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By Karsten Hagenah, Tor Jensen, Jens Laugesen, Øyvind Fjukmoen, Lucy Brooks

This paper discusses operational environmental threshold levels for exploitation of mineral resources in the deep sea. Such criteria are needed to be able to monitor and control deep sea mining with respect to the stringent environmental requirements that are needed. It is recommended to use existing environmental threshold levels for comparable underwater activities. Fields of application are mainly but not exclusively seabed mining operation activities under the governance of the International Seabed Authority (ISA). The threshold levels and limits mentioned in this paper are proposed recommendations based on other activities than seabed mining but are a proven and accepted approach in other maritime industry activities. An example of such other activities with proven and accepted environmental threshold levels are Oil & Gas exploitation activities in the sea. Background The first exploitation of mineral resources in international waters is coming closer. Presently regulations for exploitation for mineral resources in the Area are being developed by the International Seabed Authority (ISA). The ISA regulations will contain the framework related to environmental monitoring of exploitation. However, the regulations will not contain operational environmental threshold levels for the Contractor.

Jan 1, 2018

By Karen C. Armfield, Gisele R. Passalacqua, Joanna Smith

When selecting a solution for improving resiliency at facilities, such as airports, utility and transit sites, there are many options to protect structures and equipment against potential flooding. Each case involves an evaluation of the several key factors such as: design flood parameters, the geography and geological conditions below the site, the facility, and the layout of buildings and equipment to be protected. Upon reviewing these conditions and conducting a cost analysis of various options, the most suitable approach to protecting a facility can be determined. This paper will compare the conditions at various New York City sites, and give detail to the solutions utilized at these sites to improve resiliency and protect each facility. Flood wall types varied as did the strategies for raising critical equipment, to meet the Federal Emergency Management Agency (FEMA) and American Society of Civil Engineers (ASCE) 7 guidelines. Due to granular soil conditions, some sites may experience soil seepage below the flood wall resulting in the need for underground cut off systems. The authors will also present detail regarding the solutions used to control seepage. Various cut off systems will be discussed such as grouting and sheeting, explaining the factors that may impact the choice of systems. Another consideration in flood resiliency is the potential for a buoyancy condition on basement slabs when localized flood barriers are employed on first floor doors and windows. The authors will discuss the potential impacts of this condition on facilities and methods to mitigate this issue. 1. INTRODUCTION New York City is an urban coastal Metropolis with varied geology and low land areas. This includes but is not limited to sandy soils at Coney Island and the John F. Kennedy Airport. Soft marshes are found near Flushing Queens and LaGuardia Airport. Heavy rains and coastal storms caused disruption to daily life and heavily affected the economy of this vibrant City. For instance, in lower Manhattan business was interrupted in the Financial District. Power outage was widespread; commuter trains and subways were stopped and put out of service. Additionally, numerous residential homes were damaged in Coastal Neighborhoods such as the Far Rockaways and Staten Island. 1.1. Superstorm Sandy Flood Statistics On October 29, 2012 Superstorm Sandy impacted numerous facilities in the New York City Metro area. The resulting damage cost New York City more than $42 billion in repair costs. $33 billion was allocated to repair housing and infrastructure, and $9 billion was allocated to protect transit systems1. One of the major issues that impacted the city in terms of its preparedness was the high flood surge. The surge surpassed the former base flood elevation and reached as high as 13.88 feet (above mean lower low water - MLLW) in Battery Park at 9:24pm that evening. Tottenville, Staten Island experienced more damage where the water was recorded at +16 (North America Vertical Datum of 1988 - NAVD88), which is equivalent to 18.7 feet above MLLW (see Fig. 1). Not only was the surge at record levels, the waves in New York Harbor were also at record level where some buoy stations recorded waves of up to 32.5 feet. The City released “A Stronger, More Resilient New York” in June 2013, a plan laid out to rebuild communities impacted by Sandy and improve the resiliency of the infrastructure and buildings in New York City. Figures below help to illustrate the extent of the inundation relative to the projects being discussed.

Jan 1, 2018

By B. P. von der Heyden, P. Neethling, M. Tadieb, L. Babedi

The effects of trace element substitutions in sphalerite mineral structure on optimised floatation response have, as yet, not been fully constrained or fully understood. To further this important field of study, this contribution focusses specifically on mineral and surface chemistry, and electro-chemistry of Cd- and Co- substituted synthetic sphalerites using Raman spectroscopy and Zeta potential experimentation. Raman spectroscopy illustrates that the presence of these impurities results in the introduction of a new mode, the relative intensity of which can be correlated (Cd r2=0.95 and Co r2= 0.99) to the dopant concentration. Comparison to X-ray Diffraction results measuring the unit cell parameter further shows that this relative intensity (Cd r2=0.81 and Co r2= 0.99) may provide insights into the degree of lattice strain within the mineral structure. The zeta potential distribution of an un-activated Cd-sphalerite show no detrimental effect as function of Cd content. Although the iso-electric point shifted from 2.45 at 1 wt.% Cd to 2.69 at 3.68 wt.% Cd, the zeta potential remained negative at alkaline media. Conversely, cobalt at low concentration of 0.36 wt.% had a detrimental effect on the surface charge, resulting to a close to neutral zeta potential at different pH. The adsorption of Cu ions on the surface of Co-bearing sphalerite conditioned in an alkaline media slightly increases the zeta potential of Co-sphalerite. While the Cd-bearing sphalerite decrease in negative zeta potential at >1 wt.% Cd indicating a complete exchange between Cu and Zn. The results presented herein illustrate that, based on the chemical nature of the substituting metal; sphalerite will exhibit multiple response to flotation reagents. Maximum recovery of zinc can thus only be achieved through multidisciplinary study and fundamental understanding of the effects of cation substitution on mineral structure and surface chemistry, the latter necessarily affecting the floatation response.

