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By Huayang Luo, Hui Li, Wei Zhou, Gang Chen, Scott Huang

The beach and offshore gold resources demonstrated at Nome, Alaska are some of the richest found in Alaska. They contain potentially significant resources that may be exploited in the future. Several companies have contributed to the exploration and reserve estimation in Nome offshore gold deposits. More than 3,000 holes were drilled and over 10,000 offshore samples were analyzed in the Nome offshore areas of approximately 40 km2. Those 3,000 plus drill hole logs were converted into digital formats comparable with ArcGIS software. Considerable amounts of mineral resources data were processed and visualized using ArcGIS 8.3 and its geostatistic, 3D analysis, and spatial analysis components. In this study, based on the data processing and visualization results of ArcGIS, a user-friendly website for mineral resource management and utilization is developed using ArcIMS 4.0.1. ArcIMS is a GIS solution to build and deliver maps, data, and tools over the Internet. The Nome offshore mineral resources website presents the geostatistic and GIS analysis information. This site allows clients to access the information and perform ArcGIS analysis, such as interactive data query, and map layers display of the gold resource distribution, average grade, gold reserve, and relative mineral resource estimation via remote computers. With linkage to other related mining web sites, this web site allows users to search for related publications and more flexibly manage the information. A few other appropriate customized tools are also being developed to assist interactions between the server and clients for data analysis and management.

Jan 1, 2005

By Richard Brink, Eric M. Klein, Kenneth B. Andromalos

"A portion of the roof for a 129 x 144-inch, nearly 100-year-old sewer outfall in the City of Baltimore had deteriorated to the point that it resulted in the development of a large sinkhole in a residential neighborhood. A subsequent video inspection of the sewer outfall indicated that there was a hole in the sewer outfall, and it would need to be repaired . After initial backfilling of the sinkhole and repairs to the water service lines, a conventional wood shoring system was used to support the excavation and expose the Main Outfall Sewer to inspect and repair it. This excavation was unsuccessful because of loose sandy soils and high groundwater conditions. An innovative use of a steel reinforced jet grout excavation support system was ultimately used to underpin an adjacent 20-inch water main and other nearby utilities, and provide access to the top of the Main Outfall Sewer some 22 feet below the street surface to facilitate inspection and repair of the sewer. This excavation support system was also successfully utilized in the final repair of the sewer roof by serving as a buttress for the new roof system.1.0 IntroductionThe project site is located in a residential neighborhood with brick masonry row houses situated on the south side of Chase Street and a brick masonry church on the north side of the street. Figure 1 illustrates the location of the site. The City right of way is 65 feet wide, and the street is 40 feet curb to curb. The centerline of the Main Outfall Sewer runs parallel to and a few feet south from the centerline of the street. Other utilities running parallel to the street include a cast iron 20-inch water line built about 1910, a 24-inch terra cotta storm drain, a 6-inch terra cotta sanitary sewer, a 4-inch cast iron gas line and a 40-inch electrical duct. Cross utilities included a 4-inch gas line and several smaller water and gas service lines to the church and row houses. One gas line that was not shown in the City's GIS database was exposed during the excavation."

Jan 1, 2005

By A. Ashrafi

The electrochemical deposition of polypyrrole coating on different pretreated aluminum-alloy 7075 substrates was carried out using cyclic voltammetry, The pretreatment of specimens consisted of mechanical polishing and/or electrochemical etching, In the latter case, an aqueous solution of phosphoric acid and ethanol was used, The electrodeposition solution was 0,25 M pyrrole and 0,1 M oxalic acid in double-distilled water, The cyclic voltammetry scan rate used was 700mv/s, Morphology of the coatings was examined using scanning electron microscope (SEM), Using the Tafel experiment, corrosion resistance of the coated substrates was investigated in 0.1 M NaC1 solutions, Results obtained revealed that electropolymerization of polypyrrole on 7075 aluminum alloy would increase the resistance against corrosion in 0,1M NaC1 solution, Also it was observed that, compared with mechanical polishing, electroetching pretreatment would be more effective.

