Search Documents

By J. T. Nel

The establishment of a pilot plant for the continuous production of titania pigment and nano-titania is discussed. The plant was designed, constructed and operated on the Necsa site. The TiO2 production capacity is 7?10 kg.h-1 by the reaction of TiCl4 and O2at>1000°C. Liquid TiCl4 is sprayed under pressure into a plasma reactor where it evaporates and reacts with O2 to form TiO2. Process optimization has allowed for continuous production without any clogging or blockages. The primary advantage of the plasma-assisted process is the possibility to recover and recycle the chlorine values in high yield as Cl2 for use in the manufacture of TiCl4. The HCl formed in most conventional fossil-fuelled processes makes Cl2 recovery and recycling much more difficult. Particle size distribution analysis of the fine, white product revealed a d50= 125 nm. The raw product consisted of 60% rutile that could be increased to 80?100% rutile by post-annealing. The specific surface area (SSA) of the pigment was 8?20 m2?g-1(BET). According to the CIE colour index the ?whiteness? (L*>95) of the plasma-produced pigment was better than that of several commercially available pigments. The particle size could be manipulated by controlling the TiCl4 feed rate, gas flowrates, and the particle quench rate and residence time. Nano-sized TiO2 powders with a particles size (d50) as small as 50 nm were also successfully produced in this way.

Jan 1, 2010

By C. H. Bucknam

Acid neutralization titrations were applied to the characterization of soil and overburden for the control and prediction of acid rock drainage in the coal fields of the eastern United States in the 1970?s (1). These became known as the Sobek methods as a result of the early United States Environmental Protection Agency publication and the methods have been modified (2) to be adapted to many applications in the metal mining sector (3,4,5,6,), and, as a result, there are a large number of acid neutralization potential methods being used that are referred to as Modified Sobek methods. Standardization of neutralization potential methods for metal bearing ores and related materials based on carbonate carbon, rather than titration, commenced in the 1990?s through the American Society of Methods and Materials (ASTM) Committee E01 on Analytical Chemistry for Metal Ores and Related Materials Subcommittee E01.02 on Ores, Concentrates and Related Metallurgical Materials (7). A subcommittee section, E01.02.05 on Environmental Methods, was organized to coordinate the method and material standardization efforts of ASTM and the Acid Drainage Technology Initiative Metal Mining Sector (ADTI-MMS) Prediction Committee (8), which took on the project of standardization of the acid neutralization potential acidity titration method (ANPA) to supplement the carbonate carbon method in E1915 (9) for application to samples which have metal carbonates (10), in particular, which result in overestimation of the neutralization potential using the carbonate carbon methods (11).

Jan 1, 2010

By Peter Moser, Michael Messner, Florian Bauer

The existence of ammonia in underground blasting fumes was frequently measured in various field tests (6, 7). Ammonia in fumes with a TLV (threshold limit value) of around 30 ppm (slightly different in various countries) is a toxic gas but not considered to be a high risk for the underground work force as ammonia smells very itching and is extremely annoying. This might be the reason why ammonia is hardly measured in routine underground blasting fumes control. Another reason for the lacking measurement might be the circumstance that ammonia is a very reactive gas and the ammonia sensors available on the market are very cross sensitive to other gases like carbon monoxide. Nevertheless, especially since the introduction of bulk emulsion explosives in underground blasting, complaints from miners about ammonia in the blasting fumes increased. Research work by various institutions [8] around the world relates the ammonia in the fumes back to various mechanisms. Amongst others these comprise: a) non ideal (low temperature) detonation of explosives, with NH3 in the reaction products; b) reaction between rock and non detonated bulk explosives (especially when the rock is of a basic nature (high pH value); c) reaction between shotcrete and non detonated bulk explosives. Numerous blasting tests in an experimental underground set up have been made in order to check these hypotheses for ammonia origin in blasting fumes. None of them has been found to be responsible for sometimes high concentrations of ammonia in the fumes. The major reason for ammonia concentration in blasting fumes has been found in mine water of a high pH value (either natural or from using shotcrete). The mechanism identified is as follows: the moment a non detonated ammonium nitrate bearing explosive comes in contact with mine water of a high pH value, ammonia is formed immediately. The source for the undetonated explosive is twofold: firstly there is a certain spillage of explosives when the holes are charged (especially when using bulk products) and secondly not the entire explosives detonate completely. These undetonated remaining of the explosives end up in the muck pile after blasting. In case there is water of a high pH value the reaction between the explosives and the water starts immediately. This explains also the observation why ammonia can be measured in the blasting fumes quite a long time after the blast. The majority of the ammonia is not formed during the detonation; it is formed inside the muck pile even a considerable long time after the blast.

