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By Artem Dolotov, Alexander Ter-Oranesyants, Saveliy Kaplan, Boris Axenov, Vasiliy Kovalev, Valeriy Tsyplakov, Konstantin Grigorjev, Nikolai Vorob’ev-Desyatovskii

The issues of double refractory gold ores pressure oxidation were considered. It was demonstrated that along with chloride autoclave preg-robbing which has been studied there are other negative external and intra-autoclave processes resulting in gold losses. It was found that an ingress of even low concentrations of NaCN, ferrum(II) and ferrum(III) cyanide complexes, as well as thiocyanate compounds into the autoclave leads to decrease of gold recovery during further cyanidation in a "carbon in leach" process (CIL). Admixtures depressing recovery of gold can get into the autoclave together with water in the result of industrial accidents or due to peculiarities of recirculation of industrial water used for feed pulp preparation or with quench-water used for process temperature maintenance. In contrast to a chloride preg-robbing which occurs only at pressure oxidation of double refractory gold ores, cyanide preg-robbing starts in the autoclave feeding tank (so-called «upper» preg-robbing). Possible causes of cyanide autoclave preg-robbing and requirements to the quality of water supplied to autoclaving were discussed.

Jan 1, 2014

By Jose R. Parga

In mining operations, cyanidation is the ,predominant method by which gold and silver are recovered from their ores and it is recognized that cyanide consumption can be a major factor that contributes to the operating costs for such operations. Also after extraction and recovery of precious metals a certain amount of cyanide is delivered to the tailings pond and must be considered with respect is environmental problems due to the toxicity of cyanides. In this regard, the Air-Sparged Hydrocyclone (ASH) has been used as a reactor for the treatment of cyanide solutions in two ways; first for cyanide recovery by acidulation using the Mexican modification of the Mills-Crowe process and second for cyanide destruction by oxidation with the use of chlorine dioxide (ClO2). In both cases, excellent performance can be achieved using the high capacity ASH system.

Jan 1, 1998

By P. A. Riveros, J. Binvignat, V. M. McNamara, D. Koren

The recovery of cyanide from a gold mill solution containing high levels of copper (400 mg/L to 900 mg/L) using the AVR process was evaluated. It was determined that acidification to pH 2 to 3 provides a suitable balance between HCN generation, copper precipitation and acid consumption. A short pilot plant campaign showed that ~75% of the feed WAD cyanide was recovered while the remainder precipitated along with copper upon acidification. The acid consumption averaged 3.5 g H2SO4 per litre of solution. The copper precipitate, consisting mostly of CuCN and CuSCN, was readily separated from the solution by gravity. The volatilization of HCN in countercurrent packed columns averaged 98.7% efficiency. Reabsorption of HCN was practically 100% in NaOH solutions and slightly lower in a lime slurry. Basic volatilizer design parameters applicable to a large-scale operation were determined, including the Henry’s Law constant and the mass transfer coefficient of HCN gas.

Jan 1, 1998

By Matthew A. Omofoma, Andrew P. Hampton

The application of the Cyprus Cyanisorb process was investigated using a pilot scale facility at the NERCO DeLamar Silver Mine (DSM) in Owyhee County, Idaho. The purpose of this process is to remove cyanide from the DeLamar mill tailings slurry prior to its introduction to the tailings impoundment. This will maintain the tailings impoundment solution in a detoxified condition and thus prevent migratory bird mortalities. The cyanide removed is to be collected and recycled to the mill. The process successfully recovered approximately 90 percent of the weak acid dissociable cyanide (WAD), reducing the effluent tailings cyanide concentration from about 300 ppm to less than 20 ppm. This was accomplished by stripping the slurry with air in a packed tower and recovering the volatilized HCN in a packed absorption tower. Data were obtained for the design of the full scale facility including the stripping and absorption towers, currently under construction at the DeLamar Mine site. Finally, test results indicated that the final pH of reneutralization can be optimized to provide for minimal gold and silver losses, while selectively precipitating unwanted metal impurities (Zinc, Selenium, Iron, and Copper) from solution

