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By T. Wajima

"A novel carbonaceous immobilizing agent for heavy metal contaminated soil was prepared from rice straw using sulfur immersion and pyrolysis, and the lead immobilization in artificial contaminated soils using sulfur-impregnated carbonaceous material was estimated. The rice straws were cut to 1 cm pieces, and then immersed in 0.1 - 1 M K2S solution for 0 - 24 h to prepare sulfur-immersed materials. The immersed-materials were heated at 400 oC for 1 h in nitrogen gas to produce the sulfur-impregnated carbonaceous material by pyrolysis. The abilities of the product to immobilize lead from aqueous solution were examined to obtain the product with high lead immobilization ability. With increasing K2S concentration, the immobilization ability of the product for lead gradually increases and then above 0.5 M K2S those are almost constant, while 15 min is sufficient for the immersed time to obtain the product with high lead immobilization ability. The product prepared from material immersed in more than 0.5 M K2S solution for less than 15 min has a maximum immobilization ability for lead ion. The lead immobilization using the sulfur-impregnated product is sustainable due to the formation of leadhillite [Pb4SO4(CO3)2(OH)2] and anglesite [PbSO4]. The product can immobilize lead ion in various artificial lead contaminated soils. By mixing artificial lead contaminated soil with the sulfur-impregnated product, the eluted solution became neutral, and the eluted concentrations of lead ion dropped below the Japanese elution standard for soil.INTRODUCTION Soil contamination with heavy metals is a worldwide problem. Accumulation of heavy metals in soils affect soil ecology, agricultural productivity, quality of agricultural products, water resources, and serious health problems for human and animal (Raicevic, et al., 2005). In the United States, for example, approximately 63 % of the sites on the National Priority List (NPL) for the treatment of contaminated soils are contaminated by metals, and lead is the most common metal, found at 15 % of the sites. In Japan, according to a report by the Ministry of Environment, 43 % of the contaminated sites that exceed the environmental quality standards are contaminated by lead compounds. Soil contamination by lead compounds is also prevalent in other developed and developing countries where lead compounds are used extensively in industrial activities without careful contamination management. Lead is a ubiquitous heavy metal pollutant in soils due to their use widely. The primary sources of Pb contamination include industrial activities such as mining, smelting of metals, and the use of Pb-containing products such as paints, lead-acid batteries, bullets, gasoline and pesticides (Cao, et al., 2009). It can damage human nervous (especially children) and reproductive systems (ATSDR, 2007). The high concentration of Pb in the soil poses risks to human and animal health by the leaching of metals from the soil into water and the consumption of edible plants growth in the contaminated soil. Therefore, proper remediation is necessary to reduce metal availability in soil for protecting human health."

Jan 1, 2018

By S. Espley, T. Nyabeze, D. Beneteau

"Many mentorship programs are available to Canadian mining industry employees. Some are company-led initiatives, whereas others are provided through educational institutions or nonprofit organizations. In 2016, a national survey was launched to gain insight into perceptions of what mentorship is, learn about available programs, and collate experiences with formal and informal mentorship opportunities. This paper outlines survey findings and delivers recommendations to industry for consideration in employee mentorship programs. In addition, mining industry leaders share their mentor/mentee perspectives. The intent of this paper is to bring awareness of best practices that can help employees grow and develop in their profession.RÉSUMÉ Les employés de l’industrie minière canadienne ont accès à de nombreux programmes d’encadrement. Certains sont des initiatives menées par les sociétés, d’autres sont proposées par le biais d’établissements d’enseignement ou d’organismes à but non lucratif. En 2016, une enquête à l’échelle nationale a été lancée en vue d’obtenir des informations quant à la perception de ce qu’est réellement l’encadrement, de découvrir les programmes proposés et de comparer les expériences aux possibilités d’encadrement, officielles ou non. Cet article présente les résultats de cette enquête et fournit des recommandations à l’intention de l’industrie afin qu’elle les prenne en compte dans ses programmes d’encadrement des employés. En outre, des chefs de file de l’industrie minière partagent leurs points de vue conseillers/protégés. L’intention de cet article est de sensibiliser les employés aux meilleures pratiques, ce qui les aidera à évoluer et à se développer dans leur profession. INTRODUCTIONThis paper about mentorship in the mining industry is based on voluntary responses to a cold survey, written and circulated by the authors. In 2016, a link to an online mentorship survey was circulated to males and females in the mining industry with the belief that mentorship programs should be available to everyone. The link was delivered via the authors’ personal networks in mining, the CIM Reporter, Women in Mining (WIM) email blasts, LinkedIn, and Facebook. This paper summarizes the answers to the survey questions. The paper is a follow up to one by the same authors (Nyabeze, Espley, & Beneteau, 2010), which was written to gain insight into why women join and stay in the mining industry, and to learn why the overall representation of women is low."