Jan 1, 2010

By V. A. Scovazzo

The analytical pillar design procedure employing the Wilson equation is based on the site-specific material strength of the floor, pillar, and roof rock. Stable pillars so designed will sometimes be larger than those designed using empirical methods thus providing more stability or at other times smaller than empirically designed pillars thus conserving natural resources. Presented here is a detailed procedure for the analytical design of soft rock pillars using the Wilson Equation. An example of this procedure is presented that uses data from a mine in the Owl Seam in Southern Appalachia. These Owl Seam pillars are now in use and are performing as expected. Also addressed is an assessment of the Dr. Scovazzo?s analytically designed pillars based on pillar performance data gathered by Dr. Mark in the Southern Appalachian Coal Field.

Jan 1, 2010

By B. M. Stewart

Researchers at the U.S. Bureau of Mines conducted a long-term groundwater monitoring and site characterization program at an abandoned 10-ha, acid-producing, copper-gold tailings impoundment in north-central Washington State. The purpose was to investigate contaminant release and transport, and attenuation mechanisms in the tailings, sediments below the tailings, and gravels downgradient of the impoundment. This report summarizes the monitoring results and physical properties of the tailings, the sediments below the tailings, and the groundwater system associated with the tailings. Water samples from the vadose and saturated zones of the impoundment were analyzed for 15 constituents. Concentrations of the same constituents were determined in water samples up to 3 m beneath the impoundment and in the shallow colluvium and deep bedrock at 76, 335, and 550 m downgradient and 168 m upgradient. Constituent concentrations within the tailings are quite variable and are influenced by pH, depth of oxidation, grain-size differential (surface area), hydraulic gradient, groundwater mixing, and the presence of hardpan layers, carbonaceous material, and organic matter. Most of the metal constituents decreased to background or near-background concentrations in the farthest downgradient well.

Jan 1, 2010

By E. A. Barrett

The U.S. Bureau of Mines (USBM) conducted experiments to determine if training using a latent-image, three-dimensional (3-D) slide simulation exercise improved miners' ability to recognize roof and rib hazards. The effectiveness of this innovative type of classroom training was investigated by measuring workers' performance on a hazard recognition task. The study was unique in that hazard recognition skills were assessed in the workplace using actual coal mine roof and rib hazards. Results showed that training with a latent-image, 3-D slide simulation exercise significantly improved each subject's performance on the in-mine hazard recognition task. Further, the USBM researchers concluded that transfer of learning from the classroom to the workplace occurred.

Jan 1, 2010

By E. R. Bauer

The U.S. Bureau of Mines is investigating strata interactions associated with mining of multiple coal beds to provide the mining industry with improved methods of planning and developing multiple coalbeds, conserving resources, and increasing the safety of underground coal mining. This study involves analytical predictions and underground observations of longwall development ground control problems at a south-central Pennsylvania coal mine affected by subsidence induced by multiple-seam mining. As predicted, strata interactions were found in upper mine areas mined over lower mine gob. Observations revealed roof deterioration accompanied by excessive water inflows in the first 170 ft after crossing the gob line as mining entered and exited the subsided area (over the lower mine gob). In contrast, superimposed mine areas and areas mined a substantial distance out over the gob showed no signs of interaction with previous lower seam mining, again as predicted.

