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By S. Lohmeier, D. Gallhofer, B. G. Lottermoser, T. Schirmer

At a time of resource consumption, it is important to study the chemical composition of mining and metallurgical wastes to prevent the dissipative loss of metals and metalloids from the mining value chain. In particular, the recovery of critical elements from wastes is an option to increase the resources of such materials that are economically significant and have an overall supply risk. In this paper we report on the chemical composition, in particular the critical element content, of granulated slag originating from historical smelting activities in the Tsumeb area, Namibia. Laboratory-based inductively coupled plasma–mass spectrometry (ICP-MS) and X-ray fluorescence (XRF) analyses as well as portable X-ray fluorescence (pXRF) demonstrate that the slags are on average enriched in base metals (Cu 0.7 wt%, Pb 2.7 wt%, Zn 4.7 wt%), trace metals and metalloids (Cd approx. 50 mg/kg, Mo approx. 910 mg/kg) as well as critical elements (As approx. 6300 mg/kg, Bi approx. 3 mg/kg, Co approx. 200 mg/kg, Ga approx. 100 mg/kg, In approx. 9 mg/kg, Sb approx. 470 mg/kg). While metals and metalloids such as As, Mo and Pb can be determined reliably using pXRF instruments, the technique has inherent limitations in evaluating the contents of certain critical elements (Ga, Sb). However, there are positive correlations between the As, Mo, and Pb contents determined by pXRF and the Ga and Sb contents obtained through ICP-MS and XRF. Thus, quantitative pXRF analysis for As, Mo, and Pb allows calculation of Ga and Sb abundances in the slags. This work demonstrates that pXRF analysers are a valuable tool to screen smelting slags for their chemical composition and to predict the likely contents of critical elements.

Mar 1, 2021

By I. C. Knight

The current levels of copper smelter by-product acid production are reviewed on a regional basis, together with the possible changes in the future. There will be increasing pressure for all smelters to achieve a sulphur capture level of at least 95% by the end of the decade.

Jan 1, 1996

By Clint L. Milliken

The smelter is often considered the flywheel of the copper industry. No other unit can produce such a uniform product from so many starting materials. Direct-smelting ore, concentrate, precipitate, refinery slag, and scrap in almost any combination can be processed into blister or anode copper. Copper smelting practice has advanced little in the last century. It is still basically matte smelting, although the source of matte has changed from the blast furnace to the reverberatory furnace because of changes in smelter feed, and the Great Falls converter has been replaced by the Peirce-Smith converter. This lack of progress has continued because the economic forces required to produce change have not been of sufficient magnitude. Traditionally, the smelting, operation has required only about 10% of the total cost of producing copper from its ores and this minor cost item has not warranted change until recently.

Jan 1, 1971

By S. L. Chen

The Kumera Technology Center developed a unique type of steam dryer for drying copper concentrate in the mid 1990s. The dryer has been chosen in several copper smelter projects since 1999. To expand production capacities, the Norddeutsche Affinerie smelter, the Pirdop smelter of Cumerio, the Toyo smelter of Sumitomo Metal Mining and the Tamano smelter of Hibi Kyodo Smelting have carried out projects in which Kumera Steam Dryers were installed. The capacity of a single steam dryer varies from 70 t/h to 160 t/h. This article summarizes the latest operation results of the Kumera Steam Dryers in these smelters and introduces the progress of the ongoing projects in Yanggu Xiangguang Copper, Guixi smelter of Jiangxi Copper, Jinlong Copper, Boliden Harjavalta, and Onsan smelter of LS-Nikko Copper.

Jan 1, 2007

By Staff

The uninitiated, first-time visitor to the Copper Cliff Smelter of The International Nickel Company frequently finds it strange that the world's largest nickel producing works is located at a site seemingly named in honour of another metal. Industry-wise persons who know The International Nickel Company through its nickel producing, fabricating and sales organizations can be just as surprised to learn that Inco's annual copper production from the Sudbury area mines nearly equals that of nickel. But when the history of the mines and smelters of the Sudbury district is reviewed it is impossible to separate the stories of copper and nickel. In fact, going even further back in time (I), it was due to the similarity in appearance of the nickel bearing mineral niccolite (NiAs) to that of copper ore that led nickel to be tagged with the rather uncomplimentary name of kupfer-nickel or Old Nick's Copper - The Devil's Copper. This was in approximately 1650 and it would take another hundred years, until 1751, before Axel Cronstedt of Sweden obtained nickel in its pure form and permitted it to take its own place in the family of metals. One hundred more years passed before mining came to northern Ontario and approximately one hundred thirty before the beginnings of development of the Sudbury Basin.