Jan 1, 2018

By R. Holmestad, M. Gazizov, S. Wenner, R. Kaibyshev, J. K. Sunde

"Mechanical properties and microstructure of an Al-4.7Cu-0.74Mg-0.51Si-0.48Mn-0.10Cr-0.09Ti-0.02Fe (wt. %) alloy subjected to various thermomechanical processing (TMP) have been investigated and compared to conventional ageing at 170°C (designated T6). Three TMP routes involving cold deformation of solution treated samples were tested. These were (i) 3%-stretching (T8-3%), (ii) equal-channel angular pressing (ECAP) to true strain (e) of ~1 (T8-1) and (iii) ECAP to e~2 (T8-2), all with subsequent ageing at 170°C for 0-96 h. At peak age conditions, both yield stress, ultimate tensile strength and elongation-to-fracture decreased for the T8-3% state as compared to the T6 condition. Intermediate ECAP (T8-1 and T8-2) lead to significant increase in maximum yield stress, ultimate tensile strength and elongation-to-fracture. The changes in mechanical properties were related to microstructure evolution, encompassing changes in grain sizes, dislocation densities, precipitate morphology and phase fractions, which were characterised using transmission electron microscopy. Relations between TMP, precipitation behavior and contributions to different strengthening mechanisms are evaluated.INTRODUCTION Al-Cu-Mg-Si alloys are widely used as structural materials in aerospace industry due to their attractive combination of high specific strength, good fracture toughness and enhanced creep resistance. These properties are largely due to the formation of a large number of nano-sized metastable precipitates during artificial ageing (Polmear, 2006; Eskin, 2003; Gazizov, Dubina, Zhemchuzhnikova, & Kaibyshev, 2015). The precipitation behaviour in these alloys is complicated and depends among other things on Cu concentration and the Mg:Si ratio (Wolverton, 2001; Chakrabarti, & Laughlin, 2004). In general, the precipitation sequence has been presented in a prior study (Eskin, 2003) as follows:"

Jan 1, 2018

By E. Barnard, J. Tero, J. Rajala, N. Avenido, M. Fullam, A. Nashitati, S. Mbalamba

"The Otjikoto mining and milling complex is 90% owned by B2Gold Corporation, and began commercial operation on February 28, 2015. The milling circuit operates at a throughput 3.3 million tonnes per annum, with an average reserve gold grade of 1.28 g/t. The ore is high in Gravity Recoverable Gold (GRG), which varies between 73-91%, depending on ore type. Overall gold recovery since start-up is 98.2%, with about 63.5 % coming from the gravity circuit as doré. 2016 cash operating costs, and all in sustaining cost (“AISC”) were $361 and $604 per ounce, respectively.During design, three ore types were tested for GRG content, and based on the high GRG value of all three ore types, the decision was made to treat the full ball mill circulating load by gravity. Once operating, the gravity circuit performance was characterized by performing a detailed gravity audit, which included the ore, cyclone classification, Knelson concentrators, and the Consep Acacia intensive leach system. The deeper ores contain significant pyrrhotite, and this created some unusual challenges that had to be overcome. This paper presents the gravity circuit design process, the circuit commissioning, and the audit results and ongoing improvements.IntroductionHeadquartered in Vancouver, Canada, B2Gold Corp. was founded in 2007. Currently, B2Gold has five operating mines, and numerous exploration projects in various countries, including Nicaragua, the Philippines, Namibia, Mali and Burkina Faso. The Otjikoto Mine is located in the north-central part of the Republic of Namibia. It is situated approximately 300 kilometers north of Windhoek, the country’s capital, within the Province of Otjozondjupa. The Otjikoto mining and milling complex is 90% owned by B2Gold Corporation, and began commercial operation on February 28, 2015. The milling circuit operates at a throughput 3.3 million tonnes per annum. During design, a large emphasis was placed on gravity recovery, as the Otjikoto ores are unusually high in Gravity Recoverable Gold (GRG)."

