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By X. Yin

Surface force measurements based on atomic force microscopy (AFM) are used to describe the wettability of surfaces, specifically kaolinite basal plane surfaces at a high resolution. The kaolinite particles (~500 nm) were ordered with either the silica tetrahedral face exposed or the alumina octahedral face exposed, and surface force measurements were made between a hydrophobic diamond-like-carbon (DLC) tip and the kaolinite faces at pH 4, which is around the isoelectric point of the DLC tip. Under these conditions, the effect of electrostatic interaction should be eliminated and only van der Waals interactions and hydrophobic-hydrophobic interactions are expected to contribute to the surface force. The wettabilities of the surfaces were determined from the magnitude of the surface force. Wettabilities of the kaolinite basal planes thus determined were compared with the corresponding wettabilities of talc and mica surfaces, which are well-known to be naturally hydrophobic, and hydrophilic surfaces, respectively. The results reveal that the silica tetrahedral face of kaolinte has a modest level of hydrophobicity, which may be due to the lack of hydrogen bonding sites. In contrast, the alumina octahedral face showed no hydrophobicity, since a layer of surface hydroxyl groups is present at the alumina face, resulting in a relatively strong interaction between this surface and water molecules. It is expected that, with a better understanding of the surface properties of kaolinite, further improvements in flotation separations and dewatering may be achieved.

Feb 1, 2012

By Doris Hiam-Gálvez

El presente trabajo describe las últimas tecnologías que mejoran la minería en América Latina y la eficacia en el procesamiento del mineral. Así también se revisa el modo innovador de energía a través de la fundición de sales con energía solar, particularmente en regiones desérticas de América del Sur. Cada tecnología ofrece mejoras sustanciales en eficiencia, capital, y costos operativos y contribuye a la reducción el impactom ambiental de las operaciones mineras.

Feb 1, 2012

By J. Kou

The adsorption process, density and structural property of the oleate layer adsorbed onto a hydroxyapatite (HAP) surface at six different concentrations and three pHs (pH 8, 9 and 10) have been studied using the technique of quartz crystal microbalance with dissipation (QCM-D). The present study demonstrated the versatility and accuracy of the QCM-D for surface adsorption characterization. The real-time measurements of frequency and dissipation shifts with a hydroxyapatite-coated sensor revealed changes in the hydroxyapatite surface during the entire adsorption process. Chemisorption and surface precipitation of sodium oleate were also observed on the surface of hydroxyapatite through the use of Fourier Transform infrared spectroscopy(FTIR). Chemisorption dominated at low concentrations and high pH values and formed a rigid and thin adsorption layer. Surface precipitation of calcium oleate and micelles dominated at concentrations higher than critical micelle concentration (CMC) and lower pHs and formed a thick but dissipated adsorption layer with a high hydration level. Three distinct adsorption behaviors were identified from the different slopes of ?D-?f plots. The adsorption density was less than a monolayer at concentrations <0.164 mM, but increased significantly at concentrations higher than 0.821 mM at all three pHs. The critical concentration at pH 8 was 0.33 mM, which was lower than at pH 9 (0.821 mM) and pH 10 (3.3 mM).

Feb 1, 2012

By T. V. Nguyen

The feedwell performance in gravity thickeners and clarifiers relies on the efficient mixing between solid particles and flocculant to achieve effective flocculation, as well as energy dissipation of the incoming feed stream. A population balance-computational fluid dynamics (PB-CFD) model has been developed and validated to provide new insights into the operation and performance of industrial feedwells. In particular, the PB-CFD model enables the efficacy of the main functions of a feedwell to be investigated for a wide range of feedwell designs and process conditions. This paper describes how PB-CFD was used in the design and development of a new feedwell concept for the flocculation of particles in a solid-liquid stream. The patented feedwell design includes an upwardly converging flow diverter to create two separate compartments for energy dissipation and flocculation. PB-CFD simulations of this simple and easy-to-retrofit feedwell design illustrate a superior performance in terms of flocculation and energy dissipation compared to typical feedwells over a wide range of flow conditions. The potential benefits include reduced flocculant consumption, better de-aeration, greater stability and the ability to cope with a wider variation in volumetric throughput, better flocculation and fines capture, and a more symmetrical discharge that may also offer improved overflow clarity in some applications. The new feedwell design has been installed in a full-scale thickener at an Anglo American Platinum site in South Africa. A number of operational factors complicate this application, but indications are that the new feedwell has led to improvements in stability and underflow properties.

