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By S Grant, S Emeric, P Baker, E Jones, D Clark

As we strive for a sustainable and resilient future, repurposing assets has become a top priority. In Australia alone, we have a significant number of mineral projects in the pipeline, extensive existing operations, and over 50 000 legacy sites. Collectively, this presents a unique opportunity to be a world leader in mine rehabilitation. Complex stakeholder landscapes, inflexible policies, aged regulatory frameworks, technical uncertainties and increasing liabilities are all barriers hindering effective transition of legacy assets. The impetus for change is further catalysed by shifting consumer preferences, workforces in flux and regional Australians questioning what the transition means for their local community. We need innovative approaches to take a leading role in the industry and support global efforts more broadly. Co-designing an ambitious, shared vision spanning projects, operations and legacy assets with all key parties is a fundamental step to unlock and realise maximum societal, environmental, economic and reputational value. Serious play and gamification can further enhance this visioning process.

Aug 2, 2023

By D. Roy Eccles

A multi-element geochemical response, with contrasts of up to 29 times background, was obtained in soil above the Mountain Lake Diatreme, northwestern Alberta. The overall geochemical signature is indicative of an ultramafic source; geochemical responses contain elevated concentrations of Co, Cr,O, Cu and Ni with the presence of high Ba, Ga, HI, PO,, Rb, Ta, Ti and light rare earth elements suggestive ofa kimberlite or lamproite body. The shape, or morphology, of the enzyme leach-based geochemical signature over the Mountain Lake Diatreme combines moderately strong to strong oxidation halos, or a rabbit's- ear geochemical profile, with a sharply-defined apical geochemical profile. Because some Alberta diatremes discovered to date form positive topographic highs, the resultant geochemical signature may express the soil development profile that forms directly on top of kimberlitic and lamproitic bodies. The enzyme leach technique, which has proven to be a useful tool in base metal, precious metal and petroleum exploration, may have a significant impact on exploration for kimberlite, lamproite and related rocks in Alberta by providing industry with a useful and cost effective tool to probe blind and/or buried anomalies identified by airborne and ground magnetic surveys in areas of glacial overburden.

Jan 1, 2001

By Jeffery Denit, Steve Hoffman, Van Housman

The Environmental Protection Agency (EPA) is in the early stages of developing a national mining waste program. Our goal is to develop a mining waste program that will be state implemented, multimedia in nature, flexible, utilize and enhance existing state programs, and protect the environment. The Agency appreciates the cooperation the mining industry is providing through its participation in the Policy Dialogue committee on Mining and by providing the Agency with technical data. The following is a discussion of what led to the development of a national mining waste program, the agenda initiative to evaluate Toxic Substances Control Act authority in phosphate manufacturing, and the important steps being taken through the Policy Dialogue process to frame and discuss issues. EXTRACTION AND BENEFICIATION OF ORES The Resource Conservation and Recovery Act of 1976 (RCRA) and subsequent amendments created a framework for the regulation of hazardous wastes under Subtitle C and nonhazardous waste under Subtitle D. In 1978, initial regulations were proposed for hazardous waste management units under RCRA. These identified a universe of special wastes that were large volume, low hazard and less amenable to Subtitle C control techniques. EPA noted that waste materials from the "extraction, beneficiation and processing of ores and minerals m fit these criteria. In October 1980, Section 3001 of RCRA was amended. This Bevill amendment excluded solid waste from the extraction, beneficiation and processing of ores and minerals from regulatory control under RCRA's hazardous waste Subtitle C. This was done pending a report to Congress and a regulatory determination regarding the Subtitle C status of these wastes. Thus in November 1980, EPA published an interim final amendment to the RCRA Subtitle C regulations to reflect the Bevill amendment. RCRA requires EPA to perform studies and make reports to Congress regarding the management methods and potential hazards of managing waste. RCRA also calls for a regulatory determination regarding whether Subtitle C (hazardous) or D (non- hazardous) controls are warranted for these wastes. In December 1985, EPA submitted a report to congress entitled, “Wastes from the Extraction and Beneficiation of Metallic Ores, Phosphate Rock, Asbestos, Overburden from Uranium Mining and Oil Shale." In that report, EPA found that some mining wastes exhibit hazardous characteristics, that the range of risk from mining waste is broad, and that waste management practices have caused environmental damage. In July 1986, EPA published a regulatory determination based on information gathered in the 1985 report to Congress and comments from interested parties. In the report, EPA concluded that RCRA Subtitle C regulation of extraction and beneficiation wastes was unwarranted because mining wastes tend to be disposed of in arid climates, waste volumes are high, and facilities and wastes are located in sparsely

Jan 1, 1992

By V. E. Housman

EPA's Office of Solid Waste (OSW) is developing a program, under Subtitle D of the Resource Conservation and Recovery Act (RCRA) to regulate the management of non-coal mining wastes. In May 1988. OSW produced a "Strawman", which is a working document that is precursor to a proposed rule. OSW has been working closely with environmental groups, industry, and States to solicit comments and feedback on the mining waste program. OSW currently plans to release a second "Strawman" in early 1990. A proposed rule is tentatively scheduled to be published in the spring of 1991.

