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By Samrat Mohanty

The construction of underground hydrocarbon storage caverns in Jurong Island, Singapore, is nearing completion. The facility, located beneath the seabed of Banyan Basin, is comprised of five storage caverns with a storage capacity of approximately 1.5 million cubic meters. The galleries of each cavern are 20 m wide by 27 m high and approximately 340 m long. In addition to the storage caverns, various access and operations tunnels are required to support the facility. Among these are water curtain galleries to ensure that hydrostatic pressures in excess of hydrocarbon storage pressure are maintained in the rock mass surrounding the storage caverns. Early in the design process, conventional steel rock bolts with resin polymer grout were considered for ground control. However, the construction contractor proposed using fibe-reinforced polymer (FRP) bolts with cement grout due to the corrosive hydrologic environment, weight and handling considerations, local construction preferences, and the requirement to have a cavern design life of 50 years. FRP bolts with cement grout were ultimately chosen for the project. The FRP bolting system has proven to be very successful, with no ground failures experienced where systematic FRP bolting has been applied. This paper discusses the properties of FRP bolt/cement grout bolting systems, their characteristics in relation to steel bolt/resin bolting systems, and numerical modeling results assessing their performance.

Jan 1, 2014

By David B. Paul

"ABSTRACTThe US Army Corps of Engineers (USACE) has 704 dams in their inventory and over 100,000 miles of levees with a capital value of over $150 billion. Currently, there are 319 dams that are classified as high hazard and have actionable failure modes that will require structural modifications. The most frequent actionable failure mode associated with the inventory is seepage and piping. One of the most effective engineering solutions is the installation of a cutoff to limit seepage. Currently, USACE has over $1.5 Billion of cutoff wall projects under construction and/or design. Given the magnitude of the dam and levee safety issues, USACE is developing a new Engineering Manual (EM) titled “Seepage Control Cutoffs for Dams and Levees.” This EM covers all of the methods to construct cutoff walls. USACE has partnered with the Deep Foundation Institute (DFI) in preparation of the EM to ensure that it is comprehensive and draws from the expertise of the specialty foundation engineering companies that design, manufacture, and construct seepage control cutoffs around the world. The EM contains case histories as well as a comprehensive project statistical summary and guide specification paragraphs. The goal of USACE was to make the EM a state of the art document for use by Districts.HISTORYSlurry wall construction techniques were developed in the late 1940’s in Italy by ICOS. The first use of the slurry trench method of construction in the United States was by the USACE Memphis District in September 1945, to form a partial cutoff along the Mississippi River levee on the Arkansas side of the river just below Memphis, Tennessee. The idea for the project probably evolved from the use at that time of puddle clay trench cutoffs combined with the use of drilling mud for advancing borings. A paddle wheel mixing device was constructed for making slurry from native clays. Trenches were dug to a 20-ft depth using a trenching machine and to a 35-ft depth using a dragline with a 100-ft boom and 2-cu-yd bucket. Backfill was mixed in windrows at the site from hauled-in clay gravel and native materials and pushed into the trench by a bulldozer when the length of the trench was equal to about twice the trench depth. It is amazing that after almost 70 years, the technique is still about the same as it was when first developed by the Memphis District. A soilbentonite cutoff was constructed under the Kennewick Levee adjacent to the Columbia River as part of the McNary Dam Project in Washington by the Walla Walla District in 1952 The first application of a soil-bentonite slurry trench cutoff for control of underseepage at a major earth dam was at Wanapum Dam on the Columbia River in Washington in 1959.The first cement- bentonite cutoff in the United States was constructed at the Tilden Tailings Project to store tailings from the Tilden Mine in Michigan in 1976. The first cement-bentonite cutoff constructed at a dam on a river retaining a reservoir in the United States was completed in 1978 at the Elgo Dam (formerly the San Carlos Dam) in Arizona.The USACE has designed and constructed some of the deepest and most complex cutoff walls for dams since the 1970’s. The first major concrete panel cutoff wall constructed in a dam in the United States was at Wolf Creek Dam (Nashville District) by the ICOS Corporation between 1974-77. The dam has a long history of seepage issues associated with the karst geology that comprises the foundation. In 1968, about 17 years after first being impounded, wet areas, muddy flows in the tailrace and sinkholes in the downstream toe adjacent to the switchyard occurred."

