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By M. A. Ford

This paper reviews the history, sources, mineralogy, extraction metallurgy, conversion, and enrichment of uranium in South Africa. Over the past 40 years extraction plants were built at 27 sites, an9.over 140 kt of uranium have been produced. Older plants have had to adapt to changing market conditions, no single technology has had the opportunity to become entrenched, and costs have been reduced to a third of those of the original flowsheet. The research efforts aimed at developing the country s nuclear raw materials have been particularly rewarding, as they have enabled South Africa to become a world leader in the extraction of uranium from low-grade ores and to develop methods for uranium enrichment and the production of nuclear fuels.

Jan 1, 1993

By P. Clinton Milne

Uranium mines in Washington State include the producing Midnite and Sherwood mines and several mined-out deposits, the most productive of which was the Daybreak mine. The Midnite mine is generally classified as a hydrothermal deposit consisting of tabular orebodies in Precambrian pelitic and calcareous metasedimentary host rocks. The host rocks occur as roof pendants in a Cretaceous porphyritic quartz monzonite intrusive; the quartz monzonite averages 12 ppm U308 The uranium deposit appears to have undergone a complex genesis, involving a series of depositional and enrichment stages. The Sherwood uranium deposit, approximately 4 miles south of the Midnite mine, occurs near the bottom of a basal Late Cretaceous to Paleocene arkosic conglomerate. The conglomerate lies nonconformably on the porphyritic quartz monzonite that is associated with the Midnite deposit. The Sherwood and Midnite uranium deposits may have had a similar genetic history linked by a common uraniferous pluton source, ground-water action, and/or leaching of uranium-rich ash flows from now-eroded, overlying, Eocene volcanics. The Daybreak deposit, in northeastern Spokane County, consists entirely of secondary uranium mineralization (metaautunite) in a quartz monzonite pluton. Mineralization is confined to a low-angle fault zone and is most highly concentrated at the intersection of primary and secondary shears. Both hydrothermal and ground-water origins are feasible. Besides the Midnite-Sherwood area, 14 other areas in the western Okanogan Highlands physiographic province and Cascades region have favourable characteristics for uranium potential. Criteria include the existence of uranium occurrences, Tertiary basin sediments with intercalated volcanic and volcaniclastic rocks, favourable geochemical data, alkaline plutons associated with uranium occurrences or borders of Tertiary basins, and structural controls.

Jan 1, 1979

By John B. Goddard

In-situ leaching of uranium by aqueous ammonium carbonate containing oxygen or hydrogen peroxide as oxidant results in the partial dissolution of sulfides. While some of the sulfide sulfur is oxidized to sulfate, a considerable portion is oxidized only to thiosulfate and polythionates. Polythionates poison the anion exchange resin used to extract uranium. At the Palangana operation in southeast Texas, the trithionate ion (S3062-) was found by infrared spectrometry to be the major resin poison. Treatment of ion exchange feed solutions with hydrogen peroxide only resulted in partial conversion of reduced sulfur species to sulfate, and trithionate conversion was particularly slow. Poisoning of the resin also occurred from the ammonium chloride eluant, which built up trithionate because of recycling. This was essentially eliminated by chlorinating the eluant prior to yellow cake precipitation.

Jan 1, 1984

By Robert G. Beverly

The presence of radioactivity in uranium mill wastes has resulted in somewhat unique waste disposal methods. In addition to the common problems of disposing of large quantities of solid wastes, neutralizing acids, minimizing dissolved heavy metals, and clarifying all liquid effluents, the uranium mill operator must sample and analyze liquid effluents for micro-micro quantities of radionuclides such as, radium-226, thorium-230 and lead-210. Special disposal methods or decontamination procedures are required to meet the stringent limitations established by the U. S. Atomic Energy Commission on the concentration of radionuclides in liquid effluents. Routine monitoring of the receiving stream is also normally required. In recent years there has been a growing concern about the radioactivity remaining in the uranium mill tailings, particularly at the sites of shut-down or dismantled mills. The State of Colorado, in cooperation with the industry, has adopted regulations for stabilization of inactive uranium mill tailings. The Mining and Metals Division of Union Carbide operates mills for the recovery of uranium and vanadium at Uravan and Rifle in Colorado and a mill in the Gas Hills of Wyoming for uranium production. The company also owns former mill sites on which mill tailings are located at Maybell, Rifle, and Slick Rock in Colorado and at Green River, Utah. The purpose of this paper is to describe the methods used by a few uranium mills, largely those operated by Union Carbide Corporation, to dispose of radioactive wastes, to discuss briefly the regulations under which the mills operate, and to present reference information on the subject.

