Search Documents

By Q. Xiao, R. Naidu, W. Li, S. Song

Acid mine drainage (AMD) derives from the oxidation of sulfide minerals, primarily pyrite (FeS2), and is the most severe environmental issue facing the minerals industry. The most common short-term approach to AMD treatment is migration control, such as acid neutralization and metal/metalloid and sulfate removal, through the addition of alkaline materials, including lime (Ca (OH)2), limestone (Ca CO3), gangue minerals and industrial wastes. This requires the continuous input of materials and may result in the production of a vast amount of secondary sludge requiring further treatment and disposal. Addition of chemicals is usually more important in metal/metalloid removal than in sulfate removal unless the sulfate is present in very high concentrations. A more promising long-term strategy for AMD prevention is source control through the complete removal of pyritic minerals and encapsulation of potential risk minerals by coating with impermeable surface layers. This is regarded as the most cost-effective approach, although the mechanisms underpinning this and the implementation procedures are yet to be fully elucidated. It is likely that long- and short-term practices can be combined to optimize the remediation of contaminated mining sites. Some factors such as differing geological and mineralogical characteristics and transportation costs must also be considered for the successful implementation of AMD prevention and remediation strategies. This review also considers some implications for AMD remediation, but the promising bioremediation of AMD is not discussed as it has been extensively reviewed.

By M. P. Filion, K. Ferguson, L. L. Sirois

Acidic drainage is the largest single environmental problem facing the Canadian mining industry today. Technologies to prevent acidic drainage from occurring in wasterock piles and tailings sites, and on the walls of open pits and underground mines, need to be developed and demonstrated. There are two groups in Canada which have accepted this challenge: the national Mine Environment Neutral Drainage (MEND) program and the British Columbia Acid Mine Drainage (BCAMD) Task Force. This paper summarizes the activities of these two organizations.

Jan 1, 1990

By J. A. Murray

Maintaining satisfactory air quality in electro-winning tankhouses has been problematic and costly, particularly as plant operating current densities have increased. Conventional approaches, including the use of beads, hollow spheres, surfactants and coalescer devices, have not proved completely effective, requiring that powerful ventilation systems be installed. As workplace and environmental regulations become more stringent, containment of the acid mist at its source is more attractive. An electrode cap system based on this approach has been developed and tested in two commercial copper electrowinning tankhouses. The design, development, installation and cost of the new electrode cap system are described.

Jan 1, 1996

By Irshad A. Rana

In a modern copper smelter, the capital cost of a sulfuric acid plant constitutes the largest single cost item of the total investment. It is thus essential to properly size the acid plant in order to reduce its capital cost and enhance the economic viability of a new smelter project. Whereas the off-gas from a smelting furnace is continuous and generally uniform, the gas flow from the Peirce-Smith converters is intermittent with significant fluctuations. The converters off-gas volume is dependent upon a number of interrelating factors. The most significant factors are the matte feed grade, the system air infiltration, the converter's size and blowing rate, the maximum number of converters simultaneously blowing and the gas cooling system employed. The acid plant size, therefore, is heavily influenced by the converter off-gases. Several of these factors are discussed, and their impact in determining the acid plant size is explored.

Jan 1, 1993

By Walter R. Hibbard

Precipitation in the northeastern United States, Florida, California and in many industrialized areas of the world is now more acidic (lower pH) than can be accounted for by natural causes. At the same time, the acidity of many lakes and streams in the northeastern United States has been measured and found to be similar to that of actual rain. These facts have led to conclusions that the two conditions are related. Coal burning utilities, 700 to 1000 miles upwind, have been accused of being the cause, leading to proposals for strict emission controls on the alleged offenders. The costs of these controls would place an estimated $10 to $15 billion capital burden on utility customers in about 15 states plus $2 to $6 billion annual operating costs. There appears to be no direct well-established scientific evidence that the accused are guilty but that the indictment is based largely on circumstantia1 evidence. This study examines the evidence, describes the situation and proposes what must be done to reduce the acid precipitation in an orderly cost beneficial manner. It is interesting to observe that studies by the different adversaries on the acid precipitation issue come to different conclusions largely because they do not read the same literature, but selectively develop evidence to support their own points of view, This study will try to review the issues impartially and reach a position of scholarly balance.