Jan 1, 1976

By Gary Walters, Thomas Gonzales, David George, William Davenport, Andreas Siegmund, Suping Yao, Shijie Wang

The previous survey of world copper smelters was in 2016 (Copper, 2016). The copper smelting industry has grown and improved considerably since then, including continuing growth in China and modernization in Japan (Extraction, 2018). Outotec flash smelting and Outotec flash smelting/Kennecott - Outotec flash converting continue to be adopted while newer processes continue to be adopted in China. In addition, some of the world's original flash furnaces have been completely rebuilt (Extraction, 2018). This paper provides recent industrial production data and discusses these new developments. INTRODUCTION A world copper survey was redone in 2016 after a thirteen year lag since 2003. Some of the notable changes were the significant increases in production particularly from China. Since then, several smelters have gone through modernization processes and decommissioning of older technologies. This paper will review the notable changes since the last publication at Cu2016. In the last paper, Copper Smelting: 2016 World Copper Smelter Data, the author gave an audible sigh after observing that copper smelter sites as well as new and notable smelters have been spreading like wildfire in China since 2003. Indeed, seeing is believing. Figure 1 shows the Ningde Copper Smelter (double flashing, 400,000 MT Cu/Year capacity) that started up producing copper in 2018; Figure 2 shows the Nanguo Copper Smelter that is under construction with 300,000 MT Cu/Year capacity (first phase, side blown smelting and continuous top blown converting). We should not only admire the Chinese copper industry’s significant technological developments, but also the copper price support that it has provided throughout this century.

Jan 1, 2019

By O. S. Tinkler, K. C. Sole

Approximately 20% of current world copper cathode output is produced using a hydrometallurgical process route, generally referred to as the leach–solvent extraction–electrowinning flowsheet. Since its commercialization in the late 1960s, steady improvements in the performance and efficiency of the solvent-extraction reagents and equipment, combined with significant developments in leaching and electrowinning, have made an ever-widening range of ore types amenable to this technology. Following successful implementation on all major continents, a large proportion of growth in recent years derives from the re-emergence of copper solvent extraction in the Central African Copperbelt. This review provides a brief history of the development and evolution of copper solvent extractants and mixer-settler contactors, and the significance of the Copperbelt region in achieving commercialization and acceptance of the technology. The opportunities and challenges presented by the abundant high-grade oxide ores of the Copperbelt are contrasted with the processing of solutions derived from the low-grade mixed oxide–sulfide ore bodies that are prevalent in other geological regions. The current status of hydrometallurgical copper production in the African Copperbelt, within a global context, and a medium-term outlook for the technology are discussed.

Jul 5, 2023

By K. A. Dudley

Basic solvent extraction theory indicates that pH initiates the basis of an oxime's metal complex formation and therefore its selectivity toward certain metal species. The recommended optimum pH for some of the commercial copper reagents is in a range that should maximise copper loading of the oxime. However, this pH range also tends to maximise iron(III) loading under certain operational conditions resulting in low selectivity values. Recent operational parameters at Girilambone Copper Company have highlighted some of these conditions that have a major influence on the oxime's selectivity for copper over iron(III) in the leach solutions. The result is that the pH for maximum copper extraction is no longer within the optimum range to maximise oxime selectivity. Therefore, specific copper and iron(III) pH isotherms have been determined on-site for the changing leach solutions that are fed to the solvent extraction plant in order to optimise oxime selectivity. The influences of solvent extraction plant configurations are also discussed as a controlling parameter.

Jan 1, 1999

By Martin B. Schranz

Copper sulfate pentahydrate is recovered from the spent etchant waste stream of a printed circuit board manufacturing facility by cooling crystallization. The fluidized bed crystallizer contains submerged cooling surfaces which are bathed in a stream of air. The air bubbles provide agitation which improve heat transfer, reduce fouling and maintain crystals in suspension. The recently patented apparatus (US 5,523,064) has advantages when compared to a conventional surface cooled crystallizer including capital cost, ease of operation and production of larger more uniform crystals