Jan 1, 1992

By W. de Moura, R. Fueyo, M. M. Botz, J. C. Scola

The Cerro Vanguardia mine is an AngloGold Limited operation in southern Argentina that includes multiple open pits and a hybrid Merrill-Crowe and CIL circuit to recover gold and silver from oxide ore. Operations were commissioned at the site in 1998, which included a plant in the metallurgical circuit to recover cyanide from mill tailings. The cyanide recovery plant was initially configured to process tailings slurry and achieved greater than 90% cyanide recovery from tailings containing about 600 to 800 mg/L WAD cyanide (as CN). The cyanide recovery circuit was operated in this manner for approximately eight months, during which time the consumption of sulphuric acid and sodium hydroxide was relatively high, leading to high rates of scale formation in the acidification tank and stripping towers. In July 1999, several piping changes were made in the cyanide recovery system to permit its operation with clear solution, which reduced the sulphuric acid consumption and eliminated scale formation in process equipment. The cyanide recovery system currently operates with a two-stage counter-current decantation (CCD) circuit which provides clear solution for processing in the cyanide recovery plant. The cyanide recovery efficiency now averages about 90% to 92% from solution containing about 350 mg/L WAD cyanide (as CN). Recovered sodium cyanide now accounts for about two-thirds of the total cyanide added to the leaching circuit. This paper presents a description of the cyanide recovery plant and details regarding its current operating efficiency.

Jan 1, 2004

By Andrew Briggs, Denis Kidby

VITROKELER cyanide recovery technology has been successfully piloted at the Gabanintha and Cosmo-Howley mines by Nedpac Engineering Pty. Ltd. The pilot campaigns were designed to confirm technical and economic feasibility of the recovery process including the production of base metal concentrates and return of re-useable cyanide to the leach circuit. The capital and operating costs of full-scale plants is now able to be estimated to within ±20% on the basis of hydrometallurgical data. Firm quotes are subject to on-site test-work, and any special requirements or site peculiarities.

Jan 1, 1990

By Charles H. Buclmam

"Environmental regulatory requirements for discharge of solutions and closure of operations for the gold mineral processing industry have been gradually lowered and in certain instances have been targeted to USEP A inorganic drinking water standards for dissolved ions in solution. The use of jar tests for water treatment process development is suitable for preliminary scoping work to be conducted in the research laboratory, as well as for optimization studies at the site of the treatment requirement. This paper will describe experimental methods which were performed using standard jar test equipment in efforts to produce solutions which meet USEP A inorganic drinking water standards after chemical treatment of cyanide solutions. The materials tested included gold bearing pregnant solutions from heap leaching operations, gold plant barren solutions from the Merrill-Crowe zinc cementation gold recovery process and gold heap leach wash solutions after carbon-in-column gold recovery. Experiments included cyanide destruction with sodium hypochlorite and arsenic and selenium co-precipitation coupled with mercury precipitation.IntroductionCyanide leaching solutions are used to selectively dissolve metallic gold from commercially viable mineral deposits. The heap leaching process involves stacking of gold bearing ores on specially designed solution containment pads and percolating alkaline cyanide solutions through the ore to dissolve the gold. Pregnant solutions containing the dissolved gold are collected and sent through a gold recovery process. After selective recovery of the gold, the barren solutions are recycled to the gold extraction process after adjustment of the solution alkalinity and available cyanide concentrations."

Jan 1, 1997

By Roger L. Beals, George A. Tweedy

I. INTRODUCTION. THE results of the cyanide-operations, given in detail in the following paper, show the progress that is being made at the Minas del Tajo. The old pan-amalgamation process, in operation up to and including 1905, while paying a profit on high-grade ores, was no longer able to treat profitably the ores in sight at that time, hence an alteration in the process was imperative. The success of this alteration is eloquently expressed by the following data Pan- Amalgamation. Cyanidation. 1905. 1907. 1903. Tons treated, . . 51,387 53,983 69,300 Value per ton (U. S. currency),. $10.75 $8.39 $8.28 Extraction, per cent., 65.00 88.50 S7.45 Extraction, per ton. .- $7.00 $7.4.; $7.24 Total cost, per ton treated, 6.50 4.311 4.01 Profit, per ton treated, . . 0.50 3.07 3.23.;

Feb 1, 1910

By Courtney A. Young

Cyanide is a fast-acting, highly toxic substance but, at the same time, is deemed essential for sustaining life as well 'as our standard of living. In this manuscript, the facts about cyanide are presented beginning with a brief history and definition and ending with a discussion on cyanide alternatives. Other topics include speciation, physical characteristics, toxicity, manufacturing, cyanogenics, cyanide cycle, separation, destruction, and markets including those outside the mining industry. Emphasis, of course, is placed on gold production by leaching and how it is influenced by ore type, mineral characteristics and economics as well as its advantages and disadvantages.