Jan 1, 1968

By C. Edwards

ABSTRACT: Milling operations in northern Saskatchewan’s Athabasca Basin have produced uranium continuously since 1975. During that period, the Athabasca Basin has been one of the world’s premier uranium camps, yielding more than 660 million lb (299,370,964 kg) of U3O8. In this paper, the author describes former and current milling operations and discusses why and how the milling process has changed and developed over the past 35 years. The author’s considerations for the future of uranium extraction in the Athabasca Basin conclude the paper.

Jan 1, 2012

By Peter Waggitt

Northern Australia has been home to uranium mining for over 70 years, more or less continuously. In the early days, post World War 2, there was little effort made to remediate workings at the end of operations. The three “campaigns” of uranium mining (1951-55; 1960-70; and 1979-present) are all now in various stages of remediation. This includes not only the large legacy site at Rum Jungle but also smaller fields like the South Alligator Valley, as well as contemporary works at Nabarlek and the ongoing closure at Ranger– Australia’s longest operating uranium mine. This paper briefly describes some of the past remediation activities before providing an update on the Ranger closure programme and future timetable.

Jan 1, 2020

By R. J. Munday

Although uranium deposits in northern Saskatchewan are clustered around the Athabasca basin, basement lithostructure determines their distribution. Basal Wollaston Group pelites are invariably graphitic and carry uraninite in felsic segregations and biotitic pegmatite. Where these intersect the Athabasca Formation, remobilized uranium concentrated as pitchblende. Uranium is also concentrated in silicified and hematized sandstone where the Athabasca Formation overlies post-orogenic faults. Presumably, pregnant solutions associated with the fault were stripped of their metals as they emerged into the contrasting physico-chemical environment of the sandstone basin. Both these types of mineralization correlate with a Grenvillian (-1,000 m.y.) heating event and associated diabase intrusions. However, the rich pitchblende veins at Uranium City appear to predate the Athabasca Formation, but display spatial correlation with the Martin Formation. They are tentatively associated with a syn- to post-D3 retrograde metamorphic event which thoroughly leached crystalline basement and generated uraniferous fluids which escaped, and precipitated metals, into fractures associated with faults that define the grabens in which the Martin Formation was deposited. Remobilization events allowed some of this uranium to move upward into fractures within Martin sediments.

Jan 1, 1979

By Savory P. J

Uranium mining operations commenced at Ranger mine site, Jabiru NT Australia in May 1980. The Ranger orebodies, totalling approximately 110 000 tonnes contained U305 had been indicated by airborne radiometric survey in 1969 and confirmed by drilling the following year. Both diamond and percussion drilling methods were used to define the mineralisation and samples were analysed using a combination of radiometric and neutron activation techniques. Ore reserve estimates were calculated from conventional and geostatistical methods, and following the mining of 15 million tonnes of ore, reconciliations with before mining estimates are well within acceptable industry standards. In-pit grade control employs radiometric techniques including a radiometric truck discriminator built in Australia to mine specification to meet production requirements and improve productivity. Environmental requirements associated with uranium mining are a daily consideration.

Jan 1, 1993

By Thomas N. Walthier

ROSPECTING for uranium in the East is hampered by the lack of bedrock exposure due to extensive overburden and residual soil. But, despite the problems of this physiographic province, it has not been ignored in the search for radioactive materials. Since 1951 both the U.S. Geological Survey and the Atomic Energy Commission have had field parties in the eastern U.S. Tempo of private prospecting is increasing, and many discoveries have resulted. AEC work so far has been concentrated in the areas of most numerous discoveries-Pennsylvania, New Jersey, and New York. Accounts of uranium mineralization in the eastern U.S. are found in the old literature and one site in the Mauch Chunk area of Pennsylvania has been known since 1874. In 1949 McKeown examined the original occurrence there and found another southeast of the town. The deposit appeared to have commercial possibilities and a short period of production began in July 1954

