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By A Marta

Geomembrane (GMB) liners are being used more frequently for the storage or capping of mine waste due to stricter regulatory requirements relating to environmental protection. The longevity of any liner system will be a function of environmental conditions, design (including materials selection), construction and condition monitoring during operations or closure. Based on experience and case studies, this paper presents a review, from design to handover, of some of the smaller and often overlooked details that can have significant impacts on the performance of the GMB and the project overall.The topics covered will include approaches to selecting and testing GMBs to ensure they are suitable. Design considerations to aid installation and quality assurance during construction. Understanding action leakage rates and the consequences of leakage when it creates whales. Construction quality control and assurance procedures, including a brief discussion on non-destructive liner integrity testing. CITATION:Marta, A, 2018. Geomembranes – from design to handover and some of the lessons learnt, in Proceedings Mine Waste and Tailings Stewardship Conference 2018, pp 190–207 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 23, 2018

By D Reid

The engineering properties of soils and tailings often exhibit significant anisotropy. One area where this has been well documents is undrained shear strength. Materials sheared in directions close to the principal stress direction in situ, i.e. triaxial compression, typically exhibit higher undrained strengths than those sheared in other directions such as simple shear. Importantly, along the most common critical failure surfaces relevant to tailings stability, whether primarily through tailings or a critical foundation layer, saturated materials are generally much closer to the simple shear loading direction than triaxial compression. Therefore, testing undrained shear strength of tailings or foundation soils in triaxial compression is likely to result in overestimation of the relevant strengths for design. Although these issues have repeatedly documented in the geotechnical literature for over three decades, they are not appreciated sufficiently across our industry. In an attempt to address and highlight these issues, a review is carried out of historical reference to the importance of simple shear loading. Attention is then drawn to the techniques applied in three recent post-failure investigations, where simple shear testing was applied. Finally, some relevant laboratory test results from a recent project in which the author was involved are outlined.CITATION:Reid, D, 2018. Importance of the simple shear loading direction to the stability of tailings storage facilities, in Proceedings Mine Waste and Tailings Stewardship Conference 2018, pp 274–284 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 23, 2018

By E M. Gama, L Resende

The tailings are waste from mineral processing operations. The type of tailings of iron ore processing are classified into sandy tailings and mud. Already the overburden are showing significant levels of useful mineral. Both iron ore`s waste have in your composition phyllosilicates/clay that indicates the potential for use in niche markets as paving and cement. According to several studies, there are various technologies in bench and pilot levels that could be used on a large scale but there is not an economic environment, tax, regulatory and tax set. Many of these technologies are associated with the reuse of tailings and overburden in construction. All these factors influence for that so many initiatives remain in search formats and cannot advance to the new business format. There is no way to set goals of reuse of this waste, as already occurs in China, if there is not a fiscal, tax and economic structure to support such measures. The way to foster and ensure that reuse of tailings and overburden is an incentive for promoting a culture of circular economy that would allow the emergence of an ecosystem between the private, public and Government sectors with the objective of accelerating and subsidize the entire network of reuse of this waste. The closure of the mine could be the tool used to ensure and boost this ecosystem of reutilization to align it with the vocation of the area of the mining law. Following this model, the end of the mining activity could provide a financial return to the local population, a more effective environmental compensation and a reduction in costs related to the closure of the mine. In this study are shown how the Vale is working in the reuse of tailings and overburden.CITATION:Resende, L and Gama, E M, 2018. The challenges of the reuse of tailings and overburden, in Proceedings Mine Waste and Tailings Stewardship Conference 2018, pp 117–125 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 23, 2018

