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By W. K. Collins

Engineered scavenger compounds (ESC's) developed by the U.S. Bureau of Mines are a novel class of compounds that selectively can recover a desired element from a solid or molten alloy. Lithium titanate (L2Ti307 or Li2O?3Ti02) is used as an ESC to recover lithium (Li) from aluminum-lithium (Al-Li) alloys. X-ray diffraction measurements have shown that Li2Ti307 undergoes a phase change during scavenging from an orthorhombic structure to a hexagonal structure. This change is due to the incorporation of lithium in the matrix of the material and the effect of temperature. Although both phases are metastable, the hexagonal phase that forms during the scavenging of lithium from Al-Li alloys appears to be the more stable phase. Recovering lithium from the ESC by electrodeposition does not cause the structure to revert to the orthorhombic phase. The orthorhombic and the hexagonal structures of Li2Ti307 have similar scavenging capacities for lithium. This report proposes a new mechanism for the phase transformation.

Jan 1, 2010

By Glen Smith

Nautilus Minerals, the world?s leader in exploration and development of deep ocean seafloor resources, is today focused on the recovery of high-grade copper and gold in seafloor massive-sulphide mineralization. These targeted mineralized belts, analogous to land-based volcanogenic massive sulphide deposits, are located near plate boundaries in the back arc basins of the Western Pacific. The first deposit to be developed by the company is located at a depth of 1,600 meters at Solwara 1, in the benign waters of the Bismarck Sea. This location lies within the territorial waters of Papua New Guinea. From 2006 to 2009 the company completed detailed environmental and geological studies at Solwara 1, culminating in a number of world firsts, including the first Environmental Permit granted for the extraction of seafloor massive sulphide deposits and the first NI 43-101 compliant seafloor massive sulphide deposit resource statement. Nautilus has relied heavily on proven deepwater technologies from the oil and gas industry in the design of its production system. Pipeline trenching units, workclass ROVs, deepwater production risers and drill cuttings removal systems will be adapted to initiate this new and exciting industry. Key contractors used by Nautilus on this innovative project have all been selected for their deepwater experience (gained in the oil and gas industry), creativity and determination to launch this new industry successfully. Innovation is at the forefront of Nautilus? success to date. This paper summarizes the progress to date of this development which will provide a new source of minerals for the world and which will contribute to sustainable growth for the future.

Jan 1, 2010

By Randall Head

The drilling at the Taum Sauk Reservoir was a unique compilation of the latest technology and everyday common sense. This site is comprised of rhyolite, which is 30 times harder than limestone in comparison. Using some of the most state of the art drills, coupled with GPS guidance, angular drilling systems, and an ordinary piece of string, some of the most amazing drilling feats were accomplished. By constructing the new dam on top of a mountain that had been blasted once before nearly 50 years ago treacherous conditions for the drills and crew were a challenge. The drills had to be flown in by cranes to get to their locations, where they then drilled anywhere from 2.5 to 6 inch (6.4 to 15.2 cm) holes at angles up to 24.4 degrees. Custom drill bits were designed by the drilling crew to tackle feats such as drilling holes up to 120 feet (36.6 m) deep. A main challenge was the shape of the reservoir, as it is not in a straight line, but rather round, so no technological way was readily available to use to drill. Common sense came in and an ordinary piece of string was used to aide in drilling the hole. A revolutionary step was that our drill was used to core our own samples. By using our own equipment, we were able to complete this task for one-third of the cost of having a third party contractor obtain the core samples. On this unmatched jobsite, it has been established that technology has come a long way, but when all else fails, a piece of string will do just fine.

Jan 1, 2010

By C. W. Smith

Research was conducted to evaluate the effectiveness of a well-point dewatering system in conjunction with a french drain to intercept waste impoundment leakage while reducing the volume of waste water requiring treatment. A well-point dewatering system composed of 585 production wells was installed around the perimeter of a leaking impoundment that previously used only a french-drain system for leakage control. The placement of the well-point system was designed to intercept and remove the leakage from the groundwater before the contaminant reached the french drain. Groundwater monitoring at this site revealed that after a period of approximately 40 days the well-point dewatering system had stabilized and effectively prevented the further spread of contamination to the french drain.