Jun 1, 1955

By J Davidson

Ion exchange using strong base resins is a well established technology for the recovery and purification of uranium from sulfuric acid leach liquors. Production of uranium at the Beverley Mine in South Australia includes acidic in situ leaching, ion exchange and uranium precipitation. The salinity present in the groundwater results in a relatively high concentration of chloride in the leach liquor reporting to the ion exchange plant. The impact of chloride on the ion exchange process is discussed in this paper. The results presented show that an increased chloride concentration in the lixiviant solution feeding the ion exchange plant leads to increased uptake of chloride by the resin during the loading cycle. At the highest chloride concentration studied (7.5 g/L Cl) chloride took up to 60 per cent of the resin loading sites. The impact of the chloride can be summarised as follows: for a given uranium concentration in the lixiviant feed solution, the uranium loading decreased with increasing chloride concentration; a consequence of decreased uranium loading is an increase in the frequency of elution, with an associated increase in elution reagent costs; and for a given elution efficiency, the uranium concentration in the barrens is expected to increase with increasing chloride concentration.A few options were examined to counteract the impact of chloride: an increase in elution efficiency was targeted to reduce the amount of uranium returning to the loading circuit; increasing the pH improved uranium loading, but this was found to also increase iron extraction; and preliminary screening of alternative resins showed that the higher the theoretical ion exchange capacity of the strong base resin, the higher the uranium loading.Work is continuing on uranium recovery from saline leach liquors, specifically investigating the performance of alternative resins.

Jan 1, 2005

By Catherine Cai

A granular sorbent, prepared by gel-coating polyethyleneimine (PEI) on high surface area silica followed by crosslinking with a low-molecular weight diepoxide, has significantly higher uranium capacity, greater salt tolerance, and faster kinetics than the commercial resin Dowex 21K. Though having lower U(VI)/Fe(III) selectivity than Dowex 21K, the gel-coated PEI affords much higher sorptions of both U(VI) and Fe(III) and also their separation by selective stripping with acid.

Jan 1, 1999

By Jr. Koch

In the Hydrogeochemical and Stream Sediment Reconnaissance (HSSR) phase of its National Uranium Resource Evaluation (NURE) pro¬gram, the U.S. Department of Energy (DOE) samples about 1400 sites for stream sediments in each two-degree quadrangle of the National Topographic Nap Series (NTMS) and about 1200 sites for ground or stream water. Through a geological/statistical analysis, we find that NURE data are useful for assessing the uranium resources of the NTMS quadrangles. Our computer-implemented System for Uranium Resource Evaluation (SURE) calculates a score for each NTMS quadrangle based on the HSSR, geologic, and radiometric data; we score the four Colorado quadrangles--Pueblo, Montrose, Durango, and Trinidad--that comprise the study area. We interpret the scores in terms of geology and the known occurrences, which include the Hanson ore deposit with reserves of 30,000,000 lbs. U308 and the Pitch mine with reserves of 1,740,000 lbs. SURE depends in part on distinguishing mineralized or metalliferous granitoids from barren ones through "geochemical signatures."

Jan 1, 1980

By Robert Ditchburn

Within New Zealand?s extended EEZ there exists a vast submarine hydrothermal mineral resource associated with the Kermadec intra-oceanic arc. Along this arc more than thirty submarine volcanoes have been explored by GNS-lead researchers and, of these, c. 60% are known to be hydrothermally active and a site of active seafloor mineralisation. Assessment of whether this mineralisation is economically viable in terms of grade and tonnage is now underway. A key aspect of these investigations is determining the age of the mineralization which will have a direct bearing on its mode of formation, the time elapsed to amass an economic deposit and, ultimately, its capacity for sustainable extraction. Intact barite-rich ?black-smoker? chimneys similar to that depicted here (86 cm long) have been recovered from Brothers volcano in the southern part of the arc. These and other hydrothermal deposits provide evidence of active volcanic massive sulphide (VMS) mineralisation along the arc, the age of which can be determined from the disequilibrium between isotopes within the thorium or uranium decay chains. A chimney from Mariana arc has also been dated using these radiometric methods. The principle dating technique for chimneys up to 15,000 years old uses the decrease in 226Ra/Ba due to radioactive decay after the VMS was deposited. An initial ratio is obtained from chimneys that are proven to be less than 100 years old and this involves dating with 210Pb, 228Ra and 228Th that have short half-lives compared with 226Ra.

Jan 1, 2005

By Edward S. Bell, Frank Angebrandt

"Nuclear reactors must have very large heat outputs to compete with conventional sources and the only feasible applications are in the production of electric power or large quantities of process steam. This paper considers alternative fuels for electric power generation in Canada. In a publicly owned utility, nuclear stations are economic for base-load generation for unit sizes of 500 mega• watts or larger where competitive fossil fuel costs are higher than about 30 cents per million Btu. In British Columbia, Alberta and Saskatchewan, fossil fuels will continue to be in adequate supply at costs lower than 30 cents per million Btu and thus, except for the special case of Vancouver Island, power generation in Western Canada will continue to be the hydraulic and conventional thermal type. In Eastern Canada, fossil fuel prices are likely to be higher than 30 cents per million Btu and most utilities will be able to install units of 500 mw or larger, so that nuclear power plants will provide much of the base-load generation required. Base-load generation comprises about two-thirds of the energy generated by power utilities. By 1990, the total annual electrical energy load will be over 600 billion kwh, with two-thirds of this load in Eastern Canada. Allowing for additional hydraulic resources which may be developed in Quebec, British Columbia and Manitoba, hydraulic generation is forecast to provide a little more than a third of this electrical energy, nuclear generation a third and fossil-fuelled generation about a quarter."

