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By M. R. Julien, A. Maqsoud, J. Martschuk, B. Bussière

Acid mine drainage (AMD) from mine wastes is one of the most challenging environmental problems currently facing the mining industry. When mining wastes have the potential to produce AMD, the effluents produced have to be managed to meet existing regulations on water quality. The LTA impoundment (property of Barrick Gold Corp.) located near Malartic, Quebec, contains sulphide tailings that have the potential to generate an acidic leachate. The closure option selected by Barrick was to construct a cover with capillary barrier effects (CCBE), in which the moisture- retaining layer is made of non-acid-generating tailings. Since its construction in 1996, the cover has been monitored to evaluate its performance. For that purpose, various parameters have been measured, including the volumetric water content and matric suction in the different layers of the cover. This paper presents some of the main results from the monitoring program that started eight years ago. The results show that the cover is able to maintain a high degree of saturation in its moisture- retaining layer, acting as an oxygen barrier. The actual performance of the CCBE on the flat surface of the 60 ha site is better than expected at the design stage. The only concern with the LTA cover is the effect of slopes that can reduce the performance of the CCBE during dry periods. However, these effects appear only for short periods of time, and are limited to very localized areas, so that they do not significantly affect the overall performance of the CCBE and its ability to limit the production of AMD.

Jan 1, 2006

By St. E. Deák

This paper focuses on maintenance of underground salt air curative quality using environmental friendly solutions. Possible ways to preserve its curative properties, in relation with the admissible salt air quality parameters, are analyzed. In situ investigations regarding microbiological impregnation in walls and the air inside the Romanian salt sanatorium were initiated. The results of a pilot project, which is in progress at Praid salt mine, are presented. After the end of the investigation at this site, investigations will continue in other Romanian salt mines, such as Slanic Prahova, Targu Ocna and Cacica.

Jan 1, 2006

By I. Ciabatti

Inorganic salts of hexavalent iron (ferrate (VI)) are versatile reagents for water and industrial effluent treatment because of the strong oxidising effect of the ferrate ion (FeO42-) and the well-known coagulation properties of the resulting ferric ion. Among other applications, ferrate can effectively remove arsenic, cyanide and phenols from industrial effluents. Furthermore, ferrate salts can be prepared from ferrous sulphate, a common byproduct of the steel and titanium industries, and possibly from other iron wastes. Notwithstanding their many potential advantages, the industrial-scale application of ferrate salts, such as potassium ferrate (K2FeO4), for effluent treatment has been hindered by the difficulties inherent in their synthesis and stabilisation. Within a project co-funded by the European Commission, the large-scale synthesis of stabilised potassium ferrate was realised through a new synthesis process, and different applications of the resulting ferrate to effluent and wastewater treatment are under investigation. This paper reports the results of the application of stabilised potassium ferrate for the purification of textile effluents. Laboratory and pilot-scale tests were carried out and the performance of the ferrate was compared to that of chemicals currently used in wastewater treatment. According to these experiments, potassium ferrate is a promising reagent for an effective treatment of textile and other industrial effluents.