Jan 1, 2014

By William Reisz

In our line of work,like many other professions, there may be times when circumstances or a series of events may arise, contributing toward unacceptable risk. When multiple parties are involved, there will almost inevitably be differences on how best to deal with these situations. Unless approached in an intelligent and these differences may often have the potential for costly and unexpected results.

Jan 1, 2014

"1.0 DESCRIPTIONThis work consists of furnishing all necessary labor, equipment, and materials to install prefabricated vertical (wick) drains in the ground in accordance with the Plans and as specified herein.2.0 REFERENCED CODES AND STANDARDSASTM D4716-08 Standard Test Method for Determining the (In-plane) Flow Rate per Unit Width and Hydraulic Transmissivity of a Geosynthetic Using a Constant HeadASTM D4632-08 Standard Test Method for Grab Breaking Load and Elongation of GeotextilesASTM D4533-11 Standard Test Method for Trapezoid Tearing Strength of GeotextilesASTM D4491-99a Standard Test Methods for Water Permeability of Geotextiles by Permittivity (2009)ASTM D4751-04 Standard Test Method for Determining Apparent Opening Size (A.O.S.) of a GeotextileASTM 6918-09 Standard Test Method for Testing Vertical Strip Drains in the Crimped Condition3.0 QUALIFICATIONSThe Contractor shall have successfully completed a minimum of five wick drain installation projects in similar ground conditions, and installed not less than 5,000,000 linear feet (1,525,000 linear m) of wick drain in the past five years. The Contractor shall have a minimum of five continuous years of wick drain installation experience."

Jan 1, 2014

By Kun Wang, Xinhui Li, Huaqing Xie, Qingbo Yu, Qin Qin

"Three typical model compounds of bio-oil (ethanol, acetone and phenol) were studied in the steam reforming process for hydrogen production. In the thermodynamic analysis, the three componds showed the similar trends. The hydrogen yields increased with the increase of steam/carbon (S/C) ratios, and the temperatures of the maximum hydrogen yields moved afterward to low temperature zone. However, the hydrogen contents were just about 70%. For improving hydrogen yield, a new system for steam reforming of bio-oil with site CO2 capture was put forward. This system required the catalst with the larger granularity having greater mechanical strength and higher abrasion resistance. So, six Ni-base catalysts loaded on Al2O3 particles prepared were used and among them, Mg-Ni/Co catalyst showed the best catalytic performance. For the simulated bio-oil (the mixture of the compounds), the hydrogen yield can attain 63% with Mg-Ni/Co catalyst with the good stability and regeneration ability.IntroductionCurrently the interest in the use of hydrogen as a clean energy carrier is increasing, and the main way for producing hydrogen is steam reforming of fossil fuels, containing steam reforming of nature gas, naphtha and coal. But this way caused substantial amounts of CO2 emitted, and these sources of hydrogen which are non-renewable energy will eventually be used up [1, 2]. As a kind of renewable energy, biomass is recognized as an attractive alternative to fossil fuels, because of its neutral CO2 emissions [3]. There are mainly two thermochemical processes using biomass to produce hydrogen, gasification and flash pyrolysis followed by steam reforming (SR) of the biooil produced in the flash pryolysis process [4]. The latter was known as one of the most promising and economically viable methods for hydrogen production [5]. In the last decades, the biomass flash pyrolysis technology was adequately developed and fairly mature [6]. But the steam reforming of bio-oil is still at the research stage and yet has been leading to more and more concerns by the researchers. In their research, the catalysts were widely studied and yet mainly were powdery[7-10], and the reactors manily were fixed bed reactors[11-13], readly causing the carbon deposition and the catalyst deactivation, against the continuous running. In this paper, a new systerm was put forward and could realize continuous production of hydrogen, yet needed catalysts with the larger granularity having greater mechanical strength and higher abrasion resistance, as well as powdery CO2 sorbents which mainly calcium oxide based ones.In this paper, the thermodynamic analysis of the steam reforming processes of three typical bio-oil model compounds (ethanol, acetone, phenol) was performed, and the effect of S/C ratio and temperature on the hydrogen yield and the compositions of gaseous products were investigated. Then, a new systerm for steam reforming of bio-oil with site CO2 capture was put forward, and the catalysts with a certain granularity were prepared and studied."