Jan 1, 2012

By Peter Moser, Mark Ganster, Radoslava Ivanova, Florian Bauer

Blasting accurately in underground drifts and creating a smooth contour requires proper drilling, knowledge about the apparent geology, a well designed blast pattern and ideally a smooth blasting product. These products are usually cartridged explosives with less energy and are charged in the contour holes in order to reduce the energy concentration and therefore the cracking into the surrounding rock. With the development of a new contour blasting system, a device can now be delivered to the industry that that avoids the additional storage of cartridged products when bulk explosives are used. The system consists of a foldable hose that is charged with bulk emulsion, in the same way as the rest of the blast, from the base to the collar of the hole. It centers automatically in the borehole and provides a decoupled charge. The paper describes the system in detail, gives background information on smooth blasting and presents the first successful field tests using the system in the drifts of an underground mine. It shows the advantages of blast results that produce more stable contours that reduce the amount, time and cost for support but also increase safety underground.

Jan 1, 2012

By J. B. Hadaway

The operation at Phu Kham commenced design and construction in early 2006 and was commissioned in May 2008. This paper will examine and discuss the project from the inception of flow sheet development and equipment selection, equipment design and manufacture, construction, commissioning and ramp up to full production. The paper will touch on the strategies employed to achieve a short schedule and the efficient use of capital, but with the main emphasis on the grinding circuit. Various challenges during the early years of operation will be discussed including the effect of ore characteristics, including competency, on the performance of the grinding circuit. Actions to overcome these challenges and to enhance performance will also be discussed. Finally, current and future plans to improve the performance of the grinding circuit and the overall plant will be summarised.

Jan 1, 2012

By E. Gratz, U. Pal, A. Powell, S. Pati, J. Milshtein

"The solid oxide membrane (SOM) process has been used at 1150 'C to produce magnesium by direct electrolysis of its oxide. Magnesium oxide is dissolved in a molten CaF2-MgF2 ionic flux. An oxygen-ion-conducting yttria-stabilized zirconia (YSZ) SOM membrane separates the cathode and the flux from the anode. During electrolysis, magnesium ions are reduced at the cathode and Mg(g) bubbles out of the flux into a separate condenser. The flux has a small solubility for magnesium which imparts electronic conductivity to the flux. The electronic conductivity decreases current efficiency of the process and also degrades the YSZ membrane. This study investigates different methods for reducing the electronic conductivity of the flux due to magnesium solubility. One effective method shown here is inert gas flushing near the magnesium nucleation site. Potentiodynamic and potentiostatic experiments along with AC impedance spectroscopy are used to characterize the effectiveness of the approach.IntroductionMagnesium is the third most abundant metal in the earth's crust. Since magnesium is the lightest of all metals used for construction alloys, magnesium is the leading candidate to replace steel and aluminum in automobiles. Automobile manufacturers would like to increase magnesium content from 4-5kg per vehicle to 40-IOOkg per vehicle [I]. Using magnesium alloys instead of steel and aluminum can reduce automobile weight and improve fuel efficiency. However, in order for automobile manufactures to make this change, it is generally believed that new cost effective methods of magnesium production must emerge.One approach for magnesium production which has been shown to be effective on a laboratory scale is the direct electrolysis of magnesium oxide utilizing an oxygen-ion-conducting solid oxide membrane (SOM), this is known as the SOM process [2]. A recent study estimated that a commercial SOM plant could produce magnesium from magnesium oxide at a cost that is 40% less than current technologies [3]."

Jan 1, 2012

By Albert H. Clough

The West Lynn Canal subarea of the Juneau Mining District (JMD) is defined by Lynn Canal on the east, Davidson Glacier to the north, Icy Strait to the south and the Glacier Bay National Park Boundary to the west (figs. C-l and C-2). This area extends along the main-land west of Juneau (across Lynn Canal) northerly, to approximately 20 miles south of the city of Haines. The only roads in the area are relatively new logging roads at the southern end constructed to support a U.S. Forest Service timber sale. There is also local road access near the community of Excursion Inlet. Access to the remainder of the region is either by boat, aircraft, or &apos;foot. Helicopters provide the only time effective access to all but the coastal parts of the West Lynn Canal subarea. Coastal areas may be reached by small boat or float aircraft. There is an unimproved dirt airstrip just north of the mouth of the Endicott River. This airstrip is suitable for use by light aircraft. The subarea lies within the Tongass National Forest and is managed by the Department of Agriculture, U.S. Forest Service. Approximately two-thirds of the forest lands are open to mineral entry under the current Tongass Land Management plan. The remaining forest lands comprise the Endicott River Wilderness area, which is closed to mineral entry. Private lands within the study area are sparse, with scattered homestead tracts along the coastal regions and in the Excursion Inlet area. Sealaska (Southeast Alaska Regional Native Corporation) also has land selections in the southern Chilkat Range. Tidal and submerged lands are owned by the State of Alaska.