By H Cifuentes, D J. Williams

Despite the recognised importance of tailings management, there remain little data on the potential benefits of biological treatments compared with physical and chemical treatments. The operation of the majority of tailings storage facilities (TSFs) continues to employ mainly physical solutions, such as sub-aerial tailings slurry deposition, with increasing adoption of thickening, paste and filtration to dewater the tailings involving the addition of chemicals such as flocculants and coagulants. However, with tailings production continuing to escalate rapidly due to the increasing demand for commodities and reducing ore grades, available technologies have not demonstrated cost-effective performance at high tailings production rates. This paper examines the emerging role of bacteria to better manage tailings, reducing risks and optimising storage capacity. Bacteria have the potential to enhance tailings dewatering, maintain their permeability, delay the onset of desiccation cracking, and improve their shear strength. Bacteria-treated tailings may be suitable for use as construction materials. Bacteria also have potential in limiting the dusting of tailings and facilitating rehabilitation on closure. The paper describes a series of laboratory involving the addition of harmless bacteria to a range of tailings. The bacteria form a compact material called calcite (a common and stable form of calcium carbonate), which immobilises the tailings particles, releases water, and cements the tailings in a stable and natural matrix. The water released can be recovered or evaporated, depending on site objectives. The bacterial reactions are linked to physical and chemical processes, providing the potential for an optimal mix of technologies for particular tailings and site conditions.CITATION:Cifuentes, H and Williams, D J, 2018. Potential improvement of tailings geotechnical behaviour using bacteria, in Proceedings Mine Waste and Tailings Stewardship Conference 2018, pp 228–238 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 23, 2018

By A M. Sardo, D E. Sinnett

This study uses the Q Method to examine how those living in former metal mining landscapes value this heritage and their preferences for the long-term management of mine waste. Such sites are often perceived as derelict or degraded, and of very little value. It is therefore assumed that their reuse, for example for development or recovery of metals, is likely to be beneficial. There are around 5,000 former metal mines in England and Wales, many of which are protected for their ecological, geological or cultural value. The Q Method is particularly suitable for issues where there is no consensus of opinion. We asked 38 residents of six mining areas in England and Wales to ‘sort’ a series of statements based on their resonance with the resident’s perspective; this is the Q sort. The statements covered a range of opinions of the mining legacy, its value and options for its management with a particular focus on the potential for metal recovery from the wastes. Analysis of the Q sorts revealed five perspectives on the mining heritage. All placed a high value on the cultural and ecological value of this heritage, however, they differed in their priorities for long-term management. For example, emphasis was placed on either nature conservation, cultural heritage, water quality or the opportunity for job creation through reworking the mines. Cutting across these themes there were also differing perspectives on the role of experts and local people in shaping the future management of the wastes. This research suggests that the views of local people are nuanced; they value their mining heritage but opinion is split on the most effective way to manage these sites especially where there is an impact on water quality.CITATION:Sinnett, D E and Sardo, A M, 2018. Former metal mining areas in England and Wales – local residents’ preferences for the management of wastes, in Proceedings Mine Waste and Tailings Stewardship Conference 2018, pp 126–134 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 23, 2018

By R Stefansen, T Wisdom, A Nicholson, K Rahal

The challenges of increasingly scarce water resources and the risk of dam failures has seen the mining industry turn to sustainable tailings management solutions such as dewatering and dry stacking. Filtering tailings has been seen in the past as a cost-prohibitive process for larger throughput mines. However, as larger pressure filters are developed, the economic case for filtered tailings has gained traction.Focus has largely been placed on the correct design and operation of the filters. It is critical, however, that the material handling portion of the disposal system is also properly designed and operated. Thorough testing at laboratory and pilot scale to determine the conveying properties of the filtered material needs to be conducted. This testing will insure the material handling system meets the important availability needs of the mine even during periods of variability in the upstream processes and mine plan.The control system must also be robust and flexible in design to compensate for this upstream process variability. The control system needs to allow for different flowsheets including straight filtered tails as well as EcoTails™, a low-energy solution for co-mingling waste rock and filter cake.This paper will present case studies of different material handling solutions, the testing required for them and the lessons learned from each.CITATION:Rahal, K, Nicholson, A, Stefansen, R and Wisdom, T, 2018. Material handling testing and control system requirements for dry stack tailings, in Proceedings Mine Waste and Tailings Stewardship Conference 2018, pp 361–368 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 23, 2018

