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By H. Zhong, S. Wang, Q. Sun

The flotation performance of 2-(benzylthio)-acetohydroxamic acid (BTHA) to diaspore was first evaluated by micro-flotation tests. The adsorption mechanism was further investigated through adsorption experiments, molecular dynamics simulation, zeta potential and X-ray photoelectron spectroscopy (XPS). The results demonstrated that BTHA had a stronger ability to collect diaspore in comparison with another diaspore collector, benzohydroxamic acid (BHA), especially under the condition of weak alkalinity, the flotation recovery can reach 90%. The more negative interaction energy (ΔE) between BTHA and diaspore from molecular dynamics simulation results revealed that BTHA had an easier adsorption ablity onto diaspore than BHA, which matched with adsorption results. The zeta potential and XPS revealed that Al atoms might bond with -C(=O)NHOH by formation of Al-O bonds. Keywords: Diaspore, flotation; adsorption; 2-(benzylthio)-acetohydroxamic acid

Jan 1, 2020

By V. A. Myazin, M. V. Korneykova, A. V. Svetlov, V. G. Minenko, D. V. Makarov, A. L. Samusev

The paper discusses the treatment problem of mine (waste) water for enterprises of the Russian Arctic. The wide range of relevant pollutants, financial resources, the availability of land for the construction of a treatment plant, waste generated during the treatment process are some of the factors controlling current and future process design solutions. All mining operations have adopted water treatment and water quality monitoring solutions, however there is no single approach to the problem and each industry participant operates within the scope of its available resources. The range of existing and emerging methods is extensive — from using constructed wetlands for the deposition of mineral nitrogen compounds in settling ponds, reagent deposition and chemical coagulation in exhausted mine workings, and filtering dams on the surface to retrofitting existing mine drainage treatment plants with the adoption of the electrochemical coagulation process. Methods of wastewater treatment from heavy metals, oil products, and nitrogen compounds are demonstrated in the example of two industrial facilities in the Murmansk region. It was found that the use of electrochemical coagulation provides effective treatment of mine water from NO3, NO2, Ni, Fetotal and petroleum hydrocarbons (the degree of purification from 50.5-99.7%), the use of phytotreatment system provides wastewater treatment from ammonium ions and nitrite ions by 53-84%, nitrate ions - by 22%. Keywords: Industrial water treatment, treatment flowcharts, settling ponds, constructed wetlands, reagent sedimentation, chemical coagulation, electrochemical coagulation

Jan 1, 2020

By A. Chryssoulis, D. Venter, R. Dunne

An often-overlooked parameter of flotation processing is the impact of surface chemistry. Flotation processing, being a heterogenous process is largely reliant upon the chemistry occurring at the interfaces between solid-liquid phases. Development of analytical techniques such as Auger electron spectroscopy, X-Ray photoelectron spectroscopy (XPS) and low energy electron diffractions (LEEDS) has allowed for a dynamic view characterizing surface composition and structures. The advent of ‘static’ systems, capable of measuring ultra-thin layers on surfaces at low concentrations, was the next step in surface analytical developments. In general, it is the low concentrations and fragmentation patterns which limit the analysis of certain chemical species at plant concentration ranges. At present, analysis of inorganic and organic surface modifiers by time of flight mass spectrometers with a variety of ionization techniques has become a common analytical method to measure chemical species on the outermost surface of mineral particles. By studying the relationship between surface analysis results with metallurgical outcomes, the implications of the presence of surface species can be determined. The presence of flotation activators or depressants can be established using Laser Ionization Mass Spectrometry (LIMS) and Resonant Ionization Mass Spectrometry (RIMS) which are highly versatile surface sensitive analytical techniques. A case study applied to sphalerite flotation in the Neves Corvo Cu-Pb-Zn concentrator and the implication inorganic surface modifiers have is presented. By determining the relative concentrations of Cu, Pb, oxidation products, Ca and other surface species in floated and rejected mineral particles, rationale for improving recovery and selectivity is elucidated. Keywords: Cu-Pb-Zn Flotation, Process Mineralogy, Surface Chemistry, Flotation kinetics

