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"10.1. IntroductionAs discussed by Westland (1981), the six platinum-group elements (PGE) belong to the Group VIII transition metals, to which iron, nickel and cobalt also belong. The chemical similarity between these nine metals accounts for the fact that they tend to be concentrated together as a result of geological processes. These processes started to effect the distribution of these metals at the very beginning of the earth's history.The first line in Table 1 gives the concentration of nickel and certain other Group VIII transition metals in carbonaceous chondrites, those meteorites with a composition that is believed to reflect best the composition of our planetary system apart from hydrogen and helium. The second line is the estimated concentration of the same elements in the earth as a whole. It is seen that these two estimates are quite similar, the earth being perhaps 2 to 3 times richer in these particular metals than the planetary system as a whole. The reason for this is not fully understood, but it may be due to the earth being formed by the accumulation and capture of a greater proportion of iron (and therefore siderophile-rich) than stoney (and therefore siderophile-poor) planetesimals than the planetary system itself.The third line in Table 1 is the average composition of the crust of the earth. With the exception of iron, all of the Group VIII transition elements are rare in the crust, present at concentrations of It tOO to Itt ,000 of that of the bulk earth. This is because the outstanding chemical characteristic of this group of elements is their siderophile nature; that is, their tendency to alloy with metallic iron. Because of this, once the earth became molten very early in its life history, these elements dissolved in the molten iron present at this stage and were removed from the outer accessible parts as this dense liquid sank to the centre of the earth to form the core. Although iron was the main instrument of concentration of the Group VIII metals, its much greater over-all abundance and its ability to combine with oxygen more easily than the others in the group means that significant amounts still remain in the oxidized portions of the earth.The fact that most of the Group VIII metals are available to use in workable concentrations at all is that they are 5 to 30 times more concentrated in the earth's mantle than the crust, as shown in line 4 of Table I. There has been a constant, if slow, interchange of matter between the mantle and the overlying crust throughout most of the earth's history and, under certain circumstances, this interchange has given rise to economic concentrations of metals."

Jan 1, 1979

By Gunnar Nord, Per-Anders Persson, Duri Prader

The paper gives a short resumé of the findings of the joint US - Swedish "Mechanical Boring (MB) or Drill and Blast Tunneling (DB) ? Workshop" in Stockholm December 1976. New developments and trends in both MB and DB techniques in Europe since 1976 are described, and information is given on some interesting new projects. Differences in contracting principles between the US and Europe lead to different practices for preinvestigations, design, excavation and arbitration and legal affairs. It is shown that this often leads to a higher cost in the US than in Europe for similar excavation jobs. A typical US tunnel job also has more men on the site than a similar job in Europe. This adds to the cost difference and is only partly balanced by a slightly higher rate of excavation in the US. A comparison is made between two quantitative methods of predicting MB penetration rates. These are in reasonable agreement. A probable future development in machine design is an increase in cutter load towards perhaps 25 tons per disc where the tunnel diameter is large enough to house the machine size dictated by the size of the very large electric motors required. Recent European developments in drill and blast technique include improved methods for cautious blasting, precision hydraulic drilling of small diameter holes, and non-electric interval blasting techniques. These developments still keep the drill and blast method ahead of mechanical boring costwise for tunnels in igneous rock whereas for most sedimentary materials mechanical boring has a lead, particularly for long tunnels.

Jan 1, 1979

By Garland R. Dever, Preston McGrain, George W. Ellsworth

Limestone resources for industrial, constructional, and agricultural uses occur on the surface and at minable depths in several areas along the Ohio River and its navigable tributaries in Kentucky. High calcium and high carbonate limestones suitable for use in cement and lime production, steel manufacture, environmental control measures, and other special uses are present in the High Bridge Group (Ordovician) and Warsaw and Ste. Genevieve Limestones (Mississippian). Deposits with thicknesses of 7.3 to 20.7 m,(24 to 68 feet) have been documented by the analysis of samples taken at 0.3-m (1ft) intervals. Active and potential mine and quarry sites afford access to water transporation and proximity to a number of industrial and metropolitan centers. Geologic factors affecting the distribution of deposits include the Cincinnati arch, regional dip into the Appalachian and Eastern Interior basins, complex faulting in and near the western Kentucky fluorspar mining district, and late Paleozoic erosional unconformities in northeastern Kentucky.