Jan 1, 2006

By Koichi Kobayashi

Performance-based approach to design of structures including foundations was adopted after enforcement of the revised Building Standard Law in Japan in 2000. The use of piled-raft foundation is favorable for medium-rise buildings in soft ground because of its good performance. In the design of the piled-raft foundation (Architectural Institute of JAPAN2002), vertical load is usually carried by the raft foundation, while the pile is primarily meant to control settlement of the structure. Shaft friction is expected to be larger in a nodular pile(Karkee, et.al., 1998) since it has larger surface area than a straight pile, and such piles are frequently used in piled-raft foundations. Since few structures with piled-raft foundation exist currently, the settlement characteristics of piled-raft foundation have not been fully clarified. To design piled-raft foundations with better confidence, the mechanism of vertical bearing capacity and the spatial distribution of settlement should be clarified, for which the actual behavior of the building-foundation system needs to be evaluated. This paper presents observations of settlement of a building with a piled-raft foundation at a soft ground site. The building is a steel structure covering an area an 766 m2, and consists of two-storey office block and one-storey warehouse block. The filled ground of about 5-m thickness at the ground surface is underlain by approximately 4-m thick alluvial sand layer below which lies about a 17-m thick alluvial clay layer with SPT N-value less than 2. The piles used in the piled-raft foundation are 12-m long nodular piles with nodal diameter of 500 mm (pile shaft diameter is 400 mm). The bored pre-cast piling method (Karkee, et.al., 1998) was used to install the piles. To evaluate the foundation settlement, the method of analysis of three-dimensional frame system, utilized widely in Japan, was adopted in combination with the foundation system. Basic assumptions were: (i) total ground settlement is evaluated as the sum of immediate settlement and consolidation settlement, (ii) immediate settlement is evaluated from the Mindlin?s solution in which strain dependency of shear modulus of soil is considered, (iii) settlement in clayey layers is evaluated by the one-dimensional consolidation theory, and (iv) shear spring between soil and pile shaft is represented by a hyperbolic function. The applicability of the method of analysis was verified by comparison with results of field monitoring of building settlement.

Jan 1, 2006

By B L. Dickson, E, M F. Lee, P A. Mikula

Computational techniques are needed to assist in the analysis and interpretation of the increasing amounts of geoscientific and mining related data and information that are routinely gathered at mine sites. New interpretation methods are needed to provide an integrated approach so as to establish relationships (cause and effect) or to be predictive about possible outcomes based on acquired data. Traditional multivariate statistical methods are often confused by variable relationships that are non-linear, data distributions that are non-normal, and by the data themselves that may contain missing values, text and both continuous and discontinuous numeric values. Modern data mining methods are available to understand the relationships within and between diverse data sets, and identify relationships or trends associated with processes, measurements and mine design parameters in mines. The self-organizing map (SOM) is a data mining approach with the advantage that all input data samples are represented as vectors in a data-space defined by the observations (variables). The SOM procedure is an exploratory analysis tool that highlights patterns and relationships. Results are internally derived, in an unsupervised fashion based on measures of vector similarity. Our SOM outputs are highly visual, which assists in understanding and illustrating the dataÆs structure and internal relationships. Two studies are presented. The first uses SOM to investigate the relationships between a range of measured and derived rock property parameters and their observed behaviours during mining. Our aim was to determine whether a SOM analysis would allow a better understanding of observed and predicted rock behaviours from their rock properties. The SOM analysis showed that there were indeed relationships between æbrittleÆ, æsugaryÆ, æslabbyÆ and æsqueezingÆ rock behaviours and a number of the input parameters. The computed SOM æstructureÆ was then used to assess the likely behaviour of unknown samples by assigning them into behavioural fields based on their measured and derived geotechnical responses. The second study was aimed at assessing whether a SOM analysis of microseismic data at the Kalgoorlie Consolidated Gold MineÆs (KCGM) Mt Charlotte mine can contribute towards understanding and potentially forecasting/minimising seismicity at the mine-design stage. The database comprised 40 sample æclustersÆ of microseismic parameters from the MS-RAP software package, which were derived from 2500 individual seismic events. The SOM analysis showed that some of the initial mining conditions are related to the seismic parameters. In each of the studies, the SOM procedures assisted in understanding the data and provided new insights. Because of its æordered vector quantisationÆ foundation, the SOM procedure is a substantial improvement over traditional statistical methods in three main areas:its ability to analyse data from disparate sources, including different data types; its ability to analyse sparse data sets with missing values; and its ability to analyse and visualise non-linear relationships within a data set.