By D J. Williams

The majority of surface tailings storage facilities continue to employ sub-aerial tailings slurry deposition. Surface TSFs are typically sized and operated in a way to minimise the initial capital cost of the facility, driven largely by the net present value approach to accounting. This generally leads to too small a storage, too fast a rate of rise of the tailings, and difficulties in managing supernatant water. In turn, this results in wet and soft tailings deposits of high moisture content and low density, and the need for frequent and costly tailings dam raises. Further, such tailings deposits often do not facilitate closure and rehabilitation of the facility. Globally, there are on average over two failures annually of such tailings dams, resulting in loss of life, damage to infrastructure and environmental impact downstream, and the loss of company shareholder value and reputation. Recent high profile tailings dam failures are threatening the mining industry’s financial and social licence to operate.Among the physical processes that tailings undergo on sub-aerial deposition are beaching, hydraulic sorting down the beach according to particle size and specific gravity, settling, consolidation, and desiccation on exposure to the sun and wind. Beaching and hydraulic sorting have proved difficult to test at laboratory scale and difficult to model, and are best assessed in the field. Settling, consolidation and desiccation may be assessed at laboratory scale, but to date there has been an absence of tests to form the basis for the design and management of tailings deposition, and ultimate closure and rehabilitation. The paper describes recent advances in tailings testing methods, including a purpose-built slurry consolidometer that tests the settling and consolidation of tailings from a slurry consistency, simulating increasing tailings depth to about 50 m; and a purpose-built instrumented column that tests the settling, self-weight consolidation and desiccation of a surface layer of tailings, also from a slurry consistency. Selected test results from these two apparatus are presented in the paper, together with brief descriptions of how they may be used to better design tailings slurry deposition. In addition, planned further advances in tailings testing methods are briefly described.CITATION:Williams, D J, 2018. Recent advances in tailings testing methods, in Proceedings Mine Waste and Tailings Stewardship Conference 2018, pp 8–37 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 23, 2018

By C Armstrong, B Wentzinger

Upstream embankment raises often represent the lowest cost option for increasing the capacity of tailings storage facilities (TSF), but also pose the highest stability risk due to constructing on top of previously deposited tailings.This paper presents an overview of key aspects in the geotechnical investigation and design of upstream raises and some recent lessons learnt from experience across a number of TSFs in Australia. A summary of recommended field investigation and laboratory testing methods is provided with a focus on collecting quality information for design purposes. A strong focus is given in developing an accurate assessment of pore water pressures, which, if not correctly understood can have disastrous consequences on tailings strength parameter interpretation and wall stability assessment in static and post-seismic conditions.The assessment of the contractive or dilative shearing behaviour of the tailings material and rigorous interpretation of design characteristic values are presented. Some comments on stability analysis options and proposed methodology are also provided.CITATION:Wentzinger, B and Armstrong, C, 2018. Lessons learnt in geotechnical investigation and stability analysis for upstream tailings storage facility raise design, in Proceedings Mine Waste and Tailings Stewardship Conference 2018, pp 333–348 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 23, 2018