Jan 1, 2018

By R. Schlüter

"The global mining industry is facing increasing challenges in terms of geological, technological and social aspects. Potential exploi-tation of deposits shows a tendency to increasing depth with complex ores and decreasing grades. A promising approach to deal with these constrains is by applying alternative extraction methods like (bio-)hydrometallurgy as in-situ leaching (ISL) technology. The Bergakademie Freiberg University of Mining and Technology established the “Biohydrometallurgical Center for strategic Elements” (BHMZ) to foster the interdisciplinary research along the entire biohy-drometallurgical process chain to extract indium from sulfide ores. The involved Department of Underground Mining Methods deals with the design and implementation of a pilot-scale underground testing facility for microbial in-situ stope leaching in its “Research and Educational Mine”. This paper discusses the potential of in-situ bioleaching under technological aspects. In addition, different conditioning approaches based on hydraulic and explosive methods for enhanced permeability in the formation are introduced and the gathered data will be presened. INTRODUCTION A reliable, substantial and sustainable supply of raw materials is of crucial importance for any industrialized country. This dependency applies to “strategic elements” including rare earth elements (REEs), platinum group metals (PGMs) as well as a variety of other metals like indium and germanium which are needed for high-tech industry and products such as electric and electronic devices, fibre optics and laser technology (Barakos et al., 2016; European Commission, 2010). Due to the economic growth of the BRIC-countries (Brazil, Russia, India, China), the resource policy of China as well as the volatile world mar-ket prices of different metals the availability of these critical raw materi-als and therefore the dependency of the high-tech producing countries has become increasingly important (Barakos et al, 2016). Adequate supply is often affected by the increasing depth of de-posits, lower metal concentrations and more complex ore mineralogy. In addition, mining activities are increasingly restricted by their envi-ronmental and social impact and footprints. As a consequence, con-ventional mining and processing methods are limited by high energy consumption and technical constraints."

Jan 1, 2018

By A. Rousselet, H. Gilbert-Tremblay, A. Berton

"Robex Resources interrupted production at the Nampala Mine in September 2014 following throughput and gold recovery results which were below expectations during the first months of operation. After a thorough plant audit, an important brainstorming took place in order to identify an economical path to resume production. It was clearly identified that a significant investment was necessary at the concentrator prior to restarting the plant, namely the addition of a ball mill and a new elution system.The mineral processing simulation software USIM PAC was used in order to simulate the grinding circuit in design. The simulations’ outputs allowed the ball mill characteristics and the surrounding classification devices to be designed with more accuracy. Many ball mills available from second hand retailers were therefore studied in the simulated circuit. The chosen ball mill, which was in perfect condition, had the advantage of being available for rapid delivery on site.The paper first describes the ball mill sizing method in comparison with the conventional Allis Chalmers method. It then describes the phase 2 concentrator start-up (that took place in 2016) with the commissioning of the ball mill, the classification circuit, the gravity concentration, the four (4) new carbon-in-leach (CIL) tanks, and the Zadra elution system (The phase 1 start-up took place in 2014). It finally provides production data compared to expected simulation data, as commercial production was reached in January 2017.IntroductionDesigning a new concentrator or new equipment within an existing concentrator requires significant efforts to identify possible bottlenecks and their causes (i.e. limiting equipment or sectors) and accurate sizing of major equipment can have a tremendous impact on the economy of the whole project. In the presented case study, the ball mill was the critical equipment and oversizing it could have brought the Capex to a level where the project would not have gone through. Inversely, undersizing the mill could have resulted in lower production and therefore no economic viability for the project once it is in operation.During engineering studies, equipment sizing often relies on a static mass balance and one-by-one sizing of all pieces of equipment. The sizing is then left to the equipment manufacturer or in the case of mills, evaluated with empirical models mostly relying on the Bond equations (Allis Chalmers method) [Rowland and Kjos, 1978]. This methodology shows the disadvantage of not considering interaction between equipment in a mineral processing circuit, especially when recirculation occurs. Also, it has the disadvantage of not using the more advanced grinding models that include the use of the whole particle size distribution as well as phenomenological components by only using limited parameters in the ore particle size distribution (i.e. the P80). This can be explained by the lack of data that sometimes needs to be gathered in order to tune the more advanced models but also by the conservative mindset in mineral concentration engineering which does not always favor the use of process simulation. In many aspects of process engineering, Soutex has demonstrated its affinity to using simulation in order to size equipment with more accuracy, consider process variability, simulate complex systems, and study supply chain management (Berton et al., 2015)."