Jan 1, 1982

By Rosa G. de Pena

From the MAP3S Precipitation Chemistry Network data bank five years of data from January 1, 1977 to December 31, 1981 have been analyzed. No definite trend has been observed in the concentrations and the total depositions in the analyzed period. Comparison between the weekly and event samples show that the weekly samples could underestimate the total deposition. Preliminary results show that there is a reasonably good correlation between the precipitation composition and the emissions feeding the air in which the precipitation is formed.

Jan 1, 1983

By Michael Sheedy

Sulfuric acid is widely used as an electrolyte for the electrorefming and electrowinning or metals. Impurities in this electrolyte are controlled by continuously bleeding solution from the tank house. In addition to the contaminant these bleed streams contain high levels of sulfuric acid and the metal being recovered. Subsequent treatment of these bleed streams often requires neutralization which generates large volumes of solid waste. Absorption resin technology employing a novel ion exchange technique known as Recoflo® allows the separation of the mineral acid from dissolved metal salts. The recovered acid is suitable for recycle back to the electrolyte circuit. The metal salt and other contaminants leave the process free .of the sulfuric acid. In this process, known commercially as the APU®, ion exchange resin is used to sorb sulfuric acid while excluding the metal salts. The purified acid is then removed by washing the resin with water. The process has been extensively used for the recovery of waste pickling acids in the steel industry and anodizing solutions in the aluminum industry. In the mining and metallurgical industries the process has been successfully evaluated for the separation of excess sulfuric acid from copper electrolytes, the removal of magnesium and manganese contaminants from zinc electrolytes, and nickel and copper from copper electrolytes. A full scale installation on a copper refinery bleed stream at Palconbridge's Kidd Creek plant in Timmins, Ontario has now been operating successfully for more than 1 year while pilot field trials have been successfully completed on other applications.

Jan 1, 1997

By F. Baerhold, S. Mitterecker

"Acid recovery is an important process step in pickling and leaching processes. Pyrohydrolysis in spray roasters and fluidized beds is a well-established technology to recover hydrochloric acid, but the hydrolysis in the liquid phase is more and more considered as an alternative new process route. The characteristic features of these three processes will be discussed along with select industry trends. For example, hydrochloric acid based leaching processes for ilmenite and nickel laterite ores produce far larger volumes of waste acid streams than the steel industry. Scaling-up of the spray roasting technology to the highest possible capacity is necessary in order to become more cost effective. In addition, process routes based on ferric chloride pyrohydrolysis allow the production of super-azeotropic HCl (up to 30 wt.%). Finally, the new ECOmode concept optimizes the operation of both pickling lines and the spray roast acid recovery plant. Long term results from industrial applications show that fuel savings in the spray roaster of 25% are easily achieved without additional process steps. An attractive feature is also to upgrade existing installations to higher plant capacities.INTRODUCTION Pyrohydrolysis is the conversion of metal halides into metal oxides at elevated temperatures in the presence of water vapor. Reaction products are a hydrogen halide gas and a metal oxide. The process was originally developed and introduced into the market by ANDRITZ Ruthner in the 1960’s. It has found wide technical application in the field of acid recovery and oxide production. The introduction of this process has revolutionized pickling technology. The use of hydrochloric acid has strongly increased over the last decades, since pyrohydrolysis is available for the total recovery of waste pickle liquors from mild steel pickling, as illustrated in Figure 1.Chloride media are also used increasingly in the metallurgical industry. Oxide production processes for Mg, Co, Ni, and Al have been installed. Processes using hydrochloric acid are known for the leaching of ores as well as for the re-extraction of metals from organic solvents. In both cases the recycling of HCl is of substantial importance to achieve highly economic processes and to reduce waste."

Jan 1, 2016

By A. Davis, K. Nelson, C. Webb

Abandoned mines in parts of the Black Hills of South Dakota have the potential for acid rock drainage. For this work, ten sites were examined on Black Hills National Forest land or on private land whose drainage could affect Forest Service land. Water samples from all the sites had pH values less than 6. Results of analyses from water samples and rock samples showed a correlation between metals content and pH. Acid-base accounting was used to determine acid drainage potential of the sites. One site (King of the West Mine) had a high potential for acid generation; fortunately, little or no surface runoff leaves the mine site. Six sites appeared to have moderate potential, including the Minnesota Ridge Mine, which currently is being remediated. Three of the sites had low acid drainage potential.