Jan 1, 2010

By F. H. Nehl

Ion elutriation was used to extract silver cyanide complexes and free cyanide from aqueous streams containing up to 10 ppm silver and 5 ppm free cyanide. Screening tests selected nine of 350 different surfactants for further, larger scale experiments. The screening procedure used 0.1 g of each of the surfactants in 300 mL of synthetic wastewater. Air was sparged into the test cell at 50 cc/min. The foam was refluxed during the tests and was not sampled. Samples of the solution were taken at specified intervals and analyzed by wet chemical methods for free cyanide and by atomic absorption for silver content. The most effective surfactants lowered the silver and free cyanide concentrations to less than 0.5 ppm in 1 h or less. These surfactants were quaternary amine salts with one long chain (C12-C18) organic group and three methyl groups. Experiments using 3 L batches of wastewater or an ion elutriation cell continuously fed with solution draining from an inactive heap leach operation confirmed the results from the screening tests.

Jan 1, 2010

By Alan A. Campoli

The U.S. Bureau of Mines conducted research to characterize longwall gob loading under bump-prone geologic conditions. Bureau-designed stress meters were installed in the floor rock beneath two longwall panels and coal pillars in the gate road between them. Gob and gate road pillar stress was monitored continuously by a state-of-the-art data acquisition system. The timing of the final destruction of the abutment pillar's load-bearing core was optimal, since the pillar is located between two gob areas and no longer of significant importance for ground control. Maximum stress was observed immediately in front of the longwall face, and this pressure quickly dropped as the face moved past the instruments. The center of the longwall panels regained significant overburden load, while the instruments located less than 100 ft from the edge of the panel showed little or no increase in pressure due to gob reloading.

Jan 1, 2010

By Jon C. Volkwein

The U.S. Bureau of Mines investigated a method of using inert gas to prevent the formation of explosive gas mixtures in auger highwall mining of coal. A combination of gasoline and diesel engine exhaust gases was introduced into the auger drill hole using a short section of pipe located at the collar. Gas samples were taken and analyzed on-site with infrared detectors for oxygen, carbon dioxide, methane, and carbon monoxide. Evacuated bottle samples were also taken and analyzed by gas chromatography in the laboratory. These gas results were analyzed for explosibility. Coal samples from various depths were used to obtain the gas content of the coal using the modified direct method. Personal expo- sure to carbon monoxide was also monitored. The highest methane level observed was 9.55%. The levels of inert gas (carbon dioxide and nitrogen) were sufficiently high to prevent any ignition of the methane. Results showed that for all conditions during mining, gas concentrations were nonexplosive. The gas content of the coal was about 0.30 cm3/g. The maximum personal time-weighted average Sample for carbon monoxide was 20 ppm. This system provides a safe, inexpensive, simple method for preventing explosions during auger mining.

Jan 1, 2010

By Kenneth Eltschlager

Blasting represents the highest risk of any surface coal mining activity that could result in injury and/or property damage off the permit area. In addition, blasting related issues e.g. flyrock, vibrations, air blast, etc., are responsible for a large percentage of citizen complaints. Thorough and consistent regulation of individuals certified to conduct blasting by the Office of Surface Mining Reclamation and Enforcement in Federal Program states and on Indian Lands under Federal jurisdiction is vital, as it serves to: facilitate coal production to meet the nation’s energy needs; protect people and property on and adjacent to Federal mining permits; form a basis for states to grant reciprocity certificates to Federal blasters; and be a positive example to primacy states. OSM issues Federal blaster certificates for blasting on Federal surface coal mine permits. The certification program includes experience, training and testing components similar to many of the states. But where a state program may focus on the specific blasting applications within its boundary, the OSM certificate requires a very diverse test to cover all potential blasting applications and products across the nation. Therefore, the Federal certificate is a good surface mining credential for blasters anywhere in the United States.

Jan 1, 2010

By Michael J. Pazuchanics

This report documents the current status of the U.S. Bureau of Mines ongoing investigation of the use of adaptive signal discrimination (ASD) systems to distinguish between cutting coal and cutting rock. Cutting-tool forces and vibrations were measured in the laboratory using both conical bits and roller cutters in a linear-cutting apparatus for several material samples and two cutting directions. A number of ASD systems consisting of one or more signal classifiers were trained and tested to study how data window size, type of signal feature, and combining (polling) of classifier results influence system performance. The results show that ASD system recognition rates can be improved by increasing data window size, removing air-cutting portions from the signal data, overlapping data windows, and combining (fusing) information at various levels of ASD system operation.