Jan 1, 2012

By K. S. Liddell

The Kell Process has been developed for the extraction of platinum group metals (PGMs) and base metals from sulphide flotation concentrates. The process has been successfully tested on several different sulphide flotation concentrates, including those from the UG2 chromitite horizon and the Platreef mafic/ultramafic layer. It has been shown to provide high (>95 per cent) and selective extraction efficiencies for the key valuable metals, i.e. Pt, Pd, Rh, Au, Ni, Co, and Cu. The Kell Process consists of several commercially proven unit operations. S, Ni, Co, and Cu are first selectively removed by use of a pressure oxidation step during which the dissolution of PGMs is minimized. The residue from pressure oxidation is subjected to a thermal treatment to ensure efficient PGM recovery by subsequent chlorination. All the core steps are very similar to well-proven conventional unit operations in common use, as are the subsequent metal recovery steps to provide marketable end products. Typical metallurgical responses of flotation concentrates from UG2 and Platreef to the Kell Process are provided, and key outcomes of an energy comparison study with smelting are summarized in this paper. Kell presents a potentially substantial improvement in PGM concentrate processing technology, in terms of economics via much-reduced power costs, ease of processing, and various environmental benefits. It allows for the treatment of high-chromium low-grade &apos;dirty&apos; concentrates, such as secondary concentrates from the platinum industry&apos;s &apos;mill-float-mill-float&apos; (MF2) flotation circuits and concentrates from retreatment of tailings. It allows greater concentrate mass pulls, has higher tolerance to gangue intergrowths in concentrates, and its use can provide substantial increases in overall PGM recovery. Its adoption would be a step change in the platinum industry, and given the commercially proven unit operations embodied in the Kell Process, at much-reduced risk compared with other more experimental technologies. Since the initial process development work, significant improvements and refinements have been introduced as a result of further compre¬hensive testing and process modelling. Pilot-scale testing and engineering study work is in progress for several selected sites.

Jan 1, 2012

By Binxu Zhaug, Mark Jolly, Xiaojun Dai

"In conventional investment casting process of aluminium alloys for the application of the aerospace industry, to assure the quality of the final casting, usually the foundry uses large runner system which results in low yield, high energy consumption and high GHGs emission. In one case of this investigation, the yield is between 5 ~ 10% which means that the current casting process wastes large amount of energy and generates lots of scraps. By applying a new casting method, the bulky runner system and the melting/holding time are significantly reduced, the quality of the casting is improved, and in the meantime the related energy consumption and GHGs emission are significantly decreased. In the investigation, the energy efficiencies and GHGs emission between the current and traditional processes are calculated and compared.1. IntroductionAs one of the conventional casting process, Investment Casting Process (ICP) and its applications can be traced to thousand years ago [l]. In current casting industry, ICP still plays an important role in the production of small and precious castings with high quality requirements in automobile and aerospace industries. Both casting quality and manufacturing costs which mainly consist of energy costs have crucial effects on the competitiveness of castings in the market. In the production of aluminium alloy castings using ICP, the energy cost and energy efficiency of a casting facility depend mainly on the efficiency of its melting and heat treating performance. In association with the two performances, more than 60 % of the total process energy costs are symbolised in a typical casting facility [2]. Additionally, in conventional ICP of aluminium alloys for the application of the aerospace, to assure the quality of the final casting, typically the foundry uses huge runner system including big risers/feeders which cause low yield, creates lots of scraps and generates high energy consumption. Consequently, there are huge opportunities for casting industry to choose the best practices for potential energy saving. Furthermore, the reasons such as the stringent limitation of environmental legislation in Europe and the pressure of the rising energy price force the casting industry to reduce the energy consumption and greenhouse gases (GHGs) em1ss10n."

Jan 1, 2012

By Drew Martin

In March 2010 the Boral Linwood Quarry, Adelaide South Australia, implemented the blasting contractors Monte Carlo Blast Vibration Model as part of their blast design process. The Linwood Quarry was developing an area where blasting activities were marginally complying with the statutory vibration limits. Compliance to the statutory limits was only being achieved through the use of small blasts (less than 15 000 T (14 763 ton)) at a high cost to the quarry.