By T Alexieva

Since the early 1900s the geotechnical community has investigated every significant failure of a tailings dam, improved our knowledge of the behaviour of the tailings storage facilities, developed analysis methods, compiled lessons learned, and committed to zero failures. The rate of occurrence of tailings dam failures has reduced since the 1980s, however, failures continue to occur and continue to surprise us. At BHP, we have decided to take an approach to the tailings management that is similar to the approach to safety. We are looking at ways to eliminate, substitute, separate or engineer around the hazard (tailings dam failure). As such, our ultimate long term goal would be to eliminate the need for new tailings facilities. Unfortunately, we have not developed yet technologies for extracting many of the common metals and minerals without producing tailings. Our shorter term goal is to substitute the current conventional slurry tailings facilities with less risky dryer facilities. We are working with vendors and research organizations to develop technologies that can be efficiently applied on a large scale. At the same time, we are committed to using the best available engineering to reduce the risks associated with our existing and new conventional tailings facilities. The best engineering can be achieved by people with the appropriate education, experience, attention to detail, discipline and authority. We have implemented a system of governance to make sure, we have the best engineering applied to all our facilities, considering the specific conditions at each site.This paper presents the current tailings governance process at BHP, and the initiatives that were undertook towards achieving a zero failure goal. CITATION:Alexieva, T, 2018. Tailings governance, in Proceedings Mine Waste and Tailings Stewardship Conference 2018, pp 2–7 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 23, 2018

By M Barker, H Li

The total number of tailings accidents has reduced from over 50/decade in the 1960s-1980s to less than 30/decade in the 2000s to 2010s. However, the rate of significant tailings dam failures has not been reduced. The significant tailings dam failures the mining industry experienced in the recent history include: Merriespruit, South Africa, 1994; Los Frails, Spain, 1998; Kolontár, Hungry, 2010; Mount Polley, Canada, 2014; and Samarco, Brazil, 2015. The conventional Factor of Safety approach itself may not be enough to further reduce the rate of significant tailings failures due to its limitations such as uncertainty. For example, the same factor of safety could have a vast range of annual probability of failure for different tailings dams, and insufficient consideration of failure consequence. This paper presents a risk based approach for design with the objective being to minimise tailings dam failures, especially those significant tailings failures with high consequence and low probability. This approach includes risk based design and risk management using bowtie tools. In the risk based design, quantitative analysis will be used to estimate the annual probability of failure and the tolerable failure criteria is linked to the consequence category. Bowtie analyses will be used to understand hazards and risks and identify and select independent controls that are effective in preventing and mitigating catastrophic failures. In this paper, examples of risk based design and bowtie analyses are presented and discussed. CITATION:Li, H and Barker, M, 2018. Risk-based approach for minimising tailings dam failures, in Proceedings Mine Waste and Tailings Stewardship Conference 2018, pp 397–414 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 23, 2018

By A Li, H Jinto, M Laxman

The behaviour of tailings under cyclic loading has an impact on the stability and deformation of tailings dams and a good understanding of the cyclic behaviour of the tailings under earthquakes is important for tailings engineers and tailings operators for the design and safe operation of tailings dams. This paper presents an investigation into the cyclic behaviour of tailings using both laboratory cyclic direct simple shear (DSS) testing and numerical modelling. The laboratory testing involved cyclic DSS tests on gold tailings and zinc-copper tailings under different loadings and loading frequencies. The gold tailings specimen tested at a higher loading frequency and a higher cyclic stress ratio experienced spontaneous liquefaction during cyclic shearing and the zinc-copper tailings specimen tested at a lower loading frequency and a similar cyclic stress ratio exhibited ductile behaviour and liquefied due to cyclic mobility. The liquefaction behaviour of the tailings was modelled using an advanced constitutive model (UBCSAND), which was developed specifically to model soil liquefaction and strain softening under cyclic loading. The constitutive soil model presents the nonlinear soil behaviour under dynamic loading using a hyperbolic stress-strain relation. Dynamic analyses were carried out using a finite difference program FLAC. The cyclic stress-induced excess pore water pressures measured in the laboratory were modelled using numerical simulations of the laboratory tests under different loading conditions. The results of the non-linear dynamic analyses demonstrated the capability of numerical modelling of cyclic shearing induced excess pore water pressure and the onset of the spontaneous liquefaction. The laboratory investigation and numerical modelling technique provided the key properties and parameters for the dynamic analyses to assess the stability and deformation of tailings dams under design earthquake events. More importantly, the laboratory tests and numerical modelling provided some insights into liquefaction behaviour of the tailings during earthquakes. CITATION:Li, A, Laxman, M and Jinto, H, 2018. Liquefaction behaviour of tailings under cyclic simple shear testing, in Proceedings Mine Waste and Tailings Stewardship Conference 2018, pp 250–262 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 23, 2018

