the present study modulus values obtained by different in-situ equipment at different project sites have been compared. KURZFASSUNG: Der Verformungsmodul von der Felsenmasse ist technisch ein wichtiger Parameter, den man zur Konstuktion des Grunds fuer die Hydro – Tektonik, benoetigt um auch die gegenseitige Beeinflussung der Felsenmasse und der Tektonik am Traggrund zu betrachten. Verschiedene Geraete und Methoden werden angewandt, um den Ausfuehrungsmodul -Wert zu erreichen. Es ist erforderlich, die Zuverlaessigkeit der Pruefeinrichtung sowie des Verfahrens zu kennen, da irgend ein Fehler in der Abschaetzung von Modulwerten in der Analyse zu einer Vervielfachung ihrer Einwirkung fuehrt. In der vorligenden Arbeit werden die Modulwerte gewonnen aus unterschiedlichen Einrichtungen an Ort und Stelle and verschiedenen Projekt -Stellen mit einander verglichen. SOMMAIRE: Le module de deformation d’une roche est un parametre important pour la conception et realisation des ouvrages hydrauliques ainsi que pour etudier l’interaction de la roche et de la structure d’appuis de base. De divers equipments et techniques sont employes pour determiner la valeur de ce module de conception. Puisque l’effet d’une erreur d’evaluation du module devient multiplie dans l’analyse, il est necessaire de savoir la fiabilite des equipments et des methods qu’on ulilise. Dans cette etude, on a compare les valeurs des modules obtenues en employant les equipments in-situ aux sites differents de projets.

Jan 1, 2003

By E. Anelli

Based on experimental continuous cooling transformation (CCT) diagrams, an artificial neural network has been trained to predict the amount of microsturctural constituents and hardness resulting from and controlled cooling at rates from 150 to 0.015 K/s. It can be applied to quenching and normalizing processes of low-alloy steels with 0.05-0.30 C% and 0.4-2.0% Mn -with possible microalloying additions. Examples of the good predictive capabilities about 15 Vickers standard deviation for hardness and a few percent for volume fraction of phases) are reported' Keywords: Austenite decomposition, low. And medium-carbon steels, artificial neural networks

Jan 1, 2003

By G W. Wilson, M Aubertin

A desulfurised tailings cover was installed at the Detour Lake Mine in Ontario, Canada, to reduce oxygen penetration into the underlying sulfidic tailings. The cover ranges from one to 1.5 m in thickness and was intended to maintain high water saturation to reduce oxygen diffusion and consume oxygen by oxidation of the residual sulfide minerals. The tailings impoundment was instrumented to measure climatic parameters, water levels and water content profiles within the tailings and single-layer cover. One year of monitoring data was collected. Additional tailings samples were obtained for geotechnical and geochemical characterisation. The average grain size of the cover material was found to be coarser than the underlying tailings. Monitoring also indicated that air entry values of the cover material were lower than the tailings. Numerical modelling was conducted on the cover to predict water content profiles under varying climate conditions together with the depth of oxygen penetration and diffusive oxygen fluxes. Estimates of the diffusion coefficient and kinetic oxidation rates from field data compared well with values obtained by laboratory measurements. Numerical simulations indicate water saturations of less than 85 per cent can be expected under varying climate conditions. Predicted oxygen flux rates through the desulfurised cover over tailings with high acid potential indicate low flux rates reaching these tailings due to either consumption of oxygen by residual sulfur within the cover or saturation of the underlying tailings.

Jan 1, 2003

By Karl J. C. Harries

13.1. RIGHT TO RECEIVE ROYALTY CONTRACTUAL ONLY1

Jan 1, 2003

By A. Hasko

Phytoremediation is a new low cost alternative technique for remediation of contaminated soils from heavy metals that are emitted by ferrous and nonferrous mining and extracting processes. It is based on the possibility to use several plants that accumulate high level of metals in order to remove metallic pollutants from soils and render them harmless. Phytoextraction is an adjacent new technique that uses these hyper-accumulator plants in order to extract the metals from them using even the conventional smelting or refming processes. In our previous work, an extensive investigation of about 150 plants have been carried and several species were identified that could be used for nickel phytoremediation and phytoextraction because of their high accumulation of nickel. It has been found that five taxa from Alyssum genus specie had the highest ability to accumulate nickel with concentrations more than 10000 ug/g (dry weight) or 1%. The taxa showing the highest accumulation of this metal is Alyssum murale var. chlorocarpum with 28 600 ug/g or 2.86%, a good candidate for Phytoextraction. In this work, in order to optimize the phytoremediation and phytoextraction processes further Absorption Spectrometry measurements and biological studies were carried out to determine the parts of the plants that accumulate the highest amount of nickel and the best biological cycle during which they accumulate the highest amount. The results show that the greatest accumulation of nickel occurred in the leaf material (2.86%) and the least in the roots (0.43%). The investigation of the biological cycle of the genus Alyssum showed that: (1) the seeds germinated between 50 C to 30 0 C and more in 25 0 C; (2) 62.9 % of seeds germinated at A.m. var. chlorocarpum; (3) the emergence is almost continue from March to April; (4) the anthesis occurs from May to July; (5) the ripening of the fruit takes place 30 days after flowering; (6) the dissemination of fruits occurs from September to October. Due to these special characteristics it is reaffirmed that Alyssum murale var. chlorocarpum, as a nickel hyperaccumulator, is the most promising plant to be used for feasible phytoremedation and phytoextraction purposes. Keywords: Key words: Phytoextraction, PhytoRemediation, Nickel accumulators, Alyssum sp., Biological cycle