Jan 1, 2005

By L. Landryova

The Department of Control Systems and Instrumentation, VSB - the Technical University Ostrava, has been involved in a project dealing with utilization of landfill gases, when the methane gas utilization and minimization of its release into the atmosphere was the main concern. The landfill site is generally a place, where technology for energy production can be built. The conditions for this technology implementation vary and depend on various factors. This paper is presenting findings and experience gained regarding a method of methane gas utilization for energy production. This method is concerning building bioreactors at the landfill sites, which are already operated. Every bioreactor can be thought of as a process, which is controlled in order to maximize energy production and minimize the methane gas escape into the atmosphere. The bioreactor landfill can represent a number of environmental and cost savings and, at the same time, is able to comply with all legislative issues.

Jan 1, 2005

By Frank Cappuccitti, James A. Finch, Stéphanie Gélinas

"A colorimetric technique, originally developed for methyl iso butyl carbinol (MIBC) based on the Komarowsky reaction, has been extended to a wide range of common mineral flotation frothers. The procedure, which is briefly described, is shown suited to on-site determinations in a campaign at Kennecott Utah Copper Copperton Concentrator (Rio Tinto). Some observations are described, including: frother (MIBC) concentration evolution down a bank, frother distribution between pulp and froth phases, and loss of frother over time due to adsorption on certain minerals. A possible interference with a fuel oil addition was overcome. MIBC in recycle water was also measured.The ability to monitor frother easily will help interpret gas dispersion behaviour and should permit further optimization of flotation cell hydrodynamics and chemistry. The capability to directly measure should help optimize the type, amount and location of frother addition, and to assess frother recycled with reclaim process water.INTRODUCTIONOwing to the lack of analytical methods, the task of determining frother concentration in plant flotation circuits is not routinely performed. Industrial sites seldom outsource analyses that are both costly and inconvenient, due to the necessity of shipping freeze-dried samples to remote testing facilities. A more direct colorimetric method has recently been demonstrated for the laboratory characterization of common industrial frothers (Gélinas and Finch, 2004). The approach, based on the Komarowsky reaction (Penniman et al., 1936; Coles et al., 1942; Duke, 1947), was previously described by Parkhomovski et al. (1976) for methyl iso butyl carbinol (MIBC). The reaction involves the interaction of the OH group of a higher alcohol, concentrated sulphuric acid, and salicylaldehyde, to yield coloured solutions with intensities that can be analyzed by UV-visible spectrophotometry."

Jan 1, 2005

By A. M. Milev

A stand-alone instrument especially designed for recording strong ground motions was used in this study to create a large data base of peak particle velocities measured on stope hangingwalls. A total number of 58 sites located in stopes mining the Carbon Leader Reef, Ventersdorp Contact Reef, Vaal Reef and Basal Reef were monitored. The peak particle velocities were measured at the surface of the excavations to identify the effect of the free surface and the fractures surrounding the underground mining. From the monitoring results obtained, the velocity criterion of 3 m/s will bean adequate value that support systems have to sustain during a rockburst in most cases. However, PPVs in excess of this criterion were recorded, and some PVDs were damaged or irretrieveable, a consequence of which was that possible extreme events were not recorded. The data recorded on the skin of the excavations were compared to the data recorded by the mine seismic networks to determine the site response, defined as the ratio of the measured peak ground velocity to the peak ground velocity inferred from the mine seismic data. The site response measured at all mines studied was found to be 9 ±3 times on average. Values of the site response did not vary significantly with seismological parameters such as peak ground velocity, hypocentral distance and source radius.

Jan 1, 2005

By T C. Westerfield, G, M J. Mankosa

An innovative separator known as the HydroFloat cell has been developed specifically for the upgrading of coarse particles that are difficult to recover using conventional flotation cells. The novel characteristic of this separator is the formation of a hindered teeter-bed of fluidised solids into which small air bubbles are injected. The air bubbles selectively attach to hydrophobic particles and form particle/bubble agglomerates that segregate atop the teeter-bed due to their lower apparent specific gravity. The low-density agglomerates are eventually carried into the product overflow launder by the rising current of teeter water. Hydrophilic particles remain in the teeter-bed and are discharged to underflow as a high solids content tailing. Benefits of this hybrid flotation-density separator include enhanced bubble-particle contacting, increased particle residence time, and very low air demand. Test data indicate that significant improvements in the recovery of coarse particles can be achieved using this innovative technology. This article describes the theoretical basis for the development of the HydroFloat cell and provides an overview of recent pilot-scale tests conducted for the phosphate industry.