Jan 1, 2018

By D. Purdie

"This paper aims to remind researchers, designers, operators, and managers about the benefits of seeding in the design of precipitation stages in their flowsheet. Including a high density solids (HDS™) process encourages the precipitating solids to form on the surface of existing precipitated particles. This paper discusses the application of the HDS technology at Kennecott Smelter, where the authors have witnessed significant improvements in settling and filtration rates. The authors have also applied this technology at various smelter bleed treatment plants worldwide with similar improvements in precipitation and filtration rates. HDS is a registered trademark of De Nora Water Technologies. RÉSUMÉ Cet article a pour objectif de rappeler aux chercheurs, aux concepteurs, aux exploitants et aux administrateurs les avantages de l’ensemencement dans la conception des étapes de précipitation de leur schéma de traitement. L’introduction d’un procédé des boues haute densité (procédé HDS™, de l’anglais high density sludge) encourage la formation de substances solides précipitantes à la surface des particules précipitées existantes. Cet article porte sur l’application de la technologie HDS à la fonderie Kennecott, où les auteurs ont observé des améliorations importantes au niveau de la vitesse de sédimentation et de filtration. Ils ont également appliqué cette technologie à diverses usines de traitement des rejets liquides des fonderies dans le monde entier, et ont constaté des améliorations similaires en termes de vitesse de précipitation et de filtration. Le procédé HDS est une marque de commerce déposée du fabricant De Nora Water Technologies.INTRODUCTION In 1966, the lead author worked as an assistant smelting metallurgist for the Tsumeb Corporation Limited copper and lead smelter in Tsumeb, Namibia. The smelter produced copper and lead, as well as cadmium and arsenic trioxide as byproducts. The cadmium was concentrated in the lead blast furnace off gas dust, and was collected by a baghouse. The baghouse dust was leached with dilute sulfuric acid (H2SO4) in a batch process. The iron and arsenic in the solution were oxidized with potassium permanganate (KMnO4) and basic ferric arsenate (BFAS; Fe(AsO4)x(SO4)y(OH)z·wH2O) was precipitated using milk of lime. The cadmium was cemented from the purified solution using zinc dust."

Jan 1, 2018

By S. I. Anufrieva, N. A. Permyakova, E. G. Likhnikeevich

"Russia’s rare metal reserves are composed of compositionally and structurally complex ores and are characterized by an increased content of natural radionuclides due to their geochemical similarity with rare metals. For instance, concentrates of Zashikhinsky daeposit are characterized by an increased content of uranium (0,06%) and thorium (0,59%); Beloziminsky deposit holds pyrochlore-apatite-magnetite-carbonate ores characterized by increased radioactivity (130 mkR/h) and containing 0,0016-0,0025% of uranium; Etykinsky deposit is characterized by columbite-pyrochlore-microlith mineralization with an average ore grade of 0,013% of uranium and 0,0020% of thorium; eudialyte concentrate of Lovozero deposit (Alluaiv area) belongs to Class II of mineral reserves. Industrial development of these mineral reserves involves the need to comply with environmental standards, public health requirements applicable to finished core and by-products, to take into account the amount and class of the generated radioactive waste, the possibility of disposal or recycling of the radioactive production waste. Concentration processes of radioactive rare metal feeds most often lead to a concentration of natural radionuclides and their accumulation in concentrates. Comprehensive hydrometallurgical processes are currently under development for such concentrates, aimed at producing salable products compliant with the radiation safety standards. The choice of the hydrometallurgical processing method for radioactive rare metal concentrates is based on the mineralogical component of the concentrate, textural and structural features, the distribution of valuable components and impurities, and the content of radionuclides. A systemic approach to the selection of processing methods, in particular integrating several methods, is an effective solution. Methods may not only be combined, but also inextricably linked with each other. Hydrometallurgical processing methods include leaching by acidic and alkaline agents; sulfatization for selectively decomposing the minerals and moving the bulk of U and Th into solution; fluorine extraction process. Methods of precipitation and co-precipitation, extraction (by liquid and solid extractants), sorption, and ion exchange are used to decontaminate the solutions by removing thorium, mezathorium, uranium, and their radioactive decay products. Agents used in hydrometallurgical processing of radioactive rare metal ores include sulfuric, nitric, hydrochloric, hydrofluoric acid, alkali (NaOH, KOH), sorbents (for example, AB-17) for sorption of uranium and extractants (mono- and bidentate organophosphorus compounds, diamides, etc.) for the extraction separation of rare, rare-earth, and radioactive elements."