Jan 1, 2003

An Environmental Impact Statement (EIS) for a major mining development typically has to address various aspects of surface water management, including some which generally tend to be the more contentious: the diversion of rivers and creeks from areas disturbed by mining, and their rehabilitation; the effective management of disturbed area run-off via the collection, containment and treatment of contaminated water on site in sedimentation dams; the collection, containment and treatment of mine pit water; the decommissioning of surface water storages; final void water quality; and water discharge criteria. Environmental Impact Assessment processes for proposed mining developments in Australia at the state and commonwealth level usually involve a form of Initial Advice Statement (or Notice of Intent), Terms of Reference, an EIS, and a Supplementary Report (or similar) which responds to agency and public comment on the EIS. The EIS is used by approval agencies to decide the acceptability of the Project, and to set the conditions of approval. The conditions are often in the form of a state-issued æOperational LicenceÆ or similar. With mining, the initial approval at the EIS stage is often just a pre-cursor to various other planning related approvals, including obtaining a mining lease. Afterwards, mine plans and plans of operations must be submitted to government at various stages of the mineÆs life, ostensibly to provide the detailed mine planning over periods of one û five years. Despite all this additional planning and documentation beyond the submission of the EIS, government approval agencies are increasingly not satisfied with conceptual water management designs and commitments to an outcome (such as meeting a specified water quality standard) in the EIS. Agencies are also requiring sufficient water management design information to be convinced that the outcomes are achievable. To assist proponents of major mining developments, the Queensland Government has published Technical Guidelines for water management, and Environment Australia has published a æBest Practice Environmental Management in MiningÆ booklet on water management. In addition, the Australian and New Zealand Environment and Conservation Council (ANZECC. 2000) has published Water Quality Guidelines which provide an approach to water management, and provide receiving water investigation trigger criteria. So, what are the water management issues that are likely to be the subject of comment, debate and negotiation prior to the EIS being approved? and what commitments may a mining proponent have to make in order to convince the approval agencies that sufficient investigation and design has been provided? This paper provides some answers to this question, by reference to recent major mining proposals which the author has managed through state and commonwealth Environmental Impact Assessment processes.

Jan 1, 2003

By M E. Malmstr÷m

Quantification of site-specific sulfide oxidation rates is crucial to accuracy of prediction of, for example, the environmental impact of a mine site. Sulfide oxidation reactions are reportedly increased by bacterial mediation; determination of abiotic and biotic weathering rates thus requires the establishment of sterile control samples. However, sterilisation often involves exposure of samples to extreme conditions that may alter the physical, chemical, or mineralogical characteristics of the tailings and hence affect element release rates. The impact of various sterilisation techniques, common and novel, on the element release rates from tailings from the Kristineberg site, northern Sweden, has been investigated. Batch weathering experiments indicated that the different methods of sterilisation (autoclaving, heat treatment, ethanol/heat treatment, application of antibiotics, rinsing with distilled water, and γ-radiation) did not greatly affect long-term element release rates. Long-term experiments (>30 days) are thus to be recommended for establishment of weathering rates. Sterilised and untreated control samples showed similar element release rates after ~100 days of experiments; possible explanations include that microbial oxidation is not important under our experimental conditions (Po2 = 0.2 atm, pH ~2.3, 22¦C, 0.01 M HNO3, no additional nutrients).

Jan 1, 2003

By Steven R. Izatt

IBC Advanced Technologies, Inc. (IBC) has developed a mercury selective product, which can be used by sulfuric acid producers as either a polisher, or as the primary technology for mercury removal from sulfuric acid. The Molecular Recognition Technology (MRT) separations material selectively binds Hg2+, and to a lesser extent Hg+, out of concentrated sulfuric acid. Mercury output levels of less than 0.1 ppm can be attained by the MRT system. Pilot plant tests have been successfully conducted at base metal smelting operations. A large-scale commercial plant is due for commissioning in 2003. Results from these projects will be discussed.

Jan 1, 2003