Jan 1, 1969

By James McNally, Adam Stremcha, John MacGregor

With 13.7km of TBM tunneling in Atlanta’s hard gneiss well under way, drill and shoot work continues on several sites throughout the city. In order for the City of Atlanta to meet the consent decree imposed by the federal government, an aggressive construction schedule was a necessity. Construction consists of two deep, large diameter tunnels, four construction shafts, a pumping station, one overflow shaft, three large intake structures, and two connecting tunnels. Due to the multitude of blasting insensitive urban environments, a high standard of seismic and air-overpressure criteria, coupled with time restrictions, was adopted for the project. At any given time, drill and blast operations were under way at four of the seven sites requiring a certain amount of coordination between the TBM excavation, surface work, and the forces of Mother Nature. This paper addresses the challenges faced and the techniques used to safely and successfully complete the rock excavation of the West Area CSO Tunnel and Pumping Station project.

Jan 1, 2007

By Pawan L. Sethi

Design and construction of deep foundations and basements is increasingly becoming more complex, as the density and frequency of urban development increases. This growth brings various associated challenges in the form of design considerations and construction challenges. This paper discusses some of the challenges routinely encountered as well as some specific complications in this area, based on author’s experience gained through exposure as specialist contractor (designer), consultant and specialist consultant, along with some information on how these challenges were overcome. The paper highlights some of the key aspects of design coordination and importance of having an awareness of the overall perspective. Examples will be used to illustrate practical problems and the approaches used to respond.

Nov 1, 2022

By Patrick B. Kenny

Generally speaking, it is safe to address this conference as a conclave of Engineers, Owners' Agents, Governmental Representatives, and Contractors. As a group, we have assembled here to learn of our compatriots engaged in similiar underground operations throughout the United States and the World. We are here to learn of improved methods, higher technology, and better management. Through the acquisition of this knowledge, we each hope we can improve our own particular services, products and projects. This session is dedicated to a discussion of "Costs". The most apparent reason for a discussion of costs at this level is to expose subjects affecting costs and propose methods to reduce them. From that premise a contractor can identify three areas of discussion: design considerations, contract considerations, and governmental considerations. A fourth area of consideration is an introspective view of the contractor's role in the design construct process. Unnecessary costs and risks attributable to these areas are contributing excessively to ever increasing project and system costs. DESIGN CONSIDERATIONS On April 20, 1977 the Metropolitan Sanitary District of Greater Chicago accepted proposals for the Tunnel and Reservoir Plan on Contract A and Contract B. This letting called for construction of over 33 km (21 miles) of the Mainstream Tunnel bored at 9.75 m (32 ft) to 10.67 m (35 ft.) in diameter. Also included were all the appurtenant collecting and regulating structures. The proposal allowed the

Jan 1, 1979

By Karen C. Armfield, Gisele R. Passalacqua, Joanna Smith

New York City is an urban environment with a history spanning over 200 years. The coastline of New York has changed over the years. In the East River, old bulkhead and remnant of relieving platforms together with variable bedrock elevations pose challenges in the design and construction of deep foundations. This paper presents a Case History of high capacity deep foundations along the Franklin D. Roosevelt (FDR) Drive on the Upper East Side in New York City. The project consists of a ramp that overpasses the FDR Drive allowing heavy trucks to access the Marine Transfer Station (MTS) facility built over the East River. Large diameter drilled shafts and mini-piles socketed to bedrock were designed and constructed. Remnant of old bulkhead was encountered at the site and a Ground Penetrating Radar (GPR) investigation was completed during the subsurface investigation phase of the design. This paper discusses details of the subsurface investigation program and design methodology of the high capacity drilled shafts and mini-piles. It also describes construction methods and results of Osterberg Load tests documenting the field values of skin friction through the rock socket. Other construction challenges include construction and drilling rock sockets for drilled shafts over sloping bedrock. 1. INTRODUCTION New York City is a renowned urban city that always calls for the most delicate, yet complex, and robust superstructures and most importantly substructure designs. The historic preservation of this large 200 years old city of 319 square miles is ever changing. Shorelines are often extended to accommodate new infrastructure and very often many miscellaneous structures are discovered below the ground surface. The East 91st Street Ramp was constructed to provide access to the East 91st Street Marine Transfer Station over FDR Drive and York Avenue. Another alternative ramp will be relocated to the South Bound (SD) of the FDR Drive at 92nd Street. A subsurface exploration program was completed in accordance with the New York City Department of Design and Construction (NYCDDC) general requirements, Section 4.5, to perform subsurface investigation along the FDR Drive in Manhattan, New York.

