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By S J. Kim, S W. Kim, L Tomas da Rocha, S Jung

Al2O3 has been regarded as a harmful gangue component in iron ore, especially causing reduction degradation in industrial sintering of iron ore. The current study aimed to utilise low-grade iron ore containing high Al2O3 content in sintering process. In order to counteract the adverse effect of Al2O3 on reduction behaviour of iron ore sinter, mill-scale and calcined dolomite were chosen as FeO- and MgO-bearing materials. Firstly, mill-scale was added to high Al2O3 sinter and addition was optimised as 10 wt per cent, then calcined dolomite was added further. Magnetite and magnesio-ferrite were identified as the major phases in iron ore sinter when adding mill-scale and calcined dolomite. As the dosage of calcined dolomite increased beyond 4 wt per cent of in sinter mix, unreacted MgO particles were observed, which is ascribed to the limitation of MgO dissolution into magnetite matrix. Both mill-scale and calcined dolomite were effective in improving compressive load and Reduction Disintegration Index (RDI) of iron ore sinter although its reduction degree was highly decreased. The addition of both FeO and MgO-bearing materials to high Al2O3 sinter has a potential to improve the sinter quality, also contribute to the recycling of industrial by-product. However, the amount should be optimised in views of phase development and deterioration of reducibility.

Jun 19, 2024

By V Shrotri L Muhmood, P Gandhre

The current work deals with the measurement of some thermophysical properties of Ca(NO3)2 based ternary nitrate molten salts as HTF (heat transfer fluid) / TES (Thermal Energy Storage) material for CSP (Concentrating solar power) plants. The density and viscosity of different compositions of the ternary salt mixture containing Ca(NO3)2, NaNO3 and KNO3 close to the liquidus has been experimentally measured. An attempt has also been made to measure the melting point of the salt using the cooling curve technique as well as Differential Scanning Calorimetry (DSC). Thermogravimetric analysis has also been performed to estimate the peak operating temperature of the salt. Compatibility of suitable pipe material (SS304) with molten salt has also been discussed. The salt mixture proves to be a viable alternative to the already existing HTFs like Therminol VP-1 (organic oil) or Solar Salt® in regards to its lower melting point, wider operating range, low cost, nontoxicity, sufficiently high density and comparable viscosity.

Jun 19, 2024

By J H. Park, M J. Lee

Because the environmental problems are occurred by greenhouse gases such as CO2, the industries have tried to increase electric motor efficiency to reduce CO2 emissions. A core material of electric motor is high-silicon electrical steel. The ferrosilicon (FeSi) alloy, a raw material for the production of electrical steel, affects the electric properties of silicon steel. The main impurities such as Ca, Al and Ti make inclusions or precipitates that causes core loss. The slag treatment has been widely used to remove impurity elements. Thermodynamic principles for the refining of several impurities, specifically Ca and Al, have been investigated, whereas thermodynamic behaviour of Ti has not been fully understood yet. Therefore, in the present study, the titanium distribution ratio () between ferrosilicon and CaO-SiO2-Al2O3 slag system at 1773 K was investigated. The results show that is influenced by both the basicity and stability of titanium ion in the slag. Specifically, exhibits a minimum value at about C/S=0.7 indicating a shift in the titanate structure unit from [TiO5]-square pyramid to [TiO4]-tetrahedron because of lack of Ca2+ ions in a C/S<0.8 region, contributing to an increase in titanate capacity and .

Jun 19, 2024

By G Brooks

The control of phosphorus in steelmaking is one of the famous challenges of pyrometallurgy. It is well established that highly basic slags, the presence of FeO in the slag and lower temperatures (less than 1650°C) are favourable for phosphorous removal. The thermodynamics of this reaction have been extensively studied under laboratory conditions and the general trends confirmed through industrial trials. However, in general, phosphorus slag/metal distributions measured in industry are far from equilibrium and quite specific to the oxygen steelmaking technology being used. This variability was quantified by Urban, Weinberg and Cappel (2015), who found that the phosphorus partition ratio measured in plants varied with blowing practice, stirring intensity and even converter life. Some recent kinetic studies by Gu, Dogan and Coley (2017) have shown how the kinetics of these reactions vary with FeO content and dissolved sulfur at the droplet scale. A global kinetic model by Rout et al (2018) provides meaningful predictions of where dephosphorisation occurs in an industrial basic oxygen furnace (BOF) and some recent heat transfer modelling by Madhavan et al (2021, 2022) implies that temperature difference between droplets and slag has a role to play in explaining why equilibrium is not achieved. This paper will review the current state of knowledge and provide suggestions on predicting phosphorous removal for industrial operations and how greater removal could be achieved.