Jan 1, 2018

By Masaomi Kurihara, Seiya Kawano, Norihiro Yamaji, Satoshi Shiokawa, Nobuyuki Okamoto, Hironobu Sakurai

Seafloor polymetallic sulphides are distributed in the EEZ of Japan, including substantial deposits in the Okinawa Trough and Izu-Bonin back-arc basin. In this new frontier, the successful development of these resources in Japan is expected to bring about a new domestic supply of mineral resources. The initial stages of this development are authorized by the Basic Plan on Ocean Policy, approved by the Japanese Cabinet on April 26, 2013, and the Plan for the Development of Marine Energy and Mineral Resources, formulated by the Ministry of Economy, Trade and Industry (METI) on December 24, 2013. In 2008, the Japan Oil, Gas and Metals National Corporation (JOGMEC), commissioned by METI, began a survey and technological development programme for the development of the seafloor polymetallc sulphides (PMS) based on these Plans. The examination of four different fields: the evaluation of the amount of the resource, environmental assessment, mining technology, and processing & smelting technology, are concurrently promoted, aiming for commercialization as soon as possible. Based on the results of research for properties of geomorphology and marine environments of the target test sites in the Okinawa trough, which have been ongoing for several years, the preparation of the pilot lifting test included an in-situ excavation and crushing test conducted using test excavating and crushing systems.

Jan 1, 2018

By A. Lewis

"Thiol collectors including the xanthates and dithiophosphates have dominated the sulfide mineral processing industry for over a century. Tecflote represents completely different chemistry, without sulfur or phosphorus, and will float all sulfides and associated precious metals. As these collectors are surfactant in nature, they comprise a head group which binds to mineral surfaces, a spacer and a long hydrophobic tail. The modification of the spacer behind the head group allows for collector optimisation for different sulfide ore types and process conditions.The Tecflote surfactants have been designed to be either very selective against pyrite at the natural pH of the ore (pH 7-9) or to float all sulfides including pyrite. Depending on the ore type and the process flow sheet, the use of lime can be maintained, reduced or completely eliminated.Tecflote can be used either as a rougher collector giving good recovery and grade for the sulfide minerals or it can be used to target valuable minerals after regrind and through cleaner flotation. It has repeatedly shown to be very effective at holding onto gold through the cleaner steps. The low solubility has a significant impact on the mechanism and surface activity of the collector, resulting in a very different flotation response compared to conventional thiol collectors.INTRODUCTIONXanthate was first made in 1882 by Zeise and first used in flotation in 1924 (Keller, 2018). In 1946 Keller patented thionocarbamate as a collector, which was produced by Dow Chemicals (Keller, 2018). Later it was replaced by Dow product Z-200, while dialkylthionocarbamate was discovered by Harris et al. (Harris, 1954. No significant chemistry change to collectors has occurred since they were introduced in the mid-20th century and now that the feed grades have been declining over the last decades creating a need to find more selective collectors to extract difficult and complex ores and pushing the industry to look at other reagents."

Jan 1, 2018

By M. Kosugi, M. Kawata, J. V. Satur, K. Mitsuhashi, R. Kawarabuki, W. Kracht, Y. Ebisu

Copper concentration is becoming more difficult because remaining copper ores are more complex and of finer copper mineral grain size, making copper minerals harder to float because of the fine particle size required to liberate the valuable species. The purpose of this work was to study the flotation behavior of fine copper sulfide ores at different conditions of agitation and aeration. The experimental campaign was carried out in a laboratory Denvertype flotation cell of 1 L volume modified to be operated with forced air that allows decoupling air flow rate and agitation speed. Four ore samples from Chile were used, all of them containing copper sulfides such as chalcopyrite, bornite, chalcocite, and tennantite, but with varying grain sizes and compositions. Preliminary flotation tests for establishing the flotation conditions of grinding size and collector dosage were conducted before the kinetic flotation tests that were carried out at different agitation speeds varying from 900 to 1300 rpm for gas flow rate ranging from 1.6 to 7.2 L/min. The flotation products were analyzed by ICP-MS and MLA (Mineral Liberation Analyzer). The results showed that high agitation speeds with corresponding air flow rates resulted in better recovery than moderate agitation speed and air flow rate, and an excess in gas flow rate resulted in bad performances. The flotation rates of the fine copper minerals were improved despite the different improvement rates among the fine size fractions. The impact of these operational variables, however, was different when comparing the results for the four ore samples. While it was found that the order of floatability in the four samples was the same, that is, chalcocite > tennantite > bornite > chalcopyrite, the kinetic constants of the copper minerals in the samples were different, indicating that mineral composition in the sample affects the flotation kinetics.