Jan 1, 2004

By Z W. Orndorff

Excavation through sulfidic geologic materials during construction activities has resulted in acid rock drainage (ARD) related problems at numerous (>40) locations across all five geologic regions of Virginia, USA. Potential acidities ranging from >100 to develop a statewide sulfidic materials risk map; document ARD impacts to soil and water quality and engineered structures; and develop methods to assess site-specific risk potentials within a given highway corridor. A statewide sulfidic materials GIS risk map was developed based upon the state digital geology map which assigned four levels of relative risk to all mapped strata based upon predicted lime requirements and probabilities of encountering highly reactive materials. Non-highway construction activities have also routinely disturbed sulfidic materials, and a recent airport project in northern Virginia resulted in over 150 ha of extremely acidic (pH 45 mg/L) run-off from this site heavily damaged a receiving stream, partially due to the fact that it dissolved the galvanised steel water control structures in stormwater detention basins, leading to direct discharge of run-off and sulfidic sediments. The airport area was treated and revegetated in 2002 with a combination of lime-stabilised biosolids, straw mulch, and acid-tolerant grasses. Water quality in a receiving second-order stream quickly responded to the treatment, but some release of N was also noted as a secondary effect. Collectively, these results point out the importance of accurately assessing the potential for excavation of sulfidic materials in construction environments, and the necessity of developing toxic materials handling strategies similar to those employed in mining environments.

Jan 1, 2003

By R Carreau

The results of a detailed acid rock drainage (ARD) prediction program were used to revise the waste rock segregation criteria at the Restigouche open pit mine. Waste rock at the site was predominately derived from altered volcanic rocks that hosted a massive sulfide lead/zinc orebody. The program assessed the five years of drainage chemistry from both the potentially acid generating and the non-acid generating waste rock storage facilities in addition to laboratory-based kinetic test results. Material-specific leaching characteristics including relative metal-release rates and neutralisation potential depletion rates were determined from 12 laboratory-based kinetic tests. Solid-phase analyses indicated that, although pyrite was typically the most abundant sulfide mineral in the waste rock, its abundance varied significantly as documented by total sulfur contents ranging from 4.0 per cent. Kinetic test results were used to establish revised waste rock segregation criteria based on total sulfur content and neutralisation potential. The revised criteria maintain that waste material with a total sulfur content 4.0 per cent as potentially acid generating. When present in sufficient quantities, ankerite provided an effective source of neutralisation potential for the range of observed sulfide oxidation rates. Kinetic testing documented that up to 6 kg CaCO3/t was ineffective at neutralising acidity in samples that contained >4 per cent S. The carbonate molar ratio measured from the humidity cells was adjusted to reflect the stoichiometry of the ankerite and applied as an NP/AP criteria for waste rock containing 0.1 <S per cent <4.0.

Jan 1, 2003

By H Barrie, L Ameglio

"Current methods for acid rock drainage (ARD) mitigation revolve around insulation of the waste from oxygen in the atmosphere with water and dry (soils and liners) covers. Both are of limited effectiveness and present significant drawbacks. Furthermore, while they reduce oxygen influx, they reduce but do not prevent ARD.The inert gas mixture (IGM) technology has been designed to overcome the deficiencies of gas transfer into tailings and waste rock materials across the surface and instead block oxidation by controlling the transfer of oxygen from the atmosphere. Inert gas is injected into the mine waste at low flow rates and the positive but low flow purges the oxygen that tends to diffuse into the sulfide waste across the surface. The positive flow of IGM compensates for inward oxygen diffusion and creates a pressure drop across the cover layer preventing inward diffusion of oxygen and, hence, acid generation.The IGM processes are evaluated in this paper: theoretically, with a review of the theory of ARD and the current state of knowledge about the performance of notably dry covers as atmospheric oxygen barriers via models to predict the performance of the IGM technique practically, with a bench-scaled experiment.The results demonstrate the effectiveness of IGM to prevent oxidation of sulfide minerals and ARD in waste rock. The laboratory experiments further identified key variables to be used to monitor performance and control efficiency of IGM, which is now awaiting field-scale application.The IGM technology is a patented process by Terraquest Technologies Ltd (Canada) in USA, Canada and Australia. The IGM technology can be cost-effectively manufactured on-site with commercially available compressors and gas filtration membranes. It is predicted that low-cost covers can then be utilised with IGM, which in turn lowers the overall capital costs of ARD mitigation.CITATION:Ameglio, L and Barrie, H, 2015. Acid rock drainage prevention using inert gas mixture technology, in Proceedings Tailings and Mine Waste Management for the 21st Century, pp 85–96 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Jul 27, 2015

