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By Venkataramana Runkana, Pradip Gautham, Beena Rai, Sreedhar Reddy

"IT enabled platforms are the key to provide an integrated view of the business activity or an enterprise as a whole. Attempts to integrate all functions in an enterprise such as mine-to-market initiatives, wherever and to whatever extent implemented, have provided significant benefits to the industry. The transformative potential of IT enabled integration platforms is illustrated in this communication from our own work in this field. TCS PREMAP (Platform for the Realization of Materials and Products) is a knowledge-driven engineering design and development platform which leverages modeling and simulation and artificial intelligence into the engineering design process. We illustrate the customization of this generic platform for the design and optimization of mineral processing plants in an integrated manner. TCS PEACOCK (Process and Equipment Analytics for Optimization and Control) has been developed to enable automation of data analytics in the operating plants. We illustrate its utility and power in improving the plant performance with the help of case studies from our work on pelletization of iron ores and optimization of flotation plants. INTRODUCTION We are living in an exciting digital era. With the advent of cloud computing and social media on the one hand and rapid advances being made in several research areas of interest to us in the minerals and metals industry such as artificial intelligence (AI) & machine learning, robotics, unmanned vehicles including drones, big data analytics, 3D printing, sensor technologies, renewable energies and internet of things (IoT), many disruptive transformations in our industry are on the horizon. Recent advances in information technology (IT) and knowledge engineering, in combination with appropriate domain expertise, that is, our enhanced understanding of the underlying science of mining and mineral processing operations and the availability of a variety of powerful modeling-simulation tools make it possible to address the challenging problems facing the mining and mineral processing industry, in an integrated manner."

Jan 1, 2018

By A. Ang-Ug, L. Gurieff

"The Phu Kham Cu-Au mine in Laos is owned and operated by Phu Bia Mining Limited. The deposit is a complex and low grade Cu-Au porphyry ore. The rougher feed has a particle size distribution of 80% passing 110 µm, and the rougher concentrate is reground for cleaning to 80% passing 25 µm. The Cu losses in the cleaning circuit are primarily in the <12 µm fraction. A randomised paired ON-OFF test of magnetic conditioning in one of the two parallel cleaner 1 circuits was undertaken. The results showed that with magnetic conditioning there was approximately a 10% reduction in the <12 µm Cu distribution in the cleaner 1 tail to a 98% level of confidence. The Cu distribution in the <12µm fraction is a less variable measure of changes in the <12µm Cu recovery, therefore, this was used to evaluate the impact of magnetic conditioning. Subsequently, magnetic conditioning was installed in both cleaner 1 circuits and the plant results monitored after this installation. Comparing the plant results immediately before and after this installation showed that there was a 20% reduction in <12µm Cu losses to the cleaner tail. INTRODUCTION The Cu-Au, Phu Kham Mine (PKM) is located within PanAust's Phu Bia Mining Contract Area in Laos, approximately 140 kilometres from the capital city, Vientiane. PKM is PanAust's flagship operation and the significant cash flow generated by PKM has supported PanAust’s growth, while contributing to a strong balance sheet. PKM comprises an open-pit mine and a conventional milling and flotation operation that produces and exports a Cu and precious metals concentrate. The concentrate contains around 23% Cu, 6 ppm Au and up to 35 ppm silver. Process Overview The PKM deposit consists of complex heterogeneous mineralogy horizons of Cu-Au stockwork and skarn mineralisation. It contains areas of soft-leached zones, overlying transition zones and supergene chalcocite dominant secondary Cu mineralisation and clay-rich gangue. Areas of high As and Zn also pose a challenge in treating the highly variable ore. In addition, hardness of the ore increases with deposit depth. The ROM is hauled to a primary gyratory crusher to produce a coarse ore stockpile with size distribution suitable for the 13 MW semi-autogenous mill. The SAG product feeds two parallel ball mills each equipped with a cyclone cluster producing a product particle size distribution of 80% passing 110 µm. The conventional flotation circuit consists of two parallel rougher banks. The rougher concentrates feed the regrind cyclone where the underflow is split and reports to two parallel, 3MW, M10000 IsaMills. The regrind mill discharge combines with the regrind cyclone overflow with a product particle size distribution 80% passing 25 µm and reports to the Jameson cell."