Jan 1, 2014

By Paulo Sérgio de Oliveira, Joaquim D. Donda, Andreia C. Rosa

"The search for energy efficient technologies for comminution processes is constant in mineral processing studies, since those processes represent a major percentage of operational costs. In this context the use of stirred mills is increasing, especially for ultrafine grinding. Although many authors claim that these new equipment are more efficient than the conventional ball mills, there were very little chances to prove that in a practical way, since there are few industrial circuits where those technologies perform the same duty. Therefore, the regrinding circuit of Germano second concentrator offers an interesting opportunity: a vertical mill operating in parallel with two ball mills. During almost two years of operation, several sampling campaigns were conducted to evaluate the vertical mill performance and to compare the operational data of the three mills. The industrial data was also compared to jar mill tests results, which are monthly conducted in Samarco labs in order to predict the specific energy consumption required by the ore fed to these circuits. The vertical mill demonstrated the same ability to achieve the product specifications of the ball mills while proved to be able to reduce the medium specific energy consumption in about 40%."

Jan 1, 2014

By Behzad Vaziri Hassas, Firat Karakas, Mehmet Celik, Onur Guven

Since dewatering is a costly process, removal of moisture from relatively fine size lignites is an important industrial problem. As the lignite gets finer, the presence of micropores and relatively low hydrophobic nature of lignite lead to trapping of large quantities of water in the coal matrix. Lignites used in power stations need to be dried to a certain degree of humidity before it is transferred to the combustion chamber. It is generally wise to dewater coal as much as possible by physical means before it is dried. However, dewatering cost in some cases may be prohibitive. Thus, sometimes removal of even little percent moisture may be of great help in such operations. Surfactants have been used to increase the efficiency of coal dewatering. It is crucial to select appropriate type and amount of surfactants in order to get higher efficiency. Since the hydrophobic characteristic of coals increases with increasing the coal rank, dewatering of bituminous and anthracite can be accomplished using low HLB surfactants (Oily), however, these surfactants are not efficient in the case of low rank coals like lignites and brown coals. It is suggested that adsorption of low HLB surfactants on high rank coals is governed by Acid-Base interactions rather than electrostatic and van der Waals forces. Since this characteristic in lignites is not strong enough, low HLB surfactants could not be effectively adsorbed on low rank coals to make surface more hydrophobic. In this paper, a special set-up has been designed to study the effect of high HLB surfactants on dewatering of fine lignite particles. It is shown that high HLB surfactants function more efficiently on low rank coals than low HLB ones.

Jan 1, 2014

By Matthew Novak, J. Brent Hiskey

It is well known that when chalcopyrite is put in direct contact with copper in an acidic medium a galvanic cell is created. Chalcopyrite is reduced to iron and sulfur deficient defect phases such as bornite, chalcocite, and at very low potentials to elemental copper. Galvanic conversion experiments were performed using three chalcopyrite concentrates. The first chalcopyrite contained less than 10% impurity phases. The second concentrate had a high concentration of pyrite, and the third concentrate had a high concentration of pyrrhotite. The effect of temperature, acid concentration, chalcopyrite grain size, copper grain size, and agitation on the rate of chalcopyrite conversion was studied.