Jan 1, 1997

By Alexander Sutulov

1. INTRODUCTION According to the classical economic approach of the open market economy, copper supply should be regulated by market forces which are (a) demand and (b) prices. In fact, demand is of primordial importance because prices are a reflection of supply-demand balance: they go up in times of shortages of supply and down when over-supply situation exists. In the past few years, this basic mechanism of market economy has been under pressure from a number of non-market forces, such as social and monetary problems of sane important copper producing countries; structural changes in copper mining companies through mergers with oil companies; and other factors which greatly contributed to distortion of the basic supply-¬demand equation. As a result, we have faced in the last three years a situation of oversupply rarely seen in the past, with a catastrophic fall in copper prices, huge losses at mines and unprecedented indebtedness of copper producers. This has deep repercussions in the copper business and its future supply outlook. This is particularly so when taking into consideration that high indebtedness and high interest rates conspire against the very survival of some traditional producers. As we write this comment (July of 1985), close to one half of U.S. copper production capacity is closed down, sane of it for good, while the same precarious situation exists in Canada, Australia, Zambia, and some other primary producers who cannot face present low prices with equally low costs. The question is then what this situation means for the medium-¬term future, until the end of this decade, Particularly when taking into consideration the fact that some of the factors influencing it are of a long-term character. 2. SUPPLY-DEMAND SITUATION IN THE LAST FIVE YEARS Since the last boon year, in 1979, when world copper consumption reached a record of 9.8 million metric tons of refined copper, demand dropped to only 9.0 million tons in 1982, when the crisis bottomed out, and then steadily recovered to the level of 9.7 million tons in 1984. Meanwhile, copper production, which in 1979 was only 9.4 million tons, in spite of the fall in demand, grew to 9.7 million tons in 1981 and 1983 and only temporarily was cut to 9.4 million tons in 1982 and to 9.5 million tons in 1984. As a result of this imbalance, hugh copper stocks were accumulated with supply systematically out¬growing demand by over 2 million tons at one time. With the Western World refined copper demand running at an average of 115,000 tons per week, this oversupply was equivalent to between 15 and 18 weeks production, i.e. twice as large as normal. This was immediately reflected in very low copper prices. Another contributing factor to relatively low copper prices was the lack of speculator interest for this commodity. Between 1981 and 1984 the world experienced a very intensive period of wealth distribution, high interest rates and intensive restructuring off world economy and its industrial sector. Therefore, much of the available money was attracted to more lucrative and attractive investments rather than to the lack-luster performance of copper, and for that matter, of the metal sector in general. The much announced and discussed recovery of the U.S. economy since 1983, and particularly in 1984, with an overall growth of the GNP by 6.8% in 1984, happened to be more oriented to the service sector than the industrial sector and therefore this recovery was not adequately reflected in copper consumption nor to metals in general. This put serious doubts about the future demand for copper. Consequently copper prices failed to improve in spite of an apparent fall in stocks and a healthy increase in the demand for copper since 1982. At the time of this writing (July, 1985), although same analysts claim that the available stocks are running at about 8 weeks of supply, which are considered to be below normal, copper prices are still very low at between 65 and 67 cents per pound of copper. Part of the answer may be the normal seasonal slow-down period in the Northern Hemisphere due to summer vacations and

Jan 1, 1986

By Javier Baladron, Mijail Villar, Brandt Henriksson

"In this presentation an overview will be given of what has been observed by the authors in the copper concentration industry, with a large diversity of tailing thickeners operating under different conditions, although many of them are located in the same neighborhood. A closer look will be taken at the reported performance from different sites and from different thickener designs, either conventional or high rate, including those that were retrofitted, regardless of the thickener brand. An analysis is also made of the generic correlation of the size of the thickener and the performance in terms of solids loading (or unit area) and % solids. The paper envisions a technology development route, makes a brief analysis of the economic impact of the suggested route and points out the need for development in technologies around tailings thickeners, such as automation, yield stress measurement, slurry pumping and construction methods."