Jan 1, 1998

By Mark R. Lamb

THE various methods of treating pulp in air-agitation tanks offer problems for experiment and study which are fascinating as well as practical. The usual method heretofore has been to fill each tank in turn, agitate the mixture the required period and then discharge the treated pulp into a storage-tank, from which it. is drawn to the filter as required. A later method is to run the pulp from the tube-mill, classifier, thickener, or settler into the first of a set of tanks, and thence continuously or in series through the remaining tanks, finally drawing off the pulp to a continuous filter, or to a pulp-storage tank if the filter is of the intermittent type. It is this method which I propose to discuss here in a preliminary way, with the idea of going exhaustively into the examination of the results of a series of experiments in a later paper. It may be of interest to note that the design of a cyanide-plant has recently been completed in which the estimated cost of the agitation-tanks, storage-tanks, and pumps was 30 per cent higher for the charge-agitation arrangement than for the series plan. The first question in studying the series method is, "What is the actual period of treatment undergone by the pulp?? One first supposes that by chance some of the pulp may get through with little or no treatment, while other portions may stay in the tanks a needlessly long period. The former is not probable or even possible, and the latter is, practically, true to only a limited extent. The greater the number of tanks the greater is the percentage of chance that all the pulp will be treated equally. Without going into the mathematical analysis of the problem (which is of little value, since it is based on problematical premises), its important terms may be clearly grasped by thinking of, or " visualizing," the conditions when,

Jan 1, 1910

By Yazen Khasawneh, Osvaldo P. M. Vitali, Mohammad Nassim

Wind turbines are subjected to complex form of cyclic loadings with variable amplitudes and frequencies. The cyclic loading and the accumulation of plastic strains with the number of cycles will result in degradation of the foundation soil stiffness. The foundation stiffness degradation will result in a shift (reduction) of the fundamental frequency of the wind turbine. Although this issue is recognized in the guidelines for wind turbines foundation design, no specific provisions are provided in the guidelines to consider the long-term stiffness degradation. In this paper, a practical procedure to consider the long-term cyclic loading effects on the stiffness of wind turbine foundations in cohesive soil is proposed. The procedure is based on 3D FEM modeling and reliable empirical methods to estimate the stiffness degradation due to the cyclic loading. Using the proposed procedure, the long-term performance of the P&H tensionless pier foundation with and without a reinforcing collar at the top of the pier is assessed. The numerical results demonstrated that the long-term performance of the P&H tensionless pier foundation with a reinforcing collar at the top of the pier is outstanding with negligible long-term degradation of the foundation stiffness.

Sep 8, 2021

By W. Choi

The present study revealed that the bioleachability of a chalcopyrite flotation concentrate is influenced by the semiconductor properties of CuFeS2. The overall reaction of biooxidation,

Jan 1, 1991

By Raymond L. Jones

With the inauguration of the open pit operation in Bagdad, plans were formulated for a large scale leaching operation. Dump stockpiling was started almost immediately, but actual production was not initiated until the spring of 1961. Like all neophytes, we started something about which, on a commercial scale, we knew next to nothing, either dump preparation or leach procedure, and as a consequence, we are still paying the piper. True, we had been through an extensive laboratory pilot program, but it soon became apparent that there was considerably more to increasing solution volumes than simple multiplication. Had we initially possessed our present acumen, the Cyprus Bagdad plant could be operated more efficiently and at a better profit. During the past several years, the art of dump leaching of copper has improved in many ways, primarily because of the application of scientific principles gleaned from general mining practice. Rigid pH control and the use of atomic absorption techniques for rapid," accurate assaying have probably played a leading role in this respect, although we cannot overlook the other sophisticated electronic controls lending improvement to acid addition and pumping, better piping materials, and lastly, the more efficient use of our pregnant liquors. Thin too, the years of experience have given us a greater understanding of dump behavior in general; and, we can, to a greater extent, measure, predict, and avoid some of the idiosyncrasies inherent in every dump. However, it is my firm belief that we will still be confronted with unexplainable dump behavior as long as we are involved in leaching. We have found our dump to be a wonderful money bank, but one that is capable of yielding a wildly fluctuating profit.