Jan 1, 2014

By Ulrich Leiste

If the iron ore loss is 15% in the process of mining, the total iron ore loss in the world will be about 461 million tons, this is equal to the total production of 230 iron ore mines each of which produces 2 million-tons of iron ore per year. Based on a series of blast tests in the Malmberget mine, this paper shows that ore recovery can be markedly increased by improving blasting technology such as choosing a correct primer position and making use of shock wave collision. The paper further suggests that a high ore recovery can not only reduce natural resource loss and mining cost but also prolong the life of a mine. In addition, the paper shows an example of reducing blast-caused rock damage in the roofs and walls of underground drifts (tunnels) by using new blasting methods in the Malmberget mine. Finally, the paper shows how the Malmberget mine has successfully reduced the ground vibrations, without adversely affecting fragmentation and ore recovery in sublevel caving mining.

Jan 1, 2014

By Rudolph P. Frizzi

"Abstract Pile design for building structures in the United States is typically performed by: 1) investigating and assigning engineering parameters to the respective ground bearing materials, 2) calculating ultimate pile to ground (geotechnical) capacity which is then reduced by a Safety Factor deemed appropriate by a registered Design Professional thereby arriving at an allowable pile geotechnical pile capacity, and 3) determining the required pile structural section using allowable pile section material properties. It is advantageous to use a Working Stress Design Method (WSDM) approach as one system of loads (service loads) are used in both the geotechnical and structural evaluation. There are a variety of methods used to determine the ultimate and allowable geotechnical capacity, and Building Codes often require a registered Design Professional to determine the appropriate method(s) and capacities. The International Building Code is the Code typically referenced in building design and construction in the United States. Structural design usually follows Building Code requirements and Allowable Stress Design (ASD) procedures. As design of the overlying structure typically follows a Strength Design Method (SDM) approach using factored loads, in some cases piling is first designed for pile-to-soil interaction using service loads, followed by evaluating the pile geometry for factored loads. Construction is the finalization and implementation of the designed piling. As such, project-specific technical specifications are typically developed by a registered Design Professional such that a project Owner can bid, buy, and instruct a Contractor as to the desired piling work and acceptance criteria. There are several Industry groups, including DFI, PDCA, ADSC, and ACI that provide guidance documents which the registered Design Professional can refer to in developing the piling technical specifications. It is the author’s opinion that the registered Design Professional is best suited to observe and verify the piling installation; many Building Departments require verification and documentation by a registered Professional as a condition of final acceptance.INTRODUCTIONPile design for building structures consists of: investigation, design, specification, and verification. In major metropolitan areas within the United States, Building Codes typically identify minimum requirements for each of the above steps. The International Building Code (ICC, 2012) is the Code typically referenced in building design and construction in the United States. Recognizing the ground conditions as well as piling construction means and methods can vary on a site-by-site basis, latitude is given to the registered Design Professional and Contractor to optimize the piling system for the respective project conditions. Field testing and quality control / assurance measures are typically implemented to verify the design intent is attained for the production pile elements."

Jan 1, 2014

By Mario Terceros H., Bengt H. Fellenius

"ABSTRACTFour strain-gage instrumented bored piles were constructed in a sedimentary, dense to very dense, fine to medium sand in Santa Cruz, Bolivia. Two of the test piles were the normally used bored pile constructed with bentonite slurry and two piles were Bauer Full Displacement Pile (FDP). One of each pair was equipped with the Expander Body, an inflatable steel cylinder that on pressure-grouting provides an enlarged pile toe. Head-down static loading test were performed on three of the piles and a bidirectional test was performed on the fourth pile, a standard pile with Expander Body and a bidirectional cell placed immediately above the EB. The latter pile was tested in 3 phases. First by activating the cell, second, by a head-down test, and, third, by a repeat bidirectional cell test. The static loading tests proved the shaft resistance of the FDP pile to be about twice that of the standard bored pile and that the Expander Body more than doubled the toe stiffness. The strain-gage records showed that the standard bored piles had multiple bulges and neckings, which affected the evaluation of the axial stiffness and load distribution of the piles. The testing programme was used for a prediction event with 60 persons, ahead of the tests, submitting predictions of the load-movement curves for the test piles and also a capacity appraised from the curves.1. INTRODUCTIONOn April 23 - 26, 2013, the First International Conference and Seminar on Deep Foundations was held in Santa Cruz, Bolivia under the auspices of INCOTEC SRL, the UAGRM University, and the Bolivian Association of Civil Engineers and Chamber of Construction. To coincide with the conference, a research study on construction and static and dynamic testing of four instrumented bored piles was undertaken. To ""add spice"" to the conference, a prediction event was organized on the test programme. This paper presents the soil conditions at the site, the type and construction of the test piles, the outcome of the prediction event, and the results of the static tests.2. SOIL CONDITIONSGeotechnical studies comprising SPT and CPT tests with routine laboratory analysis were performed on recovered soil samples. Three SPT boreholes were put down at three of the locations of Pile TP1, TP2, and TP3, at 5.0 m distance from each other. The SPT procedure consisted of manual hoisting of the weight by three crew members pulling on ropes over a pulley supported by a tripod and letting the weight fall by gravity. The groundwater table lies at 3.5 m depth.Figure 1 shows diagrams of the SPT N-indices and the distribution of water content in the three boreholes. The SPT-indices show the soil density to be compact. The average water content is about 15 %, plus-minus a few percent."