By N Murphy and, S Santomartino, M Cramer

Acid rock drainage (ARD) can have detrimental effects on mining infrastructure, water reuse options and environmental discharge. As a result, some form of short- or long-term treatment is required at many mine sites. Successful treatment depends on a number of factors including the selection of an appropriate treatment technology and its correct implementation. A variety of passive and active technologies are available for dealing with ARD. Passive treatment solutions do not require continuous chemical inputs but take advantage of naturally occurring chemical and biological processes. They are often low cost, site specific approaches and are predominantly used in post-closure situations. Passive systems are well suited to drainage with low acid loads and low soluble aluminium concentrations, and are more effective with highly reduced (ie low oxygen) water. While they are often regarded as permanent fixes, most require some form of ongoing maintenance and all have an engineered life expectancy (ie finite carbonate and organic matter budgets). Passive treatments include, oxic limestone drains, anoxic limestone drains, limestone diversion wells, various reducing and alkalinity producing systems, pyrolusite limestone beds, aerobic and anaerobic wetlands, permeable reactive barriers (organic ¦ carbonate and zero valent iron), slag leach beds, and gas redox and displacement systems (GaRDS). Active treatment solutions require a continuous or semi-continuous activity (eg reagent dosing) to correct water quality issues. They can be engineered to treat virtually any type of drainage or site specific ARD issue, and have no set acid load or redox limitations. Tasks handled by active treatment systems are almost invariably larger and more costly than for passive systems. Active treatment approaches include; pH control, adsorption/absorption, ion-exchange, electrochemical concentration, biological mediation/redox control, flocculation/filtration and crystallisation. A range of generally available and proprietary technologies has been developed around these approaches. Active treatment involving pH correction with alkaline amendments is the most common and cost-effective form of ARD treatment. A variety of fixed plant and portable treatment systems are available. Calcium-based reagents, including quicklime (CaO), hydrated lime (Ca(OH)2) and limestone (CaCO3) remain the reagents of choice for the majority of active ARD treatment worldwide. This is principally due to their widespread availability, non-proprietary nature, and variety of proven dispensing technologies and cost-effectiveness. Limestone, in particular, is a very low cost reagent. However, due to æefficiency of useÆ problems with limestone in passive treatment systems, combined with its very low cost, there has been a recent emphasis on developing active treatment systems that use limestone efficiently. As the requirement for treatment increases, there is a growing emphasis on treatment sludge management and sludge stability. The final choice of a suitable treatment technology is dependent upon water chemistry (eg pH, type of metal contamination, acidity), flow rates, acid load, local natural resources (neutralising materials, topography), climate, site logistics, environmental risk and economics. The benefits and limitations of both passive and active treatment technologies are summarised.