Jan 1, 1979

By Frederick W. DeVries

Since we first agreed to present this talk we have learned that some of you may have been covering ground we intend to discuss: Bob Schechter, Daryl Tweeton, Don Seidel, Herb Burgman; however, the ideas were original when we began, "novel" as in the title of the talk, and whether our results are news or merely corroborative, we feel they point a direction that could be valuable to all. We worked with many of you in the past on using hydrogen peroxide in in-situ uranium leaching. Our talk today is not directly related to peroxide; it is, I hope, illustrative of Du Pont&apos;s interest in providing service to this industry in any way we can. The scouting work we are presenting was stimulated by field inputs: First, ammonium carbonate leaches cause restoration problems, primarily because ammonium ions exchange on clays with calcium. Second, sodium carbonate solutions, especially in South Texas deposits, can cause intolerable swelling of clays. From discussions with Dr. van Olphen, who wrote the book on clay chemistry, we inferred by comparison of the radii of the hydrated ions of the elements in these clay systems, that since potassium had about the same radius as ammonium, and sodium was much larger, potassium occupied a unique position to solve both problems. We have shown: FIGURE 1 Potassium bicarbonate systems leach uranium without loss of permeability found with sodium Potassium salts are very effective in restoring ammonia-leached sites Before reviewing the details of our work, which was performed by Hazen Research, Inc., I should like to stress its scouting nature. We are trying to assist the in-situ industry by pointing out new, potentially important directions. But, as with our previous work on sodium silicate to restore permeability, we feel the development phases can generally best be carried out in cooperative programs with companies directly involved with operations. DISCUSSION Test Parameters Now for the details: Our leaching tests were designed to note pressure-drop changes across the ore sample as the uranium was leached. Figure 2 shows the apparatus. The [ ] packed length was 20.5 inches (52 cm) with fifteen hundred grams of ore in the two-inch (5 cm)-diameter bed. Pressure drop was measured by manometer and feed rates were maintained constant with a tubing pump. The samples, from a South Texas leach site, were sealed in "Zip Loc" bags, frozen with "dry ice", crushed (still frozen) through six mesh, and blended before placement into the columns. The ores analyzed as shown here: FIGURE 3 Ore Analyses [Sample A Sample B U308 015% 0122% Mo 0004% 0086% Se0012% <0001% Fe3,078%076% Fee- 098% 044%]

Jan 1, 1979

By D. D. Downing

This paper is a review of material selection considerations concerning protective coatings in the mining industry. The discussion will cover both capital-dollar projects and maintenance requirements. Emphasis will be on industrial finishes for structural steel and process equipment subjected to aggressive atmospheres. The presentation will cover the total needs of a job, emphasizing not only the owner&apos;s requirement for a cost-effective system during plant operations, but also taking into consideration the short-term requirements of general contractors, steel fabricators, erection firms and paint contractors.

Jan 1, 1979

By Håkan Stille, Kjeld Boye-Møller, Lars Lundström

BACKGROUND Forsmark Power Station is a nuclear power plant under construction at the Baltic abt 120 km north of Stockholm. Investigations on the Site were started in 1969. Areas were reserved for a maximum of 6 units of which the buildings for two of them, Unit 1 and 2, were nearly finished in 1976, when the investigation for Unit [3], here presented, was carried out, cf Fig. 1. [ ]

