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By B M. Patterson, A J. McKinley, M E. Grassi

Large-scale column experiments were undertaken to determine the effect of a step decrease in groundwater pH on metal remediation by bioprecipitation. Metal contaminated groundwater at pH 5.5 was amended with ~1 g/L of ethanol in one column using a polymer mat ethanol delivery system to promote bioprecipitation, while another column was left unamended and used as a control. Sulfate reduction and zinc removal were observed after eight weeks. Zinc removal was observed in the zone of sulfate reduction, indicating precipitation as ZnS, while, copper was removed in the denitrification zone. Once steady state bioprecipitation of zinc had been established, the pH of the metal contaminated influent groundwater was decreased stepwise from 5.5 to 4.25. As a result of the change in pH, a significant increase in copper concentration was observed in both columns. In the ethanol column, the zones of denitrification and copper removal migrated up the column, while both sulfate reduction and zinc removal ceased. Bioprecipitation of metal contaminated groundwater via sulfate reduction was shown to be an effective remediation strategy for zinc removal. However, this in situ biological remediation process was sensitive to changes in groundwater pH.

Jan 1, 2004

By A. V. Roschin, N. V. Malkov, V. N. Karnoukhov, V. E. Roschin

Reduction interactions in solid phases are widespread and occur in most complex metallurgical processes. Among these processes, reactions between oxides and carbon have a special importance. The authors conducted experiments for comparison of reduction by different reducing agents of impregnated chromite ores, in which grains of the reducible chromite spinel are isolated from direct contact with the reducing agent by layers of non-ore material. The results of the experiments have revealed that the beginning of reduction is preceded by thermal and impurity order-disorder transformation of the oxide lattice whilst the transformation of the oxide lattice into the metal lattice takes place as a result of removal of oxygen anions from the zone of metal germ nucleation. Since anions are charge carriers, increase of their mobility can be monitored by changes in electrical conductivity of oxides. Respective measurements of electrical resistance of ores of different metals and a number of pure refractory oxides under heating have indicated that the beginning of reduction coincides with the time of drastic (tens of thousands times) increase of conductivity of the oxides. Besides, the temperature of the beginning of carbon-thermal reduction is in line with the Tammann temperature, i.e. the temperature of transition from the predominantly surface diffusion to volume diffusion. Segregation of metals from the oxide lattice occurs as a result of merging of anion vacancies with defect electrons on defects of the oxide lattice. The transformation of the oxide lattice into the metal lattice requires a certain concentration of anion vacancies and inflow of electrons from the reducing agent to the site of metal segregation. Such inflow has no difficulties due to the mixed anion-electron nature of high-temperature conductivity of oxides. Thus, the reduction is not determined by oxygen diffusion, it is determined by oxygen vacancies diffusion whose speed exceeds the speed of oxygen diffusion by orders of magnitude. This determines that the kinetics of reduction considerably exceeds the kinetics of oxidation at similar temperatures since oxidation proceeds by means of mass transfer of oxygen through the layer of the generated oxide.

Jan 1, 2004

By Lawrence W. Gubbe

Air blast associated with detonation of explosives in mining, construction or military applications is often responsible for complaints by people who live or work in the vicinity of the activity. Most often, the complaints are based on the perception that vibration caused by the airblast damaged one or more residential buildings that may be located within several hundred feet or several miles from the blast site. The potential for airblast to cause damage is related to the amplitude and frequency of the airblast overpressure wave at the receptor. Amplitude and frequency of the overpressure wave are, in turn, dependent upon the type and amount of explosive detonated; the degree of confinement; the distance the wave travels; the topography between the blast site and the receptor; and, atmospheric conditions. It is well known that, as the result of atmospheric focusing, the amplitude of airblast overpressure that exists relatively far from the blast site may be substantially higher than the amplitude associated with the attenuated wave in an isotropic atmosphere. Two methods are available to predict baseline overpressures 1) the Sandia Laboratories, Atomic Energy Commission method as extended by the Naval Ordinance Laboratory (NOL method) and the Ballistic Research Laboratory method (BRL method). These methods are developed by different techniques, are based on different idealized atmospheres and predict widely different results. The amplification factor applied to account for the effect of focusing must be consistent with the method used to predict the baseline overpressure. Theoretically, the amplitude of the overpressure at distances several miles from the blast site could be more than 25 to 100 times the amplitude of the attenuated wave predicted by the BRL method. However, based on comparisons with measured overpressure data is probably less than approximately 3 times the amplitude of the attenuated wave as predicted by the NOL method. This paper is based on research conducted as part of investigations of airblast damage complaints associated with an accidental explosion near Eveleth, Minnesota and with the disposal of military explosives by detonation at the Sierra Army Depot near Herlong, California. The techniques available for estimating the airblast overpressure that might be generated at various distances from the blast site and criteria for evaluating the potential for damage are examined.