Jan 1, 2003

By M. Gomo, L. S. Mokhahlane

"Underground coal gasification (UCG) is an unconventional mining method that converts coal in situ into a fuel gas that can be used for electricity generation. Residue products from UCG have the potential to leach into surrounding groundwaters. The geochemistry and leaching dynamics of these products are explored in this study. The products include char, ash, and the heat-affected zone in the surrounding rocks. Core samples from the pilot plant at Majuba are the first ever to be recovered from a UCG cavity in Africa, and they give key insights into the geochemistry of the gasification zone. Mineralogical and chemical analyses were performed on the samples, and acid-base accounting (ABA) was used to predict the acid-producing capacity of the gasification zone, particularly for char samples. Some of the char contained pyrite, although not all samples were acid-producing as determined by the ABA analysis. The ABA results showed that some of the unburned coal has moderate levels of sulphur, which could be the driving medium for acidic conditions. The ABA analysis indicated that water in contact with the gasification zone would eventually have a pH lower than 7, which could lead to acid rock drainage. These results form part of a preliminary investigation into the geochemistry of the reaction zone, post gasification. IntroductionUnderground coal gasification (UCG) is an unconventional mining method that converts coal in situ into a fuel gas that can be used for industrial purposes, including electricity generation. The gasification process leads to the formation of a cavity composed of char, rubble, and void space (Bhutto, Bazmi, and Zahedi, 2013). Residue products from UCG have the potential to leach into groundwater. These products include char (devolatilized coal), which can generate acid rock drainage (ARD). ARD is caused by the oxidation of sulphide minerals, which acidifies the leachate, thus increasing the solubility of some environmentally toxic metals (As, Cd, Hg, Pb, Zn, etc.) (Bouzahzah et al., 2015).The main source of ARD is oxidation of sulphide-bearing minerals due to interactions with oxygen, water, and microorganisms (Simate and Ndlovu, 2014; Kefeni, Msagati, and Mamba, 2017; Bouzahzah et al., 2015). Although ARD occurs naturally, it can be enhanced by mining activities that escalate exposure of sulphide minerals to water, air, and bacteria (Simate and Ndlovu, 2014). At the Majuba pilot plant, the unburned coal remaining in the cavity has been in contact with groundwater since the gasifier was shut down in 2013. It is possible that in a commercial UCG plant, most of the coal will be consumed and no unburnt coal will be left in the cavity. Most of the sulphur will be converted to H2S during the gasification process and transported with the syngas to surface, where it can be removed and captured as elemental sulphur."

Oct 1, 2018

By J. Simmons, P. Ziemkiewicz

Acid-Base Accounting (ABA) is an analytical procedure that provides values to help assess the acid-producing and acid-neutralizing potential of overburden rocks prior to coal mining and other large-scale excavations. This procedure was developed by West Virginia University scientists during the 1960s. After the passage of laws requiring an assessment of surface mining on water quality, ABA became a preferred method to predict post-mining water quality,and permitting decisions for surface mines are largely based on thevalues determined by ABA. In order to predict the post-mining water quality, the amount of acid-producing rock is compared to the amount of acid-neutralizing rock, and a prediction of the water quality at the site (whether acid or alkaline) is obtained. We gathered geologic and geographic data for 56 mined sites in West Virginia, which allowed us to estimate total overburden amounts, and values for maximum potential acidity (MPA), neutralization potential (NP), net neutralization potential (NNP), and NP/MPA ratios for each site based on ABA. These values were correlated to post-mining water quality from springs or seeps on the mined property. Overburden mass was determined by three methods, with the method used by Pennsylvania researchers showing the most accurate results to actual overburden mass. A poor relationship existed between MPA and post-mining water quality, NP was intermediate, and NNP and the NP/MPA ratio showed the best prediction accuracy. In this study, NNP and the NP/MPA ratio gave identical water quality prediction results. Therefore using NP/MPA ratios, values were separated into categories: <1 should produce acid drainage, between 1 and 2 can produce either acid or alkaline water conditions, and >2 should produce alkaline water. On our 56 surface mined sites, NP/MPA ratios varied from 0.1 to 31, and six sites (11%) did not fit the expected pattern using this category approach. Two of eight sites with ratios <1 did not produce acid drainage as predicted (the drainage was neutral), and four of 40 sites with a ratio >2 produced acid drainage when they should not have. These latter four sites were either mined very slowly, had non-representative ABA data, received water from an adjacent underground mine, or had a surface mining practice that degraded the water. In general, an NP/MPA ratio of <1 produced acid or neutral drainage sites, between 1 and 2 produced mostly alkaline drainage sites, while NP/MPA ratios of >2 produced alkaline drainage with a few exceptions. ABA is a good tool to assess overburden quality before surface mining and to predict post-mining drainage quality after mining. The interpretation from ABA values was correct in 50 out of 52 cases (96%), excluding the four anomalous sites, which had acid water for reasons other than overburden quality.