Jan 1, 1979

By John D. Morton, J. H. LaVerne Palmer, Douglas J. Belshaw

An extensive programme of ground instrumentation and observation was carried out for the West Duff in Outfall Sewer tunnel project prior to and during construction, to establish the performance characteristics of the rock through which the tunnel and appurtenant openings were dug and to examine the nature of the lining-to-ground interaction. The existence of high horizontal residual ground stresses was confirmed, and values established by overcoring. Rock deformations and stress changes were monitored during tunnelling. Permanent stress and strain monitoring devices were set into the final lining and these are continuing to operate. INTRODUCTION The site is located on the north shore of Lake Ontario at Pickering, some 20 miles (32 kilometres) east of Toronto, Canada where a variable thickness of glacial or interglacial sediments overlies bituminous shale bedrock of. the Collingwood Formation which is lower Ordovician age. Approximately 50 feet (15 metres) of glacial cover exists at the shaft, though this thins abruptly at the regressing cliffed shoreline such that several small areas of exposed bedrock exist in the lakebed. The general location, overall geological section and detailed site plan and profile are illustrated in Figs.1,2 and 3 respectively. General properties of the rock as established during an extensive test drilling and site investigation programme are listed in Table 1, while stress determination by USER overcoring stress meter device are given in Table ll. These data formed the basis of analyses which were done to examine the intended outfall design, and to detail the construction procedure and the observational instrumentation programme.

Jan 1, 1979

By K. D. Hester

This paper will review the metallurgical aspects of the completed expansion program at Quirke, and the current rehabilitation and refurbishing program at Panel. During the Quirke program, completed at the end of 1977, the plant capacity was increased from a nominal 4,500 to 7,000 short tons per milling day. The expansion of crushing, grinding, neutral thickening and filtering, leaching, partial neutralization, sand-slime separation, sand washing, C.C.D., clarification, ion exchange, mine water treatment, and tailings neutralization and pumping will be considered. The application of Enviro-Clear thickeners in the mine water treatment circuit and in the C.C.D. will be briefly reviewed. An automatic grinding and classification circuit for limestone will also be covered. The refurbishing program underway at Panel will be discussed. The Quirke and Panel plants will be contrasted and compared. In particular, reference will be made to environmental considerations. The innovative system for producing yellow cake at Panel, LAMIX, will be considered as well as the proposed treatment system for Panel tailings.

Jan 1, 1979

Mitsui Aluminium Co. of Japan announced that it would finance 25 percent of the construction costs for the 217,000 ton-per-year primary aluminum smelter being built by Alumax, Inc. at Holly, SC. Mitsui would receive 25 percent of the plant&apos;s production in return. Construction on the smelter began early in 1978, and is scheduled to be completed in 1981. The Aluminum Company of America (Alcoa) announced plans to restart a third potline at its Point Comfort, TX primary aluminum smelter in July. The company previously announced plans to restart two potlines at the facility in May. Reynolds Metals Co. began preparations to restart primary aluminum production in May in one of two 57,000 ton-per-year potlines at its Corpus Christi, TX smelter. The plant has been closed since 1975.

Jan 1, 1979

By R. J. Lytle

INTRODUCTION Prior to excavation in soil and rock, it is useful to know the subsurface structure. This is important information both for safety and for equipment scheduling reasons. It is useful to know whether parts of the subsurface might be potentially troublesome or of different character than is generally thought present. By using geophysical probing, it is possible to infer the location and size of these unusual regions. The ground structure is commonly estimated from core samples taken from boreholes. These cores give a detailed knowledge of the structure in the borehole. However, knowledge of the structure exterior to the borehole can only be extrapolated from core data. By using seismic and electromagnetic cross-borehole geophysical probing, remote probing can be used to sense the region exterior to boreholes. A recent advance has significantly improved the state-of-the-art for defining the ground structure between boreholes. This new procedure utilizes large amounts of data and provides a detailed picture of the subsurface. The data processing algorithms used are similar to those in medical imaging of the human body using x-rays, a science called x-ray tomography. This imaging of the ground is called geotomography, which is a shortened acronym for geophysical tomography. Several examples of geotomography applied to imaging ground structure are presented. Our approach has been to probe the ground with electromagnetic and seismic waves. We map the region of interest with signals transmitted between multiple source and receiver pairs lowered in boreholes on opposite sides of the region (Figure 1). The received signals vary according to the transmission properties of the media