Jan 1, 2018

By K. V. Fedotov, G. I. Sarapulova

The study is devoted to the earth's surface protection and is aimed at improving the ecological safety of the territories in the mining industry. Identification of the diagnostic signs and quantitative criteria for the disturbance of soil geochemical properties and water chemistry represent an important scientific task in anthropogenically disturbed landscapes in the context of comprehensive exploitation of mineral resources. The study is aimed at geological and ecological analysis of the migration peculiarities of the man-caused chemicals and elements in soils and soil-surface water environment. We received new results. These results assist in estimating the peculiar features of distribution of heavy metals total and mobile forms (Cu, Ni, Zn, Pb), depending on the physical and chemical parameters of the disturbed soils. We obtained the empirical relationships describing heavy metals localization and accumulation processes depending on buffer properties of soils (pH, N, Corg), salinization factor and contamination with oil products. Anthropogenic geochemical barriers spontaneously formed in the area of industrial facilities were revealed in the territories of industrial facilities. These barriers prevent the further distribution of elements and pollutants in the landscapes. This makes it possible to create their artificial analogues in order to limit further migration of pollutants and to immobilize valuable components. Analysis of diagnostic features of soils geoecological state and factors influencing the distribution of heavy metals in the soil-surface water geosystem allows the identification of the geochemical barrier type with the aim of elements immobilization in a limited area of the territory. We applied modern physical and chemical methods of analysis, a package of statistics programs in Excel and modeling techniques. The proposed approach is innovative and therefore can be attractive. The accumulation of useful components losses in mineral resources exploitation is a promising reserve for their recovery from the soil with specifically arranged properties. The methodology of this research is also promising for the prediction of the environmental emergencies of the anthropogenic nature. This is consistent with the requirements of state control of environmental safety in the course of comprehensive exploitation of mineral resources.

Jan 1, 2018

By J. van Wijk

"Vertical material transport is one of the major challenges for the successful implementation of deep sea mining projects. The EU research project „Blue Mining” is focusing on sustainable solutions for deep sea mining operations, with one major goal being the advancement of Vertical Transport Systems (VTS). To investigate flow effects under realistic conditions, especially clogging effects, a 136 m high test facility for flow analysis in vertical transport has been constructed using available mining infrastructure. Tests are run in a closed circuit, using a system of downfall and riser pipelines connected to a compact sediment injection- and separation unit as well as the centrifugal pump. The riser is equipped with pressure sensors, as well as temperature sensors, flow meter, concentration meter and high speed camera to allow comprehensive analyses of the flow regime and behavior of transported material within the flow. Additional mobile measurement devices allow wear and tear analyses of pipe material. This paper focuses on the determining factors of the tests leading to the design as well as the installation and trial of the test facility itself and explains the used components and work principles. INTRODUCTION Since the 1970s several research projects had been conducted investigating in the possibility of deep sea mining. In recent times projects for deep sea mining operations have started again, considering the rising demand on natural resources, especially raw earth elements. Yet projects like the Nautilus project on the deposit Solwara 1 [1], or Japanese projects focusing on the region of Okinawa [2] and Chinese projects [3] planning on depths of “only” about 2,500 up to 3,000 m. Until now no economical deep sea mining project was realized, due to the enormous difficulties of deep sea environments. Vertical material transport is one of the major challenges for the successful implementation of deep sea mining projects, considering transportation heights up to 5 km. The EU research project „Blue Mining” is focusing on sustainable solutions for deep sea mining operations, with one major goal being the advancement of Vertical Transport Systems or VTS [4]. Critical parts of the system would be identified and investigated to deliver solutions and higher the technology readiness level to a level were planning of a pilot project can be considered. At first case examples for mining projects of seafloor massive sulfides (SMS, 1,600 m water depth) and manganese nodules (MnN, 5,000 m water depth) had been calculated on basis of economical frame conditions, such as planned production rates to be efficient. As depicted in Figure 1 two major possible systems had been used for comparison, airlift system and pump system, considering multiple pump stations or single pumps. Based on the results and comparisons for the calculated vertical transport systems critical components and flow effects had been identified."

Jan 1, 2018

By Mingxia Liu, Qi Liu, Tao Jiang

"In addition to physical parameters such as small mass and high specific surface area of fine and ultrafine minerals, chemical parameters such as the adsorption affinity of collectors on the minerals also plays an important role in fine particle flotation. In this study, we have examined collectors with two different ionized groups, carboxylate and hydroxamate, on the flotation of fine niobium oxide (pyrochlore). To facilitate comparison, two hydrocarbon radicals were tested: octyl and oleoyl, which led to four collectors that were studied: octyl hydroxamic acid (OHA), sodium octanoate (C8OONa), oleoyl hydroxamic acid (C18HA), and sodium oleate (NaOl). Small-scale flotation and isothermal microcalorimetric titration measurements were performed to determine the flotation recoveries of different sized pyrochlore and the enthalpic behavior after adsorption of the collectors on pyrochlore. It was found that the flotation performance of the carboxylate-based collectors was generally inferior to hydroxamate-based collectors. Sodium octanoate could not float pyrochlore irrespective of the particle size of the pyrochlore tested. With a longer hydrocarbon chain, sodium oleate was effective to float the relatively coarse pyrochlore (>20 µm) but its collection efficiency dropped sharply for particles smaller than 20 µm. On the other hand, the two hydroxamate-based collectors, octyl hydroxamic acid and oleoyl hydroxamic acid, showed good collecting ability to both the coarse and fine pyrochlore. The isothermal microcalorimetric titration studies indicated a consistent correlation of chain length with floatability of collectors for relatively coarse pyrochlore, as well as a positive relationship between the adsorption affinity and fine pyrochlore flotation recoveries. The key finding of this study was that efficient fine particle flotation could be achieved when strongly chemisorbing collectors were used.INTRODUCTION The first detailed study of the effect of particle size on flotation was made by Gaudin (1931) with sulphide ores. In 1942, Gaudin again demonstrated that (Gaudin et al., 1942) fine particles possess different flotation properties from larger particles. Since then the effect of particle size on froth flotation has been an important research topic by many researchers, e.g., Gaudin (1957), Miettinen et al. (2010), Warren (1976) Jameson (2010), summarizing the behavior of fine particles in terms of their low particle momentum, leading to low rate of collision with bubbles which reduces the chance of adhesion. The suggested remediation methods are mainly based on two approaches: increasing particle size or decreasing bubble size (Warren, 1976). Sand-fine splitting followed by separate flotation treatment of the sand and fines, using deep flotation cells, using starvation quantities of collectors, and using long flotation times, are also strategies to address the problems of fine particle flotation."