Jan 1, 2018

By E. Emelyanenko, P. Solozhenkin, J. Yagudina, O. Ibragimova

To recover tetrahedrite-tennantite series minerals from porphyry copper-pyrite ores by the froth flotation method, further research on thiol collectors is launched to promote the utilization efficiency of copper ores. In the present paper the adsorption mechanism of the collectors on tennantite surface has been investigated by computational modeling and FTIR-spectroscopic analysis, which have revealed that the decrease in prognosis of collector activity evaluation (PCAE) for tennantite is in the following order: BX (-0.34318), AEROPHINE 3418A (- 0.61756), AERO 5100 (-14.18857). The lower PCAE the stronger the ability of the collector to interact with the mineral surface of tennantite and form the stable complex. More kinetic reliable conditions to form suitable adsorption layer and rupture of the liquid interlayer with AERO 5100 have been observed by FTIR spectra due to decrease of the intensity and stretching and bending vibrations of water (less than 20 and 65%, respectively). In order to verify the feasibility of AERO 5100 as a collector the industrial flotation tests have been conducted. Flotation performance has improved significantly with the stadially grinding and preflotation of tennantite in intercycle copper flotation that allows to avoid desliming of the fragile mineral and minimize loss of Cu and As in tailings. The recovery of copper in copper concentrate increases by 3.9% with the grade maintained.

Jan 1, 2018

By Wei Sun, Ruolin Wang, Jianjun Wang, Xiaodong Li, Honghu Tang, Yuehua Hu, Anh V. Nguyen, Haisheng Han, Kefeng Chen, Zhao Wei

It is difficult to separate scheelite especially from fluorite with fatty acid collectors because the adsorption mechanism of these collectors occurs through chemisorption of the oleate ion onto the mineral surface. A simplified flotation process using Pb-BHA complexes was developed to replace the energy-inefficient Petrov’s process of using a fatty acid, increasing the recovery of scheelite and reducing the cost. The relationship between surface chemical properties (crystal chemistry, solubility, and Zeta potential) of minerals and flotation by using a fatty acid or Pb-BHA complexes was studied in detail to provide new insights into the selective separation mechanism. The results indicate that the scheelite surface exposes more O atoms than Ca and that they are negatively charged due to the anisometric dissolution of Ca and WO4, which provides the possibility for separation using selective interfacial reaction. The FTIR and Zeta potential results indicate that both chemical and electrostatic adsorption play an important role in the adsorption of Pb-BHA complexes on the scheelite surface. The XPS results of the atomic composition and binding energies confirmed the presence of the adsorbed Pb-BHA complexes and that O and Ca may be the active adsorption sites. Therefore, scheelite was able to be collected by forming either a Ca-O-Pbcollector or W-O-Pb-collector (BHA). However, fluorite was only able to be collected by a fatty acid collector and colloidal [H2SiO3]n -, and a high temperature was needed improve the selective desorption of the adsorbed fatty acid collector by forming Ca-[H2SiO3]n - on the fluorite surface, resulting in serious problems in industry. However, the Pb-BHA complexes significantly contribute to improving the recovery of scheelite minerals, simplifying the flotation process, and circulation of the residual reagents and water. The new process has been applied in Shizhuyuan Mine, and improved the recovery by almost 10%.

Jan 1, 2018

By S. J. Schatzel, R. B. Krog, H. Dougherty

Longwall face ventilation is an important component of the overall coal mine ventilation system. Increased production rates due to higher-capacity mining equipment tend to also increase methane emission rates from the coal face, which must be diluted by the face ventilation. Increases in panel length, with some mines exceeding 6,100 m (20,000 ft), and panel width provide additional challenges to face ventilation designs. To assess the effectiveness of current face ventilation practices at a study site, a face monitoring study with continuous monitoring of methane concentrations and automated recording of longwall shearer activity was combined with a tracer gas test on a longwall face. The study was conducted at a U.S. longwall mine operating in a thick, bituminous coal seam and using a U-type, bleederless ventilation system. Multiple gob gas ventholes were located near the longwall face. These boreholes had some unusual design concepts, including a system of manifolds to modify borehole vacuum and flow and completion depths close to the horizon of the mined coalbed that enabled direct communication with the mine atmosphere. The mine operator also had the capacity to inject nitrogen into the longwall gob, which occurred during the monitoring study. The results show that emission rates on the longwall face showed a very limited increase in methane concentrations from headgate to tailgate despite the occurrence of methane delays during monitoring. Average face air velocities were 3.03 m/s (596 fpm) at shield 57 and 2.20 m/s (433 fpm) at shield 165. The time required for the sulfur hexafluoride (SF6 ) peak to occur at each monitoring location has been interpreted as being representative of the movement of the tracer slug. The rate of movement of the slug was much slower in reaching the first monitoring location at shield 57 compared with the other face locations. This lower rate of movement, compared with the main face ventilation, is thought to be the product of a flow path within and behind the shields that is moving in the general direction of the headgate to the tailgate. Barometric pressure variations were pronounced over the course of the study and varied on a diurnal basis.