Jan 1, 2006

By X. S. Yuan

With the production increase of Oil Sand in Fort McMurray Alberta, more efficient tailings disposal has become a priority for Syncrude Canada Ltd. A lot of work on tailings research and development has been compiled to determine the most effective deposition to increase reclamation options, water re-use and thermal energy recovery. Efficient flocculation of fine oil sand tailings is the key technology for thickening. It was identified that flocculation of fine transition/marine ore tailings using a single flocculant was not effective. The thickener overflow contains 1-4% solids content compared with the target solids content of <0.5% obtained with Estuarine ore. As a result, novel processes for treatment of fine transition/marine ore tailings have been developed at Syncrude Bitumen Production Development since June 2004. While the conventional processes using a single flocculant, a single coagulation, or a coagulant-flocculant combination was ineffective for transition and marine ore tailings, the new processes including Coagulation-Flocculation-Coagulation (CFC), Flocculation-Coagulation (FC) and Flocculation-Coagulation-Flocculation (FCF) were acceptable options. The key components of these technologies consist of the recipe of chemicals and their adding sequence. With these technologies, almost all sub-micron clay minerals are aggregated together and settle as a whole, resulting in a clear supernatant of less than 0.1% solids.

Jan 1, 2006

By John Canterford

Quay Magnesium Limited (QMG) listed on the Australian Stock Exchange in late September 2004 having raised approximately A$30 million with the object of designing, constructing, commissioning and operating a 15,000 t/a magnesium alloy production facility in Nanjing, China, Site construction commenced in February 2005 with installation of all major components completed by the end of October 2005, Hot commissioning was simultaneously commenced with the final stages of installation, leading to the first stage of continuous ingot casting by mid November 2005, Since that time ramp-up to the name plate capacity has been undertaken, This presentation highlights some of the more significant technical and logistical hurdles that have had to be overcome in order to meet the high quality product specifications required by a range of QMG customers.

Jan 1, 2006

By D. Verhulst

The Altair process digests ilmenite concentrate in high-chloride HC1 solution, with complete dissolution of titanium and iron. The Fe(III) ions are reduced to the ferrous form, and the solution is cooled to produce crystalline ferrous chloride. Titanium is transferred by solvent extraction into a purified, concentrated Ti stream, which is spray-hydrolyzed to produce TiO2 hydrate. The hydrate is further calcined with additives to generate a high-quality pigment. All the chloride streams are recycled. In the original flowsheet, the iron chloride is pyrohydrolyzed by spray roasting to regenerate 18% HCl, which is subsequently converted to HC1 gas and water by pressure-swing distillation. A modified flowsheet includes an alternative to iron chloride spray roasting, producing more concentrated HCl and decreasing the amount of solution to be distilled. Improvements in digestion, solvent extraction and final pigment production are also introduced. A 100 t/y pilot plant is being built and will test the new concepts and confirm the overall water, acid and impurity balances of the process.

Jan 1, 2006

By James L. Vinson

Wilbur Smith Associates (WSA) has provided planning, engineering and construction oversight assistance to the Tennessee Department of Transportation (TDOT) for three construction projects intended to widen and improve segments of I-40 and associated interchanges in Knoxville, Tennessee. The projects are within the karst terrain of the Valley and Ridge Province. Subsurface conditions are characterized by an irregular rock surface coupled with differential weathering. Because of the projects? impact to local and interstate motorists, consideration was given to innovative planning, materials and construction practices that could accelerate construction. Two innovative deep foundation measures included rock-socketed pipe piles, which act as both foundations and substructure elements for a bridge?s interior bents, and the first widespread use of rock-socketed drilled shafts as bridge foundations on a TDOT project. The pipe piles were used at a site with significant cavities within the limestone bedrock. This resulted in design verification and constructability difficulties that required delays, but measures were ultimately employed to produce a sound foundation system. Over 110 drilled shafts have been constructed at sites with generally low solution activity. Relative to H-pile footings, which were included as an alternate foundation, they have apparently allowed accelerated construction at a competitive cost.

Jan 1, 2006

By C. Blawert

In spite of various corrosion studies on HPDC AZ91, there is no clear indication which microstructure gives the best corrosion performance. The skin with its fine microstructure is sometimes reported to have the best corrosion resistance, but there is no clear definition of the skin. If the skin is the outermost part of the casting and nothing is removed from it, then it is contaminated and the corrosion resistance is low. If the outermost skin is removed (about 25 µm) then a better corrosion resistance can be obtained. However this does not automatically mean that there is no other region in the bulk of the casting which could have a similar or even better corrosion resistance. Indeed, the corrosion measurements including potentiodynamic polarization and long term electrochemical impedance spectroscopy (EIS) revealed a lower corrosion resistance of the original as-cast skin about 100 pm thick. The thickness of this region is more or less independent from the thickness of the casting section. The surface region is free from any dendritic grain growth which influences the amount and distribution of the 13-phase and therefore the distribution of the most important alloying element Al. This could explain the different corrosion behavior. Further reason can be found in the enrichment of some impurities such as Fe in the near surface.