Jan 1, 2018

By Kenta Suzuki, Toshiya Anami, Daisuke Shimosaka

"In an Al-Mn alloy heat exchanger fin stock, the effect of annealing conditions for as-cast and 0.1%Zr addition on recrystallization behavior is investigated using metallurgical analysis. Refinement of post-brazed recrystallized grains in fin stocks with Zr addition are suppressed for long-time annealing. In 0.1%Zr fin stocks, there was a decrease in the number of fine a-Al(Mn,Fe)Si dispersoids for pinning of sub grain and grain boundary. In addition, relatively homogeneous distribution of Al3Zr dispersoids was observed with increasing annealing time in as-cast. Homogeneous distribution of Al3Zr dispersoids can have a major effect on pinning of sub grain and grain boundary during brazing heat treatment. The homogenous distribution of fine dispersoids prior to brazing heat treatment is effective in causing the suppression of refinement of post-brazed recrystallized grain structure in aluminum alloy fin stocks.INTRODUCTIONAl-Mn based alloys are widely used as fin stocks in automotive heat exchangers because of their superior mechanical properties, braze ability, sagging and so on. In particular, coarsening of recrystallized grain structure is beneficial to avoid erosion, and achieve excellent sagging resistance (Lee, Yoon, Kim & Jung, 2002). For resisting grain coarsening, the alloys should contain a dense and homogeneous distribution of fine dispersoids to retarder crystallization (Humphyreys& Hatherly, 2004). It has been demonstrated that addition of Zr to Al-Mn alloys can shift recrystallization to higher temperatures because of the distribution of fine Al3Zr dispersoids in matrix(Pokoba, Cieslar& Lacaze,2012). According to Tohma, Asanoand Takeuchi (1987), coarsely recrystallized grain structure was obtained in 3003alloy with Zr addition after heat treatment. However, fine Al3Zr dispersoids are usually heterogeneously distributed because of segregation during casting and low diffusion rate of Zr in aluminum. Therefore, a homogeneous distribution of Al3Zr dispersoids can be achieved through long-time precipitation annealing(Jia, Hu, Forbord& Solberg, 2008)."

Jan 1, 2018

By S. R. Clark

"INTRODUCTION Of all the natural resources being taxed by the needs of the modern world, perhaps the most important is the continually expanding demand for water resources. As water becomes scarcer, and increasingly important, new technologies are needed to find innovative ways to preserve this precious resource. In Chile, for example, the mining industry is investing billions of dollars to build desalination plants and pipelines; bringing ocean water as far as 200 kilometers inland to meet their demand and maintain operations. It is a full-blown crisis for that nation and a top priority for their government and economy. It has been reported that world water consumption will increase by 40 percent in the next 10 years, representing nearly exponential growth. In the U.S., as more and more communities continue to be built, more drain on the current water infrastructure is created. For 25 percent of people and operations that rely on water from aquifers, this source is being consumed at a rate that will create significant problems meeting the demand in as few as two generations.1 A PROACTIVE APPROACH When it comes to controlling dust at your operation, whether a landfill, a transfer station, a haul road or another ancillary area, what are the options? We know watering is not the answer, but at the same time, we need to prevent dust from flying to ensure a safe environment and keep our skies clear of pollution, for both regulatory requirements and neighbors. Creating a Dust Mitigation Program instead of looking to buy the first dust control product off the shelf is a first step to conserve water and, at the same time, maintain the operational demands and environmental standards for a given site. The program concept is straightforward enough. However, the process of effectively constructing and executing a program is quite involved. When undertaking a program, each manager needs to work with their team and their partners/vendors in analyzing the following elements: 1. Site Expectations—It is important to understand how to balance your internal standards with your regulatory requirements, as well as how to keep your neighbors satisfied. 2. Site Aggregate—Variations in native soil, such as clay content or gravel levels, greatly affect the approach that will yield the highest results. 3. Climate—Relative humidity and seasonal variations are critical to achieving predictable results through product choice, application frequency and timing. 4. Daily Traffic—The type and frequency of traffic is an essential variable for site management. 5. Environmental Responsibilities—If you have additional, specifically defined responsibilities, the approach to your site may vary. 6. Budget—While efficiency is the goal of any program, some sites will have more stringent restrictions than others. 7. Current Usage Rates—Document and understand where you’re starting from, both with water, supporting products, and maintenance so that effective measurement of results is possible."