By D A. Williams, P J. Chapman

The acceptable rate of rise of the tailings beaches on upstream-raised tailings storage facilities (TSFs) is critical to life of mine planning. This is illustrated through a case study in Western Australia presented in this paper. Accurate estimates of expected beach slopes, the maximum rate of rise at which the tailings can be placed, and the dry density that the tailings solids will achieve after deposition (stored density) are required in order to design TSFs that will allow upstream raises to be constructed safely and economically. Where operations have been occurring for some time, these three parameters are able to be measured and can be well-defined. If process plant throughputs are proposed to increase through mine expansion, for example, increasing the rate of rise of the tailings can compromise the potential for upstream TSF raising, thus influencing the viability of such an expansion, the timing for its implementation, and significantly increase costs.This paper outlines how rate of rise can be a key constraint, and that ‘rules of thumb’ that are typically applied may not result in the outcomes they were meant to achieve. An example of an experimental method to justify an increase to the ‘rule of thumb’ ~2.5 m/year limit for gold tailings in a semi-arid climatic setting is discussed, followed by rate of rise modelling that ultimately framed the decision-making process for a mine expansion. The rate of rise modelling method was adopted to carefully distribute tailings deposition across four TSFs, comprising nine separate tailings cells, in order to maintain appropriate rates of rise. The implications resulting from various deposition splits are presented, including the need for expansion. In addition, this paper outlines the effect of rate of rise on the state (density) of the tailings after deposition, and provides commentary on how anecdotally acceptable rates of rise, based on the aforementioned ‘rule of thumb’ of 2.5 m/year may not provide assurance of geotechnical stability through the tailings achieving a dilative state, as has been thought in the past. An example of the influence of rate of rise on the state of the tailings, with respect to air-drying and the critical state line (CSL) for the material, is presented. The data indicate that reducing the rate of rise may allow a higher dry density to be achieved through air-drying (evaporative desiccation), sufficient to move the material from the contractive to the dilative zone (i.e. from above the CSL, to sufficiently below it).CITATION:Chapman, P J and Williams, D A, 2018. The importance of rate of rise in life-of-mine planning of an upstream raised tailings storage facility – a case study, in Proceedings Mine Waste and Tailings Stewardship Conference 2018, pp 350–360 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 23, 2018

By D Liu, M Edraki, L Berry

The presence of clay minerals slows down the settling rate and mitigates compact consolidation efficiency in tailings dewatering. The increasing use of saline water in many plants, affects the dewatering performance and presents the mining industry with new concerns. Efficient tailings dewatering is a great challenge due to the complexity character of tailings, especially clay mineralogy, clay content, and water chemistry. In this study, existing studies of the effect of different affecting parameters, such as pH, ionic strength and polymer flocculants, on clay aggregation behaviours are reviewed. The settling behaviours of three types of commonly observed clay minerals in tailings, kaolinite, bentonite, and illite, are also investigated in saline water with different water salinity as a case study. The settling rates of clay minerals are found to be affected by water salinity, clay type, clay content and polymer dosage levels. High salinity water hinders the settling of kaolinite but assists the settling of bentonite and illite through formation of different aggregation structures.The current work has indicated that strategies to promote more rapid dewatering could include adjusting flocculant type or level, water salinity and salt balance, and tailings solid content levels. Implementing dewatering strategies may require a more detailed knowledge of the effect of surface chemistry on the nature and strength of the clay inter-particle forces. This study discusses the research gaps on how to better manage clay-rich tailings in saline water and identifies new research directions. The development of a water management model, supported through in-line monitoring data to predict and manipulate of the surface chemistry of the clay component of the tailings could be a new direction to manage the issues associated with clay minerals in the process of dewatering and tailings management. Mine planning (water use requirements, operating costs) could benefit from more detailed studies on dewatering of clay-rich tailings in saline water. CITATION:Liu, D, Edraki, M and Berry, L, 2018. Improving the dewatering efficiency of clay-rich tailings in saline water, in Proceedings Mine Waste and Tailings Stewardship Conference 2018, pp 476–484 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 23, 2018