Jan 1, 2018

By S. Gering, R. Ruiz, C. H. Calderon-Arteaga, J. Barrios

"INTRODUCTION Located in the northeast corner of Zacatecas State, Mexico, the Peñasquito Operation is comprised of the Peñasco and Chile Colorado (Brecha Azul) deposits. Open pit mining (pre-stripping) began in 2010 and full production commenced during 2011. The open pit mines feed both a sulphide concentrator (mill) and a heap leach pad. The project is owned by Goldcorp, Inc. Penasquito is a poly metallic deposit with Au, Ag, Zn and Pb being recovered as payable metals. As a consequence of lower grade ores expected with advancing mine-life Peñasquito is facing a declining metal production profile. To maximize returns and asset value plant modifications including the addition of a carbon pre-float circuit and a pyrite leach circuit to improve recovery are currently being undertaken. This carbon pre-float circuit will enable the recovery of precious and base metals from carbonaceous sediments. This material is currently being stockpiled. With the associated increase in complexity in the process circuit, the requirement of the ore control system to accurately predict ore feed characteristics is critical to maximizing metal recovery at the Penasquito operation. The addition of the carbon pre-float circuit was also a key driver in allowing the Chile Colorado open pit to be developed. These conditions alongside Goldcorp’s drive to increase profitability, and maximize net asset value has created challenges. These challenges are numerous and are multifaceted, however the ability to accurately route materials from the ore control system is critical to site success, and some of these challenges have been overcome by the adoption and implementation of a new ore control (OC) technology. Examples of these technological innovations in the ore control program are discussed in this paper and include improvements in geo-modeling, material routing and reconciliation. Successful implementation of these elements has led to significant improvements in selectivity, performance, and data management, while reducing the variance between planning and execution, thus helping to drive overall improvement across the operation."

Jan 1, 2018

By Ihsan B. Tulu, Keith A. Heasley, Aanand Nandula

"The objective of this paper is to present the development of a software tool that will assist in an area calculation of the Analysis of Roof Bolting Systems (ARBS) support intensity while incorporating more detailed geology, stress, and intersection span input. In this area ARBS tool, a detailed CMRR distribution can be determined from the available geologic database at the mine. In addition, the overburden and multiple-seam stresses, as obtained from the boundary-element program LaModel, can be converted to a “pseudo-depth” which is then used as the depth input to the area ARBS calculation. Finally, the section-specific intersection spans can be determined from the mine design for input to the calculation. All this detailed area input information for ARBS is handled by the latest version of the Stability Mapping (StabMap) program, which now outputs an area ARBS suggested support density given the required input parameters. This final ARBS grid can be plotted, analyzed and overlaid on the mine map for optimum use in support design and for presentation to production personnel.INTRODUCTIONSince the inception of roof bolts in the 1940s, there has been a lack of a universally accepted roof bolting design method (Mark, 2002; Mark and Pappas, 2012). To address this situation, the National Institute of Occupational Safety and Hazard (NIOSH) developed roof support design guidelines, which were incorporated into a computer program called the Analysis of Roof Bolting Systems (ARBS). These guidelines were based on the effects of roof quality, stress, and mine geometry (Mark, Molinda and Dolinar, 2001). The roof rock quality in ARBS is represented by the Coal Mine Roof Rating (CMRR), the depth is used as a surrogate for the stress, and the intersection span serves to represent the mine geometry (Mark, Molinda and Dolinar, 2001). These three input parameters are used in the fundamental, empirically derived equation of ARBS to calculate a required support density factor, called ARBS, (Mark, Molinda and Dolinar, 2001):"

Jan 1, 2018

By Stankusm John C., Xiaoting Li

"Quantitatively identifying the load on a steel king beam set is a complicated issue in designing the king beam structure at the slope bottom area. From an engineering perspective, understanding the nature and support mechanism of the king beam structure as a standing support is critical in identifying the calculation input parameters for the structure design software. Based on design practices in recent years and successful applications in several slope bottom intersections, the authors present a king beam design methodology, including qualitative analysis, quantitative calculation with a structural design software, and computer Finite Element Analysis (FEA) verification.Especially important is the concept of interaction and the confinement effect between the king beam structure and surrounding rocks, which is essential in designing a proper steel structure in terms of maintaining the roof stability, as well as saving the steel materials and costs of manufacture, labor, and delivery. This paper details the design methodology and applications in several underground slope bottom intersection designs, reaching the goals of improving roof stability and reducing costs.INTRODUCTION AND DESIGN METHODOLOGYCurrently, the load on a square or arch set is typically determined by either past empirical design experiences or known heights of roof falls in current or adjacent mines. These methods work but sometimes are too conservative from an engineering perspective. For example, when designing a king beam structure for an intersection, these methods may lead to a design with extremely large and heavy steel beams, which are not convenient for delivery and installation on-site, not to mention, costly. Therefore, accurately identifying the potential maximum load on the king beam structure is important for designing a safet, effective, and cost-efficient steel structure. Based on past several years’ practices and fundamentals of ground control and structural design engineering, the authors propose a design methodology including the following components:The nature and mechanism of effective roof support (qualitative analysis),Ground reaction curve,Interaction and confinement effect between bolts and steel standing support and surrounding rocks,Factors affecting the load conditions of the king beam set"