Jan 1, 2014

Copper waste dump leaching is growing in importance because of the.large tonnages (up to 250,000 ton/day) of low grade waste rock available from open cut mining of copper deposits and proof that controlled leaching of copper from such dumps can be profitable.Overburden or waste rock, ranging in size from large boulders to fines, is dumped as cheaply as possible on sloping sites. Copper is leached from the dumps by applying up to 12,000 gal/min of leach solution (a combination of spent solution from cementation and make-up water) to the top of the dumps by various techniques.Efliuent from the dumps is sent to a cementation plant for copper recovery.Factors which may be controlled, either directly or indirectly, to give a controlled copper content in the dump efliuent (usually 1-2 g/l.) are the cycle of operations (i.e. the alternate wetting and drying periods), thevolume of solution applied to the dump, pH, Fe2+ and Fe3+ content or redox potential, oxygen content, bacteria and their necessary nutrients, and temperature.Dissolution of oxide copper minerals appears to be mainly a function of acid concentration. Copper sulphide minerals need oxidation for dissolution to occur and this is accomplished by a combination of oxygen,ferric ion, and bacteria. Oxidation of pyrite, oxidation of Fe2+ to Fe3 +, and hydrolysis of Fe3+ are of some importance in leaching practice. The presence of gangue carbonate minerals is detrimental.Physical factors connected with penetration of solution into large rocks are important and the treatment of an individual dump usually extends over a period of many years. Recovery of copper from solution is usually achieved by cementation with iron (usually in the form of crumpled cans) but the use of sponge iron is becoming more important. Iron consumption varies from 1 to 4 lbiron per pound of copper. Preconcentration of the copper in the efliuent solution by solvent extraction followed by electrolysis may become a useful method.Application of dump leaching techniques to metals other than copper depends on finding an economic method of recovering the metal from solution...

Jan 1, 1967

By M. Smit, N. C. J. Dempers, S. Lunkov, C. Saguru, J. Nel

A common method for the recovery of copper is by heap leaching, solvent extraction, and electrowinning. During solvent extraction, the solution is continuously recycled, and it is necessary to remove impurities that build up in the raffinate. For the process investigated in this study, the main impurities include Fe, Co, As, and Zn. Recovery of these impurities can provide economic benefits while adhering to legal and environmental constraints. Such impurities are often removed by precipitation utilizing a neutralizing agent, such as limestone or lime, but it is also possible to remove the impurities by sulfide precipitation. Sodium hydrosulfide (NaHS) is used to selectively precipitate copper, arsenic, and zinc from a solvent-extraction raffinate stream. The resulting sulfide precipitate is bagged and sent to a roaster for further treatment. The design of the sulfide precipitation was investigated to optimize the processing conditions (including temperature, pressure, and residence time), the materials of construction, and the toxicity and explosive nature of the hydrogen sulfide gas produced

Jan 1, 2023

By Jon J. Connor, Richard J. Ebens

The trace element geochemistry of the cherty clay-rich carbonate residuum cover in much of southern Missouri and adjacent parts of Arkansas was investigated during the earl 1970's as part of a statewide geochemical survey of Missouri.1-8 The study was environmentally oriented and focused on the character of the "natural" geochemical environment of the state. A great deal of effort was made to collect samples that would represent the geochemical variability of the near-surface environment in an unbiased way. In general, this was accomplished by use of randomization procedures in both collection and analysis. Most of the sampling sites were selected randomly to prevent personal bias from entering into sample selection. In the laboratory, samples were analyzed in a randomized sequence to circumvent the effects of any systematic bias that may have entered into the laboratory procedures. Several residuum samples contained 1000 parts per million (ppm) or more of lead, zinc, and barium. All these samples were collected in Washington County in or near the barite district. The frequency distributions shown in [Fig. 1] indicate just how unusual the residuum in Washington County is with regard to these three metals and copper. The shaded parts of the histograms represent the samples from Washington County. The histograms are based on analyses of 141 samples from 38 localities scattered over the subcrop of the Cambrian and Ordovician formations of southern Missouri and northern Arkansas. Eight localities were selected randomly from over each of four bedrock units-Bonneterre dolomite; Potosi and Erninence dolomites; Roubidoux formation; and the Jefferson City, Powell, and Cotter dolomites. Six localities were selected randomly from over the Gasconade dolomite. The geochemical "background" for these elements in residuum is defined by samples from outside of Washington County (unshaded part of the histogram); lognormal distribution curves have been fitted to the corresponding parts of each histogram. Clearly, these lognormal models (curves) describe well the background distributions of zinc, barium, and copper. The background histogram of lead concentrations is notably skewed to the right compared to the model. Lognormal distribution curves were also fitted to the data on lead, copper, and zinc in the residuum of Washington County. No model was fitted for barium in Washington County because of the distinct bimodality in the data. All samples containing more than 1000 ppm were collected in the barite mining district and obviously reflect the elevated levels of barium in the district. The frequency distributions for Washington County are clearly anomalous with respect to the background data, those for lead, zinc, and barium being exceptionally so. The models for anomalous lead, zinc, and copper seem to fit reasonably well, although the scatters in the lead and zinc anomalies are considerably larger than the scatters in the corresponding background data. The copper anomaly, although probably real, is greatly subdued compared to that of lead and zinc. Also, it has a scatter similar to that of the copper background, rather than being enhanced like the scatters of the lead and zinc anomalies. On the basis of techniques described by Miesch,4 the chemical abundance of copper, lead, and zinc in residuum in