Jan 1, 2003

By William M. Schafer

Mining projects which contain sulfide mineralization face increasing regulatory hurdles due to environmental concerns over acid rock drainage (ARD) and the ability of long-term reclamation to protect water quality. Among regulatory agencies, much of the perception about sulfide projects has been based on conditions at historic mining sites at which little or no effort was made to control ARD. With proper design measures, ARD production can be greatly reduced or eliminated. The science of ARD prediction and control must be expanded to enable mine planners to anticipate the effect of various facility design options on ARD potential. Some common-sense examples of geochemical prediction techniques and mitigation measures for waste rock dumps, spent ore heaps, and mine pits are described.

Jan 1, 1992

By H. Bouzahzah

Sulfidic tailings, subjected to atmospheric water and oxygen action, can generate acid mine drainage (AMD); which is the most important environmental problem facing the mining industry. AMD generating potential can be assessed by the static tests which consist of a screening method where the neutralization potential (NP) and the acid-generating potential (AP) of a given rock sample are determined. The AP and NP are determined separately in the different static test existing procedures which can be divided into two distinct classes: chemical and the mineralogical methods. For some chemical method, the AP is calculated on the basis of total sulfide sulfur content in the sample which may overestimate its AP if significant quantities of non-sulfide sulfur species are present (e.g. organic S in coals, some sulfate as gypsum, barite, etc.). However, the mineralogical method evaluates the AP by the sum of the individual sulfides participation on acid generation based on their concentration within the sample and can be more accurate than the chemical method. For AP calculation, the Paktunc (1999a) mineralogical static test takes into consideration all sulfide minerals occurring in the sample. However, it does not take into account the rates of acidity production of these sulfides submitted to weathering conditions. So, the present study focusses on the modification of Paktunc AP calculation by considering the acidity production rates of these minerals. To reach this objective, five base-metal sulfides (pyrite as reference, chalcopyrite, sphalerite, arsenopyrite, galena), diluted within quartz (25?75 wt.%) simulating mill tailings were subjected to a kinetic test to evaluate their AP. The results show that all the studied sulfides minerals generate acidity at different rates, so the Paktunc?s equation for AP calculation has been adapted accordingly.

Aug 1, 2013

By S. H. Ash

NO MORE important question has come before the coal-mining industry in many places, especially in the anthracite region of Pennsylvania, than prevention of stream pollution by mine drainage. Available information on acid mine drainage in the anthracite region of Pennsylvania indicates that a pollution problem must be solved in any program of anthracite mine drainage. The major problem concerns satisfactory disposal of the daily average mine-water discharge of 327,000 gallons per minute (g. p. m.), or 472 million gallons per day (g. p. d.), containing a free-acid load of 431 tons or a total acid load of 934 tons a clay as H2S04. This report indicates the scope of the problem and gives some suggestions concerning its solution.

Jan 1, 1951

By R. J. Pugh

The surface chemical sites on several fillers (quartz, feldspar, calcite and granite) were studied by the adsorption of well defined acid and basic probe molecules (benzoic acid, benzyl alcohol, ethyl benzoate, pyridine and benzyl amine) from cyclohexane. The results provided a wide variation of adsorption data, emphasizing the extensive range of site heterogeneity on the filler surfaces. In addition, it was shown that the acidic probes were strongly adsorbed on all of the minerals, thus indicating that the basic surface sites dominate the acidic ones. Also, through FTIR studies with vapor-phase probes adsorbed on orthoclase, it was possible to identify the nature of specific sites and the type of bonding occurring between the filler surface and the probe molecule. These types of surface analytical techniques could give useful information for predicting the adsorption functional groups on dispersants, dyes, thickeners, etc. and could lead to enhanced interfacial bonding between the filler and the matrix.

Jan 1, 1993

By R. J. Pugh

In addition to directly analyzing the surfaces of minerals using high vacuum instrumentation methods, some important surface properties of mineral fillers can be determined indirectly by using reactive chemical probe molecules. This technique enables the strength and the number of the surface reactive sites to evaluation and this type of information is useful in predicting interfacial behaviour of minerals. One method of classifying these surface sites is by using Lewis acid/base theory and this type of approach could enable one to predict the adsorption of functional groups in dispersants, thickeners, pigments, etc. Also the adhesion of polymer matrices to the filler surface may be improved.

Jan 1, 1992