Jan 1, 2018

By E. Karampinos, P. Morissette

"INTRODUCTION Ground support is a critical element in maintaining the stability of mining drives in deep and high stress mines. In challenging ground conditions, it is necessary to continuously explore ground support strategies that can control the resulting large deformations. It is an objective of mining operations to optimize the ground support by selecting both appropriate systems and the time of installation of each reinforcement element. A successful ground support strategy will result in the use of a system that ensures both the structural and operational integrity of the excavations and mitigates the need for rehabilitation. Preliminary ground support design is often based on empirical observations and methods. Once a design is implemented, field trials, observations and in situ pull tests are used to fine tune or improve the design. Although not often employed during this process, numerical modelling can provide helpful insights on the impact of different ground support strategies. In this respect, it is possible to explore the use of multiple options before selecting the most promising ground support system for implementation in field trials. The challenges associated with the numerical modelling of rock support for mines have been described by Lorig and Varona (2013) and Potvin (2017). The employed numerical models should capture all potential failure modes of reinforcement over the mining sequence of the excavation. In particular, it is important to emulate the observed in situ ground support performance, as well as the influence of the installation sequence of the support. However, the time and expertise required for this type of modelling of ground support is not often available at mine sites. Even when the expertise is available it requires a major time and commitment of resources to set up, run and calibrate the sophisticated models capable of explicitly capturing the behavior of ground support. Rock reinforcement is an integral part of all ground support systems used in underground mines. Long flexible tendons can reinforce the rock mass deeper into the walls and create a thicker reinforced shell around the underground excavation. This paper focuses on the optimization of the cable bolting strategy in squeezing conditions at the LaRonde Mine by integrating the 3D distinct element method (DEM) in the design process. A calibrated numerical model is used to investigate a series of cable bolt configurations and provide recommendations for the ground support design."

Jan 1, 2018

By C. H. Veloso

"Starch is the most widely used depressant in the reverse cationic flotation of iron ores. There is however, an indication from recent studies, that other polysaccharides may successfully replace them. When starches are used in the flotation of iron ores in the presence of quartz as gangue mineral, their strong adsorption on the surface of iron oxides can be explained by the molecular conformation between the available sites on the mineral surface and two hydroxyls of starches. However, when the gangue minerals are iron-bearing silicates, the strong interaction with starch can occur on these minerals since they have the same surface behaviour as iron oxide. In this work bench scale tests were conducted in order to generate scientific knowledge about other alternatives depressants for the flotation of iron ores. A magnetic pre-concentrate from a skarn iron ore processing plant was used as feed material for flotation tests. The reverse flotation approach was used to upgrade the iron content by removing complex ironbearing silicates. The depressants used in this study were: corn starch, dextrin, carboxymethyl cellulose (CMC) and humic acid. The tests were performed under different pH conditions in order to try to relate the efficiency of depression to the pH used during flotation. The results show the important role of pH as each depressant reached its best performance at different pH values. At alkaline pH the corn starch showed best depression performance while the humic acid is more efficient at pH close to neutrality.INTRODUCTIONIron corresponds to approximately 6% of earth’s crust composition (McDonough and Sun, 1995). It is the most used metal in our lives, some of its properties as resistance and facility to be shaped makes is replacement very difficult. The primary sources of iron on our planet are minerals. The iron-bearing minerals most commonly found in nature and economically exploited are magnetite [Fe3O4], hematite [Fe2O3], goethite [FeO(OH)] and siderite [FeCO3] (L O Filippov et al., 2014). These minerals are commonly associated with other minerals (most of the time not economically exploited) forming the so-called iron ore. Iron ore is the source of primary iron for the world’s iron and steel industries."

Jan 1, 2018

By Karsten Hagenah, Tor Jensen, Jens Laugesen, Øyvind Fjukmoen, Lucy Brooks

This paper discusses operational environmental threshold levels for exploitation of mineral resources in the deep sea. Such criteria are needed to be able to monitor and control deep sea mining with respect to the stringent environmental requirements that are needed. It is recommended to use existing environmental threshold levels for comparable underwater activities. Fields of application are mainly but not exclusively seabed mining operation activities under the governance of the International Seabed Authority (ISA). The threshold levels and limits mentioned in this paper are proposed recommendations based on other activities than seabed mining but are a proven and accepted approach in other maritime industry activities. An example of such other activities with proven and accepted environmental threshold levels are Oil & Gas exploitation activities in the sea. Background The first exploitation of mineral resources in international waters is coming closer. Presently regulations for exploitation for mineral resources in the Area are being developed by the International Seabed Authority (ISA). The ISA regulations will contain the framework related to environmental monitoring of exploitation. However, the regulations will not contain operational environmental threshold levels for the Contractor.