Jan 1, 2018

By Y. Foucaud, C. Eswaraiah, L. Filippov

Enhanced gravity separators such as Falcon concentrator which uses additional centrifugal force, are the most common gravity concentration techniques used for fine particles processing. Hence, understanding the kinetics and separation mechanisms within these separators is of paramount interest. Recent research yielded a predictive physical model for the Falcon Ultra Fine (UF) which however does not explain some results obtained with industrial ores. This study aims to identify the mechanisms involved in Falcon UF separation with the objective of confirming or rejecting the hypotheses on which the current model is built and suggesting potential points of improvement. The Falcon UF kinetics is investigated through the processing of complex low-grade and fine-grained ores from the Altenberg tin deposit (Germany), the Tabuaço tungsten deposit (Portugal) as well as a synthetic iron ore. Saturation tests are performed on the Falcon UF by controlling the separation efficiency in terms of recovery and enrichment ratio with time or feed mass. Results show an evolution of Falcon UF performance with time in contradiction with the stationary separation hypothesis on which the physical model is based. Observation of the concentrate bed suggests the presence of erosion figures in furrows which may play locally an active role in the separation. In terms of Falcon UF separation timing, three phases can be distinguished. First, upon initial feeding of the bowl, a bed quickly grows unselectively and ultra-fine particles are ejected from the bowl until the bed reaches its final profile. Next, actual separation occurs with selective concentration of dense particles. Finally, capture sites saturate and recovery drops. The evolution of partition curves over time confirms the existence of two separation mechanisms. First, differential particles settling within the flowing film responsible for the ejection of small size particles during the whole separation cycle which is already accounted for in the physical model. The second mechanism involved may be explained by the action of lift force, neglected in the physical model, which acts preferentially on coarse particles deposited at the surface of the bed resulting in coarser particles being rejected in the tailings. Hence, the addition of a lift force component to the existing model is suggested to account for this second separation mechanism.

Jan 1, 2018

By C. J. Simensen, R. Østhus, H. J. Roven, K. G. Skorpen, H. Kalager

"This work encompasses co-extrusion of alloy Al4.5Mg at the core and rapidly solidified Al4.5Mg1Ag forming the surface layer. The goal is to produce a multi-material by co-extrusion having a relatively hard surface as compared to a softer core. At the same time, work hardening in both alloys is expected to be significant due to Mg in solid solution. Precipitation hardening at 160°C is studied by applying solution heat treatments at 560°C. The hardness increased from 80 to 130 VH in the surface material after 236 h. Surprisingly, the Al4.5Mg alloy also shows pronounced aging at this temperature, i.e. from 70 to 90 VH. The relatively high solution heat treatment temperature introduces grain growth in the core, but this is insignificant for the RS surface alloy. Blisters forms at the surface and cracks follows large portions of the interface. However, the tensile ductility is significant in all conditions due to very pronounced work hardening, i.e. for the as co-extruded, T6, under- and over-aged. The elongation at fracture ranges between 40–45% and the tensile strengths 240–275 MPa. The tensile properties increase linearly with the thickness of the RS alloy, i.e. following the rule of mixtures.INTRODUCTION Al-Mg alloys in 5xxx-series are classified as non-heat treatable wrought alloys (Polmear, StJohn, Nie, & Ma, 2017). The formation of the binary ß-Al8Mg5 does not give a substantial increase in the strength of the alloys (Mondolfo, 1976). When a third element like Ag, Cu or Zn are added, G.P.?zones are formed at low temperatures and intermediate, partial coherent phases are nucleated somewhat higher temperatures and finally a ternary, equilibrium phase is formed (Auld, 1968; Cousland & Tate, 1986; Mondolfo, 1976). Both the formation of G.P.?zones and intermediate phases increase the hardness and strength of the materials. An intermediate, hexagonal T´?phase is formed in Al-5 wt%Mg-1wt%Ag, and finally the equilibrium, cubic phase (Al,Ag)9Mg5 is nucleated (Cousland & Tate, 1986; Mondolfo, 1976)."