By Y Xu, J Hacker, D J. Williams

Shear strength parameters of compacted clay liners are needed to analyse the stability of mine waste dumps containing compacted clay liners as sealing layers for potentially acid forming waste rock. A representative clay sample was supplied by McArthur River Mine from the mine site in the Northern Territory, Australia, with an average as-supplied gravimetric moisture content of about 13.6%. The clay was compacted in a 100 mm by 100 mm direct shear box at the as-supplied moisture content to a dry density of 1.85 t/m3, representing the field compaction specification adopted by the mine. To determine the peak and ultimate shear strengths of the compacted clay, single-stage direct shear testing was carried out at nominal initial normal stresses of 50 kPa, 100 kPa and 200 kPa, representing shallow depths of burial in the North Overburden Emplacement Facility of about 2.8 m, 5.6 m and 11.1 m, respectively (assuming a waste rock wet unit weight of 18 kN/m3). Three shearing rates of 1 mm/min (rapid), 0.1 mm/min (intermediate) and 0.01 mm/min (slow) were applied to study the influence of shearing rate on shear strength. In addition, the development of a residual shear plane was tested by reversal and re-shearing in the direct shear box. In the first shearing, the peak and ultimate shear strengths are determined. The normal load was then removed and the box rewound to its starting position. The normal load was then re-applied and the specimen re-sheared. Two reversals were applied to each specimen, and it was found that there was no significant reduction in shear strength. Finally, based on a range of shear strengths obtained in the laboratory for McArthur River Mine clay and other materials by various laboratories over time, shear strength parameters for the compacted clay were recommended for use by the mine.CITATION:Xu, Y, Williams, D J and Hacker, J, 2018. Shear strength of compacted clay liner at McArthur River Mine, in Proceedings Mine Waste and Tailings Stewardship Conference 2018, pp 208–219 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 23, 2018

By S M. Gover

Estimating the probability of failure for embankments is not intuitive. It requires not only an appreciation of the strength of the embankment, but an understanding of the variability and uncertainty in the strength parameters as well. These additional aspects are, in themselves, relatively new to most practicing engineers, and therefore require some discussion.This paper discusses the concepts of probability and uncertainty, and presents a reliability-based numerical experiment, together with a literary study and collation of some of the author’s historical slope stability analyses, to investigate whether a direct relationship between safety factors and probabilities of failure exists for certain levels of uncertainty in strength parameters. In doing so, a useful tool is presented whereby knowing the safety factor of a simple slope or embankment with a consistent level of uncertainty, one can infer an approximate probability of failure.CITATION:Gover, S M, 2018. Linking safety factor to probability of failure, in Proceedings Mine Waste and Tailings Stewardship Conference 2018, pp 384–396 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 23, 2018

By W Ludlow, C Harrington

This paper presents an overview of the design and construction challenges to implement capping systems on Tailings Storage Facility’s (TSF) based on recent projects in Australia. Key aspects discussed include the cover design and barrier system to encapsulate the tailings, designing for a service life of 1,000 years, water management considerations. construction on tailings, vegetation selection and agronomy of the available capping soils plus the Health, Safety and Enivornmental challenges faced in working on tailings. Lessons learned from experience in capping TSFs are also presented. CITATION:Ludlow, W and Harrington, C, 2018. Experience with Capping of Tailings Storage Facilities for Decommissioning Projects in Australia, in Proceedings Mine Waste and Tailings Stewardship Conference 2018, pp 157–165 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 23, 2018