Jan 1, 2018

By Karen C. Armfield, Gisele R. Passalacqua, Joanna Smith

When selecting a solution for improving resiliency at facilities, such as airports, utility and transit sites, there are many options to protect structures and equipment against potential flooding. Each case involves an evaluation of the several key factors such as: design flood parameters, the geography and geological conditions below the site, the facility, and the layout of buildings and equipment to be protected. Upon reviewing these conditions and conducting a cost analysis of various options, the most suitable approach to protecting a facility can be determined. This paper will compare the conditions at various New York City sites, and give detail to the solutions utilized at these sites to improve resiliency and protect each facility. Flood wall types varied as did the strategies for raising critical equipment, to meet the Federal Emergency Management Agency (FEMA) and American Society of Civil Engineers (ASCE) 7 guidelines. Due to granular soil conditions, some sites may experience soil seepage below the flood wall resulting in the need for underground cut off systems. The authors will also present detail regarding the solutions used to control seepage. Various cut off systems will be discussed such as grouting and sheeting, explaining the factors that may impact the choice of systems. Another consideration in flood resiliency is the potential for a buoyancy condition on basement slabs when localized flood barriers are employed on first floor doors and windows. The authors will discuss the potential impacts of this condition on facilities and methods to mitigate this issue. 1. INTRODUCTION New York City is an urban coastal Metropolis with varied geology and low land areas. This includes but is not limited to sandy soils at Coney Island and the John F. Kennedy Airport. Soft marshes are found near Flushing Queens and LaGuardia Airport. Heavy rains and coastal storms caused disruption to daily life and heavily affected the economy of this vibrant City. For instance, in lower Manhattan business was interrupted in the Financial District. Power outage was widespread; commuter trains and subways were stopped and put out of service. Additionally, numerous residential homes were damaged in Coastal Neighborhoods such as the Far Rockaways and Staten Island. 1.1. Superstorm Sandy Flood Statistics On October 29, 2012 Superstorm Sandy impacted numerous facilities in the New York City Metro area. The resulting damage cost New York City more than $42 billion in repair costs. $33 billion was allocated to repair housing and infrastructure, and $9 billion was allocated to protect transit systems1. One of the major issues that impacted the city in terms of its preparedness was the high flood surge. The surge surpassed the former base flood elevation and reached as high as 13.88 feet (above mean lower low water - MLLW) in Battery Park at 9:24pm that evening. Tottenville, Staten Island experienced more damage where the water was recorded at +16 (North America Vertical Datum of 1988 - NAVD88), which is equivalent to 18.7 feet above MLLW (see Fig. 1). Not only was the surge at record levels, the waves in New York Harbor were also at record level where some buoy stations recorded waves of up to 32.5 feet. The City released “A Stronger, More Resilient New York” in June 2013, a plan laid out to rebuild communities impacted by Sandy and improve the resiliency of the infrastructure and buildings in New York City. Figures below help to illustrate the extent of the inundation relative to the projects being discussed.

Jan 1, 2018

By B. P. von der Heyden, P. Neethling, M. Tadieb, L. Babedi

The effects of trace element substitutions in sphalerite mineral structure on optimised floatation response have, as yet, not been fully constrained or fully understood. To further this important field of study, this contribution focusses specifically on mineral and surface chemistry, and electro-chemistry of Cd- and Co- substituted synthetic sphalerites using Raman spectroscopy and Zeta potential experimentation. Raman spectroscopy illustrates that the presence of these impurities results in the introduction of a new mode, the relative intensity of which can be correlated (Cd r2=0.95 and Co r2= 0.99) to the dopant concentration. Comparison to X-ray Diffraction results measuring the unit cell parameter further shows that this relative intensity (Cd r2=0.81 and Co r2= 0.99) may provide insights into the degree of lattice strain within the mineral structure. The zeta potential distribution of an un-activated Cd-sphalerite show no detrimental effect as function of Cd content. Although the iso-electric point shifted from 2.45 at 1 wt.% Cd to 2.69 at 3.68 wt.% Cd, the zeta potential remained negative at alkaline media. Conversely, cobalt at low concentration of 0.36 wt.% had a detrimental effect on the surface charge, resulting to a close to neutral zeta potential at different pH. The adsorption of Cu ions on the surface of Co-bearing sphalerite conditioned in an alkaline media slightly increases the zeta potential of Co-sphalerite. While the Cd-bearing sphalerite decrease in negative zeta potential at >1 wt.% Cd indicating a complete exchange between Cu and Zn. The results presented herein illustrate that, based on the chemical nature of the substituting metal; sphalerite will exhibit multiple response to flotation reagents. Maximum recovery of zinc can thus only be achieved through multidisciplinary study and fundamental understanding of the effects of cation substitution on mineral structure and surface chemistry, the latter necessarily affecting the floatation response.