Jan 1, 2010

By Neale R. Neelameggham

"Most chemical process plants and metallurgical production facilities have some sort of cogeneration to minimize process energy costs. Use of Alternative Energy Production from sun and wind power with storage can become an integral part of a process plant utility. This will facilitate reduced fossil fuel usage and help minimize thermal emissions. This will be similar to Pollution Control equipment, which have become an essential part of process plants in the past four decades. Conceptual flow sheets of such Process Utility schemes are presented.IntroductionPower is supplied to industries, commercial and residential users. Over the past decade, Electric Utility companies have made major inroads, in introducing alternative energy resources in an attempt to somewhat reduce fossil fuel use in power generation. Now, on a much larger scale than in the early 1980s, residential users, motivated by government provided tax credits, have started installing alternative energy generators such as roof top wind mills or roof-top photovoltaic generators. This will minimize future energy costs, help control thermal emissions etc. This alternative power generation is typically connected to the existing power grid with two way power metering. However, the use of alternative energy generation has not been seen at large industrial sites yet.Paul Scherer Institute, Switzerland and the NREL laboratories in Colorado, are two of the several institutes which have been developing how solar thermal power can be used to supply the endothermic input energy in chemical and metallurgical processes. The theme of this present symposium addresses the above as well as the energy storage needs for such events to become continuous. This paper emphasizes the concept of how alternate energy can be used in the production of materials on a generic sense wherever there is a need for input energy – beyond endothermic process energy - while addressing how to reduce the thermal and carbon emissions.The alternative energy generation using wind or solar source is discontinuous due to the nature of the energy source. They are not only discontinuous but also variable. This necessitates storage of generated power for close to continuous use with variable loads. C Smith, et al pointed out in 2006, that 'the electric power industry has taken notice of the expansion of wind and its potential' in a summary article on integrating wind generation into utility systems.1 In 2009, the 1000 MW wind generation project in Texas had to be postponed to 2013 for lack of transmission.2 There are only a few large MW solar generation units in the US; the projects being slow mainly from lack of adequate storage and redistribution."

Jan 1, 2010

By David E. Siskind

The U.S. Bureau of Mines and the State of Indiana cooperated with AMAX Coal Co. and its consultants to determine the effects of coal mine overburden blasting on nearby pipelines. Five pressurized 76-m pipeline sections were installed on the Minnehaha Mine highwall near Sullivan, IN, for testing to failure. Four 17-to 51-cm-diameter welded steel pipes and one 22-cm PVC pipe were monitored for vibration, strain, and pressure for a period of 6 months while production blasting advanced up to the test pipeline field. In contrast to previous studies of small-scale, close-in blasting for construction, these tests involved overburden blasts of up to 950 kg per delay in 31-cm blastholes. Analyses found low pipe responses, strains, and calculated stresses from even large blasts. Ground vibrations of 120 to 250 mm/s produced worst case strains that were about 25 pct of the strains resulting from normal pipeline operations and calculated stresses of only about 10 to 18 pct of the ultimate tensile strength. No pressurization failures or permanent strains occurred even at vibration amplitudes of 600 mm/s.

Jan 1, 2010

By M. Mirzazadeh

Air cooled crackable and conventional forged steel specimens were tested under reversed push-pull conditions to examine the effect of shot-peening on their high cycle fatigue behaviour (-106 cycles). The steels were tested in the normalized as well as shot-peened conditions. The results showed that shot-peening smooth specimens had little effect on the fatigue limit of the air cooled forged steels and the detrimental effect of the rougher peened surface was not apparent. Microhardness profiles indicated that the shot peening produced a gradient of compressive residual stresses that was greater than that of the loading stresses, suppressing the anticipated beneficial effect on fatigue life. Crack initiation was more likely to occur below the surface. The results indicate that the surface roughness was not a significant factor in controlling the fatigue lives, since they were essentially the same for the non shot-peened and shot-peened steels.

Jan 1, 2010

By A. D. Marcy

The Midnite Mine is an inactive, hard-rock uranium mine in Stevens County, WA. Oxidation of sulfide-containing minerals, primarily pyrite, in the ore body produces large quantities of acidic water. An interception system installed by the mining company limits the discharge of contaminated water from the mine. The U.S. Bureau of Indian Affairs (BIA) and the U.S. Bureau of Land Management (BLM) have been actively involved in planning remediation of the disturbed areas. To assist in remediation, the U.S. Bureau of Mines (USBM) initiated research to determine water quality and to define ground water flow characteristics. USBM personnel designed a monitoring network, supervised installation of sampling wells, and collected and analyzed water samples. This Report of Investigations describes interpretation of data collected between December 1989 and April 1992. The computer program WATEQ4F was used to identify aqueous species distribution and to calculate potential solid phase controls of solubility. To assist in interpretation of changes in water quality between sampling locations and to develop models describing proposed flow paths, the computer program BALANCE was used. Using output from these programs and field observations, a description of the chemistry along proposed ground water flow paths at the mine is presented.