Jan 1, 2018

By C. V. Deutsch, T. Acorn

Understanding and managing risk is of increasing concern for the mining industry. Although methods exist to model geologic uncertainty based on stochastic modeling techniques and multiple realizations, there are few approaches to manage this geologic uncertainty in pit optimization. Block values can be penalized if the block uncertainty is high, but the goal here is to consider the reserve risk within the pit. This paper presents an approach for pit optimization that considers all realizations simultaneously with a heuristic pit optimizer. The heuristic algorithm maximizes value and also penalizes reserve risk. The inclusion of multiple realizations provides access to the risk or uncertainty in the total pit value. Considering this information permits an active risk management approach that can manage the uncertainty in the reserves within the entire pit.

Jan 1, 2018

By L. O’Connor, E. Tarshizi

The objective of this work is to provide a detailed review and a list of references in chronological order, comprising 80 recent technical papers, on the use of discrete-event simulation (DES) modeling in mining engineering. In this article, the review papers of published mine simulation projects through 2007 are summarized, and then a comprehensive review of individual articles published from 2008 to 2015 is presented. This survey work also includes analyses of the simulation tools used in the published projects, mining types and applications in order to assess these key features and evaluate the recent state of research in mine DES simulation. In addition, an interactive map visualization for the locations of the simulated projects is made available on a website to benefit current and prospective scholars in the field. The results of this investigation revealed that the most common application of DES in mining had been mining equipment selection and analysis, while ore processing and risk management projects were less frequently reported. The results also showed that modeling surface mines were in the majority, but the trend of publications for underground mine simulations had also increased. According to the results, ARENA was the most popular simulation software package, but several simulation tools that were only used once or twice in the mining projects are also included in this review.

Jan 1, 2018

By S. McPhail, D. Richardson, G. J. Simandl, C. Akam, S. Paradis, M. Yakimoski, A. Teucher, Y. Cui, F. Ferri

Historically, extracting dissolved solids from formation water was economically motivated. Today, main drivers are environmental benefits and regulations, as large volumes of water needed for hydraulic fracturing require treatment before reuse or disposal. The concentration of dissolved solids in flowback water increases with each use and may require treatment prior to disposal. Element recovery from produced water is not profitable unless market conditions are favourable, recoverable elements are abundant, and economical recovery methods are established. Sale of recovered materials could offset recycling and disposal costs. This paper describes markets for Cl, Na, Ca, K, Sr, Mg, Br, Ba, I, B, and Li, and their concentrations in produced water from oil and gas wells in British Columbia. It recommends revising sampling protocol for produced water.

Jan 1, 2018

By M. E. Buzon, M. E. Gunter

Talc has been the focus of recent civil litigation based on claims that asbestos minerals exist in talc deposits and therefore have caused asbestos-related diseases in those who have regularly used talc products. Such litigation, and ensuing confusion over the petrology and asbestos content of these deposits, challenges the talc mining industry in Montana and elsewhere in the world. The talc deposits in southwest Montana were formed by hydrothermal alteration of dolomitic marbles and are still actively mined. In general, talc formed by hydrothermal alteration of preexisting carbonate rocks is known to be nearly monomineralic and lacking in amphiboles. This paper includes data from analyses of representative ore samples from this mining region in southwest Montana. The results conclude that the presence of asbestos minerals — both amphiboles and chrysotile — is unlikely and that the ores are nearly monomineralic, as expected. Samples were characterized using a suite of analytical methods, namely, powder X-ray diffraction, X-ray fluorescence spectroscopy and electron microprobe analyses, which allowed us to determine the minerals present and the formation process. Our data and interpretations suggest that previous identification of asbestos minerals in these deposits is not accurate.