Jan 1, 2004

By Sandy Tavelli, Thomas L. Barkley

This discussion will present a case study in developing solutions to a metropolitan quarry’s public relations, legal, environmental, and productivity problems. It details an extensive and detailed project to address the blasting practice in a medium sized quarry that is surrounded by residential and industrial zones. The principle work was done over a four-month duration during the normal production season. It included detailed drilling and blasting audits for baseline information. In addition, geologic characterization, seismic modeling, correction of deviations from best practices, and implementation and monitoring of precise electronic timing to provide dramatic solutions for the quarry. The quarry is in the near suburbs of a large metropolitan city. It is framed on two sides by residential municipalities and on two sides by industrial zones. At the start of the project, the quarry was in court as a result of the lawsuit by one of the neighboring towns that was suing to close the quarry. The lawsuit had progressed to the advanced stage where in the Judge had appointed an arbitrator to make the decision of continued operation. This arbitrator was to observe our progress and recommend to the Judge the disposition of the case.

Jan 1, 2004

By Aly M. Mohammad

The Howland Hook Terminal Facility located in Staten Island, New York is one of the most active container terminals in the Northeast United States. Due to the high capacity of the facility, the Port Authority of New York and New Jersey (PANYNJ) recently acquired the adjacent 37-acre Port Ivory Facility. Expansion of this Site facilitates the additional transfer of goods for rail transport, where formerly the facility was solely highway transport. Upon completion, the facility will have the ability to transfer containers directly to a freight rail line onsite by crossing from Howland Hook Site to the Port Ivory Site via a proposed bridge over Bridge Creek. The geology of the Port Ivory Site consists of shallow glacial deposits left by the leading edge of the last advance of the Wisconsin Glacier. Glacial and marine action over the millennia and the modifications of past construction combined to form a challenging site geologically. Prior to the PANYNJ acquiring the site, the Port Ivory Facility was occupied by Proctor and Gamble for nearly 100 years. Over the course of time, the site has had a variety of structures constructed and demolished at the site. The earliest structures were often supported on shallow foundations and the foundation types used progressed over the years transitioning from low capacity timber piles to various new pile types as they became available; such as Raymond tapered piles, steel piles with concrete cores, precast piles and cast in place foundations. Currently, we are designing 4-foot diameter high capacity drilled shafts to support a new bridge over Bridge Creek to connect the two sites. Drilled shafts proved to be a very economical solution from both a design and construction point of view to carry the axial load of the bridge of approximately 400 tons per shaft. The paper will present a historical evolution of the progress of deep foundation types used at the Port Ivory Site; from low capacity timber piles to high capacity large diameter drilled shafts. The paper will also present changes and modifications of geotechnical design criteria over time that affects the type of deep foundations used. For instance, utilizing new seismic design criteria requires selecting a deep foundation system that withstands seismic loading conditions and overcomes the effects of liquefaction.

Jan 1, 2004

By K. M. Atencio, T. Pike, S. Forrest

We will introduce the Small Business Liability Relief and Brownfields Revitalization Act, which is an amendment to CERCLA and the types of sites it includes and excludes, especially as related to mine-scarred land. We will also describe the types of available funds, whether they are competitive or not, what entities are eligible to receive them, and how to access them. We will introduce the legislation’s liability provisions; for example, the recently issued interim guidance clarifying some of the conditions that contiguous property owners, bona fide prospective purchasers, or innocent landowners must meet to qualify for the liability limitations provided in the Brownfields Law.