Jan 1, 2018

By A. Plugatyr, C. P. Baxter

"Bessemer matte iron content is a critical process parameter that needs to be closely monitored and controlled in order to achieve optimal Ni/Cu smelter returns. Current process control practices during Ni/Cu converting often rely on visual observations and typically involve matte sampling to confirm that target composition was reached. A high-level techno-economic analysis study was carried out to evaluate potential direct benefits of advanced process control during the final stages of Ni/Cu matte converting. The results indicate that the magnitude of direct benefits will largely depend on matte iron control practices already implemented as well as matte iron set point. Preliminary assessment suggests that under the assumptions used in this study, implementation of advanced process control can potentially result in additional revenues ranging from several hundreds of thousands to tens of millions of US dollars per year per converter producing about 200 tonnes of Bessemer matte per day based on Ni, Cu, and Co metal recoveries alone.INTRODUCTION Real-time measurement of molten metal elemental composition, arguably, remains one of the key unresolved issues impeding full automation and real-time optimization of pyrometallurgical operations in different industrial areas, including non-ferrous metals and ferro-alloys. In particular, current process control practices during Ni/Cu matte converting often rely on visual observations and typically involve matte sampling in order to confirm target matte composition. In addition to being time consuming, this approach relies heavily on operator experience and diligence, and, therefore, requires continuous performance and quality control efforts. For instance, the need to improve quality of the Bessemer matte (BM) at the Copper Cliff smelter has prompted an impressive staff engagement and training campaign that was carried out by Vale’s team in the late 2000’s (Zanini, Wong, & Cooke, 2012). This training exercise was executed to address the compounded effect of several operational challenges, namely demand for higher throughputs, changes in the feed concentrate composition, increased feed variability, loss of process knowledge and expertise due to retirement, as well as lack of a comprehensive approach to improving the overall performance of the flowsheet rather than meeting production targets for intermediate products. Although the campaign was very successful and has resulted in significant improvements in the Bessemer matte quality, it has also highlighted the need to move away from “the-art-of-converting” and develop analytical tools that would enable real-time process monitoring."

Jan 1, 2018

By B. M. Eiter, J. Hrica, D. R. Willmer

"Mineworkers are routinely tasked with making critically important decisions about whether or not a hazard presents an imminent danger. Researchers from the National Institute for Occupational Safety and Health (NIOSH) collected formative data to investigate mine safety professional perspectives on workplace examinations, which revealed a potential gap in how mineworkers are assessing risk. During interviews, participants indicated having processes in place for what should be done once an imminent danger situation is identified. Critically, however, they report having no systematic methodology for mineworkers to use to determine if a hazard is considered imminent danger. While this is important for all imminent danger situations (e.g., failure to lockout/tagout), it is especially important for those situations that are not immediately recognizable as imminent danger. In this paper, we identify and describe, three distinct categories of imminent danger complexity and discuss potential steps that could lead to improved identification of imminent danger situations. Finally, we identify potential practices to incorporate into risk management efforts, including feedback, communication, and specialized training to increase awareness of imminent danger situations. INTRODUCTION In recent years, the metal and nonmetal (M/NM) mining sector, as categorized by MSHA, experienced an increase in the number of fatalities occurring at mine sites. From 2013 to 2015, 69 mineworkers were fatally injured; that is twice the number of fatalities that occurred in each of the previous two years (MSHA, 2015a). As a way to address this increase, the Mine Safety and Health Administration (MSHA) issued a program policy letter (P15-IV-01) suggesting that “miners would benefit from rigorous workplace examinations conducted by experienced and trained examiners (MSHA 2015b).” The goal of workplace examinations is to find hazards in the field and mitigate them before they cause injury or death to mineworkers. While it is important to identify all hazards in the workplace, it is critically important to identify those hazards that are considered imminent danger because they require an immediate response to avoid a severe or even fatal injury."

Jan 1, 2018

By A. Javadi

"Our recent studies revealed that the sulfide minerals in contact with water during grinding produced hydrogen peroxide (H2O2) where the amount of H2O2 production by the minerals found to be in the order of pyrite > chalcopyrite > sphalerite > galena. The H2O2 effect on the oxidation of pulp components and its influence on the concentrate grade and recovery in flotation have been studied and the results have been presented and discussed in this paper. Studies have also been carried out to build correlation between percentage of pyrite in the concentrate, grinding conditions and concentration of OH•/H2O2 in the pulp and as well of controlling the formation of these species through known chemical means for depressing the generation of the oxidant. Flotation tests using a complex sulfide ore with the same reagent scheme that is being used at Bama concentrator in Iran but with the addition i) Na2S reductant and ii) inorganic (EDTA) and organic (TETA) surface modifiers, during grinding stage have been performed to judge the beneficial or detrimental role of H2O2 on the selective flotation of sulfides. The results demonstrate that the selectivity of metal sulfides against pyrite increases with increasing generation of H2O2 in the pulp liquid.INTRODUCTIONOur recent studies have illustrated the formation of hydrogen peroxide (H2O2) by metal-sulphides during grinding in the presence and absence of oxygen (Javadi Nooshabadi & Hanumantha Rao, 2013a; Javadi Nooshabadi & Hanumantha Rao, 2013b; Javadi Nooshabadi & Hanumantha Rao, 2013c; Javadi Nooshabadi & Hanumantha Rao, 2014). In the absence of oxygen, it was found that pyrite surface is catalytically active and able to breakdown water molecules to form OH• free radical and thereby deriving oxygen in the formation of H2O2 from water molecules. The in-situ formation of H2O2 and its influence on sulphide flotation has not been addressed yet. The presence of strong H2O2 oxidant in the pulp liquid and its selective oxidation of pyrite would be beneficial in depressing pyrite flotation. Therefore, it is important to build correlation between percentage of pyrite in the concentrate, grinding conditions and concentration of OH•/H2O2 in the pulp as well as to study possible ways of flexibly controlling the formation of these species through known chemical means for depressing the generation of the oxidant."

Jan 1, 2018