Jan 1, 2010

By M. Gorman

The Mineral Park Mine is an open pit copper-molybdenum mine located in northwestern Arizona, approximately 74 miles southeast of Las Vegas, Nevada. The property has been owned by the Duval Corporation, Cyprus Mining Company and Equatorial Mining of Australia. Mercator purchased Mineral Park from Equatorial in 2003. Mineral Park commissioned a 25,000 tpd copper and molybdenum concentrator in November and December of 2008. The process includes two stage milling (SAG and Two Ball Mills) fed by primary crushed ore. Metals are recovered in a copper-molybdenum flotation circuit consisting of mechanically agitated roughers and cleaners. The copper- molybdenum flotation concentrate is thickened and further processed in the molybdenum flotation circuit which separates the copper and molybdenum minerals into salable concentrates. The molybdenum circuit also uses mechanically agitated cells. This paper describes the plant and some of the highlights of the commissioning process.

Jan 1, 2010

By A. House

Newmont Mining Corporation owns and operates the Phoenix Mine near Battle Mountain, Nevada, USA. The existing milling facility has operated since 2006. Following the startup of the milling operation, and coupled with the upswing in the copper market, Newmont realized that Phoenix needed a process option to treat lowgrade transition and oxide copper ores. This meant that potentially revenue generating ore was being mined as waste. With no system in place to treat the transition and oxide copper, work began to determine the most feasible approach. After evaluating multiple options, the flow sheet was set for a run-of-mine (ROM) heap leach pad and solvent extraction/electrowinning plant (L-SX/EW). This paper will discuss the synergies and challenges of developing a copper L-SX/EW plant at the Phoenix copper-gold mill.

Jan 1, 2010

By Essie Esterhuizen, Michael M. Murphy, Chris Mark

"The design of underground coal mines requires a clear understanding of the overburden response, the loading of pillars, the loading of the gob, the pillar failure process, and the ultimate load carried by partly or fully yielding pillars. Very few highquality stress measurements of yielding pillars and gob loading have been made in full extraction mining. Well-calibrated numerical models can assist in providing a better understanding of the load and failure processes, provided the coal, the overburden, and the gob are all modeled with sufficient realism. A program of numerical model calibration and validation was carried out using FLAC3D.1 The models were calibrated against observed and measured performance of coal pillars and the overburden in operating mines to provide a basic set of input parameters that can be used to provide a realistic first estimate of expected ground response and pillar loading. Input parameters for modeling coal pillar response were based on data from triaxial testing on coal samples, combined with both matching the depth of failure in the coal ribs to observations as well as matching the peak pillar resistance to an empirical equation. The models were calibrated against strong roof and floor case histories in which the pillar strength is governed by failure and yielding of the coal within the pillar and the surrounding strata only had a limited impact on pillar strength. Input parameters for the overburden were determined from a large database of laboratory tests and model calibration against maximum subsidence and subsidence curvature. Further overburden calibration was carried out by matching stresses in the mining horizon to field measurements. Three examples of the application of the calibrated dataset and modeling methodology to field measurements are presented. The results show that a reasopable estimate of the in-seam stress distribution and overburden response can be obtained for both strong and weak overburden scenarios at various depths of cover.INTRODUCTIONThe planning and design of coal mine excavations requires reliable estimates of the expected strength and loading of the mine structures to achieve global stability. Empirical methods are widely used to estimate the strength and loading of coal pillars and have been incorporated into pillar design procedures, such as Analysis of Longwall Pillar Stability (ALPS) (Mark, 1987) and Analysis of Retreat Mining Pillar Stability (ARMPS) (Mark and Chase, 1997), that are widely used in the United States. ~umerical models are finding increasing application as a tool for underground mine design because of their. versatility and the ever increasing computational power available to mine designers. A prerequisite for the application of numerical models is the calibration of the models against observed rock mass response (Hoek et al., 1990; Skiles and Stricklin, 2009). The calibration process may include comparison of model results to measured stress and deformation and modifying the input parameters in a systematic manner to achieve a satisfactory agreement between the model results and measurements. Once models have been calibrated, they can be applied to evaluating similar mining layouts in similar geological conditions."