Jan 1, 2006

By L. Shang

In conventional continuous hot rolling processes, metals are usually reheated to a temperature such that the workpiece will maintain appropriate hot working characteristics as it proceeds through the rolling mill, assuming that the temperature is continually decreasing. Metallurgically, reheating will reduce micro-segregation in the as-cast material, may increase the as-cast grain size and will affect any second phase particles present in the as-cast structure. All these changes can affect the hot working characteristics, and the final as-hot rolled microstructure. In order to study the effect of reheating on AZ31 magnesium alloy, a plate sample was cast in a water cooled copper mould and a series of compression tests was performed at a temperature of 350 °C, strain rate 0.01 5-1, and strains from 0.2 to 1.0, after different reheating schedules. It was found that there is no significant difference in flow behavior between the as-cast sample and all but one of the reheated ones. The reheat treatment of the &apos;anomalous&apos; sample was a two stage heat treatment; it was first reheated to 450 °C, cooled to room temperature, then reheated to 350 °C. The effect on the flow curve was to increase the flow stress. This result may be related to changes in second phase particle characteristics.

Jan 1, 2006

By C. Gaubert, G. Bourassa

"The construction or rebuild process in the anode baking furnaces has been modeled with the software Rockwell Arena, in order to minimize the process cost and risk. The case study was focused on the sectional rebuild (""on the fly"") that needs a high coordination of the material inventory, the on-site personnel and the construction/production schedule. Multiple entities and resources were allocated for the different part of the process (in-furnace process, prefabrication, materials transportation, etc.). Logic flow charts and VBA macros were used to simulate the space utilization (including cranes utilization) and interaction with production. MS-Excel output files can show user-friendly results."

Jan 1, 2006

By F. Ajersch, A. R. Hekmat

Apparent viscosities of hypo-eutectic (Al-7% Al) and hyper-eutectic (Al-35% Si) binary alloys were measured in the semi-solid state using a Couette type viscometer at variable shear rates. Analysis of the microstructural evolution demonstrates the differences in the rate and degree of attrition of the primary phase particles which are characteristic of the thixotropic nature of the semi-solid alloy. It was observed that the Si primary phase in the hyper-eutectic alloy is much more difficult to fragment than the dendritic a-Al phase in the hypo-eutectic alloy. For the case of the a-Al, the dendritic structure is broken down by attrition and fracture of the dendrite arms whereas the fracture of the Si hexagonal crystals in the hypereutectic alloy occurs along the {100} and {110} cleavage planes. Results are presented for fixed solid fractions of the primary phase at isotherm condition for each type of alloy.

Jan 1, 2006

By John E. Leitch

The cost of corrosion as measured by such cost components as the renovation or replacement of coated steel, or the use of expensive coating systems on steel, is considerable. Extrapolating from figures for the USA would place the overall cost of corrosion for South Africa as a figure of the order of magnitude of something over 1% of the GNP. This is a sizeable amount, of which costs associated with atmospheric corrosion would be a significant proportion. The corrosivity of an atmosphere can be defined as the ability of the atmosphere to cause corrosion in a given metal or alloy (International Standards Organization [1]). The ISO Standard 9223 specifies the key factors in the atmospheric corrosion of metals and alloys, and defines categories of corrosivity on the basis of these factors. Prior to the publication of that ISO standard, Callaghan published the results of his twenty-year exposure programme and his excellent corrosivity map of Southern Africa [2]. The present author published updates of the corrosivity map in 1999 [3] and again in 2003 [4]. The summary of the individual areas of corrosivity around Southern Africa was published in the latter paper, and is reproduced here as the following TABLE 1. Of significance in TABLE 1 are the numerous regions of very high corrosivity (C5 or beyond), particularly the rural West Coast shoreline, the North East Coast (KZN) shoreline, and the coastal cities Cape Town, Durban and Richards Bay. The corrosivity map as published is obviously based on much extrapolation as only a small number of points have been measured. During the past three years further measurements have been made, mostly however at the same sites in order to give greater reliability and to monitor long-term trends with changes in pollution. These two aspects are incorporated in this update. There has become available a greater amount of air pollution data for centres in South Africa than was the case some years ago. In this present paper the pollution data are used to extrapolate the corrosivity over areas where little or no direct corrosivity measurement has been made. This methodology is described in ISO 9223.