Jan 1, 2005

By Numan Elmas

Barite deposits located in Dinek and surrounding region have important economic features with their large reserve capacity for Turkey. The objective of this study is to elucidate geological and depositional characteristics in terms of. site investigation and chemical analysis. In order to do this, geological area of about 300 km2 was examined and detailed geological map was constructed. It was observed that Barite mineralization in these deposits was occurred in carbonate and pelitic rocks of Lower Cambrian-Lower Ordovician. Deposits were exposed to advanced diagenesis regional metamorphism and tectonics that rotated and deformed the barites; therefore, barites shows secondary veins, brecciate and fracturing structure. Even though, a few light isotope values of barites may suggest hydrothermal and exhalative sedimentary characteristics or possible mixing with magmatic fluids, generally heavy isotope values indicate that the sulfate ions were supplied from coeval seawater and, many of sedimentary features and petrological, geochemical characters support dominantly sedimentary origin.

Jan 1, 2005

By Mikko Ruonala, Pertti Lamberg, Olli Hyvärinen

The smelting of copper sulphide concentrate is the dominant route in copper production (Figure 1). Heap leaching of oxidized copper ores with weak sulphuric acid together with copper solvent extraction and electrowinning has gained popularity during recent decades, and it accounts for close to 20 % of primary copper production. Heap leaching offers advantages such as lower costs and consequently the construction of a production plant at a mine site is made possible. Limited resources of oxidized copper ores, the long leaching time of chalcopyrite and inability to recover gold inhibit this growth. The HydroCopperTM process developed by Outokumpu Technology at the laboratories of Outokumpu Research, Pori, Finland, is a new chloride leaching technology /1,2/, which offers an alternative to smelting and heap leaching (Figure 1). In the HydroCopperTM process sulphidic concentrates with various mineralogy and grade can be treated at the mine site to produce high-quality copper. Instead of copper cathodes the HydroCopperTM end products are copper wire rod, copper bars or copper billets. One of the advantages of HydroCopperTM technology is that gold can also be recovered in the process simultaneously /3/. To confirm the functioning of the new process and to dimension equipment Outokumpu Technology built the HydroCopperTM demonstration plant in Pori, Finland /4/. It has a capacity of 1 metric ton of copper per day. After testing with Pyhäsalmi copper concentrate in 2003, the first commercial demonstration run with Erdenet copper concentrate took place in 2004.

Jan 1, 2005

By Yannick Beaudoin

The source of base metals in modern seafloor hydrothermal systems can be attributed to leaching of host rocks by hydrothermal fluids and/or potentially by direct degassing of magma. From an economic perspective, metal grade is the most important consideration for seafloor deposits. Tectonic setting appears to be a key factor influencing the development of high grade seafloor base metal sulfide deposits. Back-arcs have a clear advantage over other settings in producing large and rich polymetallic sulfide ores. Microinclusions of magma or so-called melt inclusions trapped in phenocrysts of lavas have contributed to our understanding of the ore-forming process. n this study, we present data from 103 melt inclusions mainly in plagioclase crystals hosted in basaltic to rhyolitic lavas from 9 modern seafloor tectonic settings: oceanic back-arcs (Manus Basin including an ODP Leg 193 drill hole, Bransfield Straits), continental back-arc (Okinawa Trough), mid-ocean ridges (Explorer, MAR), seamounts (Foundation, Axial, Pito), and a transform (Garrett). Most sites host active hydrothermal systems that are producing polymetallic sulfides.