Jan 1, 2019

By G. R. Guillet

THE LATE Dr. D. F. Hewitt, Ontario's foremost authority on industrial minerals, was the first to point out the importance of urban minerals when he produced figures (Hewitt 1968) to prove that the Toronto-Hamilton area was Ontario's second largest mining camp in 1966 (Fig . 1). In that year, the value of mineral production within a 60-mile radius of downtown Toronto exceeded individually that of Steep Rock, Kirkland Lake, Timmins, Manitouwadge and Elliott Lake. Only the nickel and precious-metal production of Sudbury .surpassed in value that of Toronto's pits and quarries. Although that position was unchanged for some years during the early sixties, it was admittedly an unusual situation: gold was still pegged at an artificially low value; uranium was stagnant; and Texasgulf had not entered the scene. However, the point had dramatically been made. The combined value of production from hundreds of sand and gravel pits and dozens of limestone and shale quarries was of formidable proportions. The mining industry of the urban fringe could not be denied. Construction aggregates, cement, building stone and bricks were fueling an apparently insatiable appetite for urban expansion and redevelopment.

Jan 1, 1978

By Robert R. Munro

Introduction Traditional aggregate sources - riverbeds and alluvial fans - located close to developing urban centers are being foreclosed to mining. As sand and gravel reserves are depleted, nearby production plants cannot secure additional, adjacent reserves and are being forced to close down. The sand and gravel industry, in many respects, is its own worst enemy. It promotes development, street paving, home building, and industrial and commercial centers. Economics make us favor developments close to our operations. Thus, we encourage development by our neighbors, who soon become our detractors. Current Aggregate Mining Problems Urban development is not compatible with sand and gravel mining. Neighbors dislike the view of pits and quarries, and they complain about dust, noise, and trucking. In general, the neighbors are not happy being close to an aggregate source. This is reflected in land use or zoning laws. In most localities, mining requires a special-use permit. Public hearings are required before a legislative body. If a large group of opponents show up, legislators will often deny the land use. Urban areas are seeing traditional close-in sand and gravel sites becoming no longer available for industry. A parallel situation is also developing in most urban areas. That is, the not-in-my-backyard attitude toward landfills. As urban areas mature; a significant amount of change takes place in the physical makeup of a city. Streets and parking lots deteriorate and need repaving. Curbs and gutters need to be relocated. This necessitates a place to dispose of excess, or old, paving and structural material. Since landfills have become at least as difficult to permit as sand and gravel sites, they are becoming remote from urban areas. A significant portion of the structural material that needs to be disposed of is concrete and asphalt. This material is heavier than other materials. Thus, the cost of moving a large volume of very heavy material to a landfill becomes very expensive. In California, dump truck transportation is regulated by the State Public Utilities Commission through minimum rate tariffs. A rule of thumb for estimating the cost of such transportation is once the material is loaded, the extra kilometer (mile) costs $0.09/t ($0.08 per st). Thus, to haul an 18-t (20-st) road an extra 32 km (20 miles) will cost about $32. Because of its remote location, the cost of hauling aggregates to the point of use in an urban area becomes excessive - about the same as hauling the material to a landfill. Here is a classic example for synergism. If we could save the transportation cost of heavy demolition material by disposing it relatively close to the central city (its source), and at the same time provide an aggregate source close to the central city (its point of use), two difficult economic situations can be solved. Thus, the develop¬ment of recycling concrete and asphalt. Mining Concrete and Asphalt There are two methods of mining concrete and asphalt. The first is to pick up the old pavement in pieces. Thin, cracked pavement can usually be lifted from the grade with a front-end loader. It will break up into manageable-sized pieces. With heavier pavement, it is sometimes necessary to intentionally break it up with a stomper or heavy ripper. The pieces are loaded into heavy dump trucks and shipped to the crushing site. Again, a front-end

Jan 7, 1984