Jan 1, 2006

By Hodjat] [Shiri

A 4-legged jacket structure was installed by an Offshore Installation Contractor (OIC) in the Persian Gulf. In addition to four open-end pipe piles, six conductors were installed by OIC. During the installation of the piles and conductors, some cemented layers were encountered, which had not been accounted for in the foundation design performed by an independent well known offshore geotechnical site investigation contractor (OGSIC). Six months later, the Drilling Company (DC) hired by Client to execute the wells, reported that all of the six conductors were presenting anomalies, such as vertical misalignments up to 10o and/or collapse of the conductors tip and mid height. The DC faced with serious problem in drilling of the wells and in spite of several times milling the conductors and spending 40 days unpredicted extra time, some of the routes could not be opened and Client lost millions of dollars due to direct and indirect associated costs and expenses. This paper presents a complete overview of all engineering, construction and specially geotechnical investigations and shows that how an inaccuracy in interpretations of the results of an offshore geotechnical site investigation as the main reason in this case study can cause serious damages to whole project with unbelievable time and cost impacts some times up to millions of dollars.

Jan 1, 2006

A variety of environmental financial assurance instruments are in use across the globe. This paper reviews some of the more common forms currently used in New Zealand, Canada, USA and Australia. In order to be effective, the form of assurance instrument selected needs to be aligned with a countryÆs specific environmental objectives, geography and political climates and also allow for a healthy investment climate. Industry and Government both have a strong interest in ensuring financial assurance criteria meet these objectives. &nbsp; Recently Golder Associates have been involved in financial assurance assessments for various mining and quarrying companies across the South Island. Multiple stakeholders and regulatory agencies can make the setting of effective and fair financial assurance criteria a complex exercise for both regulatory agencies and industry. &nbsp;The author relates experience gained in assessing financial assurance under current New Zealand legislation (RMA, 1991), effectively dealing with issues such as ôdouble bondingö and overviews potential approaches to dealing with transitional issues for historic and existing operating mine sites.

Jan 1, 2006

By Ron Tluczek

[Power Point Presentation]