Jan 1, 2020

By T. H. Yang, Q. K. Wang, T. Song, J. W. Zhou

The grinding circuit can be one of the most important mineral processing circuits in plants. Along with the application of large-scale milling machines, the design and optimisation of the operation strategy for grinding circuits is more complicated. An in-house grinding process simulation tool was developed to mass balance, model fit and simulate crushing, grinding and classification circuits. An industrial grinding and classification circuit in a copper mine was modelled, and the modelling parameters were verified by a particular group of plant survey data. To justify the prediction ability of the fitted models, the model predictions under different operation conditions were compared with another group of plant survey data. Then the model predicted the effects on the circuit of changing operating conditions. Circuit analysis of the comminution process for water feed to a SAG mill, water feed to sump, the rolling speed of a SAG mill and the percentage of ball filling in a SAG mill was put into practise, based on the simulation results. The simulation results can be used to help plant operators understand the features of the comminution process and may help to build a knowledge library for process control. Keywords: Process modelling, grinding, comminution, circuit analysis

Jan 1, 2020

By S. Soren, K. Deo Mehta, G. Jha

The paper aims to find a sustainable sintering process through cleaner means, in order to achieve the desired outputs with zero environmental impact. At present, sintering has no control over its environmental impacts. These impacts occur when fossil fuels such as coal and coke are used in metallurgical sintering. These fossil fuels are undoubtedly effective in their assigned reducing task, but simultaneously emit about 220 kg of GHGs (greenhouse gases) per tonne of sinter produced. The current attempt has focused on reducing these emission levels by switching from coke to a renewable fuel source such as biomass. Biomass is a cleaner fuel source with a significantly lower emission footprint compared to coke. In the experimental campaign, sawdust and wood-charcoal were used in substitution for coke. Experiments were designed in a progressing substitution to obtain the maximum substitution ability without compromising the sinter properties. Sawdust as raw biomass source optimally substituted 10% of coke. The substitution levels were remarkably higher (30%) for wood charcoal due to its low moisture and high calorific values. A fuel blend with 30% biomass and remaining coke succeeded in producing a sinter with acceptable quality indices. Sinters prepared with or without biomass contribution shared an identical phase transformation and microstructures. In order to to maintain consistency in the process, every effort was made to maintain all operational and process parameters identically, except for the fuelling framework. Keywords: Sintering, sustainable, biomass, GHGs, fuel substitution

Jan 1, 2020

By T. Fraszczak, U. A. Peuker, T. Mütze, O. Ortlepp

Dolomite is a calcium carbonate sedimentary rock that can be found all over the world. In its calcined form it is employed for water treatment or as an additive in iron production. Calcined dolomite is produced at the Wünschendorfer Dolomitwerk GmbH in shaft furnaces (kilns). Because of an expansion of the mined deposit, significantly higher extraction costs were expected. Therefore, the existing upgrading processes for the kiln stone fraction had to be adapted and improved. This paper presents a process optimisation which allows for an increase of the yield of calcined dolomite by 10 % due to a redesign of the crusher circuit and by an additional 5 % due to a comprehensive characterisation of the kiln stone fraction itself. Here the interdependency between the pressure drop in the furnace during calcination and the size distribution of furnace stones was used to increase the amount of fine size fractions in the furnace feed without deterioration of the calcination process. Keywords: Dolomite, crushing circuits, kiln stone production, flowability, calcination

Jan 1, 2020

By E. Govender-Opitz, L. Lelia

The South African mining industry plays a significant role in the economy of the country. Nonetheless, the negative impacts on the environment continue to prevail. In regions where mining exists in proximity to communities, mining activities have led to the disruption of modality. Rural communities are mostly affected as they depend on land use for agriculture to sustain their livelihoods. The conversion of land for mining activities often leaves the communities vulnerable when mines close because of the limited life span of mines. An ongoing discourse focuses on how the mining industry can contribute to sustainable development of the communities in which they operate. Post-mining transformation offers an approach for the mining companies to contribute to sustainable livelihoods post-mine closure by strengthening rural-urban linkages, which ensures inclusive development of both rural and urban areas. The paper employs a case study approach to Richards Bay Minerals and the adjacent rural communities of Sokhulu and Mbonambi. It sets out to understand the post-mining transformation employed by RBM and explore the rural-urban linkages that manifest as a result. Findings show that sand dune rehabilitation employed by RBM is successful in restoring soil fertility and establishing the natural ecosystem. The casuarina planted to rehabilitate the dunes is used to spur an alternative charcoal industry post-closure. The main rural-urban linkages that manifest are flows of people due to job opportunities and flows of goods from the sale of charcoal produced. However, there is a lack of communication and lack of authority to ensure responsible management of the casuarina plantation and equitable sharing of benefits. The paper recommends that other post-mining transformation strategies such as eco-tourism should be explored and that the government, at both national and local level, the community and the mine should be involved to ensure overall success and sustainability of the strategy. Keywords Post-mining transformation, rural-urban linkages, alternative land use