Jun 19, 2024

By E Jak, P Hayes, J Chen, M Shevchenko, E Nekhoroshev, D Shishin

Recent decades have seen significant advancements in analytical and experimental techniques, thermodynamic theory, and computational capabilities in high temperature research which are particularly timely to address the challenges of increasingly complex and variable feedstocks in both primary and secondary pyrometallurgical processes, the need to optimise and improve them. Currently a research program is in progress on the development of the 20-component multi-phase thermodynamic database for pyrometallurgical smelting, refining and recycling systems describing thermodynamics and phase equilibria of molten slag, matte, speiss, salts, alloys and associated solids. The integrated experimental and modelling program has been supported for nearly two decades by several consortia of 14 major international companies with over 30 operations around the world, integrates many components, incorporates many in-house developments, and brings together many different groups of professionals of different levels from junior and mid-career to senior from both industry and university sectors. The aims of the paper are:  to outline the many components and issues of the overall program including analytical, experimental and thermodynamic modelling research as well as implementation of the results in industrial practice, professional education, planning and organisation issues.  to highlight the opportunities, challenges, and possible solutions.  to present these to all different groups of professionals involved in the current program.  and thus, importantly, to facilitate possible future further developments and collaborations in the field of phase equilibria and thermodynamics of complex high-temperature systems.

Jun 19, 2024

By K Verbeken, D Seveno, A Maslov, I Bellemans

Recycling and decarbonisation current metallurgical processes is key for our planet’s future and in both cases, digital twinning will play an important role. However, the various modelling techniques being used for digital twinning require a lot of input values on variables such as viscosities, diffusion coefficients and surface energies that need to be known as a function of temperature, atmosphere and composition, but which are not widely available, such as in databases, for molten slag phases. The need for more accurate data on physical slag properties is clear and will be extremely relevant for making more realistic and quantitative simulations. Some of these properties are difficult to determine, which is inherent to the very high pyrometallurgical temperatures. Therefore, this work focuses on some aspects related to determining electrical conductivities, viscosities and surface tensions of slags via a combined experimental-modelling method. Besides experimental work, molecular dynamics (MD) simulations can be used to investigate oxidic slag physical properties. With MD simulations, one can follow the time evolution of a system (consisting of atoms or molecules) by integrating Newton’s equation of motion. The input for an MD simulation mainly consists of a force field as well as initial positions, velocities and mass of each atom. The determination of the transport properties in existing literature of MD simulations in oxidic systems, is typically based on incorrect assumptions. For example, to determine the ionic conductivity, the frequently-used Einstein-Stokes equation fails to take into account all ionic types and neglects correlated motion. Furthermore, the viscosity determination via the Einstein-Stokes formula also assumes independent motion of the different ions. This paper gives a brief overview of the opportunities and challenges related to the use of MD simulations for oxidic slag systems.

Jun 19, 2024

By García B., Wolff E.