Jan 1, 2014

This paper discusses how elemental analysis of conveyed bulk flows in real time using PGNAA (Prompt Gamma Neutron Activation Analysis) technology has resulted in significant improvements in advancing plant control in mineral processing operations. Basis of operation of the PGNAA through belt, full stream, continuous, multi-elemental, real time analysis technology is explained. Capabilities and limitations in plant operating environments are discussed including comparison with other real time, online technologies through review of published information available for on-conveyor minerals applications. Case studies demonstrate benefits provided by this technology in two operating mines. An iron ore company had prior experience with the PGNAA analyser technology, implementing an early model in a minerals application in 2003 to develop confidence in its measurement performance and usefulness of the data. A number of analysers were subsequently included throughout the new plant design for extensive measurement and control of conveyed bulk flows, from conveying after mining through to rail load-out. A copper-gold company installed an analyser to address copper ore blending issues where an on-belt system was the only viable option for the degree of control required. Analyser suitability was evaluated through test work on site samples to determine customised multi-element precision guarantees for each application. Analyser results from normal operation are compared against laboratory analyses of multiple cross stream samples collected from conveyed flows to assess performance. Both projects discussed were able to realise benefits previously unattainable for plant quality control, surpassing capabilities of traditional technologies which were either unsuitable for measuring conveyed flows with adequate accuracy or in real time. Equipment payback within a few months was achieved for both sites. Through proven performance in these applications, the companies consider the technology an essential component in advanced plant control necessary in new process flow sheet designs, rather than an optimisation tool.

Jan 1, 2014

By Rolf Andreas Lauten, Adam Pratomo, Dani Ramdani, Helminton Sitanggang

A universal challenge for the mineral processing industry is the diminishment of high grade ores. Instead, low grade ores, sometimes also containing problematic gangue minerals is the reality. With lower head grades the industry has to put more effort into processing to maintain the output and achieve suitable recoveries. In an effort to reduce the impact of declining head grade, a biopolymer was evaluated as an additive in the gold leaching operation at Antam Pongkor in Indonesia. Laboratory testing revealed that biopolymer usage lead to an increased gold recovery without apparent negative impact on the other parts of the process. Further plant trials revealed both a recovery increase around 1.3% and higher throughput (9%) in the presence of the biopolymer. Some scenarios that can explain these findings will be discussed.

Jan 1, 2014

By Sachihiko Tokunaga, Hirofumi Taguchi, Kenji Maruyama, Hidenori Takahashi, Yoshiyuki Morikawa