By Ozgul Keles, Dila Sivlin

Lithium ion batteries are potential energy source of next generation electric vehicles (EVs). However, some problems such as safety, durability, low capacity, cycle life etc. restrict their use in EVs. These problems mostly related with cathode materials, an improvement in cathode materials may cause significant changes in battery performance. In this work, to overcome cycle life problem Al2O3 coating on LiNi0.5Mn0.3Co0.2O2 cathode material produced by sol-gel method. The surface modification of LiNi0.5Mn0.3Co0,2O2 was started by adding LiNi0.5Mn0.3Co0.2O2 powders into alumina sol. Then, sonication was started and two different sonication powers were tested (45, 100%). After the second gel is obtained, last heat treatment for Al2O3 crystallization was done at 600 °C for 4 h. X-ray diffraction (XRD) measurements showed that the material had a well-ordered layered structure and Al was not in the LiNi0.5Mn0.3Co0.2O2. Al2O3 coated materials show better cycling performance compared to the pristine material. It is believed that, this improvement is caused by the fact that Al2O3 layer prevents direct contact between active material and electrolyte and reducing decomposition reactions.

Mar 1, 2018

By Qiang Guo, Zongliang Zuo, Mengqi Wei, Qingbo Yu, Qin Qin

Activated carbons, derived from waste ion-exchange resin by CO2 physical activation, were applied to separate CO2 from flue gas against global warming. The BET specific surface areas of activated carbons at different activation temperatures and times were investigated. The CO2 adsorption capacity was tested under non-isothermal and isothermal conditions. The experimental results show that when keeping the activation temperature constant, the specific surface area increases firstly and then decreases with increasing activation time. For the given activation time, the specific surface area rises firstly and then declines with increasing activation temperature. The adsorption capacity decreases with increasing temperature. The maximum adsorption capacity is 51.46 mg/g under the condition of 298 K and pure CO2. Fractional order kinetic model is the best one to describe the kinetics of CO2 adsorption. The activated carbons show the potential to be an effective adsorbent for the removal of CO2 from flue gas.

Mar 1, 2018

By Timothy W. Ellis, John A. Howes, Roger D. Feldman

The new generation of more powerful, energy-intensive devices for communications, industrial production, energy storage and other purposes is creating new challenges to guard against environmental harm and protect national security. Many devices are designed, used and disposed of in a linear, rather than circular manner. This causes scientific, legal and economic issues because the life-cycle costs of components are not adequately considered. Dealing with these issues in isolation from each other can lead to unintended consequences. New models to confront these issues are being defined. This paper suggests a fundamental tool for dealing with material science issues while taking into account the engineering, economic and policy perspectives. That tool is the development of a true, levelized cost of energy storage model with a wide spectrum of inputs for comprehensive analysis. This paper will discuss inputs and the process which can yield meaningful, useful comparisons among batteries and energy-intensive products.

Mar 1, 2018

By J. -E. Eriksson, L. Hupa, T. Khazraie

With increased co-firing of coal and different biomasses in power plants, there is a growing need to study and characterize the produced, often heterogeneous ashes and to assess their utilization as secondary raw materials. In this work, we compare different methods for characterizing the ash compositions. These methods include scanning electron microscopy-energy dispersive X-ray analysis (SEM-EDS), X-ray fluorescence (XRF) and inductively coupled plasma emission spectroscopy (ICP-OES). The content of carbonaceous residues in the ashes was measured with CHN Sanalyzer. The methods and the pretreatment required for each of the analysis were studied in detail for three ashes: (1) coal, (2) peat and wood, (3) peat and wood residue with dolomite addition. The limitations of each method will be discussed. This work gives guidelines for selecting a rapid and reliable method for analyzing the suitability of the ash for a particular application.

Mar 1, 2018