In Colombia, northeast of Antioquia, there is a gold deposit that has produced continuously since the middle of the XIX century, located within mining title RPP-140, property of Gran Colombia Gold Segovia (GCGS) since 2010. Mining materials are taken to the “María Dama” Processing Plant where 1500 tonnes of materials are processed daily. Before 2010, the previous owner of the mining title processed about 600 tpd and directly discharged almost all tailings, given that they had no capacity to put them into final deposits. El Chocho was conceived as a final tailings deposit to store the pulp produced by the processing plant; it was divided into two phases with two dams (upper dam and lower dam) given that the presence of illegal miners at the lower phase impeded a single dam design. A squatter impeded construction of the upper dam; so afterwards, starting at the higher end was necessary (owned by GCGS), building dam 1B to store tailings in pulp; after the squatter returned the lands to the owner (GCGS), construction of tailings dam 1A was required and thus complete construction of dam 1C or the upper dam. While all of this was happening, GCGS decided to acquire a 1500 tpd filter press which currently dehydrates tailings in order to take them to the valley controlled by dam 1A. Construction of dam 1A was designed following the containment wall model, made with geotextile tubes. These improvements generated reduced pressure on renewable natural resources because water is recirculated and less fresh water contributions are required; less pressure is placed on soil, flora and fauna because the area intervened for tailings storage will have a higher storage capacity and, as such, a longer useful life.

Jun 17, 2024

By M. Z. Emad, A. Khan, N. Abbas, K. G. Li

Probability-based empirical methods were employed as an alternative approach to predicting uncertainties associated with rock mass properties. The focus was on developing probabilistic spreadsheets to forecast rock mass classification indexes. Histograms were constructed to describe the best distribution in predicting rock mass properties. The developed models also offer utility in predicting the impact of discontinuities within the rock mass on rock strength and rock mass classification systems. Statistical analyses identified volumetric joint count, joint spacing, joint frequency, and rock strength as the most influential parameters. Moreover, the statistical analysis revealed varying degrees of correlation among different rock mass properties. While some properties demonstrated significant correlations suitable for modelling, others did not align well with any correlation model. The results highlight the need for a comprehensive approach to rock mass characterization, considering multiple factors beyond volumetric joint count. Geological complexities, including tectonic activity and weathering processes, may obscure direct correlations. These results emphasize the importance of empirical modelling and detailed site investigations for accurate assessment of rock mass quality and stability in the Himalaya.

Jun 10, 2024

By J. van Zyl, K. B. Le Bron, L. J. Gardner

Pillar design is a crucial aspect of underground mining engineering, as it directly impacts the safety, stability, and overall effectiveness of mining operations. In this paper we present a method to calculate pillar stability based on the strain criterion and pillar load inversion concept, which complements the empirical pillar strength formulae. Those formulae do not account for certain parameters that can affect the stability of the pillars, e.g. weak layers, changes in stress orientations due to mining, orebody dip, mining layout complexity, and the influence of regional stabilizing pillars. The approach presented here is not intended to replace the empirical method; rather, we suggest using it as the initial step in the pillar design process. This should be followed by iterative numerical modelling to study pillar behaviour, define pillar stability, and optimize the pillar design by considering site-specific and representative rock mass properties and criteria.

Jun 10, 2024

By W. W. de Graaf, M. J. Ntsekhe

Klipspruit Colliery is experiencing coal losses, which leads to a negative impact on coal production and subsequently loss in revenue. This study aimed to identify the possible causes of coal losses in the No. 4 upper and lower seams. The objectives were to identify potential sources of coal losses through a literature survey, to identify areas where the coal losses occurred, to determine factors affecting coal losses, and to identify the most cost-effective methods to reduce coal losses. Highwall losses, top-of-coal losses, and coal edge losses were identified as the major areas of coal loss at Klipspruit. These losses were mostly attributed to the drilling and blasting practises of the pre-split, interburden waste, and the coal seams. Recommendations include re-visiting the current pre-split design and the tolerances adopted for the interburden and coal seam drilling and blasting design. It is furthermore recommended that Klipspruit implement a continuous improvement plan for the drilling and blasting and refresher training for the blasting crew and operators.