Jan 1, 2010

By Pamela J. Watson

The U.S. Bureau of Mines has demonstrated in laboratory tests that drilling with surface-charge-neutralizing concentrations of polyethylene oxide (PEO) polymer solutions simultaneously improves penetration rates and extends bit life. The applicability of this additive to improve drilling performance in coal measure rocks was demonstrated under field conditions at an abandoned mine land site in Pennsylvania and a producing coal mine property in Ohio. Penetration rate improvements ranging from 15 to 50 pet were obtained when core drilling through a variety of coal measure lithologies. Drilling cost analysis indicates that the small added cost of using the polymer is more than offset by the savings that result from demonstrated increased drilling penetration rates, which translate into drilling cost savings of about 10 to 30 pct. This report also gives chemical analyses of a variety of coal measure rocks and some corresponding local drilling water samples, obtained from a wide geographical base, along with threshold concentrations of PEO required to effect the improved drilling performance in these rocks. From these data, the threshold PEO concentrations needed to ensure improved drilling performance can be estimated for any coal measure rock suite. Proper techniques for mixing PEO solutions are also presented.

Jan 1, 2010

Gold cyanide equilibrium adsorption isotherms in the loading range typical of operating carbon-in-pulp/carbon-in-leach plants have been established and the effect of various cations and the presence of copper cyanide species quantified. It was found that the equilibrium loading of gold was enhanced by the presence of sodium or calcium, with calcium having an order of magnitude stronger effect. The presence of copper has an adverse effect on the equilibrium loading of gold. A unified model was developed to predict the effect of sodium and calcium concentrations in solution and the competitive carbon adsorption of copper on the equilibrium loading of gold on carbon. A satisfactory agreement between the measured gold equilibrium loadings and the model results was obtained over a wide range of solution conditions.

Jan 1, 2010

By H. Walqui

The Empire concentrator currently processes magnetite ore from the Empire pit which is approaching the end of its mine life. Over the past two years plant wide tests have been run to access the plant capability of processing ore from the neighboring sister Magnetite pit. The neighboring pit presents challenges to the Empire plant due to its higher feed grade, finer liberation size and higher percent silica which require additional secondary grinding and concentrating capacity to achieve concentrate grade. The following paper summarizes the results from the second full scale test, run during 2009 under a challenging market environment

Jan 1, 2010

By Benjamin Cebrian

Metallurgical testing at Cobre Las Cruces prior to production at the mill was done with overburden gossan. Some of that test gossan was a very fine material, wet by the water conditions at the bottom of the pit. When processed and stored wet at the fines material 3000 tonne (3307 tons) silo, this material cemented in a very unusual manner.

Jan 1, 2010

By Matthew Graham, Tapan Goswami, Geoff Brent

In dragline coal mining operations, throw blasting is used for the controlled placement of overburden to maximise coal exposure rates or to minimise overburden removal costs. This may necessitate sacrificing thin coal seams, generally less than one metre in thickness, which are often present in proximity to the main coal seam. This represents not only a significant loss of potential revenue and profit but also a waste of a valuable energy resource.

Jan 1, 2010

By Joshua Hoffman, Braden Lusk, Kyle Perry

Shock tubes are used to simulate large-scale arena explosions without the use of full-scale arena sites that utilize large quantities of explosives. Instead, small explosive charges can be used to drive shock tubes. When this is done, the geometries of the explosive charges can alter the resulting pressure time curve. A common geometry chosen for the explosive charge is a sphere in order to be congruent with the spherical shockwave that emanates symmetrically in three dimensions from the detonation point. This paper reports on the findings from experiments that study the effects of altering the charge geometries and explosive types while keeping the TNT equivalency constant. Peak pressures and durations were affected by these changes. Directional phenomena are exaggerated by the use of certain charge shapes and detonation points. The speed of the detonation front in the explosive being greater than the speed of the shockwave in air played a critical role in the resulting pressure time waveforms. Waveform manipulation can be used to generate job specific waveforms that ultimately benefit the shock tube operators and their clients.