Jan 1, 1979

By Mehmet Guney

This article is based on a detailed heat investigation conducted at the Rokana Division of Nchanga Consolidated Copper Mines Limited while both authors were employed in Zambia. Mindola Mine is one of the three underground mines comprising the Rokana Division on the Copperbelt of Zambia, producing about 270,000 tons of ore per month at 1.9% Cu and 0.14% Co. The total volume of air being circulated by means of five primary fan installations slightly exceeds 1,000 m3/sec at standard density. Sectional bulk cooling is practised where air cooling coils are installed at primary splits some considerable distance from the stoping operations. Total capacity of the refrigeration complex is 10,500 kw (3,500 R. tons), of which about 7,000 kw is available as effective cooling power after losses, but the heat removed from the coifs is about 3,500 kw with 61% over-all plant performance. An extension program is planned for a further five production levels with the re-deepening of a sub-vertical shaft. Thermal heat will become a major problem at increased depth associated with higher rock temperature, higher thermal conductivity of the rock groups encountered and fissure water flowing into working areas through the strata with increased rock temperature. This paper describes the ventilation and refrigeration practices in Mindola Mine, with special reference to future thermal heat problems. These are discussed with a view to mining at depth.

Jan 1, 1979

This status report contains 39 individual reports on health and safety research projects now being conducted or recently completed by the Bureau of Mines. The Reports on health research cover industrial hygiene, respirable dust, ventilation, noise control, and radiation hazards. The safety research reports cover industrial hazards, ground control, fire and explosion prevention, and methane control. Each report includes background information, a discussion of research progress, and an assessment of each project&apos;s current status.

Jan 1, 1979

Anaconda Aluminum Co. began production from a new 60,000-ton-per-year potline at Sebree, KY, which brings the total capacity of the plant to 180,000 tons per year. A strike by workers at Alcan Aluminium Corp. primary aluminum smelters at Arvida, Que., Isle Maligne, Que., and Beauharnois, Que. shut down the plants and the company announced force majeure on part of its ingot supply commitments. Kaiser Aluminum and Chemical Corp. announced plans to increase its price for primary aluminum from 60.0 cents per pound to 63.0 cents per pound effective July 1.

Jan 1, 1979

By B. W. Smee

Glacial lake sediments or glaciolacustrine deposits form a significant portion of the Canadian, Scandinavian and Russian landscapes. Furthermore, 50 per cent of the Archean volcanic belts within the Canadian Shield area are covered wholly or in part by these deposits. Because of the high electrical conductivity and low hydraulic conductivity of these compact sediments, the application of geophysical (electrical) and geochemical techniques in such areas becomes a difficult task. The presence of these sediments has therefore hampered exploration for metallic sulphide deposits in some of the most important metallogenic environments of Canada. Similar problems exist in some tropical countries, such as Australia, where the overburden may be very conductive. In this paper, the extent and provenance of the glaciolacustrine deposits within the Canadian Shield are described. The geochemical and geophysical factors that hinder exploration in the clay belts are reviewed, with case histories of successful and unsuccessful applications of some of these techniques. The most successful geochemical technique used within glacial clay belts is the sampling of lodgement till beneath the clay cover, and the analysis of the heavy mineral fraction of that till. Surficial sampling has not been successfully applied. Some geophysical techniques, more specifically electromagnetic and magnetic induced-polarization techniques, have detected mineralization beneath substantially deep clay or saline overburden layers. Some suggestions have been made, such as the use of anions in hydrogeochemical surveys and the use of wide-band multi-frequency EM systems. When implemented, they will hopefully make the current geochemical and geophysical methods more effective in exploration for base metal sulphides within clay-covered terrains.

Jan 1, 1979

By R. Lusignea

This report describes the development of a device for the nondestructive testing of resin grouted roof bolts by means of mechanical frequency response. Various alternative methods were evaluated and the mechanical frequency response method was selected. An interactive program of design, testing, and development culminating in the current prototype instrument demonstrated the capabilities of the method and suggested potential applications of the instrument. The resin bolt testing device utilizes a swept frequency dynamic compliance measurement in the 1 to 2 kHz range which is interpreted by an electronic signal processor to give a "GO" or "NO GO? readout. Field tests have shown that the device can reliably determine the bond quality of the front half of the bolt (nearest the roof surface). Tests were carried out on both experimentally installed bolts and typical mine bolts installed by a conventional bolting machine. The development program has led to recommendations for improvement of the prototype and future development work.