"Abstract The present study proposed a new liquefaction countermeasure to improve sandy ground and conducted a trial execution. The new method is a floating-type and lattice-shaped cement treatment method, where cement-treated soil is not fixed to a non-liquefiable stratum. A fixed structure such as treated soil should be formed at the side of the floating-type treated soil to reduce its lateral displacement. In the study, one-dimensional dynamic response analyses were first conducted to confirm the mechanism of the new method. Then, a series of centrifuge model tests were performed to demonstrate the effect under a stress condition at the prototype scale. The analyses and model tests confirmed the effect of the liquefaction countermeasure. Finally, trial executions were carried out to confirm high-quality vertical execution.INTRODUCTIONLiquefaction induced by an earthquake generates sand boiling and ground settlement. Other problems have also been reported, including a decrease in bearing capacity and an increase in the horizontal earth pressure against retaining walls. To prevent these problems caused by liquefaction of the ground, various countermeasures have been proposed, such as cement deep mixing and high-pressure jet mixing methods. These methods have the big advantage of being applicable to ground that contains soil with a fine-grain fraction. Furthermore, the unnecessary displacement caused by the construction can be reduced. In Japan, a lattice-shaped cement-treatment method has frequently been used at many construction sites to prevent liquefaction, where cement-treated piles are intersected to form a lattice, as shown in Fig. 1. The lattice-shaped walls can reduce the shear stress generated by an earthquake, restricting the liquefaction at that location. However, the construction cost of the cement treatment is relatively high compared to other methods such as the sand compaction pile (SCP) method, and needs to be reduced. In particular, the cost of the high-pressure jet mixing method, which can be applied to the liquefiable ground under existing structures, is significantly high. Therefore, decreasing the total volume of the cement treatment is necessary to reduce the construction cost."

Jan 1, 2014

By Nicolás Luis, Qi Liu, Gonzalo Montes-Atenas

"The prediction of froth flotation performance is still an unresolved topic. Classic industrial models based on particle size, elemental and mineralogical information provides recovery results with deviations that may become significant. One possible reason for this deviation may be the fact that the current liberation analysis provided by electron microscope based techniques does not take into account the outmost surface layer composition of liberated particles. In order to complete the description provided by the liberation analysis, other spectroscopy techniques measuring the extreme surface of the minerals can be tested. For instance, X-ray Photoelectron Spectroscopy (XPS) is a technique which measures the first tens of nanometers providing elemental composition over the particle surface and allows resolving the elemental associations present at the surface sample. However, this information needs to be statistically robust, reproducible and most importantly representative of what is occurring in the process. The aim of this research work is to develop a statistical model based on particle population to evaluate the feasibility of turning the XPS technique into a metallurgical tool. The model consists of classic statistical population arranged in a bed of heterogeneous particles with a known grade and mineral liberation. The simulations showed that the XPS results statistically followed a well-defined pattern. The statistical results were confronted with pilot plant results obtained from a rougher bank when processing a copper sulfide ore from a Chilean mine site. It was observed that the probability function distribution was in agreement with the experimental data. Further analysis on how the XPS results provide valuable information improve the computation of froth flotation recoveries is also discussed."

Jan 1, 2014

By Carnevale Francesco, Bracci Laudiero Alberto, Pampanin Piero

"SummaryIn the Port of Naples a slurry wall has been realized through a sandy layer up to a deep tuff layer using the Cutting Soil Mixing technique.The executed panels have dimensions of 2.8 m x0.65 m in plan and a total length of 25 m. Primary and secondary panels have been executed using the wet to wet technique. During the panels execution the following parameters had been measured: injection pressure, injected volume, verticality. At the end of the works an exploratory campaign has been carried out through boreholes collecting samples for laboratory tests in order to verify the diaphragm thickness and its physical and mechanical properties (i.e. unit weight, unconfined compressive strength).The interpretation of the collected data allowed to verify the efficiency of the method, the volume of slurry loss due to permeation during the panels execution, the quantity of the obtained spoil compared to the volume balance equation, both for the sand and the tuff layer.Eventually, the measured physical and mechanical characteristics of the panels have been correlated to the execution method performed.IntroductionIn the Naples Port area there is a polluted site which has to be hydraulically isolated in order to prevent the pollution of the groundwater that flows from land to the sea through the Port area. A hydraulic cut-off wall has to be realized and particularly a slurry-wall realized using the CSM method had been executed.To date, two stretches have been executed, 140 an 110 m in length respectively, as shown in Figure 1 and Figure 2.After execution, the slurry-walls have been investigated with boreholes. In-situ and laboratory tests on the recovered samples of grout have been carried out; furthermore, the geotechnical parameters of the mix composing the wall have been measured."