Jan 1, 2005

By Monica Prezzi

"Auger cast-in-place (ACIP} piles and drilled displacement piles are being increasingly used as foundation elements for structures, particularly in projects requiring accelerated construction or involving the rehabilitation of foundations of existing, overstressed structures. Auger cast-in-place piles (also referred to as continuous-flight-auger piles) are widely used to construct the foundations of all types of structures. There are many different types of drilled displacement piles, with the installation methods varying according to the equipment used. Depending on the specific rotary piling technology used, responses ranging from those associated with non-displacement to those associated with full-displacement piles are obtained. Conventional pile design methods do not account for how the various construction techniques involved in auger piling change the soil state around the pile during installation and, hence, cannot accurately estimate the pile resistance in a consistent way. Research on this subject, identifying the different variables that must be accounted for in design and linking these variables to installation methods, is lacking. This paper describes the different piling methods available for auger cast-in-place and drilled displacement piles, the equipment used to install them and the quality control processes typically used. It also reviews some of the design methods currently used.IntroductionDeep foundations are extensively used in geotechnical engineering practice. The wide spectrum of piling methods results in a variety of pile types. Each type behaves differently, depending on the installation or construction methods. On one end of the spectrum are non-displacement piles, the classicql examples of which are bored piles or drilled · shafts. These piles are constructed by removing a cylinder of soil from the ground and replacing it with concrete and reinforcement. On the other end are full-displacement piles, such as closed-ended pipe piles or precast reinforced concrete piles, which are typically driven into the ground. Driven piles preload the materials below the toe of the pile and displace the soil surrounding the pile shaft laterally during the installation process. Therefore, displacement piles are, in general, more likely to have a stiffer response than non-displacement piles. This is true particularly in the case of sandy soils where displacement causes densification."

Jan 1, 2005

By A. Nivala, S. Ulgiati, M. Canino

Mining and processing of bastnaesite ore, (Ln)CO3F, for lanthanides extraction is investigated in this paper. This series of elements proved to be applicable for a wide range of high-tech uses. In spite of the strategic importance of lanthanides, no LCA and energy analyses of their extraction have ever been published. We perform in this paper a Life Cycle Assessment of the Lanthanide production cycle, based on available database and literature data from Mountain Pass mine (USA) and other worldwide mining and processing sites, most of which in China. We investigated three main steps: mining, milling (including transport, grinding and drying), and flotation (for lanthanide chloride extraction). We do not investigate here the separation of pure oxides from lanthanide chloride, a compound which is also marketed as such. The conventional LCA was integrated by means of energy and emergy evaluations, aimed at investigating respectively the global energy cost and the environmental sustainability of the process. Indicators of material intensity, thermodynamic efficiency, and environmental impact (including LCA and ecological footprint impact categories) are calculated and discussed.

Jan 1, 2005

By P. M. Soupios

A near geophysical surface investigation of a landfill area close to the Hania city, in Crete Island, Greece, was conducted as inextricable phase of a preliminary geotechnical, geological and hydrogeological study of the area under investigation. Electrical Resistivity Tomography (ERT), one of the most promising prospecting techniques mainly concerning its effective contribution to resolve several environmental problems, was applied for the geophysical modelling. ERT is a robust imaging method the theory and implementation of which are well documented in geophysical research literature. The survey site is located in Akrotirion Peninsula, about 7km east of Hania city in Crete I. The geological setting comprises Trypalion limestones, marly limestones and a clayed weathered layer. Cavities are also identified at various scales which are recent tectono-karstic voids resulted from the combined actions of karstic erosion and tectonic stress on the Trypalion limestones where they are located. Due to the above-mentioned geological singularity and in the light of the requirement for an environmentally safe construction of the landfill, an ERT survey was carried out by deploying the dipole?dipole electrode configuration. Specifically, seven geoelectrical tomographies were conducted reaching the prospecting depth of 36m. The resulted images conduced, a) to overcome geotechnical problems, b) to plan the future sites for waste disposal and c) to reliably estimate the thickness of the already deposited wastes.

Jan 1, 2005

By R. Baker

A novel electrochemical half-cell and corresponding working electrode were designed to evaluate the electro-catalytic activities of catalysts in an environment close to that of an operating proton exchange or polymer electrolyte fuel cell (PEMFC). Cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) techniques were employed using the novel cell to characterize various methanol electro-oxidation parameters that contribute to the overall reaction on a fuel cell anode. The effect of temperature on methanol oxidation kinetics was examined in the potential range of 0.31 to 0.65V (vs. NHE). The data was collected in the temperature range of 20 to 80°C. Based on the experimental analysis and literature data, an equivalent circuit model (ECM) for methanol oxidation was proposed and was used to fit the EIS experimental data. The experimental data and ECM electrochemical data was used to extract electrochemical kinetic parameters for methanol oxidation such as the exchange current density, Tafel slope, and energy of activation for the reaction. Kinetic data, especially at different temperatures, is very limited in the literature.