Jun 10, 2024

By R. G. Diale, H. R. Chauke, T. M. Ledwaba, P. E. Ngoepe

FeCo alloys play an important role in soft magnetic materials with a wide range of technological applications due to their high saturation magnetization and Curie temperature. However, these alloys have low ductility at room temperature. The ductility can be improved by the ternary addition of elements such as V. A density functional theory supercell approach was used to generate B2 Fe50Co50-xVx (0 ≤ x ≤ 50) structures and the properties were evaluated at different atomic percentage compositions to determine the ductility at room temperature. The structures were fully optimized to obtain better equilibrium ground-state properties such as lattice parameters and thermodynamic properties for both binary and ternary systems. The stability of Fe50Co50- xVx was evaluated from the heats of formation, elastic properties, and phonon dispersion curves. Furthermore, magnetic strength was evaluated from magnetic moments. It was found that all structures are thermodynamically stable due to the negative heats of formation. The calculated Pugh’s ratio and Poisson’s ratio confirm that alloying with V effectively improved the ductility. It was also found that Fe50Co50-xVx showed a positive shear modulus for the entire concentration range investigated, in agreement with phonon dispersion curves. The ternary addition of V to the FeCo system resulted in reduced magnetic strength due to a decrease in magnetic moments. These findings reveal that B2 FeCo-V alloys can be used as components and actuators for the automotive industry.

Jun 10, 2024

By M. Grozdanovic, D. Marjanovic, M. Ilic

We present a framework for solving the problem of functional compatibility between process control equipment in control centres at underground mines and operator capabilities. The equipment incorporates displays of current ventilation, gas, and fire hazard data, status of alarm and early warning systems, a voice communication subsystem, and facilities for recording and printing ofdata and reports. The layout of the existing control panel is compared with a recommended design. The basic principles of ergonomic design and arrangement of the controls and indicators, as well as ease of use, type of operations carried out with these controls, and operators’ viewing angles are discussed. The objective is to improve the usability of control panels, display boards, and graphic screens so as to enhance the functioning of control centres and optimize control of technological processes in coal mines.

Jun 10, 2024

By S. Moolla, R. Lynch, S. Brijraj

A reliable method to locate microseismic evets is an important objective for routine mine seismic monitoring. We developed an algorithm that can automatically and reliably locate an event from a single uniaxial trace. Signals created by microseismic events are recorded as seismograms that consist of direct P- and S-waves as well as the waves reflected off the underground excavations. We take advantage of the extra complexity these reflections introduce as they make the signal more unique. In our investigation we cross-correlated unaltered synthetic seismograms against trial waveforms created from a linear combination of appropriate waveforms from a library of numerically calculated strain Green’s tensors. We use a single uniaxial synthetic seismogram to invert for the source location, six moment tensor components, and frequency. The resulting cost functions are constructed as maximal correlations at each node in the mine grid through the true source x-planes. This function is maximized by differential evolution to simultaneously yield the source parameters. Sensitivity tests such as shifting the mine plans and altering the background velocities of the media are investigated to test the robustness of the method. We contaminate the data with 40% white noise to test the resolution against simulated real recorded seismograms. The method is demonstrated using synthetic data calculated with a realistic underground 3D velocity model.

Jun 10, 2024

By Prashant Dixit, Akhil Singh, Asim Kumar Mukherjee, Sudipta Patra, Veerendra Singh

Phosphorous is an undesired element present in iron ore used in the steel making process. It leads to an increase in overall production cost as well as deteriorated steel quality. The desired phosphorus content in iron ores used in steel making is < 0.1%. Numerous beneficiation studies are mentioned in the literature; however, there is no commercial scale technology established to beneficiate high phosphorous iron. The major phosphorous bearing minerals are apatite (Ca5(PO4)(Cl/F/OH), wavellite (Al3(PO4)2(OH)3·5(H2O)), senegalite (Al2(PO4)(OH)3(H2O), barrandite ((Fe,Al)PO4·2H2O), etc. Ultrafine grinding is required to liberate phosphorous minerals from iron ore minerals and subsequently subject it to flotation, acid leaching, and bioprocessing. The selective flotation of iron ore could successfully reduce the phosphorous content from 0.82% to < 0.20% with the combination of grinding, magnetic separation, and carbothermic reduction. Acid leaching processes are also able to remove ~80% (0.85%→0.16%) of phosphorus; however, these are relatively costly and complex processes. The mechanism of bio-extraction for phosphorous removal is reported as one of the most successful processes. This process is capable of removing more than 80% of the total phosphorous and significantly reducing the phosphorous content from 1.06% to 0.16%. The main disadvantage of this process is that it occurs at a much slower pace. In today’s scenario, ultrafine grinding followed by froth flotation seems to be the most feasible solution for the beneficiation of high phosphorous iron ore in which the concentrate obtained can be utilized for pellet making and ultimately used for steel making processes. Development of additives for leaching, roasting, and bioprocessing can be explored further to make these processes more effective and economically viable.