Jan 1, 1979

By Karl E. Starch

This Bureau of Mines report is a background study of severance taxes on mineral production. The rates, bases, and other features of State severance tax legislation as of March 1978 are presented, as are the amounts of State severance tax collections for fiscal year 1977, Some statistical comparisons between severance tax collections, total State tax collections, and total value of mineral production in the States involved are presented to portray the relative importance of severance taxes both in State tax revenue systems and in mineral industry revenues. A general discussion of the purposes and principles of taxation, the unique nature of a mining enterprise, the various types of taxes imposed on mineral production, and the character and rationale of the severance tax and its impacts on mining firms sets the severance tax in perspective. A bibliography of materials on the severance tax is included.

Jan 1, 1979

Norton Co., the world&apos;s largest producer of abrasives, is enlarging its proppant operation. Proppants are strong chemical particles used to wedge open rock formations in deep oil wells, thereby increasing the well flow rate, sometimes as much as tenfold. Norton" aluminum oxide-based proppant is rapidly displacing less durable materials. The company is building the world&apos;s largest proppant plant in Fort Smith, AR. ALUMINUM--See also REFRACTORIES The price of primary aluminum ingot was increased by several producers in July. Kaiser Aluminum & Chemical Corp., and Revere Copper & Brass Inc. increased the price of primary aluminum to 63.0 cents per pound, effective July I. Reynolds Metal s Co., Anaconda Aluminum Co., Howmet Aluminum Corp., and Marti n Marietta Aluminum Inc. increased the price of 99.5% primary aluminum ingot to 63.0 cents per pound, effective July 5, The Aluminum Company of America increased the price of aluminum ingot to 62.5 cents per pound, effective July 9. The range of prices at the end of the month was 58.5 to 63.0 cents per pound.

Jan 1, 1979

By T. H. Jeffers

To help maintain an adequate supply of minerals to meet national, economic, and strategic needs, the Bureau of Mines investigated the feasibility of extracting copper from coarse native copper ore with ammoniacal ammonium carbonate solution by a simulated in situ leaching procedure. A 5.9-metric-ton (6.5-ton) sample of minus 30.5-centimeter (12-inch) conglomerate-type ore analyzing 1.96 percent copper was leached in a column for 556 days with a solu-tion that contained, in grams per liter, 2.2 NBs and 1.9 CO[3=]. The copper extraction was 71.4 percent, and reagent consumptions were, in kilograms per metric ton of ore, 1.1 NBs and 0.85 CO[3=] (in pounds per ton of ore, 2.2 NH3 and 1.7 CO[3=]). The pregnant leach solutions contained about 1.4 grams per liter copper, which was readily extracted from these low-tenor liquors with a 1:19 mixture of an organic extractant and kerosine. Copper was stripped from the loaded organic with depleted electrolyte containing 150 grams per liter H2S04, and the copper was recovered by electrowinning with antimonial lead anodes. Conditions also were established for minimal lead transfer to the cathode copper.

Jan 1, 1979

By H. M. Friede

A short survey is given of the Iron Age smelting sites and smelting furnaces that have been found in South Africa. An attempt is made to classify South African smelting furnaces by the inclusion of functional characteristics such as the numbers and positions of tuyeres. An affinity is suggested between the Venda (eastern Transvaal) type of furnace and an East African type. The principles of the smelting process in South African Iron Age furnaces and the characteristics of the smelting products are discussed. Results of metallographic and chemical analyses of 19 iron specimens found at South African sites are given and compared with those from sites in Zimbabwe-Rhodesia, Mocambique, and Nigeria. The carburization and steeling of iron during primitive smelting and forging are discussed.

Jan 1, 1979

By W. D. Bonisteel

In 1976, Rio Algom Limited began the expansion of uranium production facilities at Elliot Lake. Quirke Mine was the only property in operation at the time, and plans were made to expand its milling capacity from 4,500 to 7,000 tons of ore per day. Following this expansion, other properties in the area will be reactivated to fulfill long-term contracts for uranium. As part of the expansion program, it was decided that in view of the escalating cost and impending shortage of energy, heat reclaim and conservation would be employed wherever practicable. In general terms, heat reclaim applications fall into three main classifications: ventilation, utility and process. Two of the ventilation applications and one process application will be described in some detail. Several other systems will be presented briefly as a matter of general interest. Some future possibilities will also be mentioned, together with their potential for economical heat recovery.

Jan 1, 1979