Jan 1, 1990

By Matthew Geary, Stephen J. Marino, Jordan A. Schreiner

"INTRODUCTION Project Overview The Southeast Collector (SeC) is a new 15km long 3.0m internal diameter wastewater tunnel designed by Hatch Mott MacDonald (HMM) that twins the existing 2.6m diameter York-Durham Sewage System (YDSS) tunnel. Both sewage tunnels are located north of the City of Toronto in Ontario, Canada. The SeC provides much needed conveyance capacity for the rapidly growing York Region population, supporting development until 2036 and increasing sewage system security (Hatch Mott MacDonald and AECOM 2011). Construction of the SeC will also permit flows of the twinned section of the YDSS to be bypassed in order to clean, inspect and carry out any essential maintenance within the YDSS tunnel. Although owned and operated by York Region, the SeC spans two regional municipalities beginning upstream from the intersection of Ninth Line and Rouge Bank Drive in the City of Markham in York Region to the downstream Finch Avenue and Valley Farm Road intersection in the City of Pickering in Durham Region. See Figure 1 for the SeC and YDSS alignment. The project includes 19 shafts and chambers with depths ranging from 8 to 48m in addition to seven facilities supporting the operation and maintenance of the sewer. The construction contract was awarded to Strabag Inc. in July 2011 for $291M CAD. Construction Management services were provided by a joint venture team of Hatch Mott MacDonald and AECOM. Existing York-Durham Sewage System The YDSS tunnel was completed in 1979 and was constructed using an open shielded TBM with ribs and lagging temporary support, followed by installation of a 380mm thick unreinforced cast-in-place (CIP) concrete final lining. The YDSS sewer system has numerous connections that accumulate flows from various urban areas within York Region. The section of the YDSS twinned by the SeC flows under gravity conditions and had been putting a strain on the municipality’s potential for population and development growth having reached its maximum capacity of 420 ML/d. According to the York Region’s Water and Wastewater Master Plan, the existing YDSS would not have been able to handle wet weather flows past 2016 (Genivar and XCG Consultants 2009). The dependability of this section of the YDSS is also of concern because it is the main and critical connection between the sewer systems upstream and the downstream Duffin Creek Water Pollution Control Plant (WPCP)."

Jan 1, 2016

By Tapas Kumar Mukherjee, Sujit Kumar, Sanjay Kumar Singh

This paper dwells on the epic blast conducted at Tata Steel’s captive coal mine in India and the insights drawn from it. Optimal blast design parameters had to be ascertained for operating benches (6.56 yards (6 meters) to 16.40 yards (15 meters)) where shovels and mining pay-loaders are deployed. Better fragmentation and suitable muck profile with controlled vibration levels were the pre-requisites. The landmark blast was carried out at Quarry-AB, West Bokaro on 17th March 2017. The colossal blast was done with 275 US ton (250 tonnes) of explosives poured down 1074 drill holes of 6.5 inch (165 mm) diameter. This blast is unique from the perspective of vibration control as it was conducted near local villages situated beyond 546 yards (500 meters) but within 601 yards (550 meters)) from the blast site. The entire array of preparatory activities had been successfully and impeccably executed within the same day. The optimization was achieved through meticulous coordination between TSL team, M/s Solar and M/s IEL. When a rock is blasted, numerous interactions occur among granular particles which are impacted by rock mass properties, explosives properties, blasting geometry and the detonation timings. Optimized use of resources requires a better understanding of these interactions. Extensive field studies have shown that blast fragmentation and suitable muck profile influences the performance of downstream processes in a mine. Consequently, profitability of whole mining operation can be greatly improved through optimized fragmentation. For arriving at the best blast geometry, several blasts were conducted with differing ‘burden and spacing’ design and charging pattern at various loading benches of the mine. Eventually, the largest ever blast was successfully carried out. This accomplishment is the culmination of the insights derived, confidence built, and expertise evolved through a progression of larger blasts conducted earlier (202 US tons (184 tonnes) and 143 US tons (130 tonnes) respectively) by the same team. All blast parameters were within the recommended level and no adverse impact on nearby structures was evidenced. In-the hole VOD of different explosives was determined and placement of boosters was standardized. The signature blasts were conducted to optimize the delay interval between the holes in a row and between the rows. Blasting parameters were fine-tuned in alignment with the desired fragmentation level and muck pile profile conducive to smooth and expeditious loading and hauling by mining HEMM. Rock fragmentation analyses were carried out using photo-analysis system. The insights gained from this blast would serve as the cynosure for planning and carrying out more such blasts with highly optimized parameters in the future with the intent of improving mining efficiency and productivity