Jan 1, 2020

By D. Kumar, B. Rai, S. G. Srinivasan, V. Jain

Chalcopyrite and pyrite are among the major gold bearing minerals in the world. The gold content in chalcopyrite and pyrite varies from 0.02 to 200 ppm and 0.01 to 20 ppm, respectively. Apart from gold, chalcopyrite is also the primary source of copper. Thus, the recovery of gold and copper are often associated with the recovery of chalcopyrite and pyrite. Flotation is one of the most successful methods applied to beneficiate chalcopyrite and pyrite. The success of a flotation process depends on an appropriate choice of the flotation collector used to achieve the desired selectivity. A thorough understanding of the atomic structure of the predominantly exposed mineral surfaces can immensely aid in developing highly selective collectors that can exploit both the physical and chemical characteristics of these surfaces. In the present study, density functional theory calculations within the plane wave framework are used to understand the surface structure and reconstruction of the most stable chalcopyrite (001), (100), (110) and (112) and most stable pyrite (100) surfaces. The chalcopyrite (001) and (100) metal-terminated surfaces undergo significant reconstruction and result in metal-metal bond formation in the sub-surface layer while the surface layer is replaced by S-atoms. On the other hand, the (001) and (100) S-terminated surfaces show S—S disulfide bond formation upon relaxation, which are consistent with literature reports. The chalcopyrite (110), (112) surfaces and pyrite (100) surface undergo rearrangement, but no reconstructions in terms of metal-metal or disulfide bond formation are observed on these surfaces. Keywords: DFT, surface reconstruction, pyrite, chalcopyrite, adsorption

Jan 1, 2020

By X. Zhang, E. Li, Y. Xiao, Z. Yu, H. Han, J. Xie, J. Tian, W. Sun, K. Hong

In a pulp environment, the surface properties of magnesite and dolomite tend to be similar, due to the re-adsorption of dissolved calcium species, which makes the flotation separation difficult. In this paper, the chelating reagent EDTA is introduced to eliminate the adverse influence of the calcium species and to restore the selectivity of magnesite-dolomite separation using sodium hexametaphosphate (SHMP) as a depressant. Flotation experiments confirm that the recovery of magnesite improves significantly in the presence of EDTA. Zeta potential experiments confirm that the negatively charged EDTA4+ and HEDTA3+ species can form soluble and stable chelates with positively charged Ca2+ and Ca(OH)+ species preventing their adsorption on the magnesite surface. Adsorption measurements prove the addition of EDTA can decrease the adsorption of depressant SHMP on the magnesite surface. X-ray photoelectron spectroscopy (XPS) measurements further confirm the transformation from the surface of magnesite to dolomite in the presence of calcium ions, and the possible adsorption mechanism of EDTA and SHMP on the magnesite and dolomite surface. Key words: Magnesite; Dolomite; Surface dissolution; Flotation separation

Jan 1, 2020

By O. T. Konina, V. A. Masloboev, A. V. Svetlov, E. A. Krasavtseva, D. V. Makarov, A. A. Goryachev

Dusting phenomena have been examined at the tailings storage facility of Apatit JSC Kirovsk, a mining operation located in the far north of the Russian Federation. The material composition of the tailings was identified. Existing dust suppression methods were examined. Field observations were undertaken and official data was obtained from the Murmansk Administration for Hydrometeorology and Environmental Monitoring, and analysed. A database was built for forecasting dusting according to critical scenarios in order to estimate the peak MPCs of suspended solids in the atmospheric air. Mitigation measures were formulated and recommended to the mining operation. Keywords: Mineral dust particles, apatite-nepheline ore concentration tailings, suspended solids MPC, climate change