Jan 1, 2018

By R. Heiser, J. Vendetti, B. P. Connor, E. J. Haas

Health and safety indicators help mine sites predict the likelihood of an event, advance initiatives to control risks, and track progress. Although useful to encourage individuals within the mining companies to work together to identify such indicators, executing risk assessments comes with challenges. Specifically, varying or inaccurate perceptions of risk, in addition to trust and buy-in of a risk management system, contribute to inconsistent levels of participation in risk programs. This paper focuses on one trona mine’s experience in the development and implementation of a field-level risk assessment program to help its organization understand and manage risk to an acceptable level. Through a transformational process of ongoing leadership development, support and communication, Solvay Green River fostered a culture grounded in risk assessment, safety interactions and hazard correction. The application of consistent risk assessment tools was critical to create a participatory workforce that not only talks about safety but actively identifies factors that contribute to hazards and potential incidents. In this paper, reflecting on the mine’s previous process of risk-assessment implementation provides examples of likely barriers that sites may encounter when trying to document and manage risks, as well as a variety of mini case examples that showcase how the organization worked through these barriers to facilitate the identification of leading indicators to ultimately reduce incidents.

Jan 1, 2018

By B. A. Slaker, T. Miller, M. M. Murphy

An underground limestone mine in eastern Ohio was experiencing significant floor heave and roof falls, attributed to high horizontal stresses. Areas of the mine showing floor heave were monitored with roof-to-floor extensometers and photogrammetry surveys to determine the rate and magnitude of heave. Extensometer data were recorded hourly at four locations across adjacent entries while photogrammetry surveys of the floor were performed at the same locations every two to five weeks. A final survey was performed using an I-Site 8200 laser scanner. Following instrumentation, floor heave up to 10.1 cm (4 in.) was measured by the extensometers, photogrammetric reconstructions and laser scanner over a six-month period. The extensometers were biased by the location where they were placed, failing to consistently capture the location and extent of floor heave and cracking. The photogrammetry surveys were not precise enough to capture small magnitude movements. Mining in the area was halted and within several months the floor movement and incidence of roof falls were significantly lessened.

Jan 1, 2018

By K. C. Kocsis

Underground ventilation systems, which require electricity to operate the fans and fossil fuel for heating in winter, can account for a significant portion of the energy consumption of mines. Recent studies have shown that the ventilation system in deep and highly mechanized metal mines could be responsible for 40 to 60 percent of their overall energy consumption. Presently, underground ventilation systems are designed for peak air volume requirements, which usually occur well into a future stage of the mines’ operating life. As a result, during their early operating stages, the intake air volume of the mines could be well in excess of their true air volume needs. Such ventilation systems could be considered as uneconomic, and to remain competitive the ventilation design needs to improve while the mines are trying to reduce energy consumption and their carbon footprints. This paper introduces a new mine ventilation design method where an underground base-metal mine’s ventilation system is designed by integrating discrete-event mining process simulation (DES) with mine ventilation modeling techniques. Furthermore, based upon the output data generated by means of discrete-event mining process simulations, the air volume requirement for the operating life of the mine is determined for “traditional” versus “activity-based” ventilation requirements. The output data generated through ventilation simulations are then used to quantify the economic and environmental benefits of an activity-based ventilation delivery system.

Jan 1, 2018

By D. R. Willmer

An understanding of how health and safety management systems (HSMS) reduce worksite injuries, illnesses and fatalities may be gained in studying the behaviors of health and safety leaders. These leaders bear the accountability for identifying, understanding and managing the risks of a mining operation. More importantly, they have to transfer this knowledge of perception, recognition and response to risks in the mining environment to their workers. The leaders’ efforts to build and maintain a mining operation’s workforce that consistently executes safe work practices may be captured through more than just lagging indicators of health and safety performance. This exploratory study interviewed six leaders in occupations such as site-level safety supervisors, mine superintendents and/or general managers at surface and underground stone, sand and gravel and metal/nonmetal mine sites throughout the United States, with employee populations ranging from 40 to 175. In exploring leaders’ perspectives on how they systematically manage health and safety, examples such as approaches to task training, handling near-miss incidents, identifying future leaders and providing workers with feedback offer insights into how leaders translate their knowledge and management of site-level risks to others.