Jan 1, 2019

By KOKOWSKI J., RUDZIŃSKI Ł.

The LUMINEOS network was established in 2013 to monitor mining-induced seismicity in Legnica-Głogów Copper District (LGCD), located in south-western Poland. Since the starting time, the network was improved and today consists of 17 seismometers and 10 accelerometers. Up to now, the strongest recorded earthquake in the region had Mw4.0. Both raw seismic data and earthquakes catalog for events recorded by the LUMINEOS network are fully open and available on the EPISODES platform (https://tcs.ah-epos.eu/#episode:LGCD). During the last 7 years, the network improvements gave us a possibility to increase location accuracy for shallow mining events. This accuracy is influenced by factors such as the configuration of seismic stations, noise level at seismic stations, and the influence of the velocity model. Here we encountered two main issues which are worth to discuss. The first one is the low detection threshold of two seismic stations and their significant impact on the location errors. The second one is the large uncertainty in the S-wave picking. Even though S-waves are not so clearly visible on seismograms, they are very helpful in the estimation of source location and strength of seismic events in the region. In our work, we present the history of LUMINEOS network and corresponding improvement on location accuracy as well as the influence of noisy stations on the error distribution and how it is connected with location results. We also investigate the effect of the S-wave phases and how they are related to the accuracy of the earthquakes locations in the network.

Apr 26, 2022

By James D. Bennett, David L. Passmore

The Coal Mining Section of the National Safety Council has selected hand and finger injuries of coal miners as a major topic for safety policy analysis [Tinney, 19851. So that facts about hand and finger injuries can be used to guide the Committee's work and the work of policy-makers, we present in this paper detailed analyses of the following factors related to hand and finger injuries received by coal miners between 1975 and 1983: occupations of the injured miners; activities of the miners when injured; machines involved; objects, substances, exposures, or bodily motions that produced or inflicted the injuries; principal physical characteristics of injuries; and events directly resulting in the injuries. We analyze hand injuries for underground and surface mines separately because of the remarkably different production methods and hazards evident in these two operating environments. We do not, however, provide information about hand and finger injuries that occurred in surface operations at underground sites (such as yards, shops, or tipples), auger mining operations, culm banks, dredging operations, mill or preparation plants, offices, or laboratories. The most comprehensive information about the safety of coal mining in the United States is assembled by the Health and Safety Analysis Center (HSAC) of the Mine Safety and Health Administration of the United States Department of Labor. Mine operators in the United States report to HSAC all injuries as required under Part 50, Title 30, of the Code of Federal Regulations (mandated by Section 103 the Federal Mine Safety and Health Amendments Act of 1977, Public Law 95-164). These regulations stipulate that injuries must be reported within ten days of their occurrence on a United States government data collection form, Mine Accident, Illness and Injury Report (MSHA Form 7000-1). HSAC maintains these data primarily to produce federally-mandated reports. HSAC resolves injury reports that are incomplete, checks for errors in data coding and handling, and corrects inconsistencies in data submitted by

Jan 1, 1986

By Ashis Bhattacherjee, Bijay Mihir Kunar

A literature review on quantitative analysis of mine safety studies revealed that investigators use a wide range of statistical techniques for the analysis of mine injury data. Researchers have addressed the various issues of accident causation and prevention through analysis of mine injury data collected from mines. These studies are generally based on historical accident/injury data without considering the injured person/population at risk. In this paper, a public health approach, based on scientific methods of epidemiology, is presented to address mine safety issues. Epidemiology is the scientific study of disease and injury patterns among populations in time and space. Originally, epidemiology was concerned with epidemics of communicable diseases. Then it was extended to non-communicable diseases. Safety researchers found that epidemiologic methods are the best tools for injury research, because the occurrences of injury and the occurrences of disease are quite similar. As a result, some researchers started applying this concept to injury research. This paper presents some of the techniques used in epidemiologic studies and illustrates the application of a case-control study design to evaluate the role of some risk factors associated with injuries in underground coal mines. In this study, the injured persons were identified and, simultaneously, interviews were conducted to find the significant risk factors responsible for occupational injuries in coal mines.