May 28, 2024

By Chenxi Ding, Chenglong Xiao, Guoli Shi, Zhiwei Zhao

This study investigates the directional blasting of a 90° slit charge structure using laboratory experiments and field tests. A 90° slit charge suitable for the corner of roadway is proposed. After the slit charge blasting, two long main cracks along the slit, and several short secondary cracks in other directions. The slit charge not only significantly reduces damage to the surrounding rock, but also improves the quality of the roadway contour. In addition, a comprehensive damage evaluation system of the roadway contour and the surrounding rock is constructed using digital image analysis, borehole televiewer, and CT scanning.

May 23, 2024

By Giovanni Rubinich Moraes, Giorgio de Tomi, Irfan Ullah

The study examines productive and unproductive hours in four underground mine shifts: 6 h, 8 h, 10 h, and 12 h. Moreover, two sub-scenarios of single or two blasts examined the effect on mine utilization regarding effective working hours in underground mines. Cuiabá Mine data, the Brazilian’s largest and deepest underground gold mine, was used in both sub-scenarios. Under the first sub-scenario, which assumes two blasts per day, the 6-h shift had an effective work time (EWT) of 13 h and 30 min or 56.3% of the day. The EWT was 15 h and 20 min, 63.9% of the day, in the 8-h shift scenario. The 15-h, 30-min EWT took 64.6% of the day in both 10/12-h shifts. The 6-h scenario had an EWT of 16 h and 15 min (67.7%) in the second sub-scenario with a single blast daily. The 8-h scenario boosted EWT to 18 h and 25 min (76.7%) daily. An EWT of 18 h and 35 min daily (77.4%) was found in 10/12-h shifts. Comparisons of both sub-scenarios show that EWT positively correlates with shift length. Sub-scenario 1 has a 7.6% incremental step from 6 to 8 h, while sub-scenario 2 has 9%. EWT increases from 8-h to 10/12-h shifts by 0.7% for single and two blasts daily. Compared to the two sub-scenarios, halting operations for blasting once daily improves the EWT average by 12.5%. Reducing blasting and changing underground mining shift duration might boost economic viability.

May 21, 2024

By Emily Sarver, August Greth, Cigdem Keles, Setareh Ghaychi Afrouz

The characterization of respirable dust on the basis of constituent fractions and particle sizes is increasingly of concern for evaluating exposure hazards. For high-resolution particle analysis, scanning electron microscopy with energy dispersive X-ray (SEM-EDX) can be an effective tool. However, it requires particles to be deposited on a smooth, uniform substrate such as a polycarbonate (PC) filter for optimal results. While direct sampling onto PC is possible, this is not the standard approach in many situations. For example, in coal mines, respirable dust samples have typically been collected onto polyvinyl chloride (PVC) filters because they are intended for gravimetric and/or infrared spectroscopy analysis. Such fibrous substrates are not ideal for SEM-EDX (or other microscopy), but an effective method to recover and redeposit the dust particles could render such samples suitable for the additional analysis. Here, we present a simple method and compare SEM-EDX results for paired samples analyzed directly on PC and following recovery from PVC and redeposition on PC. Both laboratorygenerated dust samples (n = 10 pairs) and field samples of respirable coal mine dust (n = 44 pairs) are included in this study. Although some changes in particle size distributions were observed between samples analyzed directly and those that were recovered and redeposited prior to analysis, the results indicate the dust recovery method generally yields a representative sample in terms of mineral constituents. That said, results also highlighted the effects of high particle loading density on individual particle analysis. Considering all sample pairs, those with similar loading density between the directly analyzed and recovered sample tended to exhibit similar mineralogy distributions. This was generally the case for the lab-generated sample pairs, and the Freeman-Halton exact test of independence indicated that the samples in just three (of 10) pairs were in disagreement in terms of their mineralogy distributions. On the other hand, for the field samples, the directly analyzed sample often had higher loading density than the recovered sample; and the Freeman-Halton test showed that 25 (of 44) pairs were in disagreement. However, the effect of possible particle agglomeration on the directly analyzed samples cannot be ruled out—and exploration of this factor was beyond the scope of the current study.