Jan 1, 2020

By J. Petersen, T. Moyo

Waste Printed Circuit Boards (PCBs) are a metals-rich fraction of electronic waste (e-waste) streams, and globally it has been demonstrated that they can be recycled gainfully to recover the metals. Reported successful cases of PCB recycling are carried out in large volumes, using high-level technology and high capital investment smelter house operations. This presents entry barriers for recyclers in developing economies where capital may not be accessible, and the waste volumes are not sufficient to warrant large scale operations. Hydrometallurgical processes have the potential to provide an option for the scalable processing of smaller volumes of PCBs and can be set up at relatively lower capital costs. However, to date, the hydrometallurgical treatment options available rely on precursor communition and classification processes that also require high capital and energy costs. This paper presents an overview of the work done under the Minerals to Metals signature theme towards understanding e-waste recycling processes and developing pre-processing and characterisation of PCBs in order to unlock potential for local end processing in developing economies, using South Africa as a case study. The structure of PCBs is reviewed, and the current size reduction techniques and the subsequent leaching processes are discussed. Keywords: Printed circuit boards (PCBs), PCB structure, pre-treatment, liberation, ammoniacal leaching

Jan 1, 2020

By I. Zh. Bunin, M. V. Ryazantseva, V. A. Chanturiya

The paper proposes a new method for selective calciferous separation. The effect was achieved through the application of the combination of high-power electromagnetic pulses (HPEMP) and a specific reagent regime of the flotation. The combined application of HPEMP with the special reagent regime allowed for the improvement of the scheelite floatability: the recovery of CaWO4 rises from 41.2 % (untreated sample) to 58.5 (sample treated at 103 pulses). In contrast, the floatability of calcite decreases significantly: the recovery of calcite drops from 74.7% (untreated sample) to 41.1 % (sample treated at 103 pulses). The conditions were found for the selective separation of the minerals with very close flotation properties. Keywords: Calcite, scheelite, flotation, high-power electromagnetic pulses, DRIFT, XPS

Jan 1, 2020

By L. Naude, J. Cloete, S. Engelbrecht

The results of an investigation evaluating whether an industrial plant, currently operating using sodium isobutyl xanthate (SIBX) as primary collector for sulphide minerals (mainly chalocopyrite), could adapt to operate using an alternate primary thiol collector without compromising plant and metallurgical performance. Initial laboratory scale flotation tests identified commercial dithiophosphate (DTP)-based and thionocarbamate (TC)-based collectors, that when blended, showed potential to replace the incumbent SIBX primary PGM collector. Industrial plant trail results show that there was no deterioration in recovery of 4E PGMs, even at a lower concentrate grade when operating the plant on the identified (DTP + TC)-based collector blend compared to SIBX. The effect on Cr2O3 content in the final concentrate was also found to be negligible. The (DTP + DTC)-based collector blend also showed promise in terms of plant adaptability in accommodating a new primary specialty collector blend. These observations highlighted the potential of replacing xanthate primary collectors with alternate thiol collector blends for PGM flotation. Keywords: PGM, xanthate replacement, specialty collector, sodium iso-butyl xanthate (SIBX), dithiophosphates (DTP), dithiocarbamates (DTC)

Jan 1, 2020

By J. W. D. Groenewald, L. Auret, B. S. Lindner, E. C. Nienaber

Mineral processing plants have complicated control strategies, with different control layers, multiple interacting loops, and feedforward disturbance rejection. The complicated control strategies mean that oscillations can arise and propagate to multiple loops and degrade the control performance. Oscillation detection techniques, such as the spectral envelope method, can be applied to detect oscillations within an observation window. However, the start- and end-points of the oscillations within the observation window cannot be identified with current oscillation detection techniques. The start- and end-points would be useful to label the oscillatory intervals, and then to use these labels to identify process conditions associated with the oscillation. In this paper, a pattern recognition technique, Density-Based Spatial Clustering of Applications with Noise (DBSCAN), was used to label oscillation intervals. An oscillation diagnosis workflow combining spectral envelope and DBSCAN was demonstrated on an industrial case study of oscillations in a flotation circuit concentrate sump. The workflow successfully detected the oscillation, labelled the oscillatory intervals, and enabled accurate root cause analysis. The impact of time series features, namely the signal power ratio () and the oscillation frequency, on the performance and optimal parameter selection of DBSCAN was also investigated. Low oscillation frequencies and low s negatively affected the performance of DBSCAN. Additionally, the results indicated that higher oscillation frequency was related to higher optimal values for the lag parameter. Keywords: Oscillation diagnosis, process monitoring, data mining, clustering, flotation control