Jan 1, 2011

By R M. Briggs

Kapowai Caldera Complex (KCC), located 10 km west of Tairua (eastern Coromandel Peninsula), is a late Miocene composite collapse caldera, formed during eruption of several small and large volume andesitic rhyolitic ignimbrites. Numerous epithermal Au-Ag mineral deposits and associated alteration zones at the KCC are related to caldera (rhyolite lava domes, intracaldera faults) or regional structures (faults). The main epithermal deposit exposed in the central KCC is associated with an E-W striking structural boundary fault that cuts the Welcome Jack rhyolite dome. Propylitic (calcite - chlorite) and sericitic (quartz - sericite) alteration haloes surround this deposit. Sporadic zones of sericitic alteration are also exposed within and on the margins of the Bulls Run rhyolite dome complex. Epithermal systems post-dated emplacement of these rhyolite domes, but were controlled by them. Propylitic alteration of ignimbrite in the floor of the Kapowai and Kauaeranga valleys is related to the major NE-trending Kapowai Fault which extends SW to south of Thames. Alteration along this fault pre-dates alteration associated with the rhyolite lava domes. Numerous sericitic and propylitic altered welded ignimbrite, rhyolite and andesite lava lithic fragments have been sampled from intracaldera ignimbrites, and although no direct source is known, they infer the presence of buried epithermal systems. Repeated epithermal activity at the KCC is inferred by the exposed epithermal deposits/alteration zones and the older buried geothermal systems. Silicic caldera volcanoes are considered to be critical volcanic environments for epithermal Au-Ag mineralisation in Coromandel, but are highly variable and need detailed stratigraphic, structural, petrologic, and geophysical studies to characterise them.

Jan 1, 1999

By Mike Perkins

The Summitville Au-Ag-Cu district in the southeastern part of the San Juan volcanic field has been a major gold producer in Colorado. Mineralization is hosted by the composite South Mountain quartz latite porphyry volcanic dome, which is believed to have been localized by the intersection of the northwest margin of the Platoro-Summitville caldera complex and the northwest-trending Platoro fracture zone. K-Ar age dates indicate that alteration and mineralization were nearly contemporaneous with emplacement of the dome at 23-20 m.y. ago, 6-7 m.y. after collapse of the Platoroo-Summitville caldera complex. The dome consists of at least four major phases including strongly altered quartz latite porphyry; a late-mineral, coarse-grained sanidine quartz latite porphyry; and postmineral quartz latite dikes. The dome was emplaced into intracaldera rhyodacite and andesite. Gold-silver-copper mineralization is concentrated near the top of the dome and is associated with pods, pipes and steeply dipping tabular zones of silicification and advanced argillic alteration. Alteration is zoned outwards from the center of mineralization through argillically and propylitically altered rocks, and is largely confined to the area of the dome. Trace element geochemical patterns for the deposit indicate a central zone of anomalous As-Au-Pb-Ag and low Mn within an exterior zone of anomalous Ag-Au-Pb-Hg and high Mn. The chief ore mineral is native gold which is associated with goethitic iron oxide in the oxide zone. In the sulfide zone, native gold is associated with copper sulfide-sulfosalt mineralization. A genetic model for the Summitville deposit is based on recent models of modern geothermal systems, with which it shows similarities in alteration, ore mineralogy, zoning, and structural patterns.

Jan 1, 2013

In the last 40 years, New Zealand has developed a number of liquid- dominated geothermal steam fields, for electricity generation and indus- trial process steam. New technologies were developed, and in this work, New Zealand led the world. The policy of full publication of the results, in a wide range of sciences, provided a reservoir of detailed data defin- ing the geology, size and shape, and the chemical and physical regime, of many geothermal fields and their constituent parts. The discovery of precious and base metal deposits /precipitates in geothermal drill cores and steamfield equipment, suggested a clear link- age with epithermal mineral fields in general, and with that of the Coromandel (Hauraki) Region in particular. Further work on geothermal/ epithermal relationships have implied that the techniques, developed to obtain an understanding of geothermal fields, could be applied also to epithermal mineral exploration. This work is developing fast, and is now proceeding in many coun- tries. Future work may show that the presumed relationship between geothermal and epithermal deposits may be applicable in the wider con- texts of all hydrothermal deposits, and possibly in many other minera- lised areas with volcanic "country rocks".