Jan 1, 2005

By P. N. Psarropoulos

During many strong earthquakes in the past, a significant number of tailings dams failures has been recorded, leading in some cases to human life losses. However, over the last decades, seismic design of tailings dams has drawn much attention mainly due to the high environmental hazard. Although the stability of such geostructures under dynamic loading is mainly related to their liquefaction potential, there exist several technical issues that have not been adequately investigated. One of these issues is the impact of local site conditions on the dynamic earthquake stresses developed, and therefore on the inertial instability of these dams. Based on the models examined in the first part of the present study (Stability of Tailings Dams ? Part I: Static Loading), two-dimensional numerical simulations are performed in order to examine the effects of local site conditions in the dynamic response of tailings dams. Imposing dynamic loading via characteristic pulses and real earthquake records, the most commonly used types of construction methods are studied at their final stage. Emphasis is given on the special characteristics of the ground motion, while the material nonlinearity of both soil and tailings is taken into account by an equivalent-linear procedure. The results obtained indicate that local site conditions may have a significant impact on the seismic response of a tailings dam.

Jan 1, 2005

By F. L. Pirkle, D. L. Pirkle, E. C. Pirkle, W. A. Pirkle

Heavy minerals have been mined from the sands of the United States’ Atlantic Coastal Plain since the early part of the twentieth century. Production of ilmenite from beach sands near Mineral City (Ponte Vedra), Florida, began in 1916. The first reported large-scale recovery of zircon in Florida was reported from this deposit in 1922 and of rutile in 1925. These operations ceased in 1929. Today the Ponte Vedra Country Club and Golf Course is situated in the center of the former mining site. In 1942 heavy-mineral operations were established on 202 hectares of land situated in Duval County, Florida. The location is about 16 kilometers east of the center of Jacksonville, Florida, in an area known as Arlington. This operation demonstrated that low-grade sand containing only 2 to 3 percent titanium minerals could be concentrated economically with the Humphreys spiral and that the oxides could be separated from the heavy silicates by electrostatic methods. Much of this area is now covered by a large mall and is a major retail- commercial center. Between 1958 and 1964 the Skinner tract, a deposit about 4 kilometers south of the above deposit, was mined. Today the area of this deposit is known as Deerwood, a gated country club community on the southside of Jacksonville. Further inland, E.I. du Pont de Nemours and Co. has been mining heavy minerals from a physiographic feature known as Trail Ridge since 1948, and a deposit near Green Cove Springs, Florida has been in production since 1972. Since the start of heavy-mineral mining in the southeastern United States, nine heavy-mineral ore bodies either have been or are being exploited in Florida and Georgia. Other deposits either have been lost to mining or are yet to be mined. These deposits have different origins. Some formed along shorelines at the heights of marine transgressions while others formed on regressional beach ridge plains during periods of temporary stillstands or slight transgressions. These different origins are reflected in the chemical and physical characteristics of the deposits. Ilmenite in older, more western deposits has a higher TiO2 content than ilmenite in younger, more eastern deposits. TiO2 content does not very with north-south direction. Garnet and epidote are absent or rare in the older Trail Ridge deposits, but progressively become common in the younger Duval Upland, Crestal Pamlico, and Holocene deposits. Grain size is coarsest for Trail Ridge sediments and finest for sediments in Duval Upland and Crestal Pamlico deposits. The average grain size for Holocene deposits is intermediate between Trail Ridge and Duval Upland deposits. The two models for the origin of the heavy-mineral deposits – deposits formed at the height of major marine transgression; and deposits formed during periods of temporary stillstands or slight transgressions that occur during a general marine regression; - are consistent with known sedimentological data and depositional trends.