Jan 1, 2020

By W. Soetaert, P. Dhar, H. R. Kota, M. Thornhill, S. Roelants, I. V. Chernyshova

Yeast-derived bola-amphiphiles have attracted considerable attention for their applications in various industrial sectors in recent years. However, only a few studies on this class of surfactant were reported to be relevant to mineral processing applications. In this paper, one of the novel surfactants, acidic glucolipid obtained from Candida bombicola sophorolipids and modified by using Penicillium decumbens naringinase substrate has been evaluated for its interaction with chalcocite and calcite minerals because of a new Cu-ore Nussir deposit in Norway containing calcite impurity. The interaction of glucolipid biosurfactant with copper sulphide and carbonate minerals was investigated with zeta potential, adsorption and FTIR studies, and also by Hallimond tube and bench scale flotation tests using pure minerals and Nussir copper ore, respectively. The results illustrate collector adsorption and flotation of copper sulfides at neutral pH. The bench-scale flotation results demonstrate that copper sulphides can be selectively floated from carbonate and silicate gangue minerals. This study underlines the glycolipid’s high potential for its use as collector for flotation of valuable copper sulphide minerals. Keywords: Flotation, biosurfactants, adsorption

Jan 1, 2020

By S. T. L. Harrison, J. R. Amaral Filho, M. Smart, J. Broadhurst, J. Weiler

Technosol production from mine waste, following amendment with additional organic residues, to provide healthy and functional topsoil is an advantageous alternative to the long-term dump disposal of mine waste. Minimising the legacy of mine waste and supplying soil for mine site rehabilitation contributes towards more sustainable mining practices. Following the creation of the physicochemical structure of the soil from appropriate mixtures of coal waste with low sulfur content, physical ameliorants and nutrient sources, the inoculation of Technosols with active microbial suspensions may accelerate the decomposition of organic matter present and ensure nutrient availability for plant growth through active nutrient cycling, particularly of nitrogen, sulfur and phosphorous. In this paper, South African ultrafine coal waste was used as the main mineral matrix, and malt residue was used as source of organic matter and nutrients. In order to evaluate the effects of Technosol inoculation, five microbial treatments were used, including the addition of: commercial grade efficient microorganisms (EM Prosoil), anaerobic digested sludge supernatant from treating brewery waste, and ‘tea’ extracts prepared from compost, vermicompost and soil native to the mining area. Growth experiments were carried out using Eragrostis teff, commonly known as teff, a grass typically used for the rehabilitation of mined areas in South Africa. Preliminary results showed that Technosols inoculated with microorganisms performed better in terms of nutrient availability and plant growth. Varied performance was observed as a function of the microbial inoculation applied. This suggests that the inoculation of Technosols with appropriate microorganisms may be recommended to accelerate nutrient availability assisting plant growth during the initial establishing of the Technosols. Technosols continue to show promise as an alternative to both mine waste disposal and the burrowing of topsoils for mine rehabilitation. Keywords: Fabricated soil, mine waste, coal discards, malt residue, nutrient availability, soil microbiology, plant growth

Jan 1, 2020

By M. Krasowska, W. Skinner, R. K. Asamoah

Understanding chemical interactions at solid-liquid interfaces have played a pivotal role in improving mineral flotation performance, increasing the rate of mineral crystallisation and profitable leaching of valued minerals and metals. This paper highlights gold leaching with links to surface and interfacial chemical processes occurring, and opportunities to maximise extraction while reducing usage of more recent scarce resources. From the review, there is a significant link between surface and interfacial processes and gold leaching performance. Evidently, gold leaching kinetics could be increased by changing leaching conditions, including manipulating the surface and interfacial interactions. Control of surface and interfaces during gold extraction could enhance rapid, smarter gold extraction and mitigate formation of passivation layers. Keywords: Surface and interfaces, refractory ores and concentrates, gold leaching, reaction mechanism and kinetics