Jan 1, 1988

By Peter Halbach

Within the frame of the German-Indonesian cooperative Bandamin research project two short cruises (7 station days each) were carried out which led to the Flores-Banda basin located north of the active volcanic arc. This basin is part of a large island-arc subduction-collision system resulting from a complex plate tectonic situation in which three major plates collide with each other. The eastern part of the Sunda-Banda convergent margin also includes the transition from subduction of oceanic lithosphere to collision of the Australian continental crust with the arc. This transitional part is cut and displaced by various large obliquely striking fault systems. Thus, the south eastern and eastern arc segments represent geological conditions which are suitable for the development of hydrothermal convection and potential mineral precipitation. Our study area lies north of the transitional section between Flores and Wetar. We started with a high-resolution bathymetric mapping of 240 km2 in a region some 36 km north of the island of Lomblen. A small submarine neovolcanic ridge was discovered striking approximately NW-SE and consisting of several submarine volcanic structures. In the northwest of the study area, the active subaerial Komba Volcano (Batu Tara) marks the youngest continuation of the ridge system examined. From the ridge we collected fresh and hydrothermally altered volcanics with disseminated sulfides (pyrite, pyrrhotite, markasite, and chalcopyrite), together with ferrugenous gossans.

Jan 1, 2004

By D. R. Spears

The U.S. Bureau of Mines has had an ongoing interest in developing new reagent schemes for floating Stillwater, MT, chromite ore. Previous reagent schemes have been unsuccessful in achieving complete separation, primarily because little is known about the surface chemistry of the minerals in this ore. In order to design a rational reagent scheme, a study of the binding of various functional groups (R = -H, -OH, -CO2H, -NH2) on the two components (chromite and forsterite) of the Stillwater chromite was undertaken. Electron Paramagnetic Resonance (EPR) Spectroscopy was used to determine the adsorption isotherm, from a cyclohexane solution, of spin-probes which contained the functional group of interest. This was complemented by studies of the saturation surface coverage of the spin probe on the two minerals. In each case, more sites existed on chromite than forsterite; however, the forsterite sites were more strongly binding for each functional group. The results are discussed in terms of their implications for flotation.

Jan 1, 1994

By Barbara J. Arnold

The Electric Power Research Institute (EPRI) and six EPRI-member utilities are sponsoring research to define relationships between coal properties and coal handling behavior. Deratings and outages caused by plugged chutes or bunkers or frozen coal can cost utilities millions of dollars annually in lost energy production as well as in manpower to restore coal flow. There is also the added expense of maintaining redundant equipment to assure a continuous coal feed to the boiler, a common practice for utilities. Over the past two years, researchers at CQ Inc. and Iowa state university have collected and analyzed coal samples to develop a coal handleability index for utilities to use when specifying coals for their power plants. These coal samples cover ranges in ash content, rank, grindability, size distribution, and moisture content--properties that affect the handling behavior of coals. Other properties, such as the washability and ash composition, are measured as well. Over the remaining two years of the project, all of these analyses will be correlated to handling behavior, measured using a triaxial shear tester that determines the strength of a coal under compression. An index will be developed and validated at host utility power plants.

Jan 1, 1991

By Nei Bongiorni Alff de Freitas

O uso de velocidade de onda sônica tem ganhado espaço na estimativa de resistência à compressão uniaxial (UCS) por ser um método mais barato, rápido e não destrutivo em comparação com o método tradicional. No entanto, por ser uma correlação empírica, as equações de correlação geradas variam muito quanto a precisão e necessitam serem aferidas para cada nova localidade geológica estudada. Com o objetivo de alcançar correlações mais precisas, esse artigo utiliza um maior critério de seleção das amostras. Arenitos e conglomerados criteriosamente selecionados resultaram em uma forte correlação com R2=0,99. Dessa forma, se constatou que quanto mais específica for a litologia selecionada, melhor é a correlação obtida.