Jan 1, 2018

By R. Schlüter

"The global mining industry is facing increasing challenges in terms of geological, technological and social aspects. Potential exploi-tation of deposits shows a tendency to increasing depth with complex ores and decreasing grades. A promising approach to deal with these constrains is by applying alternative extraction methods like (bio-)hydrometallurgy as in-situ leaching (ISL) technology. The Bergakademie Freiberg University of Mining and Technology established the “Biohydrometallurgical Center for strategic Elements” (BHMZ) to foster the interdisciplinary research along the entire biohy-drometallurgical process chain to extract indium from sulfide ores. The involved Department of Underground Mining Methods deals with the design and implementation of a pilot-scale underground testing facility for microbial in-situ stope leaching in its “Research and Educational Mine”. This paper discusses the potential of in-situ bioleaching under technological aspects. In addition, different conditioning approaches based on hydraulic and explosive methods for enhanced permeability in the formation are introduced and the gathered data will be presened. INTRODUCTION A reliable, substantial and sustainable supply of raw materials is of crucial importance for any industrialized country. This dependency applies to “strategic elements” including rare earth elements (REEs), platinum group metals (PGMs) as well as a variety of other metals like indium and germanium which are needed for high-tech industry and products such as electric and electronic devices, fibre optics and laser technology (Barakos et al., 2016; European Commission, 2010). Due to the economic growth of the BRIC-countries (Brazil, Russia, India, China), the resource policy of China as well as the volatile world mar-ket prices of different metals the availability of these critical raw materi-als and therefore the dependency of the high-tech producing countries has become increasingly important (Barakos et al, 2016). Adequate supply is often affected by the increasing depth of de-posits, lower metal concentrations and more complex ore mineralogy. In addition, mining activities are increasingly restricted by their envi-ronmental and social impact and footprints. As a consequence, con-ventional mining and processing methods are limited by high energy consumption and technical constraints."

Jan 1, 2018

By A. Rousselet, H. Gilbert-Tremblay, A. Berton

"Robex Resources interrupted production at the Nampala Mine in September 2014 following throughput and gold recovery results which were below expectations during the first months of operation. After a thorough plant audit, an important brainstorming took place in order to identify an economical path to resume production. It was clearly identified that a significant investment was necessary at the concentrator prior to restarting the plant, namely the addition of a ball mill and a new elution system.The mineral processing simulation software USIM PAC was used in order to simulate the grinding circuit in design. The simulations’ outputs allowed the ball mill characteristics and the surrounding classification devices to be designed with more accuracy. Many ball mills available from second hand retailers were therefore studied in the simulated circuit. The chosen ball mill, which was in perfect condition, had the advantage of being available for rapid delivery on site.The paper first describes the ball mill sizing method in comparison with the conventional Allis Chalmers method. It then describes the phase 2 concentrator start-up (that took place in 2016) with the commissioning of the ball mill, the classification circuit, the gravity concentration, the four (4) new carbon-in-leach (CIL) tanks, and the Zadra elution system (The phase 1 start-up took place in 2014). It finally provides production data compared to expected simulation data, as commercial production was reached in January 2017.IntroductionDesigning a new concentrator or new equipment within an existing concentrator requires significant efforts to identify possible bottlenecks and their causes (i.e. limiting equipment or sectors) and accurate sizing of major equipment can have a tremendous impact on the economy of the whole project. In the presented case study, the ball mill was the critical equipment and oversizing it could have brought the Capex to a level where the project would not have gone through. Inversely, undersizing the mill could have resulted in lower production and therefore no economic viability for the project once it is in operation.During engineering studies, equipment sizing often relies on a static mass balance and one-by-one sizing of all pieces of equipment. The sizing is then left to the equipment manufacturer or in the case of mills, evaluated with empirical models mostly relying on the Bond equations (Allis Chalmers method) [Rowland and Kjos, 1978]. This methodology shows the disadvantage of not considering interaction between equipment in a mineral processing circuit, especially when recirculation occurs. Also, it has the disadvantage of not using the more advanced grinding models that include the use of the whole particle size distribution as well as phenomenological components by only using limited parameters in the ore particle size distribution (i.e. the P80). This can be explained by the lack of data that sometimes needs to be gathered in order to tune the more advanced models but also by the conservative mindset in mineral concentration engineering which does not always favor the use of process simulation. In many aspects of process engineering, Soutex has demonstrated its affinity to using simulation in order to size equipment with more accuracy, consider process variability, simulate complex systems, and study supply chain management (Berton et al., 2015)."