Jan 1, 2010

By M. Soderstrom

In a solvent extraction (SX) plant, stage efficiency calculations are used to determine mixer efficiency. With modern extractants and mixing equipment, it is generally taken for granted that stage efficiencies will be above 95%, but this is not always the case. Dependant on mixer/solution conditions, stage efficiencies can occasionally be low, therefore leading to higher reagent usage. Proper methods to identify when stage efficiency performance is below expectations, and ways to identify if it is an equipment or chemical issue are valuable tools for a plant metallurgist. With these tools and skills an on-site metallurgist can more quickly return their SX plant to proper operation. This paper will discuss methods for analyzing stage efficiency, evaluating factors that may affect stage efficiency, and evaluating the impact of stage efficiency on the overall operation.

Jan 1, 2010

By M. I. Brittan

A technique has been developed that analyzes routine mill operating data to determine the key operating parameters responsible for gold losses to tails. These parameters represent the prime operating variables having a dominant effect on gold recovery. The technique quantifies these effects for the specific plant being analyzed, providing a tool to optimize recovery and costs and so enhance the mine?s cash flow. The quantitative relationships generated will be different for each ore and plant: every case is site-specific and has to be treated on its merits. Examples are provided to illustrate the considerable metallurgical and financial benefits which can be realized from optimization. The examples are taken from case studies of mills in four major gold mining districts of the world.

Jan 1, 2010

By K. Oraee

Excessive emissions of methane from the coal seams can have a serious adverse effect on both safety and productivity of longwall coal faces. Mechanization of coal faces has increased production possibilities to the extent that normal ventilation systems may not be able to ventilate coal face areas in order to lower methane content in the air to within legal limits. Production increases may therefore be prohibited for this reason, especially in gassy seams. Methane drainage from the coal seam by means of long holes and before production starts can act as a useful remedial action. In this paper a two dimensional mathematical model has been produced. The model that is based on finite elements, simulates a methane drainage system where the resultant risk is linked to the coefficient of diffusion, coal permeability, holes pattern and the duration for which the seam is subject to drainage. It is concluded that methane drainage of this type can assist in achieving production increases in many coals seems, especially where high gas content is a virtue of the seam.

Jan 1, 2010

By Douglas F. Scott

Researchers from the U.S. Bureau of Mines conducted geologic investigations in an area of the Lucky Friday Mine, Mullan, ID, that included the 5300-107 demonstration stope using underhand longwall cut-and-fill mining. Structural analysis of the area suggested that argillite beds form planes of weakness between blocks of brittle quartzite, and energy may be released along these planes and at the junctures of fractures. Mapping argillite beds and fractures in the stope wall rock showed that the planes of these features diverged and that their attitudes corresponded from one wall to the other. Seismic analysis showed that the number and location of events varied as each cut was mined, with about 39 pct of the total number of events occurring above the cut being mined, about 54 pct below, and 7 pct at the same elevation.

Jan 1, 2010

By N. O. Lotter

The reliability of a set of flotation results is key to minimizing project risk, either at the commissioning of a concentrator or at the point of implementing an improvement to an existing concentrator operation. High-confidence flotation testing (HCFT) was developed for this purpose and is part of the list of technologies at various scales used by Xstrata Process Support (XPS) in addressing these projects. The methodology is based on two principles: one, to ensure that the ore sample is representative and has been well-blended and subsampled; two, to perform the flotation tests in sufficient numbers of replicates with appropriate quality controls, so as to improve the reproducibility of the test data. Across ten years of research on this methodology at Xstrata Process Support, Sudbury, several improvements to the HCFT method and complementary connections between sampling and quantitative mineralogy have been developed. Two case studies are reviewed. These show the capability of this system in both optimizing an existing concentrator operation and in serving a new mine scenario. Further work to improve the efficiency of this procedure has been identified. Key words: Flotation testing, Flotation

Jan 1, 2010

By Michael J. Friedel

The integrity of mine structures, such as the roofs, ribs, face and supporting pillars, is difficult to assess beyond the exposed surface. To mitigate potential rockfall hazards, the U.S. Bureau of Mines is assessing the usefulness of Rayleigh wave dispersion analysis to detect damage and stress-relieved zones in mine structures. Classical surface wave dispersion modeling is utilized at both laboratory and field scales in damaged and undamaged material to assess the integrity of a mine pillar and roof. To more fully exploit Rayleigh wave propagation characteristics, derivation of a novel dispersion parameter was conducted using a convolutional model. The development of a suitable Rayleigh wave dispersion system based on insight derived from forward modeling is presented. The application of inverse modeling for damage and stress assessment in the mine environment is also discussed.

Jan 1, 2010