Jan 1, 1975

By Raymond L. Jones

With the inauguration of open-pit copper mining in Bagdad, Ariz., plans were formulated for a large scale leaching operation. Dump stockpiling was started almost immediately, but actual production was not initiated until spring 1961.

Jan 9, 1977

By Ross R. Bhappu

Anticipating a major power cost increase in 1990, Cyprus Copper Company decided to modernize the Miami Smelter at a cost of $92.5 million. The modernization project included the addition of an Isasmelt vessel for use as the primary copper smelter and the modification of the existing electric furnace to a slaglmatte separating vessel. The project was completed in June of 1992 and is currently operating at close to its design capacity. This paper provides a summary of the decision making process, a description of the project, a summary of start-up problems and solutions and the current status of the smelter operation.

Jan 1, 1994

By N. S. Dalal, B. Jafari, F. H. Y. Green, V. Vallyathan

"INTRODUCTIONThe mechanistic details of the biological events leading to coal workers pneumoconiosis (CWP) are not yet fully understood, despite several decades of extensive epidemiologic1.2 and laboratory studies.2-6 Epidemiologic studies1.2 have shown, for example, that the incidence and severity of CWP differ markedly in the different regions and mines at comparable exposures, but laboratory investigations2-6 have demonstrated only partial correlation of the epidemiologic data with the differences in the mineral composition and the rank of coal mined. In particular, while epidemiologic data indicate1.2 direct correlation of the· prevalence and severity of CWP with the rank (i.e., % carbon content) of coal, this correlation has not been established by laboratory4'6 and animal exposure3 studies. In order to explain these results, in 1980 Artemov and Reznik' suggested that perhaps they arise from the fundamental differences in the surface properties of the coal. dusts inhaled by the coal miners and those used in the laboratory studies: while the miners inhale freshly fractured coal particles, henceforth called the 'fresh' coal dust, the laboratory studies generally utilize 'aged' coal dusts (i.e., dusts that have been stored for many days or even longer). Reznik and Artemov' used electron spin resonance (ESR) spectroscopy to show that the mechanical crushing of some Soviet Union coals generated organic free radicals and that the concentration and the decay times (hence the reactivity) of these radicals were higher for the coals of higher ranks. Since some of the radicals decayed within a few minutes in air, the authors surmised that while these radical species could lead to certain specific pathogenic reactions at the sites of mining operations, this might not be the case in the laboratory studies, due to the conventional use of 'stored' dusts which would be expected to contain significantly smaller free radical concentrations. This is consistent with the recent findings that, standardized, aged coal dusts exhibit minimal cytotoxicity. 8While the above mentioned work of Artemov and Reznik7 did suggest a possible new clue to the pathogenesis of CWP (i.e., the role of the coal based free radical species), no direct biological/cytotoxicity data were provided to show that 'fresh' coal dusts were, indeed, more pathogenic than the 'stale' ones. Because of the rather significant implications of the Artcmov-Reznik hypothesis to the understanding of 1hc biochemical mechanism and, hence, the strategies for the eventual containment of CWP, we have initiated a comparative study of the free radical formation and cytotoxicity properties of freshly crushed coal ·particles. As done by Artemov and Reznik, 7 we have used the ESR technique as the direct method of measuring the concentration and decay kinetics of the coal based free radicals. Our preliminary ESR studies on two Pennsylvania coals, a bituminous (carbon content 72 % ) and an anthracite (95 % carbon) coal, have confirmed the Artemov-Reznik finding that the crushing-induced free radical sites are higher on the coals with higher carbon content (i.e., higher rank).9-11 In the present work we describe our more recent results of a parallel study of the time dependence of the decrease in the free radical content of a freshly made anthracite dust (as measured via ESR) and that of the dust's cytotoxicity potential as measured by the extent of hemolysis of (sheep) erythrocytes. We have also investigated the effects of free radical scavengers on the cytotoxicity potential of the dust and deduce that indeed the free radicals could play a significant role in the initial events in the mechanism of the cytotoxic effects due to the inhalation of coal dust inhalation."