Jan 1, 2005

By Thomas E. Lobb, Harry C. Verakis

Significant progress has been made in the reduction of serious injuries and fatalities resulting from mine blasting operations. Despite the progress, injuries and fatalities continue to occur. A leading cause of injuries and fatalities from blasting continues to be inadequate blast area security. Even though significant improvements in technology have been made, insuring adequate blast area security remains a challenge and requires constant vigilance. The advances in technology have created safer blasting products and have improved productivity and economics by enabling large, more efficient and effective blasts. However, as blasts grow larger in size, the complexity of adequately securing the blast area increases even more. Periodically the basic fundamentals involved in blasting safety should be reviewed, particularly for securing a blast site regardless of the size of the planned blast. Factors such as flyrock and toxic fumes must be taken into account to insure the safety of persons and property from the results of a blast. This paper examines the factors related to injuries due to inadequate blasting shelters and blast area security, and identifies mitigation techniques. The key concepts are: (a) accurate determination of the bounds of the blast area, (b) clearing employees from the blast area, (c) effective access control, (d) use of adequate blasting shelters, (e) efficient communications, and (f) training. Fundamentals are reviewed with an emphasis on analyzing task elements and identifying root causes for selected blasting accidents. Mitigating techniques are presented along with discussions and examples.

Jan 1, 2005

By P. M. Soupios

The study of soft soil (wastes above the rock bed) an issue of great importance in civil engineering, is usually addressed by drilling boreholes. This method is rather expensive and time-consuming and although the information obtained is usually accurate, on the other hand it is much localized. Recently published researches have demonstrated the ability of the combination of geophysical exploration methods to estimate the thickness of deposited wastes, which provides the layered structure of the study area and certain, method depended, mechanical parameters as well. By theory, the frequency of resonance of an upper layer is a function of its thickness and the average shear velocity in it. Furthermore, the application of H/V spectral ratios of micro-tremors is a fast, straight forward and cost effective methodology, yielding the determination of the main resonant frequency of the soil. Based on this framework, 20 microtremor measurements have been carried out in a Landfill in Heraklion-Crete. Some of these measurements were deliberately close to drilled sites, where the basement had been reached. Three electrical resistivity tomographies were also used, in order to define the landfill structure such as, thickness, determination of different wastes distribution in the study area and other parameters. In addition, estimation of predictive Vs using empirical relationship between shear velocity and penetration resistance (SPT?s) were also conducted. Knowing the thickness and the resonant frequency, we estimated the shear (Vs) velocity of the waste cover. The final Vs model was confirmed using the results from the Vs-SPT correlation. The combinative implementation of the above mentioned geophysical and geotechnical methods have successfully defined geometrical and geotechnical/geophysical characteristics of the area under investigation in a fast and cost effective way.

Jan 1, 2005

By D. H. Schwarz

The performance of proton exchange membrane (PEM) fuel cells depends on catalyst layer composition and structure. Experimental observations reveal that state-of-the-art catalyst layers consist of microporous agglomerates of carbon-supported catalyst sites bound together by polymer electrolyte. In between the agglomerates are macropores which provide pathways for the transport of gaseous reactants. In this work, three-dimensional, multicomponent and multiphase transport computations are performed using a computational fluid dynamics (CFD) code (FLUENTTM) with a new PEM fuel cell module, which has been further improved by taking into account the detailed composition and structure of the catalyst layers using a multiple thin-film agglomerate model. In this model, it is assumed that thin films of polymer electrolyte and liquid water surround the catalyst sites. The results of CFD computations show that transport limitations associated with the thin film of polymer electrolyte and the presence of liquid water in the catalyst and gas diffusion layers have substantial negative effects on PEM fuel cell performance. Also, the results of computations with variable distributions for a given precious metal loading show that, in general, uniform catalyst loading provides the best fuel cell performance.

Jan 1, 2005

By Junya Tokita

In Japan, packaged explosives have traditionally been used as the most common explosive for tunneling. Recently, some blasting systems such as ANFO with a kettle loader and emulsion explosives with a pump loader have been trialed in order to improve safety and efficiency of the charging process. There are issues with these systems relative to the Japanese market. ANFO dissolves in water easily, and generates ammonia gas when it contacts with concrete. Emulsion explosives need costly pump ing unit s, and there is a need to control residuals in the pump unit. Additionally, there are obstacles by Japanese law to site mixing of emulsion explosives.

Jan 1, 2005