Jan 1, 1980

By W. H. (Bill) Jay

The destruction of cyanide creates a significant impost on the financial returns of gold mines. These losses increase substantially when ores containing cyanide-soluble copper are treated. Failure to remove or destroy free or WAD cyanide before it is discharged into tailings dams has, on a number of occasions, led to significant fish, bird and animal deaths. Thus, the retention of cyanide within the leach circuit and the recovery or removal of stable metal cyanide complexes needs to become standard practice for all gold mining operations. Furthermore, reducing cyanide purchases will minimise the quantity of cyanide transported to the mine site thereby reducing the opportunity for spillage of this chemical. Many different physical and chemical methods have been investigated for the removal of cyanide from process solutions. All cyanide destruction methods create a financial impost on the economic viability of the gold mine. To reduce these costs, the recycle of cyanide and the economic recovery of the metals solubilised by cyanide is of prime importance. The alternative methods currently in use, or under consideration for the treatment of copper cyanide, entail high reagent costs, produce the recovered metal in a contaminated form and require the safe handling of hydrogen cyanide. These processes will be briefly discussed within this report Environmental and financial benefits are enhanced by recent laboratory and pilot plant studies conducted by Oretek Limited. The Oretek CPC process for the recovery of copper and the recycle of cyanide from copper cyanide-containing solutions does not require pH adjustment to the alkaline cyanide leach conditions. Copper ions are coordinated to a water-soluble and/or an organic soluble polychelating agent under alkaline conditions and the cyanide ions are displaced Membrane separation, or phase separation of the polychelated copper from the cyanide ions enables the cyanide ions to be recycled and the copper to be directly electrowon from the polychelating polymer. The polychelating polymer is then recycled. Ion exchange resins and solvent extraction systems which may be incorporated into the above process will also be discussed in detail.

Jan 1, 1998

By W. S. Fyfe, G. V. Albino, Ekawat Sitthithaworn

The mineralisation is associated with a composite diorite to quartz monzonite stock of Permian to Triassic age that intrudes Devonian carbonate strata. In the intrusive rocks it is associated with potassic alteration and in the carbonate wall rocks it is hosted by prograde garnet-rich and retrograde epidote-rich skarn. Both porphyry and skarn mineralisation include disseminated and fracture-controlled mineralisation, the latter probably accounting for the major part of the contained minerals. Copper, gold, silver and zinc are strongly positively correlated within the mineralised zones, although there are small differences in metal ratios between the different ore types; molybdenum appears to be negatively correlated with copper and gold. Ore minerals include chalcopyrite, magnetite and pyrite in porphyry-type mineralisation and bornite, chalcopyrite, pyrite, magnetite and lesser haematite in skarn.

Jan 12, 1993

By P Thompson, D Rose, S Yu, W Baum, R Zahn, D Meadows, G Hall

Opportunities to improve mill operations are often cited by mining companies and recognised in many concentrators spread throughout the world but are not always followed through. Copper-molybdenum concentrator operations are challenged by a continuously increasing list of detrimental factors. They include deteriorating ore characteristics and poor mineralogical information on deeper ores, water quality and availability, steel wear and increasing power costs. Rapidly declining productivity, sustainability and environmental factors, new taxes, mining industry global skill set shortages, to name but a few, must also be considered. The days of maximising value by just increasing production or simple cost cutting are fading and will not be sufficient for the future of more complex mineral processing operations and larger plants. As a result, FLSmidth’s Global Process Technology Group has launched a plant and process optimisation program based on mineralogical and metallurgical surveys.Copper-molybdenum concentrators of the future need a paradigm shift. Modelling and simulation tools alone are not the answer to complex mineralogical associations and larger scale equipment and operations. Detailed area by area review aimed at identifying process constraints in terms of equipment and operating practice in conjunction with robust diagnostic work, ie mineralogical and metallurgical characterisation, are mandatory for process optimisation. The navigational beacon, for all operations who want to remain competitive, will be ‘process efficiency’. Since the use of automated mineral analysers has become more readily available and reliable, mineralogical-metallurgical plant surveys have proven themselves as the most efficient tool for optimising plant performance.The following paper will illustrate how operations can move toward eliminating under-performing flow sheets, fixing run-away flotation conditions, maximising individual process equipment performance, preventing shortcuts in Bond work index testing which may cause the failure of comminution models and minimising costly and time-consuming ‘debottlenecking’. As previous plant surveys have shown, the net project cash flow can be increased by 50 to 200 per cent if a combination of robust ore characterisation and plant process mineralogy is performed. The combined plant survey approach has been demonstrated successfully in a multitude of operations. This includes the use of key ore types in concert with statistically sampled process streams, bench-scale metallurgical tests and automated mineral analysis on a size-by-size basis.CITATION:Meadows, D, Hall, G, Rose, D, Thompson, P, Baum, W, Zahn, R and Yu, S, 2014. Copper-molybdenum concentrator surveys using mineralogy and process benchmarking tools to improve overall plant performance, in Proceedings 12th AusIMM Mill Operators’ Conference 2014 , pp 315–322 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 1, 2014