Jan 1, 1990

By Alexander Blatt, Franz-Werner Gerressen

Diaphragm wall technique is usually used to construct structural elements in the ground, commonly used for retention systems, permanent foundation elements or deep groundwater barriers, named Cut-Off-Walls (COW). Recent developments proof, that the technology also satisfies the demands for using the diaphragm wall technique for bulk sampling purposes. Such kind of new ideas required the adaption of equipment and tools for a depth capability never reached before by a trench cutter in any commercial application worldwide. Compared to the development of increasing depths, especially inner-city applications with limited space, demand a minimization of equipment to accommodate such projects. The paper will focus on the developments and solutions generated to fulfill these requirements and will give an outlook to future developments. Further it describes finalized reference projects and will give a general outlook on future trends and developments. The Paper/The Presentation explains as well the installation process in general.

May 1, 2022

D. C. JACKLING, the father of the porphyry coppers, has been honored for his pioneering in that field. There is another facet to Mr. Jackling's activities, one which now may prove an even greater monument than the big coppers-the story of his venture in taconite beneficiation. The essence of his porphyry development was mass handling of material. Not alone mining on a large scale, which was done on the Mesabi Range at the turn of the century, but the integration on a previously unknown scope of mining, milling, concentration, and in many cases, of final reduction to metal at the site. This was mass production applied to mining, treatment of a very low grade source material, previously considered submarginal.

Jan 1, 1954

By A. Kalmes, B. Dehler, D. Kopp

Nutrien has six potash mines in Saskatchewan and has been proactive in maintaining the integrity of their tailings facilities through ongoing assessment, design, operation, inspection, and monitoring. Nutrien commissioned a system inventory and semi-quantitative risk analysis (SQRA) of all dikes to further environmental stewardship at their potash facilities. The inventory assessed nearly 100 dikes; each dike was rated according to a probability and consequence factor and assigned a risk score. The risk scores were used to develop a risk matrix for each of the six sites and risk-response actions for each dike and segment. The inventories and SQRAs will help each site assess priorities for investigation and risk mitigation, if necessary. The study results will also help Nutrien refine corporate wide tailings governance standards and demonstrate compliance with various governance regulatory obligations.

Mar 2, 2022

By David W. Martel, Tom George

"As part of the regional water authority review and upgrade of local dams a 35m x 5m x 3m wet soil mixed block was required for stabilisation of a dam wall toe in remote Victoria, Australia. Remote access, extremely poor roads and high mobilisation costs made more traditional CSM and deep mixing methods cost prohibitive. The dam required a redesign to raise the wall by 2.0m to increase water storage. Additionally, the dam required additional stabilisation to reduce the risk of liquefaction during an earthquake event. Soil testing indicated loose, cohesionless, high permeability soils to a depth of 3.0 to 3.5m across the toe of the wall. This resulted in high dam seepage through the toe of dam wall potentially causing the factor of safety during a seismic event to decrease to a dangerous level. A number of laboratory trials were completed to determine the mix ratio of cement required to improve the strength of the saturated, liquefiable soil.Wagstaff Piling was responsible for achieving the required soil/cement strength and mix depth on site. As the ground conditions were too soft for conventional soil mixing equipment, an excavator mounted Mitsui road header was modified to fit a 20 tonne excavator. A purpose built remote batching plant was set up on more stable ground approximately 200m from the wall and utilised for preparation of cement and water slurry for supply to the machine. As the ground was too soft to support the excavator, the progressively improved ground was used as the working platform. Both wet grab sampling and in situ testing was undertaken to determine the UCS of the improved soil. These results indicated several variations in the results due to size effects.1 INTRODUCTIONA small town in remote Victoria relies totally on its water supply from a small dam. The dam wall required stabilisation works by ground improvement as studies completed on the dam classified it as a high risk of failure under an earthquake event. In addition, the earth fill dam had high levels of seepage and poor control measures, requiring the dam to be upgraded to comply with all regulations.The relevant water authority engaged a contractor under a design and construct contract to complete the works. Wagstaff Piling was engaged as the Subcontractor to provide design and construction advice including the contract for the ground improvement works. Initial discussions involved CSM walls, cut-off walls and mass soil mixing solutions. However, due to the access restrictions for piling equipment, mass soiling mixing was the chosen method of ground improvement."

Jan 1, 2015