Jan 1, 2004

State ownership of minerals results in domestic legislation regulating mining operations. The mining industry today is dominated by a number of transnational companies, each subject to internal and external pressures for a more responsible approach to resource management. Thirty to 40 major companies are responsible for the bulk of the worldÆs mineral production with the balance coming from state-owned, second tier and junior companies and from artisanal miners.Mining companies operating within competitive commercial environments formerly focussed on mineral production. Companies worked to standards and expectations then current which largely failed to recognise the impact of mining activities on community interests. The mining industry acquired a reputation for arrogance, and for placing profitability ahead of issues considered equally or more important by local communities. Current perceptions continue to reflect disquiet about industry attitudes towards traditional land-owners and access to their lands, to environmental contamination, handling and storage of waste materials, utilisation of water and electricity, and to rehabilitation of worked out areas. Major international mining companies concerned at continuing criticism sponsored a series of initiatives with the objective of providing guidance on working harmoniously within the community. Industry commissioned studies, performed through the agency of disinterested parties, resulted in May 2002, in a Declaration being issued at an International Conference in Toronto. The Declaration was based on, but did not reflect all of the recommendations of the MMSD Report, æBreaking New GroundÆ.This paper considers whether benefits would result from the negotiation of a legally binding and enforceable international protocol encompassing the objectives of the MMSD report or the Toronto Declaration. It attempts to identify the problems associated with implementing and enforcing international mining law, should it be introduced. Aspects of mining operations having cover under customary international law are reviewed, as are rights, obligations and remedies for breaches of national mining law. Conclusions are drawn based on established procedures relating to implementing international agreements. The continuing ability of mining companies to operate within communities will result from each satisfying the communityÆs expectations rather than by complying with largely unenforceable legislation.

Jan 1, 2004

By J. von Schéele

OXYFINESTM is an oxyfuel-based concept for in-plant recycling. It enables the possibility of fines, dust, sludge (without any drying step) and other by-products generated by the steel- and metal-producing industries to be recycled directly back into existing processes or a separate on-site unit. The results from a full-scale installation (20 000 t/a) and pilot-scale trials with dry and wet materials in the steel and ferroalloy industries are presented. The latter include materials arising from ferrosilicon, ferrochrome and silicon manganese production. The concept not only provides a solution to the problems associated with dust and sludge generated in metal production, it also turns these materials into a low-cost raw material which is useful for the same production process, thus replacing some of the raw material input. If required, it could also be used, possibly as an intermediate solution, to convert the dust or sludge into an inert material with a suitable shape. Under some conditions, a directly saleable product could also be obtained. The paper reviews this technology, its status and benefits as wells as its possibilities with regard to application in ferroalloy production. Keywords: recycling, fines, dust, sludge, ferroalloys

Jan 1, 2004

The need for formalised geotechnical reporting has not been fully explored at many operations. With the continuing need to provide safer and more efficient workplaces, the requirement for good geotechnical reporting systems (as with other reporting systems) has become of greater importance.Historically, the risk from rockfalls has been the largest cause of fatal injuries in the underground mining industry. The response of the ground to mining is generally poorly documented at many mines. At Olympic Dam, it was found that the existing corporate hazard and incident reporting (HIR) procedure did not record enough specifics about geotechnical issues. A separate and more specific geotechnical reporting process was set up to address this problem.This paper examines the role that geotechnical reporting plays at the WMC Resources Olympic Dam Mine; from reporting and rectifying day-to-day geotechnical issues that affect the operation to documenting and analysing longer term trends.

Jan 1, 2004

By R. W. Nice

Presently about 60% of the world's nickel resources are tied up with lateritic ores while about 25% of the world's nickel is produced from sulphides. Based on this the industry has to focus on improving lateritic nickel economics in order to maintain the high use of the metal worldwide. In 1997 three junior mining companies in Australia organised finance against all odds and commenced development of three separate nickel and cobalt extraction plants treating lateritic nickel ores. All three projects utilise similar pressure acid leaching (PAL) technologies while each has unique metal recovery technologies All projects have experienced numerous processing and maintenance related difficulties such that full ore throughput has been reached by only one operation after five years. This shortfall in performance has caused the owners considerable angst and financial pain. In 2000 Cawse went into receivership and was purchased by an international corporation. Recently, Bulong also went into receivership and has undergone an orderly shutdown, awaiting sale to a new buyer. Murrin Murrin has settled with its financiers and is in a position to operate as planned for many years forward. This paper will discuss a number of the technical difficulties that affect the ore preparation, PAL and solution treatment circuits of these plants. The objective is to identify the cause of some of the difficulties and propose possible solutions so that the next generation of lateritic operations can emerge as technically and, more importantly, economic successes. A number of these process improvements have been identified by the existing operators and in many instances have been or are being implemented into the existing operations.