Jan 1, 2018

By D. Purdie

"This paper aims to remind researchers, designers, operators, and managers about the benefits of seeding in the design of precipitation stages in their flowsheet. Including a high density solids (HDS™) process encourages the precipitating solids to form on the surface of existing precipitated particles. This paper discusses the application of the HDS technology at Kennecott Smelter, where the authors have witnessed significant improvements in settling and filtration rates. The authors have also applied this technology at various smelter bleed treatment plants worldwide with similar improvements in precipitation and filtration rates. HDS is a registered trademark of De Nora Water Technologies. RÉSUMÉ Cet article a pour objectif de rappeler aux chercheurs, aux concepteurs, aux exploitants et aux administrateurs les avantages de l’ensemencement dans la conception des étapes de précipitation de leur schéma de traitement. L’introduction d’un procédé des boues haute densité (procédé HDS™, de l’anglais high density sludge) encourage la formation de substances solides précipitantes à la surface des particules précipitées existantes. Cet article porte sur l’application de la technologie HDS à la fonderie Kennecott, où les auteurs ont observé des améliorations importantes au niveau de la vitesse de sédimentation et de filtration. Ils ont également appliqué cette technologie à diverses usines de traitement des rejets liquides des fonderies dans le monde entier, et ont constaté des améliorations similaires en termes de vitesse de précipitation et de filtration. Le procédé HDS est une marque de commerce déposée du fabricant De Nora Water Technologies.INTRODUCTION In 1966, the lead author worked as an assistant smelting metallurgist for the Tsumeb Corporation Limited copper and lead smelter in Tsumeb, Namibia. The smelter produced copper and lead, as well as cadmium and arsenic trioxide as byproducts. The cadmium was concentrated in the lead blast furnace off gas dust, and was collected by a baghouse. The baghouse dust was leached with dilute sulfuric acid (H2SO4) in a batch process. The iron and arsenic in the solution were oxidized with potassium permanganate (KMnO4) and basic ferric arsenate (BFAS; Fe(AsO4)x(SO4)y(OH)z·wH2O) was precipitated using milk of lime. The cadmium was cemented from the purified solution using zinc dust."

Jan 1, 2018

By S. I. Anufrieva, N. A. Permyakova, E. G. Likhnikeevich

"Russia’s rare metal reserves are composed of compositionally and structurally complex ores and are characterized by an increased content of natural radionuclides due to their geochemical similarity with rare metals. For instance, concentrates of Zashikhinsky daeposit are characterized by an increased content of uranium (0,06%) and thorium (0,59%); Beloziminsky deposit holds pyrochlore-apatite-magnetite-carbonate ores characterized by increased radioactivity (130 mkR/h) and containing 0,0016-0,0025% of uranium; Etykinsky deposit is characterized by columbite-pyrochlore-microlith mineralization with an average ore grade of 0,013% of uranium and 0,0020% of thorium; eudialyte concentrate of Lovozero deposit (Alluaiv area) belongs to Class II of mineral reserves. Industrial development of these mineral reserves involves the need to comply with environmental standards, public health requirements applicable to finished core and by-products, to take into account the amount and class of the generated radioactive waste, the possibility of disposal or recycling of the radioactive production waste. Concentration processes of radioactive rare metal feeds most often lead to a concentration of natural radionuclides and their accumulation in concentrates. Comprehensive hydrometallurgical processes are currently under development for such concentrates, aimed at producing salable products compliant with the radiation safety standards. The choice of the hydrometallurgical processing method for radioactive rare metal concentrates is based on the mineralogical component of the concentrate, textural and structural features, the distribution of valuable components and impurities, and the content of radionuclides. A systemic approach to the selection of processing methods, in particular integrating several methods, is an effective solution. Methods may not only be combined, but also inextricably linked with each other. Hydrometallurgical processing methods include leaching by acidic and alkaline agents; sulfatization for selectively decomposing the minerals and moving the bulk of U and Th into solution; fluorine extraction process. Methods of precipitation and co-precipitation, extraction (by liquid and solid extractants), sorption, and ion exchange are used to decontaminate the solutions by removing thorium, mezathorium, uranium, and their radioactive decay products. Agents used in hydrometallurgical processing of radioactive rare metal ores include sulfuric, nitric, hydrochloric, hydrofluoric acid, alkali (NaOH, KOH), sorbents (for example, AB-17) for sorption of uranium and extractants (mono- and bidentate organophosphorus compounds, diamides, etc.) for the extraction separation of rare, rare-earth, and radioactive elements."

Jan 1, 2018

By Masaomi Kurihara, Seiya Kawano, Norihiro Yamaji, Satoshi Shiokawa, Nobuyuki Okamoto, Hironobu Sakurai

Seafloor polymetallic sulphides are distributed in the EEZ of Japan, including substantial deposits in the Okinawa Trough and Izu-Bonin back-arc basin. In this new frontier, the successful development of these resources in Japan is expected to bring about a new domestic supply of mineral resources. The initial stages of this development are authorized by the Basic Plan on Ocean Policy, approved by the Japanese Cabinet on April 26, 2013, and the Plan for the Development of Marine Energy and Mineral Resources, formulated by the Ministry of Economy, Trade and Industry (METI) on December 24, 2013. In 2008, the Japan Oil, Gas and Metals National Corporation (JOGMEC), commissioned by METI, began a survey and technological development programme for the development of the seafloor polymetallc sulphides (PMS) based on these Plans. The examination of four different fields: the evaluation of the amount of the resource, environmental assessment, mining technology, and processing & smelting technology, are concurrently promoted, aiming for commercialization as soon as possible. Based on the results of research for properties of geomorphology and marine environments of the target test sites in the Okinawa trough, which have been ongoing for several years, the preparation of the pilot lifting test included an in-situ excavation and crushing test conducted using test excavating and crushing systems.