Jan 1, 2020

By Y. R. Murthy, S. Angadi, A. K. Bhatnagar, S. K. Tripathy, L. O. Filippov

Dolomite is an essential raw material for the refractory industry, a flux in the iron and steel industry and also for the extraction of magnesium metal. Generally, particle size reduction, screening and classification are used for the preparation of the high-grade sized material for different applications, whereas low-grade fine fractions are not utilised. These fines or low-grade overburdens are dumped at the mine site for future utilisation, which creates environmental issues along with inadequate space management. In the present investigation, a detailed study was carried out to decrease the silica content of the low-grade dolomite fines from Gomardih , India, containing 28.6% CaO and 20.1% MgO along with 8.3% silica. Different process flow sheet options were evaluated with a combination of dry classifier, wet classifier, gravity concentrators as well as flotation. Different process variables were assessed along with mineralogical characterisation to optimise the process for efficient rejection of siliceous gangue minerals. Results indicated that dolomite, calcite and quartz are the major mineral phases present in the ore along with other minor minerals. It was concluded that two-stage flotation was an effective process for the reduction of silica up to below 1% after grinding to a particle size below 212 μm. A process flow sheet with a combination of gravitation air classifier and flotation can produce a concentrate with silica content below 4.5%. Keywords: Dolomite, flux, dry classification, flotation, characterisation, beneficiation

Jan 1, 2020

By R. Kuyvenhoven, A. Parbhakar-Fox, X. Prieto, J. Quevedo, L. V. Danyushevsky

This paper presents the results of a study focussed on determining the distribution of cobalt in different types of pyrite of the La Estrella IOCG deposit in Chile. In the IOCG mineral deposits, where copper is the main product, the quantification and distribution of cobalt is required to correctly define the technical and economic viability of recovering cobalt as a by-product. In the La Estrella mineral deposit, seven alteration and mineralisation events were recognised through both optical and automated electronic mineralogical analysis. Of these seven events, five different types of pyrites were identified, each with unique characteristics of the pyrite crystals. Through advanced elemental analysis of these five types of pyrites, it was determined that the concentration and distribution of cobalt within the pyrite crystal is dependent on the mineralisation event. The results indicate high cobalt concentrations in the early pyrite mineralisation events, associated with relatively fine pyrite grains, and cobalt generally occurring in a solid form in the pyrite core. The late pyrite mineralisation event exhibits the lowest concentrations of cobalt, with cobalt predominantly present along the outer periphery of the pyrite. These results are relevant from a metallurgical point of view because the preferential location of cobalt within the pyrite crystal will influence the maximum metallurgical recovery of cobalt. For this, a cobaltiferous pyrite concentrate must be formed which, according to the characteristics of pyrite, must be processed with the optimal solubilisation method. The overall objective is to ensure both good cobalt recovery and a high concentration of cobalt in the leach solution resulting from pyrite leaching. Keywords: Cobalt, pyrite, IOCG, copper, metallurgical recovery, solubilisation, Chile

Jan 1, 2020

By Wei Sun, Ruolin Wang, Wenjuan Sun, Junhao Fu, Haisheng Han, Zhao Wei

Pb–benzohydroxamic acid (BHA) (lead complexes of benzohydroxamic acid) exhibits high selectivity but low collecting efficiency in scheelite flotation. This paper reports the manner in which BHA and sodium dodecyl sulfate (SDS) were employed as ligands to coordinate with the lead ions to obtain a colloidal lead-group multiple ligand complex, i.e., the Pb–BHA–SDS, for improving the collecting efficiency of Pb–BHA. The flotation mechanism of Pb–BHA–SDS with respect to scheelite was investigated from the viewpoint of interface science based on the pure mineral flotation, Fourier transform infrared spectroscopy (FTIR), X-ray photoelectron spectroscopy (XPS), and contact angle measurements. The results showed that the BHA and SDS coordinated with Pb2+ to form novel leadgroup multiple ligand complexes, which are different from the traditional understanding associated with the mixed collectors. Pb–BHA–SDS was a better collector with stronger collecting ability and excellent selectivity in regard to a scheelite flotation than Pb–BHA. The addition of SDS to Pb–BHA enhanced the latter’s adsorption ability on the scheelite surface and improved the hydrophobicity of the collector’s nonpolar groups, rendering Pb–BHA–SDS as a more efficient collector at a low dosage. Keywords: Scheelite; Pb-BHA complexes; sodium dodecyl sulfate; multiple ligands; Pb–BHA–SDS

Jan 1, 2020