Jan 1, 2004

By J R. Robinson

Prior to mine development, exploration drilling within the Luise Caldera on Niolam Island encountered gold mineralisation to the northwest of the main Minifie and Lienetz orebodies. This mineralisation was referred to as the Kapit orebody, and ten diamond drill holes were subsequently completed over the area to investigate its economic potential. Several significant mineralised intercepts were returned. These were interpreted using the orebody model developed for Lihir at that time which invoked a strong horizontal control to mineralisation. Additional consideration was given to the elevated geothermal temperatures encountered, the proximity of the mineralisation to the ocean, and its perceived depth below sea level, resulting in the Kapit area being given a low priority for follow up investigation. As a result, no further work was completed over Kapit until recently. The Kapit orebody was the target of an intense diamond drilling programme during 2002/2003. Data from this latest round of drilling has significantly improved understanding of the mineralisation and associated geology. The significant orebody now delineated at Kapit substantially differs from past interpretations, and the latest data has upgraded its economic potential. A resource estimate and other critical studies completed in 2003 enabled an updated reserve statement to be issued in February 2004 including the Kapit mineralisation for the first time. Total Probable Reserves at Kapit stand at 25.2 million tonnes (Mt) at 5.28 grams of gold per tonne (g Au/t), for a total of 4.3 million ounces (Moz) of contained gold.

Jan 1, 2004

By V. L. Ketellapper

This paper discusses the technical issues and stakeholder collaborative processes which resulted in achieving a balance between the reclamation of abandoned mine sites, providing affordable housing, and preservation of open space at the French Gulch Site. Through this process, it was discovered that mine site reclamation would need to be conducted in conjunction with two priorities for community sustainable development: providing affordable housing for locals who work in the resort town of Breckenridge, and open space preservation. It was found that conducting these activities concurrently would result in providing resources necessary to complete mine site reclamation. The first phase of the affordable housing development is almost completed. This development resulted in redevelopment of mining impacted lands and was recognized by the U.S. Environmental Protection Agency (EPA) with a National Smart Growth Award in 2002.Negotiations are also underway to preserve the remaining 1,800 acres of land held by the mining company as open space. This transaction will in turn provide resources to address water quality issues associated with mine discharges.

Jan 1, 2004

By Adrian J. Moore, Alan B. Richards

Responsible blasting requires that rock throw be controlled to ensure that no danger will result to people and property. This paper describes the development and testing of empirical field calibrated formulae that can be used to evaluate rock throw, provide an early warning of when reduced burden will endanger people and property, and prevent flyrock incidents. Inputs to the formulae are charge mass, burden or stemming height, and a site constant that lies within a general range that can be tightened by site calibration. The output is the distance that rock will be thrown, and this ‘design your own flyrock’ quantification can be used to establish both safe clearance distances, and the critical range of burdens and stemming heights where the situation changes rapidly from safe to hazardous. Examples are given of the use of the model to control flyrock in open-pit mining and quarry operations, in situations which are controlled by both burden and stemming height.

Jan 1, 2004

By S. Kahraman, K. Develi, E. Yasar

Four hydraulic top hammers, one pneumatic top hammer, and three down-the-hole drills were observed in several rock types at quarries and highway construction sites to measure the performance data. At the same time, drill cuttings from each drill hole were collected for the determination of the coarseness index (CI), which is the sum of cumulative weight percentages of a particular size-graded sample of debris, and for the determination of median particle size (MPS), which is defined as the particle for which the quantity of particles equals 50% of the total of the cumulative distribution. After the sieve analysis was carried out on the drill cuttings in the laboratory, CI values were calculated and MPS values were obtained from the plots of cumulative undersize vs particle size. The performance data of the drills, CI values, and MPS values were analyzed using the least square regression method. It was seen that strong linear relationships usually exist between penetration rates and CI values, and penetration rates and MPS values for both top hammer drills and down-the-hole drills. Penetration rates increase linearly when increasing the CI and MPS values.

Jan 1, 2004

By D-J Min

Strategies and achievements in the Asian steel industry to construct industrial ecological chain are reviewed largely in the case of Japan, Korea and China. Emphasis is placed on the development of resource circulatory system for the minimisation of various wastes and emissions of green house gases (GHG), toxic gases and polluting particulates. The minimisation includes:Rationalisation of iron and steelmaking processes; Implementation of available relevant measures/technologies; Life cycle assessment in designing steel from semis to assembled products; Reduction, reuse and recycling of materials and energies; and Utilisation of core competence technologies to process domestic and industrial wastes. In view of global nature of the above wastes- and emission-issues, inter-industrial linkage and international cooperation across the borders in the Asian countries have become more important. Inter-industrial linkage definitely serves to cut back the wastes and emissions. Examples of such linkage and factors influencing the sustainability of the linkage are described with expectation for further development of the linkage. Importance of international cooperation cannot be overstressed under the circumstances where steel production in China exceeded 220 Mt and world production exceeded 945 Mt in 2003 and is still increasing. Practical measures are discussed to enhance the linkage and cooperation for effectively promoting the reduction, reuse and recycling, including implications for the nonferrous industry.