Jan 1, 2018

By A. Lewis

"Thiol collectors including the xanthates and dithiophosphates have dominated the sulfide mineral processing industry for over a century. Tecflote represents completely different chemistry, without sulfur or phosphorus, and will float all sulfides and associated precious metals. As these collectors are surfactant in nature, they comprise a head group which binds to mineral surfaces, a spacer and a long hydrophobic tail. The modification of the spacer behind the head group allows for collector optimisation for different sulfide ore types and process conditions.The Tecflote surfactants have been designed to be either very selective against pyrite at the natural pH of the ore (pH 7-9) or to float all sulfides including pyrite. Depending on the ore type and the process flow sheet, the use of lime can be maintained, reduced or completely eliminated.Tecflote can be used either as a rougher collector giving good recovery and grade for the sulfide minerals or it can be used to target valuable minerals after regrind and through cleaner flotation. It has repeatedly shown to be very effective at holding onto gold through the cleaner steps. The low solubility has a significant impact on the mechanism and surface activity of the collector, resulting in a very different flotation response compared to conventional thiol collectors.INTRODUCTIONXanthate was first made in 1882 by Zeise and first used in flotation in 1924 (Keller, 2018). In 1946 Keller patented thionocarbamate as a collector, which was produced by Dow Chemicals (Keller, 2018). Later it was replaced by Dow product Z-200, while dialkylthionocarbamate was discovered by Harris et al. (Harris, 1954. No significant chemistry change to collectors has occurred since they were introduced in the mid-20th century and now that the feed grades have been declining over the last decades creating a need to find more selective collectors to extract difficult and complex ores and pushing the industry to look at other reagents."

Jan 1, 2018

By M. Kosugi, M. Kawata, J. V. Satur, K. Mitsuhashi, R. Kawarabuki, W. Kracht, Y. Ebisu

Copper concentration is becoming more difficult because remaining copper ores are more complex and of finer copper mineral grain size, making copper minerals harder to float because of the fine particle size required to liberate the valuable species. The purpose of this work was to study the flotation behavior of fine copper sulfide ores at different conditions of agitation and aeration. The experimental campaign was carried out in a laboratory Denvertype flotation cell of 1 L volume modified to be operated with forced air that allows decoupling air flow rate and agitation speed. Four ore samples from Chile were used, all of them containing copper sulfides such as chalcopyrite, bornite, chalcocite, and tennantite, but with varying grain sizes and compositions. Preliminary flotation tests for establishing the flotation conditions of grinding size and collector dosage were conducted before the kinetic flotation tests that were carried out at different agitation speeds varying from 900 to 1300 rpm for gas flow rate ranging from 1.6 to 7.2 L/min. The flotation products were analyzed by ICP-MS and MLA (Mineral Liberation Analyzer). The results showed that high agitation speeds with corresponding air flow rates resulted in better recovery than moderate agitation speed and air flow rate, and an excess in gas flow rate resulted in bad performances. The flotation rates of the fine copper minerals were improved despite the different improvement rates among the fine size fractions. The impact of these operational variables, however, was different when comparing the results for the four ore samples. While it was found that the order of floatability in the four samples was the same, that is, chalcocite > tennantite > bornite > chalcopyrite, the kinetic constants of the copper minerals in the samples were different, indicating that mineral composition in the sample affects the flotation kinetics.

Jan 1, 2018

By K. V. Fedotov, G. I. Sarapulova

The study is devoted to the earth's surface protection and is aimed at improving the ecological safety of the territories in the mining industry. Identification of the diagnostic signs and quantitative criteria for the disturbance of soil geochemical properties and water chemistry represent an important scientific task in anthropogenically disturbed landscapes in the context of comprehensive exploitation of mineral resources. The study is aimed at geological and ecological analysis of the migration peculiarities of the man-caused chemicals and elements in soils and soil-surface water environment. We received new results. These results assist in estimating the peculiar features of distribution of heavy metals total and mobile forms (Cu, Ni, Zn, Pb), depending on the physical and chemical parameters of the disturbed soils. We obtained the empirical relationships describing heavy metals localization and accumulation processes depending on buffer properties of soils (pH, N, Corg), salinization factor and contamination with oil products. Anthropogenic geochemical barriers spontaneously formed in the area of industrial facilities were revealed in the territories of industrial facilities. These barriers prevent the further distribution of elements and pollutants in the landscapes. This makes it possible to create their artificial analogues in order to limit further migration of pollutants and to immobilize valuable components. Analysis of diagnostic features of soils geoecological state and factors influencing the distribution of heavy metals in the soil-surface water geosystem allows the identification of the geochemical barrier type with the aim of elements immobilization in a limited area of the territory. We applied modern physical and chemical methods of analysis, a package of statistics programs in Excel and modeling techniques. The proposed approach is innovative and therefore can be attractive. The accumulation of useful components losses in mineral resources exploitation is a promising reserve for their recovery from the soil with specifically arranged properties. The methodology of this research is also promising for the prediction of the environmental emergencies of the anthropogenic nature. This is consistent with the requirements of state control of environmental safety in the course of comprehensive exploitation of mineral resources.