By R. C. Wallace

Introduction At a time when the mineral-bearing areas in Manitoba are being fi very keenly explored because of the major developments which are now taking place in that Province, it may be timely to give an analysis of the mineralization in the two major types of deposits, with a view particularly to assist in the intensive prospecting to which the mineral-bearing areas in the Province are now to be subjected. As is already well known, there are two principal types of mineral deposits in the territory- copper-zinc and gold; and attention will be confined almost exclusively in this paper to these two types, with some indication of such modifications of the main types as may be found to be of economic value. The details of the paper are drawn from what is yet a small part of the area of the Province available for prospecting. Enough is now known of the types of mineral deposits which are described in the following pages to justify the expectation that these types may serve as criteria in the search in the newer districts. Doubtless new types will also be found as investigations proceed.

Jan 1, 1928

By Yongfeng Jia

Lime neutralization and co-precipitation of As(V) with iron(III) is the most widely used and most economical method for the removal of arsenic from mineral processing solutions and effluents. However, the arsenate fixation mechanism in the coprecipitated solids is not fully understood. It was suggested by various researchers to be a ferrihydrite precipitation process during which arsenate is removed by adsorption on ferrihydrite. In this study, XRD, EXAFS and microprobe were employed for the speciation of arsenic and the effect of various factors on arsenic solubility was also investigated. The results indicate that coprecipitation is a more complicated process than simple adsorption resulting in lower arsenic solubilities. Poorly crystalline ferric arsenate was observed for the first time to be present in the coprecipitated solids. In case of lime as base, there exists some type of Ca-Fe-arsenate association. A general term ?coprecipitate? is suggested to describe the precipitated arsenic-bearing solids instead of those widely used specific terms ?arsenical ferrihydrite? or ?arsenic-bearing ferrihydrite?.

Jan 1, 2005

By G N. Musafer, M H. Thompson, R C. Wolff, E Kozan

The most important aspect of modelling a geological variable, such as metal grade, is the spatial correlation. Spatial correlation describes the relationship between realisations of a geological variable sampled at different locations. Any method for spatially modelling such a variable should be capable of accurately estimating the true spatial correlation. Conventional kriged models are the most commonly used in mining for estimating grade or other variables at unsampled locations, and these models use the variogram or covariance function to model the spatial correlations in the process of estimation. However, this usage assumes the relationships of the observations of the variable of interest at nearby locations are only influenced by the vector distance between the locations. This means that these models assume linear spatial correlation of grade. In reality, the relationship with an observation of grade at a nearby location may be influenced by both distance between the locations and the value of the observations (ie non-linear spatial correlation, such as may exist for variables of interest in geometallurgy). Hence this may lead to inaccurate estimation of the ore reserve if a kriged model is used for estimating grade of unsampled locations when non-linear spatial correlation is present. Copula-based methods, which are widely used in financial and actuarial modelling to quantify the non-linear dependence structures, may offer a solution. This method was introduced by Bßrdossy and Li (2008) to geostatistical modelling to quantify the non-linear spatial dependence structure in a groundwater quality measurement network. Their copula-based spatial modelling is applied in this research paper to estimate the grade of 3D blocks. Furthermore, real-world mining data is used to validate this model. These copula-based grade estimates are compared with the results of conventional ordinary and lognormal kriging to present the reliability of this method.CITATION:Musafer, G N, Thompson, M H, Kozan, E and Wolff, R C, 2013. Copula-based spatial modelling of geometallurgical variables, in Proceedings The Second AusIMM International Geometallurgy Conference (GeoMet) 2013 , pp 239-246 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 29, 2013