Jan 1, 2014

By T. Fujita

The incinerated bottom ash includes titanium oxides and a small amount of chromium oxides. Initially, 89 % of chromium was removed from ash at magnetic flux density at several stages of wet magnetic separation from 0.05 T to 6 T. The bottom ash from an industrial waste incineration process includes about 10 % of TiO2. The minerals that contain titanium are rutile and perovskite. These minerals are paramagnetic and show low magnetic susceptibility, therefore, the high magnetic field strength, created by a superconducting magnet, is necessary to capture these minerals. At the first stage of separation, a magnetic field strength of 6T was applied in order to attract the particles that contain iron oxides to the higher magnetic field region. At the second stage of separation, the magnetic capture rate of weekly magnetic particles decreased with increasing the magnetic susceptibility of the aqueous solution (i.e. the medium for dispersing the particles) in order to separate the highly magnetic materials. The para-magnetic salt such as ferric chloride was dissolved in the water to increase the magnetic susceptibility of the medium. After a two-step wet HGMS with superconducting magnet, the grade of TiO2was increased from 10 % to 28 % with a recovery of 64 %.

Jan 1, 2014

By M. N. Chandraprabha

Arsenopyrite is often associated with sulphides like pyrite, chalcopyrite and galena in refrac-tory gold ores. Selective flotation of arsenopyrite from associated sulphides is desirable for effective gold extraction when the gold is preferentially associated with the arsenopyrite matrix. By contrast, presence of arsenopyrite in flotation tailings poses a serious environmental threat due to arsenic dissolution. To prevent arsenic contamination from the mine wastes, it would be more economical and environmentally beneficial to remove this mineral during the froth flotation step. Use of Acidithiobacillus thiooxidans in the detoxification of arsenic containing sulphides is outlined in this pa-per. Biomodulation using Acidithiobacillus thiooxidans resulted in the preferential depression of pyrite from arsenopyrite. By suitable conditioning with cells and collector effective separation of arsenopyrite from pyrite was achieved. Biomodulation with wild cells did not yield separation of arsenopyrite from chalcopyrite. However, bacterial affinity could be induced to a desired sulfide mineral through environmentally controlled adaptation techniques. Through the use of arsenic-adapted bacterial cells, selective removal of arsenopyrite from chalcopyrite was readily achieved.

Jan 1, 2014

By X. Y. Liu

A culture-independent approach based on 16S rRNA gene clone library was used to analyze the bacterial community change both associated to the solids and in the liquid phase during pyrite bioleaching process. Phylogenetic analyses of 16S rRNA fragments revealed that the retrieved se-quences mainly related to genus Leptospirillum, genus Sulfobacillus and genus Acidithiobacillus. During the bioleaching process, genus Leptospirillum trends to grow associated to the solids while major of genus Sulfobacillus were in the liquid fase, only accounting little portion in the solids. Genus Acidithiobacillus can grow both on the solids and in the liquid phase, but accounting high portion on the solids.

Jan 1, 2014

By C. Y. Sun

Flotation of chalcopyrite and unactivated malachite with xanthates (ethylxanthate, butylxanthate, octylxanthate and dodecylxanthate) is studied in this paper. Minerals interacted with xanthates are detected by FTIR, and simulated by molecular mechanics. It shows that chalcopyrite can be floated with 4 kinds of xanthates, and unactivated malachite can?t be floated with ethylxanthate but can be floated directly with later 3 kinds of xanthates while characteristic absorption peaks of those four kinds of xanthates are all detected by FTIR on chalcopyrite and malachite surface. After simulating the interaction between xanthate and mineral, it shows that H2O and OH-can interact with chalcopyrite and malachite, and their interaction energy may be so called energy bulwark which must be overcome by collector when collector interacts on minerals; the two sulfur atoms in xanthate group interact with copper and neighbor iron atoms on chalcopyrite. It also shows that molecular mechanics results with logP of collectors can interpret the mechanism of xanthate-mineral on atom scale.

Jan 1, 2014