Jan 1, 2010

By Michael J. Friedel

As part of an investigation aimed at improving the health and safety and competitiveness of the mining industry, the U.S. Bureau of Mines evaluated the application of common offset radar profiling, using a 250-MHz ground-penetrating radar (GPR) system, for the detection of fractures in igneous rock. A series of radar reflection surveys were conducted to detect and delineate the extent of fracturing at various granodiorite and gabbro quarries and outcrops located in Minnesota. The application of radar profiling for detecting joints, sheeting fractures, shear zones, and depth to water table was demonstrated to be feasible with minimal processing. Radar reflection interpretations were verified by visual inspection of the rock mass and field mapping of local structure. The radar reflection section provides a simple, rapid, and cost-effective means for mapping of shallow (less than 10 m) small-scale fractures (greater than 0.25 cm) in igneous rock masses (characteristic of velocities between 0.061 m/ns for gabbro and 0.125 m/ns for granodiorite). Depth or distance estimates to fractures are within 10 pct of the actual, and time-shift compensation is necessary only when topographic irregularities exceed 30 cm.

Jan 1, 2010

By Ali Kahriman, Olivio Angelini, Ibrahim Sefer, Burak Ekmen, Koray Arpak, Ertugrul Kaya, Yucel Karakus, Abdullah Sak, Aziz Ozdemir

In recent years, in order to bring solution to traffic intensity arising from transportation problems and facilitate public transportation in the modern world in paralel to urbanization and to the increase in population, it’s well known that, the construction of Access tunnels is inevitable. The driving of the tunnels is a subject of special interest in the technique of rock blasting. The essential factors in terms of tunnel driving and safety in tunnel blasting that is applied in metropolitan areas, an in depth knowledge of ground vibrations and the ways of reducing them to safer levels.

Jan 1, 2010

By Lisheng Shao

Soil mixing and jet grouting have been widely used to support heavy structures such as tanks, cement silos, and storage buildings. Although the installation methods vary between soil mixing and jet grouting, the end product of soil-cement columns behaves similarly in supporting structure loads. In many cases, soil-cement mass treatment offers the owner savings over driven/drilled piles. This paper discusses the design methodology, production work, and quality control, with supporting figures, of a recent large complex tank farm project. The project consisted of constructing six above-ground steel storage tanks and an approximately 700-foot-long fill slope. The tank farm site is located in an industrial area of southern California, with highly variable subsurface conditions consisting of compressible soils and buried construction debris. The compressible soils necessitated that the new tanks be supported on deep foundations. A test pile program performed previously at the site showed that conventional driven concrete piles were not feasible because of buried construction debris, therefore a soilcrete system was proposed. Site design included evaluating the total and differential settlement and column group bearing capacity under both static and seismic loads. Extensive field and laboratory testing confirmed the design soil-cement strength and modulus of both the soil mixed and jet grouted soil-cement columns. The project operation and quality control programs are also included in this paper.

Jan 1, 2010

By K. M. Connor, O&apos

Variations in overburden geology must be considered in applying subsidence prediction methodologies developed by the U.S. Bureau of Mines (USBM). To characterize rock mass overlying high-extraction coal mines, the USBM utilizes a computer spreadsheet program and modified Rock Mass Rating (RMR) system. The spreadsheet calculates an RMR based on a bed's engineering properties determined from core logs and laboratory tests. An in situ deformation modulus and a bending stiffness are computed for each bed. Stiffness-versus-depth plots identify groups of beds with similar stiffness. Large variations in stiffness between adjacent beds are considered significant horizontal discontinuities where slip is likely. Time domain reflectometry (TDR) is used to verify this hypothesis by measuring shear displacement along such discontinuities. A model of the overburden is built by assuming that a near-surface laminated beam exists above a transition zone in which large plastic slip occurs along horizontal discontinuities. Increasingly thicker groups of beds are modeled to determine the most probable beam thickness based on a comparison with measured deflection profiles. The inverse of maximum beam deflection is an index parameter known as "bridging potential," a single value that incorporates both overburden geology and mine geometry.

Jan 1, 2010

By D. Y. Peng

A Large Sub-structure with open top of S.Y.P. float line requires a 90m x 50m in plan and 13m-deep excavation in soft soil, Shanghai. The geological conditions in site are rather severe. The technology specifies that no permanent braces nor partition walls are allowed to be constructed inside. After a series of discussions the scheme of semi-gravity type cellular D-walling without any braces or earth anchors is finally adopted and successfully executed by SFEC. This paper deals with the technical problems in the design, construction and in-situ monitoring we met with in this difficult project.

Jan 1, 2010