Jan 1, 2004

By J. J. Gusek, T. C. Richmond, R. W. Reisinger

A high-altitude (9,500-ft [2,900-m]) historic underground copper mine in Wyoming discharges neutral but copper-laden water into a pristine creek. Under a Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) deferral agreement, the Wyoming Abandoned Mine Land Program performed site characterization and treatment studies in preparation for reclamation of the site. An integral part of the project included addressing the needs of a variety of interested and affected parties, including property owners, local populations, government agencies, and the media. This paper discusses an overall approach and specific methods employed to enlist public support for the project as well as some of the successes and failures experienced.

Jan 1, 2004

By I R. F MacCulloch

Bacterial oxidation of sulfide minerals is a familiar and commercially available process to enhance gold recovery with problem ores. Pintail Systems, a Colorado, USA based company had developed bio-processes for gold recovery based on natural mineral formation and transformation in a global mineral cycle. The biological recovery of precious metals from ore involves a number of mechanisms that are dependent on the metal-mineralogical association. These processes include: partial bio-oxidation of sulfide ores; oxidation of gangue minerals exposing gold to leaching; surfactant properties of bacteria/nutrient solutions that improve wettability of ores and solution contact with leachable gold and silver; and microbial production and excretion of trace amounts of gold lixiviants, and bio-fracturing or biological alteration of ore minerals. Pintail has demonstrated enhanced recovery of precious metals during cyanide detoxification of spent heaps at the end of mine life. Biological recovery processes also have the potential to be applied to in situ mining technologies. The in situ process application could recover gold from subgrade deposits, small deposits or those ore bodies with uneconomic stripping ratios for conventional mining. In situ biomining can be accomplished at a fraction of the cost of conventional mining and leaching and does not have the environmental liabilities associated with many conventional gold lixiviants.

Jan 1, 2004

By Martina Balic

Dynamic properties of the drilled shaft foundations supporting Doremus Avenue Bridge were determined by forced vibration testing. The main objectives of the substructure testing at Doremus Avenue Bridge were: (1) site evaluation with respect to the dynamic soil properties, and, (2) shaft evaluation for the purpose of definition of their dynamic stiffness. The site characterization entailed crosshole testing for the purpose of evaluation of the shear modulus profile. The drilled shaft impedance evaluation was done through forced excitation using an electromagnetic shaker. The responses of the tested shaft, as well as the response of adjacent shafts, were measured for the purpose of evaluation of the shaft interaction. To gain a better insight into the shaft dynamics, one of the shafts was instrumented with five triaxial geophones distributed along the full length of the shaft. The scope and results of the site characterization, shaft impedance and shaft interaction evaluation are presented.

Jan 1, 2004

By Robert Lee, Pertti Paavola

Automated vibration monitoring and web-based data distribution has proven itself on the largest single construction project ever undertaken in Finland. The excavation for the Kamppi Center Project in the center of Helsinki was completed in November of 2003 and involved the removal of over 200,000 m3 (260,000 yd3) of rock and over 1,700 individual blasts. A system was installed, incorporating 37 discrete monitoring points located throughout an underlying metro station, and other surrounding underground and surface facilities. After every blast, vibration data was automatically transferred from the monitoring network to a server database. Stakeholders were able to access and review vibration reports on a password-protected website within 90 seconds of each blast. This allowed engineers to verify that recorded levels were in compliance with established limits, before proceeding with subsequent blasts. The data was also imported into a semi-automated Scaled Distance tool for analysis using linear regression techniques. This was used to determine, and adjust for trends in blast-induced vibration.Copyright

Jan 1, 2004

By H. Hamza

Efficient and effective management of extraction process tailings is an essential ingredient for the continued success and development of Alberta's vast oil sands resources. Open-pit oil sands operations north of Fort McMurray recover bitumen from flotation circuits. Process tailings are managed in carefully engineered and monitored external tailings management facilities and in below-grade mine pits. In order to support reduction of production costs and improve upon established tailings management practices, CANMET has been working with the oil sands industry in a collaborative framework to assess the potential to integrate thickened tailings into oil sands extraction process flowsheets. Albian Sands has commercialized the process while others, including Syncrude Canada Ltd., continue to evaluate the suitability of the process for their operations. This paper provides an update on R&D work undertaken in recent years to assess and develop the potential of thickened tailings technology for the open-pit oil sands operators of northern Alberta. The aim of this work was to explore opportunities to optimize process efficiency and environmental sustainability by improving water and energy conservation and develop more alternatives for tailings management and reclamation.

Jan 1, 2004