Jan 1, 2006

By L. Diels

About 45% of the contaminated sites are dealing with heavy metal problems. Metals are spread in the environment by mining activities, surface treatment and non ferrous processing. As heavy metals can not be degraded, removal or immobilization (leading to bioavailability reduction) are the only risk reducing measures that exist. The currently best available technique for remediation of heavy metal contaminated groundwater is to pump the contaminated water and to treat it in a wastewater treatment plant installed on the surface. Next to this often used, but expensive, pump and treat technologies, heavy metals can be immobilized by inducing sulfate reducing bacteria (SRB) to transform the sulfates, that are very often present in the same groundwater (due to the metal mining or processing activities), into sulfides. These sulfides will precipitate the metals as insoluble metal sulfides. At the moment several studies have demonstrated the feasibility of this In Situ Bioprecipitation Process (ISBP) for the removal of heavy metals from ground-water as well at lab scale (batch and column tests) as at field scale. However, some questions arise concerning the continuation of the process, the efficiency and the sustainability of the precipitates. The presented study will try to answer these questions. The study is based on more than 10 different studies, all done by the same authors, on different groundwaters and aquifer samples. The presentation will give an overview of the guidelines necessary for a correct and successful bioprecipitation process with stable metal sulfide precipitates. An important question in the ISBP is related to the sustainability of the heavy metal precipitates. It could be observed that the interruption in the carbon source delivery also stopped the in situ bioprecipitation process. Depending on the metal also some release from the precipitate could be observed. It was shown that release can occur with Co and Ni. Aquifers, on which the metals precipitated during the ISBP, were treated in a sequential extraction process under an-aerobic and aerobic conditions. It could be shown that especially under the anaerobic conditions the Zn and Cd precipitates changed from the leachable and the exchangeable fraction to the organic or Fe-Mn fraction (i.e. from the unstable to the stable fraction). The same could be observed for Co and Ni but still some fraction was present under a more available form. On the other hand it could be shown that large differences were observed concerning the heavy metal speciation on the aquifer in function of the used carbon source during the ISBP. The molasses treated systems showed a much more available heavy metal fraction on the aquifer compared to the lactate or HRC® treated groundwater. The different speciation forms based on the use of different carbon sources will be discussed in detail. It will pay attention to the influence of the carbon source, the efficiency of the induction of the bioprecipitation process, the influence on the competence between sulfate reducers and methanogenic bacteria and the influence of low pH on the ISBP. It seems that acetate, which is also a degradation product of fermentation of some carbon sources, can inhibit some sulfate reducers. Also the relation between slow release compounds and immediately available compounds will be explained. Finally a pilot study will be presented showing the problems that can be encountered during this process. Focus will be put on the induction of the process, the keeping on of the process and the follow up of the process by the installation of in situ mesocosm socks. These results will allow the correct implementation of the ISBP with an eye on longevity and sustainability of the process and present the ISBP as a much more sustainable alternative to the pump and treat technology as measure for heavy metals contaminated groundwaters.

Jan 1, 2006

By R. F. Baxter, C. M. Read, R. I. McCulloch

"Globalization of the aluminium industry continues to increase the pace of change and the intensity of competition, while simultaneously, society demands better products, cleaner technologies and sustainable industries. Bechtel, a global engineering, construction and project management company, is not immune to either the opportunities or the challenges created by globalization. However, and not withstanding the challenges, for aluminium industry ""players"" with a true global perspective, globalization presents very real opportunities that may be leveraged to deliver value creating goods and services. The following paper will focus on the exploitation of one of the opportunities created by globalization in the Knowledge Management domain - the application of high level tools and methodologies to improve global delivery of greenfield and brownfield aluminium smelter construction projects. Specific examples will be presented of value driven solutions that were delivered at the early stages of project engineering."

Jan 1, 2006

By Upendra L. Karna

The pile capacity gain with time evaluated and implemented for the construction of the Route 21 Viaduct in Newark, NJ, U.S.A is discussed in this paper. The project consisted of the replacement of more than 3.2 km of viaduct and ramps. The project site consists of thick residual materials deposited by the Wisconsin Glacier over sedimentary rocks. The upper portion is glacial-lacustrine deposit underlain by marginal morainic till and stratified drift. Subsurface investigations identified significant variations in layer thickness and grain size consistency. The site was characterized into 4 Soil types, based on subsurface soil behavior. Closed end 600 mm and 450 mm diameter driven pipe piles were used for the foundation. Loading tests conducted during an advanced construction contract, established that a significant soil set-up could be expected. For the first construction contract, a pilot loading test program consisting of 112 dynamic loading tests and 77 re-strikes (at 2 to 4 weeks) using the PDA (Pile Driving Analyzer) with CAPWAP (Case Pile Wave Analyses Program) was conducted to establish the soil set-up behavior. Nine (9) quick static loading tests were conducted to substantiate the long-term pile capacity. Based on the loading test results, average set-up factors were established and utilized for developing production pile driving criteria. Bearing resistance with depth was analyzed and reviewed. The set-up factors varied significantly, ranging from 1.05 to 1.89, and averaged about 1.30. Conclusions are derived. Set-up factors behavior for each soil type plotted by linear regression are presented and discussed. An appropriate set-up with time relationship for a glacial soil is suggested.

Jan 1, 2006