Jan 1, 2018

By COLIN A. LAWRENCE, Anthony Del Vescovo

All Rights Reserved. Printed in the United States of America. Information contained in this work has been obtained by SME, Inc. from sources believed to be reliable. However, neither SME nor its authors guarantee the accuracy or completeness of any information published herein, and neither SME nor its authors shall be responsible for any errors, omissions, or damages arising out of use of this information. This work is published with the understanding that SME and its authors are supplying information but are not attempting to render engineering or other professional services. No part of this publication may be reproduced, stored in a retrieval system, or transmitted in any form or by any means, electronic, mechanical, photocopying, recording, or otherwise, without the prior written permission of the publisher. Any statement or views presented here are those of individual authors and are not necessarily those of the SME. The mention of trade names for commercial products does not imply the approval or endorsement of SME.

Dec 1, 2017

By Klaus-Peter Kinzel

Staves Coolers de cobre proporcionaram uma excelente proteção da carcaça do alto-forno em áreas de alta temperatura. Isso resultou para que os operadores de alto-forno alcançassem alto desempenho em termos de produtividade e taxa de combustível, além de campanhas de mais de 15 anos. No entanto, nos últimos anos, alguns altos-fornos experimentaram um desgaste prematuro nos staves de cobre. Algumas dessas empresas se alinharam com Paul Wurth para investigar a causa fundamental desse fenômeno com base em todos os fatores de influência e, em seguida, propor ações corretivas. Estes resultados são discutidos e apresentados a seguir no trabalho técnico.

Oct 30, 2017

By Alcy Dias Rodrigues

O Centro de Operações do Sistema Elétrico da Aperam South América possui um sistema de automação chamado SAE (Sistema de Automação de Energia) para realizar a distribuição e operacionalização da Energia Elétrica na planta em Timóteo, sistema este com mais de 20 anos de implantação. Devido ao alto grau de obsolescência do sistema SAE, a dificuldade de se atualizar todos os componentes do sistema e a complexidade e dificuldade do acesso aos dados, verificou-se a necessidade de encontrar uma forma de disponibilizar os mesmos para os demais sistemas da empresa. Com base nestas necessidades, foi desenvolvido e implantado um GATEWAY capaz de realizar a comunicação com todas UTR’s CORTEX (remotas do sistema), através do protocolo CONITEL 2020, disponibilizando estas informações coletadas em uma camada OPC SERVER para que o sistema PIMS (Sistema de Gerenciamento de Informação da Planta) realize a coleta e armazenamento destas informações, permitindo assim um melhor gerenciamento de energia pelo VIRIDIS (Sistema de Gestão da Eficiência Energética utilizado na APERAM), além de permitir que toda a planta tenha acesso em tempo real às informações de tensão e corrente de todo setor de 13,8 kV, 69 kV e 230 kV.

Oct 30, 2017

By Ryoma Fujiyoshi

In this article, the technologies of highly durable MgO-C bricks for the scrap impact zone and bottom blowing tuyere of converters are demonstrated. On the bases of our recent investigations, wear of scrap impact zone and bottom tuyere are explainable in terms of crack initiation and propagation. Theoretically, crack propagation in brittle material is regarded as generation of new crack surface area. It occurs when the elastic strain energy stored in the material exceeds the energy required to generate a new crack surface area. Since the overall energy consumed for crack propagation until fracture is evaluated by fracture energy, materials exhibiting high fracture energy can be regarded as materials with high fracture resistance. Therefore, two fracture energy-improving technologies for MgO-C bricks were developed. One is matrix reinforcement and the other is carbon bond enhancement. These technologies were applied to bricks for the scrap impact zone and bottom tuyere. As a result of commercial applications, notable decreases in wear rates were recognized for high fracture energy materials for the scrap impact zone and bottom blowing tuyere of converters.

Oct 30, 2017

By Elizaveta Cheremisina

In steelmaking process lime serves as flux. Rapid lime assimilation and slag formation of the desired composition have a significant effect on the refining reactions. It is important to know the rate limiting step of lime dissolution to control and improve the converter process. Kinetics of pure CaO and industrial lime dissolution in model slag has been studied in the range of temperatures 1300 –1600°C. Lime samples were prepared in cylinder form and immersed in the melt for predetermined time. Considering the total mass balance of CaO in the slag and linear dimensions of lime samples, mass transfer coefficients were derived. Diffusion coefficients were calculated under conditions of non-stationary diffusion. The derived activation energy of less than 200 kJ/mol indicates that diffusion is the limiting step in the process of lime-dissolution in slag.

Oct 30, 2017