Jan 1, 2012

By Steve Johnston, Mowafak Al-Jassim, Fei Yan, Omar Sidelkheir, Alain Blosse, Katherine Zaunbrecher

"Imaging techniques are applied to multi-crystalline silicon wafers and solar cells throughout the production process. Photoluminescence imaging, both band-to-band and defect-band, is used to characterize defects and wafer quality at all process steps. These steps include bricks sawn from ingots, wafer sawing, cleaning and texturing, emitter diffusion, edge isolation and glass removal, anti-reflective coating/passivation, and metallization of finished cells. Bricks, wafers, and cells can be imaged at a rate commensurate with in-line measurement, giving spatial information to characterize quality and defect content. Photoluminescence images on silicon bricks can be correlated to lifetime measured by photoconductive decay and could be used for high-resolution characterization of material before wafers are cut. The defect areas in as-cut wafers are compared to imaging results from electroluminescence and lock-in thermography, and cell parameters of near-neighbor finished cells, showing correlations to efficiency, open-circuit voltage, and short-circuit current.IntroductionImaging techniques can rapidly characterize material quality and defect density. Photoluminescence (PL) imaging can be applied to silicon from the brick level to all wafer process steps [1-8]. At the brick level, material thickness allows for measurement and correlation to lifetime where surface recombination effects are minimized [6, 7]. At the as-cut wafer level where thin unpassivated wafers prevent accurate lifetime assessment due to surfaces, defects can still be categorized and quantified to predict finished cell performance [3-5]. Defect regions can be identified by recombination-limited band-to-band PL or by defect-band emission [9-12]."

Jan 1, 2012

By Scott Scovira

All flyrock incidents have the potential to result in injuries or fatalities that can result in loss of company reputation, license to operate with clients, and bear the exposure to high cost liability. From 2007 to 2009, one NA Quarry and Construction Business experienced a series of flyrock incidents. In the Spring of 2009, this business declared that the frequency and severity of Flyrock Incidents had reached an unacceptable level. A Flyrock Elimination Program was launched.

Jan 1, 2012

By H. Paudyal, K. Ohto, H. Kawakita, S. Alam, B. Pangeni

The orange waste after lime water modification was converted into promising adsorbents for fluoride by metal loading reaction. The effectiveness and mechanism of fluoride adsorption on metal loaded orange waste gel from synthetic and real plating solution were investigated. Amount of zirconium(IV), aluminium(III), cerium(III), lanthanum(III), titanium(IV), vanadium(IV) and tin(IV) loaded on orange waste from aquearegia dissolution were evaluated to be 1.62, 1.16, 0.93, 0.95, 1.20, 1.12, 0.97 mmol/g respectively. The maximum adsorption capacity (qmax) of zirconium(IV), cerium(III), lanthanum(III), iron(III) and aluminium(III) loaded orange waste for fluoride ions were evaluated to be 1.74, 0.91, 1.07, 0.98 and 1.01 mmol/g from aqueous solution. The mechanism of fluoride adsorption by metal loaded orange waste was inferred to be ligand exchange reaction. Application of zirconium(IV) loaded saponified orange juice residue(SOJR) for real plating solution showed effective removal of trace concentration of fluoride down to the accepted standard. The negligible interference of co existing anions like nitrate, carbonate, sulphate and chloride makes zirconium(IV) loaded SOJR a promising sorbent for waste water treatment. The adsorbed fluoride from fluoride loaded zirconium(IV)-SOJR was effectively desorbed by using alkali solution for its regeneration. This work shed light on the potential application of metal loaded SOJR to remediate fluoride contaminated water for environmental relevance.

Jan 1, 2012

By Timothy Fogarty, Gregory Poole, Roger Reeder, David Switz

This project involved the construction of a new pump station and intake structure at an existing water treatment facility. Although the project involved a significant amount of rock removal, the specifications said no blasting.

Jan 1, 2012

By X. Gumede

A model is being developed to quantify the benefits for mining houses resulting from the reduction in greenhouse gas and energy consumption by the application of innovative blast designs in addition to direct financial benefits throughout the mine to mill value chain. The conversion from shock tube initiation systems to electronics and some changes to powder factor measured on an open pit mine had previously been used to show significant improvement on blast outputs. Benefits were realised on drilling, blasting, loading, hauling and beneficiation. Quantification of the relationship between powder factor and reduced greenhouse gasses is investigated in this study. The study has highlighted new data that must be recorded and hence some assumptions were made as to fuel consumption and the energy in crushing was obtained from the Bond work equation. The mine to mill projects in an open pit platinum mine and a quarry produced energy savings and reduced greenhouse gas emissions associated with the careful application of explosives and blast innovations. The less fines project showed an increased carbon footprint. The model provides a new insight into how project feasibility should be decided based on economic and environmental viability.