Jan 1, 2018

By J. van Wijk

"Vertical material transport is one of the major challenges for the successful implementation of deep sea mining projects. The EU research project „Blue Mining” is focusing on sustainable solutions for deep sea mining operations, with one major goal being the advancement of Vertical Transport Systems (VTS). To investigate flow effects under realistic conditions, especially clogging effects, a 136 m high test facility for flow analysis in vertical transport has been constructed using available mining infrastructure. Tests are run in a closed circuit, using a system of downfall and riser pipelines connected to a compact sediment injection- and separation unit as well as the centrifugal pump. The riser is equipped with pressure sensors, as well as temperature sensors, flow meter, concentration meter and high speed camera to allow comprehensive analyses of the flow regime and behavior of transported material within the flow. Additional mobile measurement devices allow wear and tear analyses of pipe material. This paper focuses on the determining factors of the tests leading to the design as well as the installation and trial of the test facility itself and explains the used components and work principles. INTRODUCTION Since the 1970s several research projects had been conducted investigating in the possibility of deep sea mining. In recent times projects for deep sea mining operations have started again, considering the rising demand on natural resources, especially raw earth elements. Yet projects like the Nautilus project on the deposit Solwara 1 [1], or Japanese projects focusing on the region of Okinawa [2] and Chinese projects [3] planning on depths of “only” about 2,500 up to 3,000 m. Until now no economical deep sea mining project was realized, due to the enormous difficulties of deep sea environments. Vertical material transport is one of the major challenges for the successful implementation of deep sea mining projects, considering transportation heights up to 5 km. The EU research project „Blue Mining” is focusing on sustainable solutions for deep sea mining operations, with one major goal being the advancement of Vertical Transport Systems or VTS [4]. Critical parts of the system would be identified and investigated to deliver solutions and higher the technology readiness level to a level were planning of a pilot project can be considered. At first case examples for mining projects of seafloor massive sulfides (SMS, 1,600 m water depth) and manganese nodules (MnN, 5,000 m water depth) had been calculated on basis of economical frame conditions, such as planned production rates to be efficient. As depicted in Figure 1 two major possible systems had been used for comparison, airlift system and pump system, considering multiple pump stations or single pumps. Based on the results and comparisons for the calculated vertical transport systems critical components and flow effects had been identified."

Jan 1, 2018

By Mingxia Liu, Qi Liu, Tao Jiang

"In addition to physical parameters such as small mass and high specific surface area of fine and ultrafine minerals, chemical parameters such as the adsorption affinity of collectors on the minerals also plays an important role in fine particle flotation. In this study, we have examined collectors with two different ionized groups, carboxylate and hydroxamate, on the flotation of fine niobium oxide (pyrochlore). To facilitate comparison, two hydrocarbon radicals were tested: octyl and oleoyl, which led to four collectors that were studied: octyl hydroxamic acid (OHA), sodium octanoate (C8OONa), oleoyl hydroxamic acid (C18HA), and sodium oleate (NaOl). Small-scale flotation and isothermal microcalorimetric titration measurements were performed to determine the flotation recoveries of different sized pyrochlore and the enthalpic behavior after adsorption of the collectors on pyrochlore. It was found that the flotation performance of the carboxylate-based collectors was generally inferior to hydroxamate-based collectors. Sodium octanoate could not float pyrochlore irrespective of the particle size of the pyrochlore tested. With a longer hydrocarbon chain, sodium oleate was effective to float the relatively coarse pyrochlore (>20 µm) but its collection efficiency dropped sharply for particles smaller than 20 µm. On the other hand, the two hydroxamate-based collectors, octyl hydroxamic acid and oleoyl hydroxamic acid, showed good collecting ability to both the coarse and fine pyrochlore. The isothermal microcalorimetric titration studies indicated a consistent correlation of chain length with floatability of collectors for relatively coarse pyrochlore, as well as a positive relationship between the adsorption affinity and fine pyrochlore flotation recoveries. The key finding of this study was that efficient fine particle flotation could be achieved when strongly chemisorbing collectors were used.INTRODUCTION The first detailed study of the effect of particle size on flotation was made by Gaudin (1931) with sulphide ores. In 1942, Gaudin again demonstrated that (Gaudin et al., 1942) fine particles possess different flotation properties from larger particles. Since then the effect of particle size on froth flotation has been an important research topic by many researchers, e.g., Gaudin (1957), Miettinen et al. (2010), Warren (1976) Jameson (2010), summarizing the behavior of fine particles in terms of their low particle momentum, leading to low rate of collision with bubbles which reduces the chance of adhesion. The suggested remediation methods are mainly based on two approaches: increasing particle size or decreasing bubble size (Warren, 1976). Sand-fine splitting followed by separate flotation treatment of the sand and fines, using deep flotation cells, using starvation quantities of collectors, and using long flotation times, are also strategies to address the problems of fine particle flotation."

Jan 1, 2018