May 17, 2024

By Shankar Kumar, Arvind Kumar Mishra, Chitranjan Prasad Singh

Formulating a predictive model for blast-induced ground vibration (BIGV) has always been challenging due to the complex non-linear relationship between the BIGV and its influencing factors. Researchers have used empirical, artificial intelligence methods and numerical modelling methods to predict BIGV. In a dragline bench blasting, a massive quantity of explosives is used compared to other loading machinery, and the height of the bench depends on the size of the dragline. For effective utilization of explosives energy, decking is used to reduce the hazardous effects of blasting. In this paper, an attempt has been made for effective prediction of BIGV, and its mitigation on dragline bench blasting considering a deck length, stiffness ratio, hole spacing to burden ratio, hole depth to burden ratio, the distance of monitoring PPV from blasting site, Schmidt hammer rebound number of the bench to be blasted, and maximum charge per hole to total charge per blast. So artificial neural network (ANN) model and random forest (RF) model have been developed considering the parameters mentioned above. For the statistical performance of the predictive model, the coefficient of determination (R2) value is 0.8895, MSE is 22.84 for the ANN model, and the random forest (RF) model whose R2 is 0.8165 and MSE is 27.18. The sensitivity analysis results show that stiffness ratio, deck length, and Schmidt hammer rebound number are more influential parameters out of the selected parameters. The reduction of ground vibration with the introduction of decking led to a 3 to 15% reduction in ground vibration.

May 15, 2024

By C. Allen, H. Zhang, L. Falk

Shock loss occurs when there is a change in the area of a drift or airflow direction. These shock losses accumulate throughout the ventilation system and will increase the mine resistance as underground development deepens or becomes more complex. Hence, shock losses should be carefully considered when establishing the resistance through a series of branches as they can be a significant contributor to the estimated mine resistance. Using computer software to simulate a ventilation system is common but applying reasonable shock loss factors in the software is not a simple or direct process. Determining shock loss values includes the consideration of historical measurements, application of factors and formulas from literature based on the geometry and complexity of junctions, and the geometry variation at different locations. For example, the shock loss at the bottom of a ventilation raise can be comprised of a 90° bend and a sudden area change. This paper presents an approach for estimating shock loss factors near raise junctions using computational fluid dynamics. Current and future work will also be compared with field measurements. Results from this approach are compared with software defaults as well as classical techniques in published literature and standards.

May 14, 2024

By Taghi Sherizadeh, Samuel Nowak, Kutay Karadeniz, Paul Brooks, Alper Kirmaci, Mina Esmaeelpour, Dogukan Guner, Gunnar Wurst

As mines continue to deepen and become more expansive, active monitoring of larger volumes of rock mass will become more critical to calibrate numerical simulations and to ensure the safety of underground workers. Monitoring larger volumes of rock mass requires low-cost sensors which are simple in construction and installation. In this study, a novel hybrid optical fiber cable (HOFC) designed for use in distributed optical fiber sensing (DOFS) via grouted boreholes was employed to monitor a bulk mining operation in an underground metal mine. The HOFC was successfully used to monitor approximately 2.7 × 103 m3 of rock mass above excavations surrounding a pillar removal area in which six large pillars were removed simultaneously. A total of six measurement boreholes (maximum depth of 22 m) were used to measure strain along the optical fiber during the pillar removal operation using the HOFC, allowing for 70 individual strain measurement points, which were constructed for under one US dollar each. Monitoring of the excavation area took place over a 44-day period after pillar removal. Extensional strains were noted in the areas closest to the removed pillars, while areas of compression were noted directly above the remaining pillar in the area. The results of the case study demonstrate that a low-cost optical fiber strain sensing network can be rapidly installed in a large excavation area and can provide highly sensitive strain measurements in a manner that would be cost-prohibitive via other methods.

May 13, 2024