Oct 30, 2017

By Brett P. Spigarelli

To meet the growing need for CO2 capture and storage technology, Michigan Technological University is researching CO2 capture and storage using alkali solutions1. Without implementing emission controls, world energy emissions will rise from 29.7 billion t in 2007 to 42.4 billion t in 2035. The first objective of the project was to determine the optimal amount of alkali in solution for CO2 absorption. This was accomplished using theoretical equilibrium calculations and experimental absorption data for alkali solutions of 1, 2, 3, 4 and 5 weight %. As the % alkali in solution increased, so, too, did the ionic strength of the solution. Theoretical calculations took into account the effect increasing ionic strength will have on the solubility of gaseous CO2. The calculations assumed negligible formation of H2CO3, constant temperature and constant pressure. In the experimental setup, a 16% CO2 /balance air gas mixture was bubbled through an Erlenmeyer flask filled with an alkali solution. The gas exiting the flask was fed to a gas analyzer to record the % CO2 in the exhaust gas stream. The % CO2 absorbed was taken as the % CO2 in the exhaust gas minus the % CO2 in the feed. Theoretical calculations found that as the % alkali in solution increases, the solubility of CO2 decreases. This was verified by experimental data, which found that a 2% alkali solution, by weight, was the ideal solution for CO2 absorption. Current research is focused on using the 2% alkali solution for permanent storage of CO2 via mineral carbonation to produce a value-added product.

May 1, 2012

In parallel work, the cyanide/silver impregnated activated carbon system was studied for the purpose of developing an alternate cyanide removal system. It was found that free cyanide can be reduced from 20 ppm to below 10 ppb with a fixed bed of silver impregnated activated carbon, since such cyanide removal might be applicable to gold mill effluents, the investigation was extended to the cyanide/gold impregnated activated carbon (GIAC) system. Batch tests were conducted varying the gold content of activated carbon, carbon/CN ratio, stirring speed, pH of the initial solution, and the reaction temperature. The adsorption isotherm of cyanide/gold impregnated activated carbon system was also studied. The results of these batch tests show that the behaviour of the cyanide/GIAC system is very similar to the cyanide/silver impregnated activated carbon system variation of the gold content of the impregnated activated carbon has some influence on the cyanide adsorption rate. The latter is mainly increased, however, by increasing the GIAC/CN ratio. The activation energy was determined to be 3.12 kca1/mole (13.08 kj/mole) and the Au(CN)2 saturation at 194 µ M/g NORIT ROX O.B. The experimental results of reaction temperature and stirring speed show that the adsorption of free cyanide on such activated carbon is controlled by pore diffusion inside the activated carbon particle or by surface reaction. The adsorption isotherm follows the linear model and it is favourable for the cyanide/gold impregnated activated carbon system.

Jan 1, 1994

By L. W. Luo

Zeolite in some regions or countries of the world have been the subjects of materials for environmental remediation involving the use of removal to heavy metal ions and some organic pollutant as a sorbent because of its capacious ions exchange and huge surface area. This article addresses the equilibrium and kinetics for manganese adsorption using zeolite modified by hexadecyl trimethyl ammonium bromide (HTMAB) as a sorbent material over a range of pH between 3.4~7.2 with eight different Mn(?) solution concentrations. PHzpc (pH of zero point charge) of the sorbent was examined according to the method proposed by Tripathy and Kanungo, and a value of 6.91 was obtained. The experimental data fit langmuir?s model for the majority of pH and Mn(?) solution concentrations tested (0.92<R2<0.97). The maximal adsorption capacity, qm ascending with pH between 3.4~7.2, rise from 15.01mg?g-1 at 3.4 to 19.46 mg?g-1 at 7.2. Besides, the constant of Freundlich Kf have the same trend with qm, increases with pH ascending. And the sorption intensity, represented by parameter 1/n in Freundlich?s model, is favorable in entire range of metal ions concentration studied. Finally, kinetics data accurately fit to pseudo-second order which indicate that there must be sorption of Mn(?) behavior occurring on inner-sphere of the sorbent.

Jan 1, 2014

By Francesco Vegliò, Luigi Toro, Francesca Beolchini, Francesca Pagnanelli, Stefano Ubaldini

"Biosorption is an innovative technology used to remove heavy metals from aqueous solutions from mining waters and other industrial wastes. A wider application of this alternative process is strictly dependent on the understanding of the chemico-physical aspects involved, in order to optimize the operating conditions. Mechanistic models are the most useful tools used for understanding purposes, even if the empirical models are still widely applied for their simplicity.In this paper especially propagated biomasses of Sphaerotilus natans, calcium alginate and some waste materials were tested as adsorbents for single and binary solutions containing heavy metals at different pH. The equilibrium experimental results were fitted according to empirical and physical models with growing complexity outlining the inadequacy of the predictive models; in fact, the non-ideal interactions among metals require the insertion of additional correction parameters."

Jan 1, 2003