Jan 1, 2012

By Jim Britton

Sustained elevated metal and coal prices in 2011 continued to drive mining projects across British Columbia. The province is the top producer of copper, exporter of coal and the only producer of molybdenum in Canada. The province also produces significant amounts of gold, silver, lead and zinc and more than 30 industrial minerals. The total 2011 value of solid metal production is an estimated $8.6 billion and the outlook for 2012 is positive. British Columbia is poised to bring several new mines onstream in the next few years. Construction continues at the New Afton and Mt Milligan copper-gold projects that are anticipated to be open in 2012 and 2013, respectively. The provincial Environmental Assessment Office indicates there are 26 mine proposals in process with three currently under review and 23 in the preapplication stage. The following text briefly describes 2011 metal and coal mining activities in the five regions reported on by the provinces? regional geologists (Fig. 1).

Jan 1, 2012

Software exhibitors at MINExpo will feature the newest, the best, the most comprehensive computer-based tools available to get minerals from the ground to the market. From the ?cloud? to the pit, the variety that will be featured is almost limitless ? a digital tool for every phase of the mining lifecycle. Blue Sky Network SkyRouter brings the Blue Sky Network to the cloud. Using its interactive Web portal, SkyRouter, with detailed mapping and integration with Google Earth, the Blue Sky Network links enterprises to personnel and assets anywhere on earth through Iridium satellites. The cloud-based solution is designed to support connectivity with remotely dispersed mobile assets, including Blue Sky?s dual-mode GSM and Iridium tracking and communications services. This enables seamless connectivity with assets in problematic cellular reception areas, where only 10 percent of the Earth is covered, and in remote locations.

Jan 1, 2012

By David Leidel, Beth Shimer, James Stuart

Periodically, the Institute of Makers of Explosives Safety Library Publications are reviewed, edited and updated to reflect recent technical developments, new commercial explosive products and new regulatory requirements. The rapid proliferation of electronic devices, particularly portable communication systems, inventory management devices, navigational aids, etc., required the revision of the IME Safety Library Publication 20, “Safety Guide for the Prevention of Radio Frequency Radiation Hazards in the Use of Commercial Electric Detonators”. The new edition of SLP-20 has been updated to correct alterations to U.S. frequency allocations and maximum transmitted power permitted and a discussion of communications and tracking systems required in underground mining by the Miner Act. Also, an entire section was added dedicated to safe distances from RF sources to the special type of resistorized electric detonators used in the upstream oil and gas industry on wellsites and an enlarged section describing the particular types of RF sources that the blaster may encounter, perhaps in construction blasting operations.

Jan 1, 2012

By W. G. Pariseau

This contribution describes rock mechanics features of the Davis Cavern at the former Homestake Mine in Lead, South Dakota, U.S.A. The mine is located in the northern Black Hills of South Dakota. In 2003 and again in 2008, the mine site was recommended for development as a national Deep Underground Science and Engineering Laboratory (DUSEL) in cooperation with the Sanford Underground Science and Engineering Laboratory under the South Dakota Science and Technology Authority (SDSTA). The original Davis Cavern was excavated about 9.1x16.8x9.7 m high (30x55x32 ft high) in 1965 (Mitchell 2009) at a depth of 1,478 m (4850 ft). The purpose of the cavern was to house apparatus for detecting solar neutrinos. The experiment ultimately proved successful and earned R. Davis a share of the 2002 Nobel Prize in physics. Recently, a new experiment (LUX=Large Underground Xenon detector for dark matter particles and WIMP&apos;s=weakly interacting massive particles) was proposed for the Davis Cavern that required an increase in height of 2.4 m (8 ft). For many years, the Homestake gold mine was the deepest operating mine in North America. Development extended to the 8000 Level (2,438 m). The mine closed in 2003. Pumps were shut off and the water level rose to the 4350 Level, about 150 m (500 ft) above the Davis Cavern. Some six years later after selection for DUSEL proposal development by the National Science Foundation (NSF), access to the 4850 Level and the Davis Cavern was regained. Pumping has lowered the water level to well below the cavern floor. Figure 1 shows the layout and location of the Davis Cavern (Cavity). Detector tank, supporting steel, and so forth were subsequently removed. The cavern was re-supported and new access was developed. By August, 2010, 13,000 ft3 had been removed during enlargement and renovation of the Davis Cavern. Figure 2 shows the detector tank under construction in 1965.

Jan 1, 2012